What Is A Metal?
What Is A Metal?
What is a metal?
Contents
Introduction
Learning outcomes
1 What is a metal?
3 A metal’s signature
3.1 Practical 1 Flame tests
4 Uses of metals
4.1 Metals and life
Conclusion
Acknowledgements
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What is a metal?
Introduction
You will have little hesitation in distinguishing the metal blade of a kitchen knife from
the handle which is probably made of plastic or wood. But what really distinguishes a
metal from a non-metal? Metals are used in many different ways, such as in
jewellery, pots and pans and in wires for conducting electricity and you can probably
think of many other examples of metal use. Each metal has its own personal
signature and metals can be identified experimentally by being burnt in a naked
flame. In this course you will start exploring some of the characteristic properties of
metals that allow their varied uses in our everyday lives. You will also undertake an
online experiment to identify metals using a ‘flame test’.
This OpenLearn course is an adapted extract from the Open University course S111
Questions in science.
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What is a metal?
Learning outcomes
After studying this course, you should be able to:
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What is a metal?
1 What is a metal?
To begin, have a look at the following questions.
Write down the names of as many metals as you can think of.
Some you may have thought of are iron, silver, gold, tin, lead, zinc,
copper, aluminium, sodium and potassium. Slightly more exotic
metals are chromium, nickel, cobalt, cadmium, titanium and
manganese.
There are a couple of chemistry terms used in this course that you may not be
familiar with, so we have defined them to help your study of this course. An element
is a substance made up of only one type of basic building block and each element is
made up of building blocks, called atoms. You might already know that an atom itself
comprises many other smaller particles (e.g. electrons, protons, neutrons).
Scientists have tended to formalise the characteristics of metals (as distinct from
non-metals) by suggesting that metals are dense, lustrous (shiny), good conductors
of heat and electricity and can be shaped by physical forces.
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What is a metal?
they can be deformed under compressive stress, e.g. by hammering
into thin sheets – a property known as malleability.
The gold is malleable (it has been hammered into thin sheets) and
the copper is ductile (it can be stretched into thin wire).
At room temperature metals are solids, with the exception of mercury which is a
liquid. There are also chemical criteria that help distinguish metals from non-metals
as you will see later.
Table 1 includes some qualitative and quantitative data for a range of metals. It also
includes the non-metallic element sulfur for comparison.
Table 1 Typical data for some common metallic elements and the non-metal, sulfur,
at 25 °C.
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Chromium 0.012 1857 7.19 7 9
Copper 0.0068 1083 8.96 2 2
Gold 0.000 0004 1064 19.3 3 3
Iron 5.6 1535 7.87 8 7
Magnesium 2.3 649 1.74 5 5
Silver 0.000 008 962 10.5 1 1
Sulfur 0.034 113 1.96 10 10
Tin 0.000 21 232 7.31 9 8
Zinc 0.0076 420 7.13 6 6
We often use percentages to express proportions. However, as you can see above,
this is less effective when there is only a very small percentage of something. For
example, the proportion of sulfur in the Earth’s crust is 0.034%, or 3.4 × 10–2%.
And as 1000 000 is a million, we can see that 0.034 parts per hundred can also be
written as 340 parts per million, or 340 ppm.
Of course, it is sensible to use the most appropriate tool for the job. So, a discussion
of the proportions of aluminium and iron would favour the use of percentages.
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What is a metal?
However, when discussing the proportions of the minor constituents in the Earth’s
crust (such as sulfur), it is more appropriate to use parts per million. Indeed, if the
proportion is very small, even parts per billion (ppb) might be more appropriate; one
billion being 109. For example, the concentration of gold in the Earth’s crust is at a
level of 0.000 000 4%, i.e. 4 ppb.
Silver, copper and gold are the best conductors of electricity. Silver
and gold are both high-cost metals. Copper is a cheaper metal so it
is often used as an electrical conductor. Generally, the higher the
abundance of the metal in the Earth’s crust, the lower the cost.
However, this is not an exact relationship, and the cost of a metal
also depends on other factors (such as the ease and cost of
extraction).
