0% found this document useful (0 votes)
86 views46 pages

What Is A Metal?

Uploaded by

Akweri Oyungu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
86 views46 pages

What Is A Metal?

Uploaded by

Akweri Oyungu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
You are on page 1/ 46

What is a metal?

What is a metal?

Contents
 Introduction

 Learning outcomes

 1 What is a metal?

 2 Arrangement of atoms in metals


 2.1 Metallic bonding

 3 A metal’s signature
 3.1  Practical 1 Flame tests

 4 Uses of metals
 4.1 Metals and life

 Conclusion

 Acknowledgements

Page 2 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Introduction
You will have little hesitation in distinguishing the metal blade of a kitchen knife from
the handle which is probably made of plastic or wood. But what really distinguishes a
metal from a non-metal? Metals are used in many different ways, such as in
jewellery, pots and pans and in wires for conducting electricity and you can probably
think of many other examples of metal use. Each metal has its own personal
signature and metals can be identified experimentally by being burnt in a naked
flame. In this course you will start exploring some of the characteristic properties of
metals that allow their varied uses in our everyday lives. You will also undertake an
online experiment to identify metals using a ‘flame test’.

This OpenLearn course is an adapted extract from the Open University course S111
Questions in science.

Page 3 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Learning outcomes
After studying this course, you should be able to:

 understand metallic bonding and how it is related to metallic


characteristics
 understand the role of metals in everyday life.

Page 4 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

1 What is a metal?
To begin, have a look at the following questions.

 Write down the names of as many metals as you can think of.

 Some you may have thought of are iron, silver, gold, tin, lead, zinc,
copper, aluminium, sodium and potassium. Slightly more exotic
metals are chromium, nickel, cobalt, cadmium, titanium and
manganese.

There are a couple of chemistry terms used in this course that you may not be
familiar with, so we have defined them to help your study of this course. An element
is a substance made up of only one type of basic building block and each element is
made up of building blocks, called atoms. You might already know that an atom itself
comprises many other smaller particles (e.g. electrons, protons, neutrons). 

 What elements can you think of that might be non-metallic?

 Some non-metallic elements that you might have thought of are


hydrogen, nitrogen, carbon and oxygen. Chlorine, bromine, sulfur
and phosphorus are also non-metals. Living organisms are made of
mainly non-metallic elements.

Scientists have tended to formalise the characteristics of metals (as distinct from
non-metals) by suggesting that metals are dense, lustrous (shiny), good conductors
of heat and electricity and can be shaped by physical forces.

Metals can be shaped by physical forces in two main ways:

 they can be deformed under tensile stress, e.g. by stretching – a


property known as ductility

Page 5 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
 they can be deformed under compressive stress, e.g. by hammering
into thin sheets – a property known as malleability.

 What properties are shown by the elements in Figure 1?

Figure 1   (a) Gold and (b) copper.

View description - Figure 1   (a) Gold and (b) copper.

 The gold is malleable (it has been hammered into thin sheets) and
the copper is ductile (it can be stretched into thin wire).

At room temperature metals are solids, with the exception of mercury which is a
liquid. There are also chemical criteria that help distinguish metals from non-metals
as you will see later.

Table 1 includes some qualitative and quantitative data for a range of metals. It also
includes the non-metallic element sulfur for comparison.

Table 1  Typical data for some common metallic elements and the non-metal, sulfur,
at 25 °C.

Element Proportion in Melting Density/      Heat Electric


Earth’s continental temperature conduction (1, conduction (1,
crust by mass/% 103 kg m– best; 10, worst) best; 10, worst)
/°C 3

Aluminium 8.2 660 2.70 4 4

Page 6 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
Chromium 0.012 1857 7.19 7 9
Copper 0.0068 1083 8.96 2 2
Gold 0.000 0004 1064 19.3 3 3
Iron 5.6 1535 7.87 8 7
Magnesium 2.3 649 1.74 5 5
Silver 0.000 008 962 10.5 1 1
Sulfur 0.034 113 1.96 10 10
Tin 0.000 21 232 7.31 9 8
Zinc 0.0076 420 7.13 6 6

We often use percentages to express proportions. However, as you can see above,
this is less effective when there is only a very small percentage of something. For
example, the proportion of sulfur in the Earth’s crust is 0.034%, or 3.4 × 10–2%.

