Thermodynamic and

Transport Properties of
Fluids

SI Units

arranged by
G. F. C. Rogers and Y. R.

Fifth Edition

Blackwell
Publishing
 CONTENTS

Notation and Units Saturated

Water and Steam
Superheated and Supercritical Steam
Further Properties of Water and Steam
Mercury-Hg
Ammonia - (Refrigerant 717)
Dichlorodifluoromethane - (Refrigerant 12)
Tetrafluoroethane - (Refrigerant
Dry Air at Low Pressure
Specific Heat Capacity of Some Gases and Vapours
Molar Properties of Some Gases and Vapours
Enthalpies of Reaction and Equilibrium Constants
A Selection of Chemical Thermodynamic Data
Miscellaneous Liquids, Vapours and Gases
International Standard Atmosphere
SI - British Conversion
Factors General Information
Principal Sources
 NOTATION AND UNITS
- velocity of sound
-specific, molar heat capacity at constant p
-specific, molar heat capacity at constant
- specific, molar Gibbs function (h -
-molar Gibbs function of reaction, of formation
- specific, molar enthalpy (u + + pi?)
- molar enthalpy of reaction, of formation

- equilibrium constant, of formation

- thermal conductivity
- molar mass
bar -absolute pressure
- Prandtl number
K, K - specific, molar (universal) gas constant
K, K -specific, molar entropy
K or -absolute temperature (K) or Celsius temperature
K -temperature interval or difference
- specific, molar internal energy
m3/kg, m3/kmol -specific, molar volume
m -geometric altitude above sea level
-ratio of specific heat capacities =
-mean free path
-dynamic viscosity
-kinematic viscosity
- mass, molar density

Subscripts
c -refers to a property in the critical state
f -refers to a property of the saturated liquid, or to a value of formation
g -refers to a property of the saturated vapour
fg -refers to a change of phase at constant p
I -refers to a property of the saturated solid
-refers to a saturation temperature or pressure

Superscripts
- refers to a molar property per unit amount-of-substance)
-refers to a property at standard pressure = 1 bar (the superscript o is often used)
Saturated Water and Steam
T
[bar] K]

and s are chosen to be zero for saturated liquid at the triple

point. Note: values of can be found on p. 10.
Saturated Water and Steam
Saturated Water and Steam
Saturated Water and
Steam
Superheated

The entries in all tables are regarded as pure numbers and therefore the symbols for the physical quantities
should be divided by the appropriate units as shown for the entries at = 4. Because of lack of space,
this has not been done consistently in the superheat and supercritical tables on pp. 6-9 and in the tables on
pp. and 23.
 Superheated Steam*

* See footnote on p. 6.
Superheated Steam*

80 v, 0.02352
(295.0) h, 2758
s, 5.744
90 v, 0.02048
(303.3) h, 2743
5.679
v, 0.01802
(3 .O) h, 2725
s, 5.615
v, 0.01 598
(318.0) h, 2705
5.553
120 v, 0.01426
(324.6) h, 2685
5.493
130 0.01278
(330.8) h, 2662
s, 5.433
140 v, 0.01149
(336.6) 2638
5.373
150 v, 0.01035
(342.1) h, 2611
5.312
160 0.00932
(347.3) h, 2582
5.248
170 v, 0.00838
(352.3) h, 2548
5.181
180 0.00751
(357.0) h, 2510
5.108
190 v, 0.00668
(361.4) h, 2466
5.027
200 v, 0.00585
(365.7) h, 241 1
4.928
210 v, 0.00498
(369.8) h, 2336
4.803
220 v, 0.00368
(373.7) h, 2178
4.552
221.2 0.00317
(374.15) 2084
4.406
* See footnote on p. 6.
Note: linear interpolation is not accurate near the critical point.
 Supercritical Steam*

[bar]

* See footnote on p. 6.
 General Information for
Triple point: Thermodynamic temperature (by definition) =
0.01
(hence 273.15 K, 459.67 R, 32 491.67 R)
Gas constant: R = = = 0.4615

Compressed Water*

* See footnote on p. 6.

