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Previous Date: 04/10/2018

SAFETY DATA SHEET

aqualead® MF CF3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or designation aqualead® MF CF3
of the mixture
Date of first issue 04/10/2018
Version number 1.1
Revision date 19/05/2020
Supersedes date 04/10/2018
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Closed system corrosion inhibitor
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
SUEZ Water Technologies & Solutions (UK) Limited
Partnership
Hydro House
Newcombe Way
Orton Southgate
Peterborough
PE2 6SE
Tel.: +44 (0)1733 385444, Fax : 01733 391775
e-mail : [email protected]

1.4. Emergency telephone number

Multilingual emergency number (24/7)

Europe, Middle East, Africa, Israel (Europe and English

language speaking countries):
+44(0)1235 239670
Middle East & Africa (speaking Arabic):
+44(0)1235 239671

National Poisons Information Centre

NHS Direct on 111
Or a doctor

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 as amended
Physical hazards
Corrosive to metals Category 1 H290 - May be corrosive to metals.
Health hazards
Skin corrosion/irritation Category 1 H314 - Causes severe skin burns
and eye damage.
Serious eye damage/eye irritation Category 1 H318 - Causes serious eye
damage.
Skin sensitisation Category 1 H317 - May cause an allergic skin
reaction.
2.2. Label elements

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aqualead® MF CF3
Label according to Regulation (EC) No. 1272/2008 as amended
Contains: Hydroxyphosphono Acetic Acid, Sodium Salt, Sodium 4(or 5)-methyl-1H-benzotriazolide, Sodium
hydroxide
Hazard pictograms

Signal word Danger

Hazard statements
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
Precautionary statements
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTRE/doctor.
Storage
P406 Store in a corrosion resistant container with a resistant inner liner.
Disposal Not available.
Supplemental label information None.
2.3. Other hazards The classification as corrosive is due to the extreme pH.

SECTION 3: Composition/information on ingredients

Mixtures
Chemical description Aqueous alkaline solution of organic and inorganic salts
Chemical name % CAS-No. / EC REACH Registration No. Index No. Notes
No.

Hydroxyphosphono Acetic Acid, 1-<3 78620-07-2 - -

Sodium Salt -
Classification: Acute Tox. 4;H302, Skin Sens. 1;H317

Sodium 4(or 1-<3 64665-57-2 - -

5)-methyl-1H-benzotriazolide 265-004-9
Classification: Acute Tox. 4;H302, Skin Corr. 1B;H314, Aquatic Chronic 2;H411

Sodium hydroxide <1 1310-73-2 01-2119457892-27 011-002-00-6

215-185-5
Classification: Met. Corr. 1;H290, Skin Corr. 1A;H314

The classification of the above substance(s) is given, including the hazard class, category code and hazard statements which are
assigned in accordance with their physicochemical, health and environmental hazards. Please refer to section 16 where the full text of
each relevant H-statement is listed.

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a physician if symptoms develop or persist.

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Skin contact Take off immediately all contaminated clothing.
Wash off immediately with plenty of water for at least 15 minutes.
Get medical attention immediately.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention immediately.
Ingestion Rinse mouth.
Do not induce vomiting.
Do not give anything to eat or drink.
Call a physician or poison control centre immediately.
4.2. Most important symptoms Corrosive effects.
and effects, both acute and May cause an allergic skin reaction.
delayed
4.3. Indication of any Not available.
immediate medical attention
and special treatment needed

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing Dry chemical, CO2, water spray or alcohol resistant foam.
media
Unsuitable extinguishing None.
media
5.2. Special hazards arising During fire, gases hazardous to health may be formed.
from the substance or mixture
5.3. Advice for firefighters
Special protective Self contained breathing apparatus. (CEN : EN 137)
equipment for firefighters Protective clothing (CEN : EN 469)
Protective gloves (CEN : EN 659)
Helmet (CEN : EN 443)
Special fire fighting Use standard firefighting procedures and consider the hazards of other involved materials.
procedures Prevent spillage and fire-fighting water from entering in public sewers or the immediate
environment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Wear protective clothing, gloves and safety goggles.
personnel
For emergency responders Use personal protection recommended in Section 8 of the SDS.
6.2. Environmental precautions Prevent from entering sewers or the immediate environment.
6.3. Methods and material for Absorb onto inert material and dispose of according to Hazardous Waste Regulations.
containment and cleaning up After cleaning, flush away traces with water.
6.4. Reference to other Please refer also to section no. 8 'Exposure controls' for further information.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe Observe good industrial hygiene practices.
handling Avoid contact with eyes, skin, and clothing.
7.2. Conditions for safe Keep containers tightly closed in a dry, cool and well-ventilated place.
storage, including any Store in corrosive resistant container with a resistant inner liner.
incompatibilities
7.3. Specific end use(s) Only for professional and industrial users
Shelf life 480 Days