For such small proportions, it is better to use parts per million.

For example, the 3.4 × 10–2% of sulfur represents 3.4 × 10–2, or 0.034, parts per


hundred. As a fraction of the total, this is . As with any fraction, the top and bottom
terms can be multiplied by 10, and the overall value of the fraction does not change,
i.e.

And as 1000 000 is a million, we can see that 0.034 parts per hundred can also be
written as 340 parts per million, or 340 ppm.

 Table 1 shows that the percentage of chromium in the Earth’s crust is


0.012%. Express this as a fraction, and as a proportion in ppm.

 To convert 0.012% into a fraction, divide by 100, i.e.

or 0.012 parts per hundred.

To convert this fraction into ppm, multiply it by a million:

Of course, it is sensible to use the most appropriate tool for the job. So, a discussion
of the proportions of aluminium and iron would favour the use of percentages.

Page 7 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
However, when discussing the proportions of the minor constituents in the Earth’s
crust (such as sulfur), it is more appropriate to use parts per million. Indeed, if the
proportion is very small, even parts per billion (ppb) might be more appropriate; one
billion being 109. For example, the concentration of gold in the Earth’s crust is at a
level of 0.000 000 4%, i.e. 4 ppb.

 In Table 1, which three metals are the best conductors of electricity?


Why do you think just one of these three metals is used much more
than the other two?

 Silver, copper and gold are the best conductors of electricity. Silver
and gold are both high-cost metals. Copper is a cheaper metal so it
is often used as an electrical conductor. Generally, the higher the
abundance of the metal in the Earth’s crust, the lower the cost.
However, this is not an exact relationship, and the cost of a metal
also depends on other factors (such as the ease and cost of
extraction).

The non-metal, sulfur, is the poorest heat (thermal) and electrical conductor of the
elements in Table 1. In fact sulfur is not regarded as a conductor at all. It is an
effective insulator, being as good as the plastic insulation that surrounds electric
cables.

 Looking at the data in Table 1, why do you think aluminium is used


extensively in the construction of civil aeroplanes?

 Aluminium has low density and this makes it ideal for the construction
of aeroplanes where weight is important. Density is dependent on
mass, as is weight; so the lower the density, the lower the mass (per
unit volume), and the lower the weight.

2 Arrangement of atoms in metals

Page 8 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
Most metal atoms pack closely together in a similar way to fruit on packing trays
(Figure 2). This arrangement is the most efficient use of space as apples are packed
as closely together as they can. Note how most of the apples are in contact with six
neighbouring apples.

Figure 2  Apples on a packing tray.

View description - Figure 2  Apples on a packing tray.

But metals are three-dimensional. The layer of atoms represented by the apples in
Figure 2 will be covered by other layers in a solid metal. For most metals, this three-
dimensional structure can be seen in the way fruit is sometimes stacked on market
stalls. A second layer of apples will fit neatly in the hollows created by the bottom
layer. The third layer of apples will lie directly above the first layer. This pattern is
known as a hexagonal closed packed (hcp) structure. Watch Video 1 which illustrates
this structure using spheres to build a model.

Video 1  Close packing in three dimensions. (2:46 min)

View transcript - Video 1  Close packing in three dimensions. (2:46 min)

Page 9 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

The ongoing arrangement of metal atoms in a three-dimensional regular ordered


pattern is known in chemistry as a lattice structure.

A simple model of an atom is a central atomic nucleus with electrons arranged in


shells at different distances from the nucleus. Lithium has the smallest atom of all
metals. Figure 3 shows a simple representation of a lithium atom. The smaller dots
represent electrons moving around the central nucleus. The large dot at the centre
represents the nucleus of the lithium atom containing protons and neutrons. Moving
outwards from the nucleus, you can see a region of empty space before a narrow
region where there is a good chance of meeting a set of two electrons. This first shell
can only contain a maximum of two electrons. Then there is more empty space
before another narrow region in which up to six electrons can be found.