Saturated Ice and Steam

Isentropic Expansion of Steam-Approximate Relations

Wet equilibrium expansion:
pun = constant, with 1.035 for steam with an initial dryness fraction 0.7 1.0
I
Superheated and supersaturated expansion:
= constant and = constant, with n 1.3

Enthalpy drop I]
volume of supersaturated steam:
Mercury - Hg

[bar]

and are zero at "C. Molar mass m = 200.59 for superheated vapour = 0.1036
K; further properties of the liquid are given on p. 23.
Ammonia - NH, (Refrigerant 717)
Superheat (T-
Saturation Values
50 K K

-
T -
[bar] ,
- 50 0.4089 2.625 -44.4 1373.3 -0.194 6.159 1479.8 6.592
-45 0.5454 2.005 -22.3 1381.6 -0.096 6.057 1489.3 6.486
-40 0.7177 1.552 0 1390.0 0 5.962 1498.6 6.387
-35 0.9322 1.216 22.3 1397.9 0.095 5.872 1507.9 6.293
- 30 1.196 0.9633 44.7 1405.6 0.188 5.785 1517.0 6.203
-28 1.317 0.8809 53.6 1408.5 0.224 5.751 1520.7 6.169
-26 1.447 62.6 1411.4 0.261 5.718 1524.3 6.135
- 24 1.588 0.7389 71.7 1414.3 0.297 5.686 1527.9 6.103
- 22 1.740 0.6783 80.8 1417.3 0.333 5.655 1531.4 6.071
- 20 1.902 0.6237 89.8 1420.0 0.368 5.623 1534.8 6.039
- 2.077 0.5743 98.8 1423.7 0.404 5.593 1538.2 6.008
- 2.265 0.5296 107.9 1425.3 0.440 5.563 1541.7 5.978
- 14 2.465 0.4890 117.0 1427.9 0.475 5.533 1545.1 5.948
- I2 2.680 0.4521 126.2 1430.5 0.510 5.504 1548.5 5.919
- 2.908 0.4185 135.4 1433.0 0.544 5.475 1551.7 5.891
- 8 3.153 0.3879 144.5 1435.3 0.579 5.447 1554.9 5.863
- 6 3.413 0.3599 153.6 1437.6 0.613 5.419 1558.2 5.836
- 4 3.691 0.3344 162.8 1439.9 0.647 5.392 1561.4 5.808
- 2 3.983 0.3110 172.0 1442.2 0.681 5.365 1564.6 5.782
0 4.295 0.2895 181.2 1444.4 0.715 5.340 1567.8 5.756
2 4.625 0.2699 190.4 1446.5 0.749 5.314 1570.9 5.731
4 4.975 0.2517 199.7 1448.5 0.782 5.288 1574.0 5.706
6 5.346 0.2351 209.1 1450.6 0.816 5.263 1577.0 5.682
8 5.736 0.2198 218.5 1452.5 0.849 5.238 1580.1 5.658
6.149 0.2056 227.8 1454.3 0.881 5.213 1583.1 5.634
6.585 0.1926 237.2 1456.1 0.914 5.189 1586.0 5.61
14 7.045 246.6 1457.8 0.947 5.165 1588.9 5.588
7.529 0.1693 256.0 1459.5 0.979 5.141 1591.7 5.565
8.035 0.1590 265.5 1461.1 1.012 5.118 1594.4 5.543
20 8.570 0.1494 275.1 1462.6 1.044 5.095 1597.2 5.521
22 9.134 0.1405 284.6 1463.9 1.076 5.072 1600.0 5.499
24 9.722 0.1322 294.1 1465.2 5.049 1602.7 5.418
26 10.34 0.1245 303.7 1466.5 1.140 5.027 1605.3 5.458
28 10.99 0.1173 313.4 1467.8 1.1 72 5.005 1608.0 5.437
30 11.67 0.1106 323.1 1468.9 1.204 4.984 1610.5 5.417
32 12.37 0.1044 332.8 1469.9 1.235 4.962 1613.0 5.397
34 13.1 0.0986 342.5 1470.8 1.267 4.940 1615.4 5.378
36 13.89 0.0931 352.3 1471.8 1.298 4.919 1617.8 5.358
38 14.70 0.0880 362.1 1472.6 1.329 4.898 1620.1 5.340
40 15.54 371.9 1473.3 1.360 4.877 1622.4 5.321
42
44
16.42
17.34
0.0788
0.0746 , 381.8
391.8
1473.8
1474.2 1.422
4.856
4.835
1624.6
1626.8
5.302
5.284
46 18.30 0.0706 401.8 1474.5 , 1.453 4.814 1629.0 5.266
48 19.29 0.0670 41 1.9 1474.7 1.484 4.793 1631.1 5.248
50 20.33 0.0635 421. 9 1474.7 1.515 4.773 1633.1 5.230
Critical point = 132.4 = 1 13.0 bar.
Molar mass = 17.030 further properties of the liquid are given on p. 23.
 Dichlorodifluoromethane- (Refrigerant
12)
Superheat T-- T,)
Saturation Values
15 30 K