The non-metal, sulfur, is the poorest heat (thermal) and electrical conductor of the
elements in Table 1. In fact sulfur is not regarded as a conductor at all. It is an
effective insulator, being as good as the plastic insulation that surrounds electric
cables.
Aluminium has low density and this makes it ideal for the construction
of aeroplanes where weight is important. Density is dependent on
mass, as is weight; so the lower the density, the lower the mass (per
unit volume), and the lower the weight.
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What is a metal?
Most metal atoms pack closely together in a similar way to fruit on packing trays
(Figure 2). This arrangement is the most efficient use of space as apples are packed
as closely together as they can. Note how most of the apples are in contact with six
neighbouring apples.
But metals are three-dimensional. The layer of atoms represented by the apples in
Figure 2 will be covered by other layers in a solid metal. For most metals, this three-
dimensional structure can be seen in the way fruit is sometimes stacked on market
stalls. A second layer of apples will fit neatly in the hollows created by the bottom
layer. The third layer of apples will lie directly above the first layer. This pattern is
known as a hexagonal closed packed (hcp) structure. Watch Video 1 which illustrates
this structure using spheres to build a model.
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What is a metal?
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However, atoms are neutral particles: that is, they carry no net charge. This means
that the total negative charge of the electrons must be balanced by the total positive
charge in these positive particles in the atom, so that the whole atom has a net
charge of zero. These positive particles are known as protons and each one carries
the same amount of charge as an electron but has the opposite sign, +1.
Each element has its own specific signature in terms of number of protons, neutrons
and electrons. Lithium has 3 protons, 4 neutrons and three electrons.
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What is a metal?
What overall charge would an atom of lithium have?
One atom of lithium would have an overall charge of zero as the three
positive protons will equal the negative charge of the three electrons.
A feature of metal atoms is that the electrons in the outer shells do not remain in the
proximity of a specific nucleus. In bulk metals, these electrons, rather than being
associated with any particular metal atom, can be thought to be part of a shared ‘sea’
of electrons that move freely (Figure 4). These are known as delocalised electrons.
Figure 4 Positively charged nuclei (plural for nucleus) in a cloud of delocalised electrons.
View description - Figure 4 Positively charged nuclei (plural for nucleus) in a cloud
of delocalised ...
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What is a metal?
Metals are good conductors of electricity and heat, because the free moving
electrons facilitate the transfer of charge or heat through the material.
Figure 5 shows a simple electric circuit with a metal wire, a battery and a bulb. When
the wire is connected between the positive and negative terminals of the battery, one
end of the wire becomes positively charged and the other becomes negatively
charged. This causes the electrons, which are free to move, to travel through the wire
towards the positive terminal of the battery, where they are removed. At the same
time the negative terminal supplies more electrons to the wire.
Within the battery there is a net flow of negative charge from the positive terminal to
the negative terminal, which balances the flow through the wire, so that charges don’t
continually build up at the battery terminals.
You may be familiar with the term ‘voltage’. The voltage of the battery can be
considered as the ‘push’ exerted on electrons moving along the circuit and the flow of
negatively charged electrons in the wire constitutes the electric current. Note that in
Figure 5 the arrows refer to the flow of electrons. By convention, the direction of the
electric current is in the opposite direction, from the positive terminal towards the
negative terminal of the battery.
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What is a metal?
Figure 5 Conductivity of electricity in a metal: (a) open circuit (switch open) (b) closed circuit
(switch closed). Arrows indicate flow of electrons.
The bulb will light only when the circuit is closed and there are
electrons flowing through it.
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What is a metal?
The delocalised electrons also explain other metallic characteristics such as
malleability. The bonding occurs in every direction throughout the metal enabling
atoms to roll easily over each other without breaking any bonds when stress is
applied (Figure 6).
Figure 6 Layers of atoms sliding over each other and creating thin layers of metal.
View description - Figure 6 Layers of atoms sliding over each other and creating thin
layers of me ...
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What is a metal?
3 A metal’s signature
In this section you are going to investigate how metals can be identified by the colour
they impart to a flame. Electrons are found in shells around the nucleus. These shells
are numbered 1, 2, 3 (and so on), moving outward from the nucleus (Figure 7). The
number of the shell is known as the principal quantum number, and is given by the
symbol n.