Page 10 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 3 Illustration of shells in a lithium atom

View description - Figure 3 Illustration of shells in a lithium atom

Each electron carries a minute but standard amount of negative electric charge, or


charge for short. Electric charge is the property of matter that causes electrical
phenomena. Conventionally, chemists and physicists speak of an electron as having
a charge of −1. The units do not matter in this case as the ‘−1’ is a comparative
amount: one electron has a charge of −1, two electrons a charge of −2 and ten
electrons a charge of −10.

However, atoms are neutral particles: that is, they carry no net charge. This means
that the total negative charge of the electrons must be balanced by the total positive
charge in these positive particles in the atom, so that the whole atom has a net
charge of zero. These positive particles are known as protons and each one carries
the same amount of charge as an electron but has the opposite sign, +1.

Each element has its own specific signature in terms of number of protons, neutrons
and electrons. Lithium has 3 protons, 4 neutrons and three electrons.

Page 11 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
 What overall charge would an atom of lithium have?

 One atom of lithium would have an overall charge of zero as the three
positive protons will equal the negative charge of the three electrons.

 If a nucleus of an atom was separated from the rings of electrons


would it have a positive or a negative charge?

 The nucleus would be positively charged because of the protons


within it. The strength of the positive charge would depend upon the
number of protons within the nucleus.

A feature of metal atoms is that the electrons in the outer shells do not remain in the
proximity of a specific nucleus. In bulk metals, these electrons, rather than being
associated with any particular metal atom, can be thought to be part of a shared ‘sea’
of electrons that move freely (Figure 4). These are known as delocalised electrons.

Figure 4  Positively charged nuclei (plural for nucleus) in a cloud of delocalised electrons.

View description - Figure 4  Positively charged nuclei (plural for nucleus) in a cloud
of delocalised ...

2.1 Metallic bonding


The attraction between the delocalised electrons and the positively charged nuclei is
called metallic bonding. The metallic bonding is strong and occurs in all directions.
Breaking this attraction is difficult, and this is the reason that metals have high
melting temperatures.

Page 12 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
Metals are good conductors of electricity and heat, because the free moving
electrons facilitate the transfer of charge or heat through the material.

Figure 5 shows a simple electric circuit with a metal wire, a battery and a bulb. When
the wire is connected between the positive and negative terminals of the battery, one
end of the wire becomes positively charged and the other becomes negatively
charged. This causes the electrons, which are free to move, to travel through the wire
towards the positive terminal of the battery, where they are removed. At the same
time the negative terminal supplies more electrons to the wire.

Within the battery there is a net flow of negative charge from the positive terminal to
the negative terminal, which balances the flow through the wire, so that charges don’t
continually build up at the battery terminals.

You may be familiar with the term ‘voltage’. The voltage of the battery can be
considered as the ‘push’ exerted on electrons moving along the circuit and the flow of
negatively charged electrons in the wire constitutes the electric current. Note that in
Figure 5 the arrows refer to the flow of electrons. By convention, the direction of the
electric current is in the opposite direction, from the positive terminal towards the
negative terminal of the battery.

Page 13 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 5  Conductivity of electricity in a metal: (a) open circuit (switch open) (b) closed circuit
(switch closed). Arrows indicate flow of electrons.

View description - Figure 5  Conductivity of electricity in a metal: (a) open circuit


(switch open) ...

 When will the bulb light?

 The bulb will light only when the circuit is closed and there are
electrons flowing through it.

The battery voltage depends on the choice of chemicals inside it.

Page 14 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
The delocalised electrons also explain other metallic characteristics such as
malleability. The bonding occurs in every direction throughout the metal enabling
atoms to roll easily over each other without breaking any bonds when stress is
applied (Figure 6).

Figure 6 Layers of atoms sliding over each other and creating thin layers of metal.