Molar mass = 120.91 further properties of the liquid are given on p. 23.
Dry Air at Low Pressure
at atm

The values for air can also be used with reasonable accuracy for CO, and 0,.
The values of the thermodynamic properties and on pp. 16 and 17 are those at zero pressure. The values
for the gases are quite accurate over a wide range of pressure, but those for the vapours increase appreciably
with pressure.
The transport properties and k for air are accurate over a wide range of pressure, except at such low
pressures that the mean free path of the molecules is comparable to the distance between the solid surfaces
containing the
At high temperatures for air) dissociation becomes appreciable and pressure is a significant
variable for both gases and the values on pp. and apply only to undissociated states.
 Specific Heat Capacity K of Some Gases and Vapours

The specific heat capacities of atomic N and are with adequate accuracy by = 2.5
where is the molar mass of the species.
Molar Properties of Some Gases and Vapours
By definition: = + and =
are virtually independent of pressure and in the following will be treated as such: hence
ii =
Sand are tabulated for states at the standard pressure pe = 1 bar and are denoted by 3" and At
any other pressure p, at a given temperature T can be found from

- =

For individual gases and vapours, changes in Sand between states (p,, and are given by
=

=
For a constituent in a mixture, and must be regarded as the partial pressures in the respective
states. When performing calculations involving non-reacting mixtures, the datum states at which and
3 are arbitrarily put equal to zero are unimportant: in the tables they are (1 bar, 298.15 K)
for and
(1 bar, 0.0 K ) for S. The datum states are important when chemical reactions are involved-see p. 20.

Carbon Dioxide (CO,) 44.010---- Water Vapour

kmol
 Molar Properties of Some Gases and
Vapours

K]

Hydrogen 2.016-- Carbon Monoxide 28.0105-

kmol kmol

Nitrogen = 3-
kmol kmol
Molar Properties of Some Gases and Vapours

Hydroxyl (OH) = 17.0075-- Nitric Oxide A30.006

kmol kmol

I
Methane Vapour (CH,) = 16.043 kmol Ethylene Vapour
kmol
- 10025 - 10025 0 - 10025 0 10519 10519 0 10519
- 6 699 - 7 530 149.39 - 21638 100 7192 8024 180.44 25236
- 3368 - 5031 172.47 - 37863 200 3 803 5466 303.85 44573
0 - 2479 186.15 - 55499 298.15 0 2479 219.22 65362
67 - 2427 186.37 I 79 2415 65 767
- 219.49
3 862 536 197.25 - 75038 400 557 233.24 - 88412
13 129 8 215.88 -116400 600 17334 2 346 258.24 - 137610
24 673 022 232.41 800 32849 26 197
38 179 29 865 247.45 -209 270 1000 50 664 42 350 300.30 - 249 640
53 27 43 293 261.18 1200 70 254 60 276 318.13 -31 510
69 609 57 969 273.76 -313660 1400 91 199 79 558 334.27 376 780
86910 73 607 285.31 - 369 590 1600 113 180 99 878 348.94 -445 120
104 960 89 994 295.93 -427 720 1800 135970 121 010 362.36 -516270
123600 106970 305.75 -487 900 2000 59 390 142 760 374.69 - 589 990

The molar enthalpies of reaction, on p. 21 are for a reference temperature of T = 298.15 K and are ,
virtually independent of pressure. Corresponding values of Gibbs function of reaction, may be
found from values of equilibrium constant using the relation
= . (Suffixes P and R refer to products and reactants)
The standard or thermodynamic is defined by
= or =
I

where are the stoichiometric coefficients, those for the products and reactants being taken as positive
and negative respectively. The constant so defined is dimensionless.
 Enthalpies of Reaction and Equilibrium Constants
Reaction values of relate to
the corresponding chemical equation with amounts of
substance in kilomoles at T = 298.15 K (25
+ - 393 520
- 282 990
- 241 830
+ 20, + -802 310
+ + - 1 323 170
+ + - 1 427 860
++ + - 3169540
,+ + + - 5 116 180
+41 160
CO
+OH - 281 540
+ NO +90 290
- 435 980
2H
- 498 340
20
-945 300
2N
At 298.15 K for = 43 990 of ofof
for = 33 800
for = 41 500 ,,