Figure 7 (a) An electron jump from shell n = 2 to n = 3 is shown by the red arrow. (b) The
electron jumps to a higher electron shell further away from the nucleus. Note that energy
levels are not evenly spaced and they become closer together as they move away from the
nucleus.
The colour of the flame arises when these excited electrons return to lower energy
levels emitting energy as light of a characteristic frequency. This gives a
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What is a metal?
characteristic colour to the flame when a metal is heated in it (Figure 8). If you have
ever let a pan containing salt in water boil over on a gas stove you may have noticed
that the flame goes yellow; this is caused by the electrons in the sodium atom.
Visible light can be split by a prism into an uninterrupted band of colours, known as a
continuous spectrum. However, the spectrum produced by the excited electrons of a
particular element falling to lower energy levels consists of discrete coloured lines in
a dark background. In Figure 9 you can see the emission spectrum of sodium when a
beam of light from a sodium lamp is dispersed by a prism; the two intense yellow
lines emitted by sodium atoms, are the main reason for the flame colour shown
above.
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What is a metal?
Each element produces a unique set of spectral lines, and in the next section you will
use the emission spectra of elements to identify some metals.
You will perform the experiment in the virtual OpenScience Laboratory (the OU
online laboratory for practical science).
1. Turn on the gas, pick up the lighter and light the Bunsen burner,
which should give a low yellow flame. Rotate the barrel of the burner
so the air hole is open and the flame is blue.
2. One end of the nichrome wire is embedded in a cork for safe
handling, and the other end has a small loop. Clean the loop of wire
by dipping it into the small beaker containing a solution of
hydrochloric acid.
3. Place the loop into the side of the blue flame, as shown in Figure
10. If the wire is clean it should make no difference to the colour of
the flame. If the colour of the flame does change there is an impurity
on the wire. Dip it again in the acid and return it to the side of the
flame.
4. Dip the loop of the wire into the acid and then use it to pick up a
few grains of a metal salt.
5. Place the loop in the side of the flame and note down the colour
of the flame in your copy of Table 2.
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6. Use the hand spectroscope provided to separate the constituent
colours present in the light and look at the emission line spectrum of
the flames. Note down the description of spectra in your copy of
Table 2. The hand spectroscope is a simple piece of equipment that
houses a prism system in order to provide spectra from visible light
(Figure 11).
7. Repeat this procedure and observe the flame colour given by the
other metal salts. Record your observations in Table 2.
Figure 10 Components of Bunsen burner and the position of nichrome wire for a flame test.
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What is a metal?
Table 2 Flame colours and spectra of common metal ions.
Follow the link to access the experiment. Instructions are also provided within the
experiment, under ‘Help’.
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What is a metal?
If you don’t know the contents of a mixture, are you able to identify
the metals present using the flame colour?
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What is a metal?
What spectrum would you expect to see if a mixture of lithium and
copper salts is placed in the flame?
The spectrum of a mixture of lithium and copper will show red and
orange lines from lithium and green and blue lines from copper.
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What is a metal?
4 Uses of metals
Metals are extremely useful in our everyday lives and are used in a wide range of
situations.
Different metals are used for different purposes (Figure 12). For example, in
construction, the alloy steel is the usual choice for structural building materials due to
its strength and flexibility while copper is used for a range of architectural parts such
as roofs and gutters, due to its durability and appearance.
As discussed, metals are good conductors and play an important role in electronics.
For example, copper is commonly used in electrical wiring; gold is used in many
computer technologies and silver is often used in electronic circuitry.
Aluminium has become one of the most commonly used metals in aircraft
manufacturing, shipbuilding and the train and automobile industry. Aluminium is a
resistant and light material that reduces the weight of transport vehicles, minimising
their fuel consumption.
In the case of the food and drink industry, stainless steel is the ideal alloy due to its
inertness and resistance to any acids present in foods. It is also tolerant to a wide
range of temperatures allowing heating and freezing, and stainless steel equipment
can be repeatedly sterilised.