View description - Figure 6 Layers of atoms sliding over each other and creating thin
layers of me ...

Page 15 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

3 A metal’s signature
In this section you are going to investigate how metals can be identified by the colour
they impart to a flame. Electrons are found in shells around the nucleus. These shells
are numbered 1, 2, 3 (and so on), moving outward from the nucleus (Figure 7). The
number of the shell is known as the principal quantum number, and is given by the
symbol n.

An electron’s energy depends on the shell it is in; in general as n increases, the


energy of the electron also increases. The energy level occupied by electrons
depend on the amount of energy in the system. At high temperatures (such as under
a flame), electrons in the metal atoms will absorb heat energy and be promoted to
higher energy levels.

Figure 7  (a) An electron jump from shell n = 2 to n = 3 is shown by the red arrow. (b) The
electron jumps to a higher electron shell further away from the nucleus. Note that energy
levels are not evenly spaced and they become closer together as they move away from the
nucleus.

View description - Figure 7  (a) An electron jump from shell n = 2 to n = 3 is shown


by the red arrow. ...

The colour of the flame arises when these excited electrons return to lower energy
levels emitting energy as light of a characteristic frequency. This gives a

Page 16 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
characteristic colour to the flame when a metal is heated in it (Figure 8). If you have
ever let a pan containing salt in water boil over on a gas stove you may have noticed
that the flame goes yellow; this is caused by the electrons in the sodium atom.

Figure 8  Flame test for sodium.

View description - Figure 8  Flame test for sodium.

Visible light can be split by a prism into an uninterrupted band of colours, known as a
continuous spectrum. However, the spectrum produced by the excited electrons of a
particular element falling to lower energy levels consists of discrete coloured lines in
a dark background. In Figure 9 you can see the emission spectrum of sodium when a
beam of light from a sodium lamp is dispersed by a prism; the two intense yellow
lines emitted by sodium atoms, are the main reason for the flame colour shown
above.

Figure 9  Emission spectrum of sodium in the visible region.

View description - Figure 9  Emission spectrum of sodium in the visible region.

Page 17 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
Each element produces a unique set of spectral lines, and in the next section you will
use the emission spectra of elements to identify some metals.

3.1  Practical 1 Flame tests


In this section you will investigate the presence of metal ions by recording the colour
observed when heating a metal salt in a flame. You will be using solid samples of
different metal salts. The metal chlorides you will be analysing are those of copper,
lithium, potassium and strontium.

This practical activity will take 45 minutes.

You will perform the experiment in the virtual OpenScience Laboratory (the OU
online laboratory for practical science).

What you need to do:

 1.   Turn on the gas, pick up the lighter and light the Bunsen burner,
which should give a low yellow flame. Rotate the barrel of the burner
so the air hole is open and the flame is blue.
 2.   One end of the nichrome wire is embedded in a cork for safe
handling, and the other end has a small loop. Clean the loop of wire
by dipping it into the small beaker containing a solution of
hydrochloric acid.
 3.   Place the loop into the side of the blue flame, as shown in Figure
10. If the wire is clean it should make no difference to the colour of
the flame. If the colour of the flame does change there is an impurity
on the wire. Dip it again in the acid and return it to the side of the
flame.
 4.   Dip the loop of the wire into the acid and then use it to pick up a
few grains of a metal salt.
 5.   Place the loop in the side of the flame and note down the colour
of the flame in your copy of Table 2.

Page 18 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
 6.   Use the hand spectroscope provided to separate the constituent
colours present in the light and look at the emission line spectrum of
the flames. Note down the description of spectra in your copy of
Table 2. The hand spectroscope is a simple piece of equipment that
houses a prism system in order to provide spectra from visible light
(Figure 11).
 7.   Repeat this procedure and observe the flame colour given by the
other metal salts. Record your observations in Table 2.

Figure 10  Components of Bunsen burner and the position of nichrome wire for a flame test.

View description - Figure 10  Components of Bunsen burner and the position of


nichrome wire for a flame ...