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

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Occupational exposure limits
UK. EH40 Workplace Exposure Limits (WELs)
Components Type Value
Sodium hydroxide (CAS STEL 2 mg/m3
1310-73-2)
Sodium molybdate (CAS STEL 10 mg/m3
7631-95-0)
TWA 5 mg/m3
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Not available.
procedures
Derived no effect levels (DNELs)
Workers
Components Value Assessment factor Notes
Sodium hydroxide (CAS 1310-73-2)
Long-term, Local, Inhalation 1 mg/m3 1
Short-term, Local, Dermal 2 mg/kg/day
Short-term, Local, Inhalation 2 mg/m3
Predicted no effect Not available.
concentrations (PNECs)
8.2. Exposure controls
Appropriate engineering Adequate ventilation to maintain air contaminants below exposure limits.
controls Eye wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Splash proof chemical goggles.
Face shield.
CEN : EN 166
Skin protection
- Hand protection Gauntlet type neoprene gloves (Protection against unintentional short-term contact)
Gauntlet type nitrile gloves (Protection against unintentional short-term contact)
Penetration time: 480 min
Coating thickness: > 0.5 mm
CEN : EN 374-1/2/3/4; EN 420
- Other Chemical resistant apron.
CEN : EN ISO 13688; EN ISO 6530; EN ISO 6529; EN 14605
Respiratory protection In case of insufficient ventilation, use a breathing mask with filter type: P2
CEN : EN 140; EN 143; EN 149
Thermal hazards Not available.
Environmental exposure Prevent from entering in public sewers or the immediate environment.
controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Colour Amber
Physical state Liquid
Odour Characteristic
Odour threshold Not available.
pH (concentrated product) 12,5 Neat
pH in aqueous solution Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point Not applicable
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Evaporation rate Slower than Ether
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Vapour pressure 18 mmHg
Vapour pressure temp. 21 °C
Vapour density <1
Relative density 1,09
Relative density temperature 21 °C
Solubility
Solubility (water) 100 %
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not applicable.
Decomposition temperature Not available.
Viscosity Not applicable.
Explosive properties Not available.
Oxidising properties Not available.
9.2. Other information
Shelf life 480 Days
VOC 0 % Estimated

SECTION 10: Stability and reactivity

10.1. Reactivity Not available.
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous Not applicable.
reactions
10.4. Conditions to avoid None under normal conditions.
10.5. Incompatible materials None known.
10.6. Hazardous No hazardous decomposition products are known.
decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Product Test Results
aqualead® MF CF3 (Mixture) Acute Dermal LD50 Rabbit: > 5000 mg/kg (Calculated
according to GHS additivity formula)
Acute Oral LD50 Rat: > 5000 mg/kg (Calculated according
to GHS additivity formula)
Components Test Results
Sodium hydroxide (1310-73-2) Acute Dermal LD50 Rabbit: 1350 mg/kg
Acute Oral LD50 Rabbit: > 500 mg/kg
Sodium 4(or 5)-methyl-1H-benzotriazolide (64665-57-2) Acute Dermal LD50 Rabbit: > 2000 mg/kg
Acute Oral LD50 Rat: 735 mg/kg
Hydroxyphosphono Acetic Acid, Sodium Salt (78620-07-2) Acute Oral LD50 Rat: 1260 mg/kg
Acute toxicity Based on available data, the classification criteria are not met.
Skin corrosion/irritation Causes severe skin burns and eye damage.
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Serious eye Causes serious eye damage.
damage/irritation
Respiratory or skin May cause an allergic skin reaction.
sensitisation
Specific target organ toxicity - Based on available data, the classification criteria are not met.
repeated exposure
Specific target organ toxicity - Based on available data, the classification criteria are not met.
single exposure
Carcinogenicity Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
Information on likely routes of exposure
Ingestion Causes digestive tract burns.
Inhalation Prolonged or excessive inhalation may cause respiratory tract irritation.
Skin contact Causes severe skin burns.
May cause an allergic skin reaction.
Eye contact Causes serious eye damage.
Symptoms Not available.
Aspiration hazard Based on available data, the classification criteria are not met.
Mixture versus substance None known.
information
Other information Not available.