I
= bar =-------atm
1.01325 = 0.99344 log,, = 0.43429 In
A Selection of Chemical Thermodynamic Data

at = 1 bar and = 298.15 K

-
K] K]
C (graphite) 12.011 0 0 0 8.53 5.69
C (diamond) 1 900 870 -1.157 6.06 2.44
12.011 714 990 669 570 -270.098 20.84 158.
16.043 -74 870 -50810 20.498 35.64 186.26
28.054 52 470 68 350 -27.573 42.89 219.33
28.0105 -110530 -137 55.331 29.14 197.65
44.010 -393 520 -394 390 159.093 37.13 213.80
1.008 217 990 203 290 -82.003 20.79 114.71
2.016 0 0 0 28.84 130.68
17.005 39 710 35010 -14.122 29.99 183.61
-285 820 -237 150 95.660 75.32 70.00
18.0155 -241830 -228 590 92.207 33.58 188.83
14.0065 472 650 . - 183.740 20.79 153.30
0 0 0 29.21 191.61
30.006 90 290 86 600 -34.933 29.84 210.76
15.9995 249 170 231 750 -93.481 21.91 161.06
31.999 0 0 29.37 205.14

Reproduced from Rogers, G. F. C., and Y. R., Engineering Work and Heat
Transfer (Longman, 1992).
 Miscellaneous Liquids, Vapours and
Gases*

Ammonia (NH
sat. liquid
= 195.4 K
a = 17.030
R-12
sat. liquid 0.902 0.980
P 1468 1304 --
=1 K ~ / l o - ~336 213
120.91
86.8 68.6

sat. liquid
= 169.85 K
= 102.03

Mercury (Hg)
liquid
= 234.3 K
= 200.59

Potassium (K) 0.710

liquid 860
336.8 K solid
= 39.098

Sodium (Na) 1.224

liquid 967
370.5 K solid
= 22.990 0.135
Sodium-Potassium 0.977 0.929
P 869 845
eutectic liquid solid 780 467
262 K k 0.0222 0.0236

Argon (Ar)
atm
= 39.948

Carbon dioxide
atm
= 44.010

Helium (He) 5.193

atm P 0.1951
= 4.003 18.40
134.0
Hydrogen 14.05
atm 0.0983
= 2.016 7.92
156.1
Steam
low pressures
= 18.015

* See footnote on p. 6.
The properties and (and for liquids) do not vary much with pressure; see also footnote on p. 16.
International Standard Atmosphere

Density at sea level = 1.2250

 SI - British Conversion Factors
The International System of Units (HMSO, 1986) may be consulted for the definitions of SI units,
and British Standard 350 for comprehensive tables of conversion factors.
Exact values are printed in bold type.
1
Mass: 1 kg = lb = 2.205
0.453 592 37
1
Length: 1 m ft = 3.281 ft
= 0.3048
Volume: 1 m3 = dm3 = 35.31 ft3 = 220.0 UK gal = 264.2 US gal

Temperature unit: 1 = 1.8 R (see p. 11 for definitions of units and

1
scales) Force: 1 N (or kg m/s2) = dyn =
9.806 65
7.233
= 7.233 pdl = or 0.2248 lbf
32.174
Pressure: p: 1 bar = N/m 2 (or Pa) = 14.50 lbf/in2 = 750 = 10.20
Specific volume v: m3/kg = 16.02ft3/lb

Density p: 1 kg/m3 = 0.062 43 lb/ft3

1
Energy: 1 = N = kcal,, = 0.9478 Btu = 737.6 ft lbf
4.1868

Power: 1 = 1 =
= metric hp
9.806 9.806 65 x 75
65
737.6 1
= 737.6 ft or --- British hp = 3412
550 0.7457
=

1
Specific energy etc. (u, h): 1 = 0.4299
= 2.32
6
1
Specific heat capacity etc. (c, R, s): 1 = --- R = 0.2388 R
4.1868
Thermal conductivity k: 1 = 577.8 hR
Heat transfer coefficient: 1 kW/m2 = 176.1 Btu/ft2 h R
Dynamic viscosity 1 s = 1 N s/m2 = 1 Pa s = 10 dyn s/cm2 (or poise)
= 2419 h = 18.67 x pdl h/ft2
Kinematic viscosity v: 1 m 2/s = cm2/s (or stokes) = 38 750 ft2/h
 General Information
Standard acceleration: = 9.806 65 m/s2 = 32.1740 ft/s2
Standard atmospheric pressure: 1 atm = 1.013 25 bar