Figure 11  Main components of the hand spectroscope.

View description - Figure 11  Main components of the hand spectroscope.

Page 19 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
Table 2  Flame colours and spectra of common metal ions.

Metal Chemical Flame Description of spectrum


symbol colour
Lithium
Copper
Strontium
Potassium
Sodium Na Yellow Two bright yellow lines, one weaker blue line, one
weaker green line and one weaker red line
 8.   Now try looking at the colour of the flame obtained with the
unknown mixtures of metals. Write down what you observed.

Follow the link to access the experiment. Instructions are also provided within the
experiment, under ‘Help’.

Page 20 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Practical 1 Flame tests in the OpenScience Laboratory

 If you don’t know the contents of a mixture, are you able to identify
the metals present using the flame colour?

 It is not easy to identify the contents of a mixture based on the flame


colour. Often one flame colour will dominate or a different colour is
observed that could be the combination of two colours.

Page 21 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
 What spectrum would you expect to see if a mixture of lithium and
copper salts is placed in the flame?

 The spectrum of a mixture of lithium and copper will show red and
orange lines from lithium and green and blue lines from copper.

 Metals are added to the gunpowder used in fireworks to produce light


of different colours when the powder burns. Which metal would you
add to gunpowder in order to produce red light?

 Strontium will produce red light.

Page 22 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

4 Uses of metals
Metals are extremely useful in our everyday lives and are used in a wide range of
situations.

 Write down as many uses of metals as you can think of.

 You might have thought of uses in, for example:


 construction
 electronic devices
 transportation
 food processing
 biomedical applications.

Different metals are used for different purposes (Figure 12). For example, in
construction, the alloy steel is the usual choice for structural building materials due to
its strength and flexibility while copper is used for a range of architectural parts such
as roofs and gutters, due to its durability and appearance.

As discussed, metals are good conductors and play an important role in electronics.
For example, copper is commonly used in electrical wiring; gold is used in many
computer technologies and silver is often used in electronic circuitry.

Aluminium has become one of the most commonly used metals in aircraft
manufacturing, shipbuilding and the train and automobile industry. Aluminium is a
resistant and light material that reduces the weight of transport vehicles, minimising
their fuel consumption.

In the case of the food and drink industry, stainless steel is the ideal alloy due to its
inertness and resistance to any acids present in foods. It is also tolerant to a wide
range of temperatures allowing heating and freezing, and stainless steel equipment
can be repeatedly sterilised.

Page 23 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
Metals have also been extensively used as medical implants. Stainless steel and
titanium alloys are commonly used in biomedical devices, such as joint replacement
parts, while gold, silver and platinum are often used in dentistry. Anti-cancer drugs
with different metals are also commonly used in chemotherapy.

Interactive content is not available in this format.

Figure 12 Common uses of metals in our daily lives.

View description - Figure 12 Common uses of metals in our daily lives.

4.1 Metals and life


Metals also play an important role in biological systems. Iron is essential for
transporting oxygen in the blood and tissues. Some metals are part of biological
structures: for example, calcium provides strength to our bones (Figure 13).
Maintaining different concentrations of sodium and potassium inside and outside
living cells is critical for body functions such as muscle contraction and heart function.
The presence of metals (such as zinc) is also required for many essential enzymatic
reactions (for example, the digestion of proteins).

Figure 13  Calcium and bones.

View description - Figure 13  Calcium and bones.

 How do we maintain adequate levels of metals in our bodies?

Page 24 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
 We acquire these elements from the food and water that we
consume.

Metals normally occur at very low concentration in our bodies and are known as trace
elements. At high levels metals may be toxic. In particular, metals such as mercury
and lead can interfere with the structure of proteins and their effective function.

Nowadays, consumption of dietary supplements is very common; however,


recommended daily allowances should be observed.

Table 3  Average levels of some metals in human blood.