SECTION 12: Ecological information

12.1. Toxicity No data available
12.2. Persistence and degradability
No data is available on the degradability of this product.
12.3. Bioaccumulative potential Not available.
Partition coefficient Not available.
n-octanol/water (log Kow)
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil Not available.
12.5. Results of PBT and vPvB Not a PBT or vPvB substance or mixture.
assessment
12.6. Other adverse effects Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Contaminated packaging According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 15 01 10

15 Waste packaging; absorbents, wiping cloths, filter materials and protective clothing not
otherwise specified.
15 01 Packaging (including separately collected municipal packaging waste).
15 01 10 Packaging containing residues of or contaminated by dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.
Disposal methods/information According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 16 03 05

16 Wastes not otherwise specified in the list.
16 03 Off-specification batches and unused products.
16 03 05 Organic wastes containing dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.

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SECTION 14: Transport information
ADR
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Sodium hydroxide, Sodium 4(or 5)-methyl-1H-benzotriazolide, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
Tunnel restriction code (E)
14.4. Packing group II
14.5. Environmental hazards No.
14.6. Special precautions Not available.
for user
RID
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Sodium hydroxide, Sodium 4(or 5)-methyl-1H-benzotriazolide, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
14.4. Packing group II
14.5. Environmental hazards No.
14.6. Special precautions Not available.
for user
ADN
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Sodium hydroxide, Sodium 4(or 5)-methyl-1H-benzotriazolide, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
14.4. Packing group II
14.5. Environmental hazards No.
14.6. Special precautions Not available.
for user
IATA
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Sodium hydroxide, Sodium 4(or 5)-methyl-1H-benzotriazolide, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
14.4. Packing group II
14.5. Environmental hazards No.
ERG Code Not available.
14.6. Special precautions Not available.
for user
IMDG
14.1. UN number UN1760
14.2. UN proper shipping Corrosive liquid, n.o.s. (Sodium hydroxide, Sodium 4(or 5)-methyl-1H-benzotriazolide, Mixture)
name
14.3. Transport hazard class(es)
Class 8
Subsidiary risk -
14.4. Packing group II
14.5. Environmental hazards
Marine pollutant No.
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EmS F-A, S-B

14.6. Special precautions Not available.
for user
14.7. Transport in bulk This substance/mixture is not intended to be transported in bulk.
according to Annex II of
MARPOL and the IBC Code
ADN; ADR; IATA; IMDG; RID

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed.
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at
work, as amended.
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Not listed.
National regulations Not available.
15.2. Chemical safety Not available.
assessment

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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

SECTION 16: Other information

List of abbreviations
CAS: Chemical Abstract Service.
EC-No: European Commission Number
CLP: Classification, Labeling and Packaging REGULATION (EC) No 1272/2008 on classification,
labeling and packaging of substances and mixtures.
CEN: European Committee for Standardization (Comité Européen de Normalisation).
TWA: Time Weighted Average.
STEL: Short-term Exposure Limit.
LD50: Lethal Dose 50%.
LC50: Lethal Concentration 50%.
EC50: Effective Concentration 50%.
NOEL: No observed effect level.
COD: Chemical Oxygen Demand
BOD: Biochemical oxygen demand.
TOC: Total Organic Carbon.
ADR: European agreement concerning the international carriage of dangerous goods by road
(Accord européen relatif transport des merchandises dangereuses par route).
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways (Accord européen relatif au transport international des marchandises dangereuses
par voies de navigation intérieures).
IATA: International Air Transport Association
IMDG Code: International Maritime Dangerous Goods Code.
RID: Regulations concerning the international carriage of dangerous goods by rail (Règlement
International concernant le transport de marchandises dangereuses par chemin de fer).
References Safety data sheets of raw materials.
Information on evaluation The physical, health and environmental hazards of this mixture are assessed by applying the
method leading to the classification criteria for each hazard class or differentiation in Parts 2 to 5 of Annex I to Regulation
classification of mixture (EC) No 1272/2008 (CLP).
Full text of any H-statements
not written out in full under
Sections 2 to 15 H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
Revision information Product and Company Identification: Alternate Name/Document Information
Composition / Information on Ingredients: Disclosure Overrides
SECTION 8: Exposure controls/personal protection: Appropriate engineering controls
SECTION 8: Exposure controls/personal protection: - Hand protection
SECTION 16: Other information: Further information
Training information Provide training on safe handling while considering the type of application and exposure scenarios.
Based on EC Directive / (EC) No 1907/2006 (REACH)
Regulations (EC) No 1272/2008
(EU) No 1357/2014
(EU) 2015/830

Further information Correction in Section: 3,8,16

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