Testing For The Presence of Different Substances (Revised Feb 2020)
Testing For The Presence of Different Substances (Revised Feb 2020)
Potassium ion Give a lilac flame in the flame test (with non-luminous flame!!)
**Note: When applying flame tests, a non-luminous flame should always be used (i.e.
the air hole should be open), or else the yellow colour of luminous flame may mask
the flame from metal ion
Sodium ion Give a golden yellow flame in the flame test (with non-luminous flame!!)
Calcium ion Give a brick red flame in the flame test (with non-luminous flame!!)
Magnesium ion Give a dazzling white flame in the flame test (with non-luminous flame!!)
Chloride ion (Dissolve the solid sample). Add aqueous silver nitrate solution to the sample,
followed by excess dilute nitric acid. The appearance of a white precipitate (AgCl)
indicates the presence of chloride ion.
Bromide ion (Dissolve the solid sample). Add aqueous silver nitrate solution to the sample,
followed by excess dilute nitric acid. The appearance of a pale yellow precipitate
(AgBr) indicates the presence of bromide ion.
Iodide ion (Dissolve the solid sample). Add aqueous silver nitrate solution to the sample,
followed by excess dilute nitric acid. The appearance of a yellow precipitate (AgI)
indicates the presence of iodide ion.
Ammonium ion Upon heating of ammonium compounds with aqueous hydroxide solution, ammonia
gas, the only alkaline gas, will be liberated, changing wet red litmus paper blue
Iron(II) ion K3Fe(CN)6(rust indicator) gives a blue colour
Oxidizing agent We may use KI(aq), a reducing agent, to test for oxidizing agents.
(oxidize others Result:
by undergoing KI(aq) reacts to give a brown iodine solution, i.e. I2(aq)
reduction itself) (starch solution is also added so that a dark blue colour could be obtained)