Metal Chemical symbol Concentration/ppb


Aluminium Al 13
Cobalt Co 0.2
Chromium Cr 3.0
Nickel Ni 5.0

Metals may enter fresh and salty water through industrial waste, sewage and run-off.
Microbes, plants and animals that depend on this contaminated water consume or
absorb these metals. Over time the metals are concentrated within the food chain, in
a process known as bioaccumulation (Figure 14). The concentration of metals in
affected organisms is greater than was initially present in the water itself, as species
consume greater quantities at each level and so the concentration increases up the
food chain.

Page 25 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 14  Bioaccumulation of metals in an aquatic food-chain.

View description - Figure 14  Bioaccumulation of metals in an aquatic food-chain.

Conclusion
The materials that have probably been the most influential in shaping society over
the past two to three millennia are the metals. You will all have a general idea as to
what is metallic and what is not and in this part you have seen some of the criteria for
the distinction.

The key concepts and principles you have learned in this part are:

 metallic bonding, and how it is related to metallic characteristics


 Metallic bonding is the attraction between the
delocalised electrons and the positively charged
nuclei. It is strong and occurs in all directions.
 Transitions of electrons from excited states to lower
energy levels result in emission spectra.

Page 26 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?
 Emission spectra are the basis of simple flame tests
for metal salts.
 the role of metals in everyday life.
 Metals are used in a wide range of applications
(construction, electronic devices, transportation, food
processing, biomedical applications) and play an
important role in biological systems.
 Bioaccumulation is the accumulation of substances
inside an organism over time.

This course is part of a suite of introductory science courses on OpenLearn.

View description - This course is part of a suite of introductory science courses on


OpenLearn.

The content of these courses comes from the Open University course S111
Questions in science. Take a look at the other OpenLearn courses that are part of this
set here.

Page 27 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 1   (a) Gold and (b) copper.


Description
Two photographs: (a) shows a thin sheet of gold on a surface, part of which is being lifted up; (b)
shows thin copper wire tightly wrapped around a wooden spool.

Back to Session 1 Figure 1

Page 28 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 2  Apples on a packing tray.


Description
A photograph of red apples arranged in rows on a packing tray. The apples in alternate rows are offset
by half an apple, to the left or the right, so that they fit into the small spaces left between the apples in
the adjacent rows.

Back to Session 2 Figure 1

Page 29 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 3 Illustration of shells in a lithium


atom
Description
Figure 3 is a schematic diagram representing a lithium atom. It shows a nucleus (a circle) at the centre,
with two concentric rings that represent its electron shells. Two electrons are shown in the inner shell,
and one in the outer. The nucleus is labelled ‘atomic nucleus containing a proton of charge +1’. The
outer electron is labelled as having a charge of -1.

Back to Session 2 Figure 3

Page 30 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 4  Positively charged nuclei (plural


for nucleus) in a cloud of delocalised
electrons.
Description
An animation representing positively charged nuclei in a cloud of delocalised electrons. Each nucleus
is represented by a circle with a plus symbol (‘+’) in it. The nuclei are arranged in staggered rows. That
is, each row of circles in alternate rows are offset by half a circle, to the left or the right, so that they fit
in between the circles in the adjacent rows. The electrons in the outer shells are represented by blue
circles that are moving freely (animated) between the nuclei to indicate their delocalisation. Each
nucleus is represented by an orange sphere with ‘+’ in it. The 16 nuclei are arranged in four staggered
rows of four orange spheres that are static. Each sphere in the second and fourth rows has been shifted
horizontally so that it is above the space between adjacent spheres in the first and third rows. The
electrons are represented by blue spheres that are moving freely to indicate their delocalisation.

Back to Session 2 Figure 4

Page 31 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 5  Conductivity of electricity in a metal: (a) open circuit


(switch open) (b) closed circuit (switch closed). Arrows
indicate flow of electrons.

