Safety Data Sheet

Revision Number: 007.0 Issue date: 10/06/2016

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: LOCTITE PC 7222 known as Fixmaster IDH number: 702267
Wear Resistant Putty
Product type: Epoxy Item number: 98742_363000
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.

HAZARD CLASS HAZARD CATEGORY

SKIN CORROSION 1B
SERIOUS EYE DAMAGE 1
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Wear protective
gloves, clothing, eye and face protection. In case of inadequate ventilation wear respiratory
protection.
Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off
immediately all contaminated clothing. IF INHALED: Remove victim to fresh air and keep at rest
in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF IN
EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If
experiencing respiratory symptoms: Call a poison center or physician. Wash contaminated
clothing before reuse.
Storage: Store locked up.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

IDH number: 702267 Product name: LOCTITE PC 7222 known as Fixmaster Wear Resistant Putty
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Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*
Aluminium oxide 1344-28-1 60 - 100
Diethylenetriamine 111-40-0 1-5
4-Nonylphenol, branched 84852-15-3 1-5
Silicon dioxide 7631-86-9 1-5
Epoxy polyamine adduct Proprietary 1-5
4,4'-Isopropylidenediphenol 80-05-7 1-5
Triethylenetetramine 112-24-3 1-5
Substituted Piperazine Proprietary 1-5
Titanium dioxide 13463-67-7 0.1 - 1
Aluminum 7429-90-5 0.1 - 1
Nonylphenol 25154-52-3 0.1 - 1
Benzyl alcohol 100-51-6 0.1 - 1
Benzyldimethylamine 103-83-3 0.1 - 1

* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Get medical attention. Wash clothing
before reuse. Thoroughly clean shoes before reuse.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.

Never give anything by mouth to an unconscious person. Get medical
attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: In case of fire, keep containers cool with water spray. Burning produces
obnoxious and toxic fumes. Personnel in vicinity and downwind should be
evacuated. Use of water may result in the formation of very toxic aqueous
solutions. Do not allow run-off from fire fighting to enter drains or water
courses.

IDH number: 702267 Product name: LOCTITE PC 7222 known as Fixmaster Wear Resistant Putty
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 Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Aldehydes. Ammonia. Nitric acid.
Phenolics. Toxic fumes. Irritating vapors.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Evacuate and ventilate spill area; dike spill to prevent entry into water system;
wear full protective equipment during clean-up. Refer to Section 8 "Exposure
Controls / Personal Protection" prior to clean up. Soak up with inert absorbent
material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape
up spilled material and place in a closed container for disposal.

7. HANDLING AND STORAGE

Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Use only with adequate ventilation. Keep
container closed.

Storage: Store in original container until ready to use. Keep container tightly closed and
in a cool, well-ventilated place away from incompatible materials. Keep away
from heat, spark and flame.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

5 mg/m3 PEL
1 mg/m3 TWA Respirable fraction.
Aluminium oxide None None
Respirable fraction. 15 mg/m3 PEL Total
dust.
(SKIN)
Diethylenetriamine None None None
1 ppm TWA
4-Nonylphenol, branched None None None None
20 MPPCF TWA 3 mg/m3 TWA
Silicon dioxide 6 mg/m3 TWA None
0.8 mg/m3 TWA Respirable fraction.
Epoxy polyamine adduct None None None None
4,4'-Isopropylidenediphenol None None None None
1 ppm (6 mg/m3)
Triethylenetetramine None None TWA None
(SKIN)
Substituted Piperazine None None None None
15 mg/m3 PEL Total
Titanium dioxide 10 mg/m3 TWA None None
dust.
15 mg/m3 PEL (as
1 mg/m3 TWA Al) Total dust.
Aluminum None None
Respirable fraction. 5 mg/m3 PEL (as Al)
Respirable fraction.
Nonylphenol None None None None
10 ppm (44.20
Benzyl alcohol None None None
mg/m3) TWA
Benzyldimethylamine None None None None

Engineering controls: Use local ventilation if general ventilation is insufficient to maintain vapor
concentration below established exposure limits.

IDH number: 702267 Product name: LOCTITE PC 7222 known as Fixmaster Wear Resistant Putty
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 Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Paste
Color: Dark grey
Odor: Ammoniacal
Odor threshold: Not available.
pH: Not available.
Vapor pressure: < 1.0 mm hg (20 °C (68°F)) < 1.0 mm hg (20 °C (68°F))
Boiling point/range: Not available.
Melting point/ range: Not available.
Specific gravity: 1.9
Vapor density: >1
Flash point: > 93 °C (> 199.4 °F) Setaflash Closed Cup
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: Slower than butyl acetate.
Solubility in water: Not available.
Partition coefficient (n-octanol/water): Not available.
VOC content: 0 %; 0 g/l
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing.

Hazardous decomposition Oxides of carbon. Oxides of nitrogen. Aldehydes. Ammonia. Nitric acid. Phenolics. Toxic
products: fumes. Irritating vapors.

Incompatible materials: Acids. Bases. Oxidizing agents. Water. Peroxides. Sodium hypochlorite. Nitrous acid and
other nitrosating agents. CAUTION! N-nitrosamines (many of which are known to be potent
carcinogens) may be formed when the product comes in contact with nitrous acid, nitrites or
atmospheres with high nitrous oxide concentrations. This product slowly corrodes copper,
aluminum, zinc and galvanized surfaces.