Molar (universal) constant: = 8.3145 Kt

= 1.986 R = 1545 ft R
Molar volume: = 22.41 m3/kmol at 1 atm and
= 359.0 at atm and 32°F

Composition
vol. analysis grav.
Nitrogen - 28.01 3
analysis 0.7809 0.7553
Oxygen - 31.999
0.2095 0.2314
Argon (Ar- 39.948 0.0093 0.0 28
Carbon dioxide - 44.010 0.0003 0.0005

Molar mass = 28.96

Specific gas constant R = 0.2871 See 16 for other properties

For approximate calculations with air:

vol. analysis grav. analysis
- 28 0.79 0.767
- 32 0.2 0.233
3.76 3.29
Molar mass = 29
Specific gas constant R = 0.287 K
= 0.0685 R = 53.3 ft R
= K = 0.240 R

= = 1.40

a = 56.7 x constant:
kW/m 2 K 4 = 0.171 x Btu/ft2 h R 4

is the amount of substance of a system which contains as many elementary entities as there are atoms
in 12 kg of carbon 12.
The elementary entities must be specified, but for problems involving mixtures gases and combustion they will be
molecules or atoms.
 PRINCIPAL
National Engineering Laboratory, Sream Tables 1964 (Her Majesty's Stationery Office 1964)
(reproduced by courtesy of the Controller of Her Majesty's Stationery Office).
ASHRAE Thermodynamic Properties of Refrigerants and ASHRAE Thermophysical Properties of
Refrigerants (ASHRAE, 1969 and 1976).
Hilsenrath, J., Beckett, C. W., Benedict, W. S., L., Hoge, H. J., Masi, J. F., R. L.,
Touloukian, Y. S., and Woolley, H. W., Tables of Thermal Properties of Gases (US. N.B.S.
Circular 564, 1955, available from the Superintendent of Documents, Government Printing
Office, Washington 25, D.C.).
Rossini, F. D., D. D., Evans, W. H., Levine, S., and I., Selected Values of
Chemical Thermodynamic Properties (ibid. 500, 1952).
D. D., Selected Valued of Chemical Thermodynamic Properties (ibid., Tech. Note 270,
1965).
Sheldon, L. A., Thermodynamic Properties of Mercury Vapour, Amer. Mech. Engrs. No.
49-A-30 (1949).
Stull, D. R., and Prophet, H. (eds). Thermochemical Tables, The Dow Chemical Company,
Midland, Michigan (U.S. G.P.O., 1971, Supplements 1974, 1975, 1978).
Thermodynamic Properties of KLEA 134a (ICI private communication, 1994)

By the same authors

Engineering Thermodynamics, Work and Heat Transfer (Longmans, 4th ed.).
By H. Cohen, G. F. C. Rogers and H. I. H.
Gas Theory (Longmans, 4th ed.)

FOR USE WITH THESE TABLES

Enthalpy-Entropy for Steam
Prepared by D. C. and F. R. Taylor
NOTES
 1995 by Blackwell Publishing Ltd

BLACKWELL PUBLISHING
350 Main Street, Malden, MA 02148-5020, USA
108 Road, Oxford OX4 JF, UK
550 Street, Carlton, Victoria 3053, Australia

All rights reserved. No part of this publication reproduced, stored in a retrieval

system, or transmitted, in any form or by any means, electronic, mechanical,
photocopying, recording or otherwise, except as permitted by the UK Copyright,
Designs, and Patents Act 1988, without the prior of the publisher.

First published 1964

Second edition 1967
Third edition 1980
Fourth edition 1988
Fifth edition 1995
Reprinted 1996 (twice), 1997, 1998, 1999,2000,
2001,2002,2003 (twice), 2004

of Congress Cataloging-in-PublicationData has been

appliedfor

ISBN 1-19703-6

A catalogue record for this title is available from the British Library.

Set by Advanced (Glasgow) Ltd

Printed and bound in the United Kingdom
by Alden Press, Osney Mead, Oxford

The publisher's policy is to use permanent paper from mills that operate a sustainable
forestry policy, and which has been manufactured from pulp processed using acid-free
and elementary chlorine-free practices. Furthermore, the publisher ensures that the text
paper and cover board used have met acceptable environmental accreditation standards.

For further information on Blackwell Publishing, visit our

www.blackwellpublishing.com
Publishing ,
I 78063 1
197034