Description
Two simple, rectangular electric circuit diagrams show the conductivity of electricity in
a metal. Figure 5a shows an open circuit. Straight lines are used to represent a
connecting metal wire. The circuit has a gap at the top to indicate a break in the
circuit, with a switch labelled ‘open’. To the right of this open switch, there is a
rectangular block that represents a battery with its positive (+) terminal next to the
switch and its negative (–) terminal on the far right. On the right side of the circuit,
there is a circle with a squiggly line in it that represents a light bulb and its filament.
Figure 5b shows a closed circuit. The same circuit as in (a) has the switch closed at
the top so that the wire has contact with and is connected to the positive (+) terminal
of the battery. There are circles, indicating freely moving electrons, around the circuit.
There is a lit bulb on the right. Arrows indicate the clockwise flow of the negatively
charged electrons in the wire from the negative terminal to the positive terminal of the
battery. What is happening within the wire is shown with a magnified diagram. This is
a repeat of Figure 1.4. Each nucleus is represented by a circle with a plus symbol
(‘+’) in it. The nuclei are arranged in staggered rows. That is, each row of circles in
alternate rows are offset by half a circle, to the left or the right, so that they fit in
between the circles in the adjacent rows. The electrons in the outer shells are
represented by blue circles that are positioned randomly, indicating they are moving
freely because they are delocalised.

Back to Session 2 Figure 5

Page 32 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 6 Layers of atoms sliding over each


other and creating thin layers of metal.
Description
An animation showing how thin layers of metal are created. The animation begins with four stacked
rows of orange spheres, which represent atoms in the metal. Each sphere in alternate rows are offset by
half a sphere, to the left of the right, so that it fits into the space between adjacent spheres in row above.
The animation shows the top two rows of atoms sliding across the bottom two, towards the right. An
arrow indicates stress being to the top two rows of atoms to cause this sliding.

Back to Session 2 Figure 6

Page 33 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 7  (a) An electron jump from shell n = 2 to n = 3 is


shown by the red arrow. (b) The electron jumps to a higher
electron shell further away from the nucleus. Note that energy
levels are not evenly spaced and they become closer together
as they move away from the nucleus.

Description
This figure represents an electron jump from shell n = 2 to n = 3. The figure is in two
parts. Figure 7(a) is a schematic diagram representing an atom. It shows a nucleus
(a circle) at the centre, with three concentric rings that represent its shells labelled
(from inside to out) n = 1, n = 2 and n = 3. An electron is shown in the n = 2 shell.
The diagram illustrates (using an arrow) than this electron jumps from n = 2 to n = 3.
In (b) there are three horizontal lines labelled (from bottom to top) n = 1, n = 2 and n
= 3. An arrow to the side of the lines indicates that there is increasing energy from n
= 1 to n = 3. The gap between n = 1 and n = 2 is around two and a half times bigger
than that between n = 2 and n = 3, indicating more energy is needed to move
between n = 1 to n = 2 than from n = 2 to n = 3. The electron jump from part (a) is
shown as an arrow between the lines, pointing from n = 2 to n = 3.

Back to Session 3 Figure 1

Page 34 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 8  Flame test for sodium.


Description
A photograph of a Bunsen burner blue flame. A piece of white metal on the end of a wire extending
from a glass rod is being heated in the flame to show the flame test for sodium. The blue flame is
turning yellow with an orange glow around the piece of metal.

Back to Session 3 Figure 2

Page 35 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 9  Emission spectrum of sodium in


the visible region.
Description
Figure 9 shows a spectrum. It is represented by a thin black rectangle in landscape format with five
vertical coloured lines positioned along its length. From left to right the lines are: blue, green, two
closely arranged yellow and red. The blue line is about a third along the rectangle. The green line is just
over halfway along. The two yellow lines are about three quarters along. The red line is between the
yellow ones and the end of the rectangle, but closer to the yellow lines.

Back to Session 3 Figure 3

Page 36 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 10  Components of Bunsen burner


and the position of nichrome wire for a
flame test.
Description
Figure 10 shows an illustration of a Bunsen burner in which its components are labelled and the
position of nichrome wire for a flame test is shown. The Bunsen burner is a metal thin hollow vertical
tube on a flat metal stand. Gas passes into this via a flexible rubber tube and is controlled by the barrel,
which is at the base of the metal tube. This can be rotated to allow gas to pass up the main tube. In the
diagram this is open, so gas is passing through and the flame at the top of the metal tube is blue. A thin
long nichrome wire is shown being held in the side of the flame. This has a loop at the flame end and a
cork at the other. The cork is used to hold the wire.