Reactivity: Not available.

Conditions to avoid: Keep away from heat, ignition sources and incompatible materials.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

IDH number: 702267 Product name: LOCTITE PC 7222 known as Fixmaster Wear Resistant Putty
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 Potential Health Effects/Symptoms

Inhalation: May cause allergic respiratory reaction. Mists, vapors or liquid may cause severe irritation or
burns.
Skin contact: Causes skin burns. May cause allergic skin reaction.
Eye contact: Causes serious eye damage.
Ingestion: If ingested, severe burns of the mouth and throat may occur, as well as perforation of the
esophagus and the stomach.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Aluminium oxide None Irritant, Nuisance dust, Corrosive
Oral LD50 (Rat) Approximate 1,140 mg/kg
Diethylenetriamine Oral LD50 (Rat) = 1,080 mg/kg Allergen, Irritant, Eyes
Oral LD50 (Rat) = 2.33 g/kg
4-Nonylphenol, branched None Irritant, Corrosive
Oral LD50 (Rat) = > 22,500 mg/kg
Silicon dioxide Nuisance dust
Oral LD50 (Mouse) = > 15,000 mg/kg
Epoxy polyamine adduct None No Data
Oral LD50 (Rat) = 4,100 mg/kg
Oral LD50 (Rat) = 3,300 mg/kg
Allergen, Blood, Irritant, Kidney,
4,4'-Isopropylidenediphenol Oral LD50 (Mouse) = 5,280 mg/kg
Reproductive, Spleen
Oral LD50 (Mouse) = 2,500 mg/kg
Oral LD50 (Mouse) = 4,100 mg/kg
Allergen, Corrosive, Developmental, Irritant,
Triethylenetetramine None
Mutagen
Substituted Piperazine None Irritant, Corrosive, Allergen
Irritant, Respiratory, Some evidence of
Titanium dioxide None
carcinogenicity
Aluminum None Central nervous system, Irritant, Lung
Oral LD50 (Rat) = 1,600 mg/kg
Nonylphenol Allergen, Corrosive, Irritant, Kidney
Dermal LD50 (Rabbit) = 2,140 mg/kg
Oral LD50 (Rabbit) = 1,940 mg/kg
Oral LD50 (Rat) = 1,230 - 3,100 mg/kg
Allergen, Central nervous system, Corrosive,
Benzyl alcohol Oral LD50 (Mouse) = 1,580 mg/kg
Irritant
Oral LD50 (Rat) = 3,100 mg/kg
Dermal LD50 (Rabbit) = 2,000 mg/kg
Benzyldimethylamine None Irritant, Corrosive, Allergen, Respiratory

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Aluminium oxide No No No
Diethylenetriamine No No No
4-Nonylphenol, branched No No No
Silicon dioxide No No No
Epoxy polyamine adduct No No No
4,4'-Isopropylidenediphenol No No No
Triethylenetetramine No No No
Substituted Piperazine No No No
Titanium dioxide No Group 2B No
Aluminum No No No
Nonylphenol No No No
Benzyl alcohol No No No
Benzyldimethylamine No No No

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 702267 Product name: LOCTITE PC 7222 known as Fixmaster Wear Resistant Putty
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 13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: It is the responsibility of the user to determine if an item is hazardous as
defined in the Resource Conservation and Recovery Act (RCRA) at the time of
disposal. Product uses, transformations, mixtures, processes, etc., may
render the resulting material hazardous, under the criteria of ignitability,
corrosivity, reactivity and toxicity characteristics of the Toxicity Characteristics
Leaching Procedure (TCLP) 40 CFR 261.20-24.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Corrosive liquid, basic, organic, n.o.s. (Diethylenetriamine, Nonylphenol)
Hazard class or division: 8
Identification number: UN 3267
Packing group: III

International Air Transportation (ICAO/IATA)

Proper shipping name: Corrosive liquid, basic, organic, n.o.s. (Diethylenetriamine, Nonylphenol)
Hazard class or division: 8
Identification number: UN 3267
Packing group: III

Water Transportation (IMO/IMDG)

Proper shipping name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Diethylenetriamine,
Nonylphenol)
Hazard class or division: 8
Identification number: UN 3267
Packing group: III
Marine pollutant: Nonylphenol

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: Alkyl phenol (CAS# 84852-15-3).

CERCLA/SARA Section 302 EHS: None above reporting de minimis.

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Aluminium oxide (CAS# 1344-28-1). 4-Nonylphenol, branched (CAS# 84852-
15-3). 4,4'-Isopropylidenediphenol (CAS# 80-05-7). Nonylphenol (CAS# 25154-52-3).

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

IDH number: 702267 Product name: LOCTITE PC 7222 known as Fixmaster Wear Resistant Putty
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 16. OTHER INFORMATION
This safety data sheet contains changes from the previous version in sections: 9, 15

Prepared by: Rebecca Coons, Regulatory Affairs Specialist

Issue date: 10/06/2016

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 702267 Product name: LOCTITE PC 7222 known as Fixmaster Wear Resistant Putty
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