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Metals have also been extensively used as medical implants. Stainless steel and
titanium alloys are commonly used in biomedical devices, such as joint replacement
parts, while gold, silver and platinum are often used in dentistry. Anti-cancer drugs
with different metals are also commonly used in chemotherapy.
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What is a metal?
We acquire these elements from the food and water that we
consume.
Metals normally occur at very low concentration in our bodies and are known as trace
elements. At high levels metals may be toxic. In particular, metals such as mercury
and lead can interfere with the structure of proteins and their effective function.
Metals may enter fresh and salty water through industrial waste, sewage and run-off.
Microbes, plants and animals that depend on this contaminated water consume or
absorb these metals. Over time the metals are concentrated within the food chain, in
a process known as bioaccumulation (Figure 14). The concentration of metals in
affected organisms is greater than was initially present in the water itself, as species
consume greater quantities at each level and so the concentration increases up the
food chain.
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What is a metal?
Conclusion
The materials that have probably been the most influential in shaping society over
the past two to three millennia are the metals. You will all have a general idea as to
what is metallic and what is not and in this part you have seen some of the criteria for
the distinction.
The key concepts and principles you have learned in this part are:
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Emission spectra are the basis of simple flame tests
for metal salts.
the role of metals in everyday life.
Metals are used in a wide range of applications
(construction, electronic devices, transportation, food
processing, biomedical applications) and play an
important role in biological systems.
Bioaccumulation is the accumulation of substances
inside an organism over time.
The content of these courses comes from the Open University course S111
Questions in science. Take a look at the other OpenLearn courses that are part of this
set here.
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Description
Two simple, rectangular electric circuit diagrams show the conductivity of electricity in
a metal. Figure 5a shows an open circuit. Straight lines are used to represent a
connecting metal wire. The circuit has a gap at the top to indicate a break in the
circuit, with a switch labelled ‘open’. To the right of this open switch, there is a
rectangular block that represents a battery with its positive (+) terminal next to the
switch and its negative (–) terminal on the far right. On the right side of the circuit,
there is a circle with a squiggly line in it that represents a light bulb and its filament.
Figure 5b shows a closed circuit. The same circuit as in (a) has the switch closed at
the top so that the wire has contact with and is connected to the positive (+) terminal
of the battery. There are circles, indicating freely moving electrons, around the circuit.
There is a lit bulb on the right. Arrows indicate the clockwise flow of the negatively
charged electrons in the wire from the negative terminal to the positive terminal of the
battery. What is happening within the wire is shown with a magnified diagram. This is
a repeat of Figure 1.4. Each nucleus is represented by a circle with a plus symbol
(‘+’) in it. The nuclei are arranged in staggered rows. That is, each row of circles in
alternate rows are offset by half a circle, to the left or the right, so that they fit in
between the circles in the adjacent rows. The electrons in the outer shells are
represented by blue circles that are positioned randomly, indicating they are moving
freely because they are delocalised.
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Description
This figure represents an electron jump from shell n = 2 to n = 3. The figure is in two
parts. Figure 7(a) is a schematic diagram representing an atom. It shows a nucleus
(a circle) at the centre, with three concentric rings that represent its shells labelled
(from inside to out) n = 1, n = 2 and n = 3. An electron is shown in the n = 2 shell.
The diagram illustrates (using an arrow) than this electron jumps from n = 2 to n = 3.
In (b) there are three horizontal lines labelled (from bottom to top) n = 1, n = 2 and n
= 3. An arrow to the side of the lines indicates that there is increasing energy from n
= 1 to n = 3. The gap between n = 1 and n = 2 is around two and a half times bigger
than that between n = 2 and n = 3, indicating more energy is needed to move
between n = 1 to n = 2 than from n = 2 to n = 3. The electron jump from part (a) is
shown as an arrow between the lines, pointing from n = 2 to n = 3.
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Description
Six photographs to show the common use of metals in our daily lives.
For (a) steel, there is a suspension bridge; (b) aluminium, the back of an aeroplane;
(c) copper, three cables with visible copper wiring; (d) gold, a circuit board; (e)
stainless steel, a can; and (f) titanium, a replacement knee joint.
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