Back to Session 3 Figure 4

Page 37 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 11  Main components of the hand


spectroscope.
Description
Figure 11 shows an illustration of the main components of the hand spectroscope. The figure is drawn
as two thin rectangles in landscape format so that they appear as square tubes, open at facing ends. The
right tube (the barrel) is inserted into the left tube to make one long tube. At the left hand end of the
long tube is an eyepiece lens, so that you can look into the tube. At the left hand end of the inserted
tube is another lens and at the right hand end is a glass window. Inside the right hand part of the
inserted tube is a prism. This is shown as three triangles, fitted together to make a trapezium.

Back to Session 3 Figure 5

Page 38 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 12 Common uses of metals in our daily lives.

Description
Six photographs to show the common use of metals in our daily lives.

For (a) steel, there is a suspension bridge; (b) aluminium, the back of an aeroplane;
(c) copper, three cables with visible copper wiring; (d) gold, a circuit board; (e)
stainless steel, a can; and (f) titanium, a replacement knee joint.

Page 39 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Page 40 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Page 41 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Back to Session 4 MediaContent 1

Page 42 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 13  Calcium and bones.


Description
A photograph of six white bones with one on the far left being bigger and more prominent than the
other five together with grey fragments of calcium in the foreground, all on a black background.

Back to Session 4 Figure 7

Page 43 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Figure 14  Bioaccumulation of metals in an


aquatic food-chain.
Description
Figure 14 illustrates the bioaccumulation of metals in an aquatic food chain. The figure is presented as
a flow chart, from bottom to top. At the bottom is the contaminant (represented by red dots), which is
then consumed by plankton (illustrated as small organisms of different shapes containing the
contaminant). The plankton is consumed by a worm, the worm by a small fish, the small fish by a
larger fish. The diagram shows that the contaminant is passed through the food chain. Eventually, the
contaminant is passed to both humans and birds, since they consume the larger fish.

Back to Session 4 Figure 8

Page 44 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

This course is part of a suite of


introductory science courses on
OpenLearn.
Description
This is a graphic of a question mark with three segments inside it, from left top to right, going down the
question mark, are the words Ethics in science? What are waves? What is a metal? At the bottom of the
question mark, inside the full point, is the text Questions in science.

Back to Session 5 Figure 1

Page 45 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0
What is a metal?

Video 1  Close packing in three


dimensions. (2:46 min)
Transcript
INSTRUCTOR
We’ll start by building the simplest of the models, which is the hexagonal close-packed array. First, we
fill a tray with transparent spheres so that the row of spheres furthest away from you contains five and
the row nearest to you contains four. Next, we put on another layer of the clear spheres. You will find
that these fit neatly in the hollows created by the bottom layer.
Notice that the hollows have an almost triangular shape. There are two possible positions for the
second layer, covering either triangles with tips pointing away from you or over triangles with their tips
pointing towards you. We’re putting the second layer of the triangles with the tips pointing away from
you, but it’s an arbitrary choice. It doesn’t matter which you choose.
The second layer now has three rows of spheres - four in the first, three in the middle and four in the
next. Now, we add the third layer of spheres. For hexagonal close-packing, they have to lie directly
above the first layer. Looking down on the model, you will see that we can do this now by covering the
triangles with the tips pointing towards you.
Layer three of the model contains five spheres. Now, look again at the hexagonal close-packed model.
We have coloured a sphere in the middle of the second layer.
Count up the number that are touching it. There are three in the bottom layer. There are six in the same
layer. In the layer above, there are also three that touch it - making 12 in all.

Back to Session 2 MediaContent 1

Page 46 of 46 21st June 2019

https://www.open.edu/openlearn/science-maths-technology/chemistry/what-metal/content-
section-0

You might also like