CAPA Polycaprolactones

CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

Chemical: CAPA® Polycaprolactones NFPA: H=0 F=1 I= 0 S=none

HMIS: H=0 F=1 R=0 PPE= Supplied by user;
dependent on conditions
MSDS Number: CAPA 6500
0307
Effective Date: 21 March 2007
Issued by: Solvay Chemicals, Inc. Regulatory Affairs Department
Perstorp Polyols, Inc. 
600 Matzinger Road 
Not valid three years after effective date or after issuance of superseding MSDS, whichever is
Toledo, Ohio  43612
earlier. French or Spanish translations of this MSDS may be available. Check www.solvaychemicals.us
(419) 729‐5448
or call Solvay Chemicals, Inc. to verify the latest version or translation availability.
Material Safety Data Sheets contain country
specific regulatory information. Therefore, the MSDS’s
Perstorp Polyols, Inc.
provided are for use only by customers of Solvay Chemicals, Inc. in North America. If you are located in
Perstorp
a country other than Canada, Mexico or the United States, please contact the Solvay Group company
in your country for MSDS information applicable to your location.

1. Company and Product Identification

1.1 Product Name: CAPA® 6100, 6106S, 6109S, 6250, 6400 (fka 640), 6406 (fka 646),
6430, 6500 (fka 650), 6500C (fka 651), 6501, 6501S, 6502S, 6503,
6505 (fka 655), 6506 (fka 656), 6506S, 6800 (fka 680), and 6806 (fka 686).
Chemical Name: 2
Oxepanone, homopolymer
Synonyms: epsilon
Caprolactone polyester with 1,4
butanediol
epsilon
Caprolactone polymer with 1,4
butanediol
®

Chemical Formula: (C6H10O2)x

Molecular Weight: CAPA® 6100, 6106S, 6109S: 10000
CAPA® 6250: 25000
CAPA® 6400 (640), 6406 (646): 37000
CAPA® 6500 (650), 6500C (651), 6501, 6501S, 6502S,6503, 6505 (655),
6506 (656), 6506S: 50000
CAPA® 6800 (680), 6806 (686): 80000
CAPA® 6430: 43000
CAS Number: 24980
41
4
EINECS Number: Not Applicable.
1.2 Recommended Uses: Used in hot melt adhesives, polymer processing aids, dispersion
medium, and orthopedic applications.
1.3 Supplier: Solvay Chemicals, Inc.
Perstorp Polyols, Inc. 
PO BOX 27328 Houston, TX 77227
7328
600 Matzinger Road 
3333 Richmond Ave. Houston, Texas 77098
Toledo, Ohio  43612
(419) 729‐5448

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 1/9 www.solvaychemicals.us 1.800.765.8292
CAPA Polycaprolactones
CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

1.4 Emergency Telephone Numbers

Emergencies (USA): 1
800
424
9300 (CHEMTREC®)
Transportation Emergencies (INTERNATIONAL/MARITIME): 1
703
527
3887 (CHEMTREC®)
Transportation Emergencies (CANADA): 1
613
996
6666 (CANUTEC)
Transportation Emergencies (MEXICO
SETIQ): 01
800
00
214
00 (MEX. REPUBLIC)
525
559
1588 (Mexico City and metro area)

2. Composition/Information on Ingredients
INGREDIENTS FORMULA WT. PERCENT CAS #
2
Oxepanone homopolymer (C6H10O2)x > 99 24980
41
4

3. Hazards Identification
Emergency Overview: Under normal use conditions, this material is considered to present
minimal human health and environmental hazards.
3.1 Route of Entry: Inhalation: Yes Skin: Yes Ingestion: Yes
3.2 Potential Effects of exposure:
Inhalation: Dust particles may require cleaning of nasal passages.
Eyes: Mechanical irritation from particulates generated by product.
Skin contact: Decomposition gases may be irritating to the skin.
Ingestion: Minimal hazard expected in normal industrial use.
®

Carcinogenicity: See section 11.3.

4. First
Aid Measures
General Recommendations: No specific treatment is necessary.
4.1 Inhalation:
• Clear nasal passages of dust and particulates.
• If exposed to excessive levels of decomposition products, remove to fresh air and get
medical attention if cough or other symptoms develop.
Eyes:
• Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes.
• Get medical attention if symptoms develop.
Skin:
• Remove contaminated clothing.
• Wash skin with soap and water. Get medical attention if symptoms develop.
• Molten polymer can burn skin.
Ingestion: If subject is completely conscious, rinse mouth and administer fresh water.
4.2 Medical Treatment/Notes to Physician: None.

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 2/9 www.solvaychemicals.us 1.800.765.8292
CAPA Polycaprolactones
CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

5. Fire
Fighting Measures
5.1 Flash point:
• CAPA® 6100, 6106S, 6109S, 6250, 6400 (640), 6406 (646), 6430, 6500 (650), 6500C (651),
6501, 6501S, 6502S, 65003 6505 (655), 6506 (656), 6506S: 527°F (275°C).
• CAPA® 6800 (680) and 6806 (686): No data.
5.2 Auto
ignition Temperature: No data.
5.3 Flammability Limits: Combustible.
5.4 Unusual Fire and Explosion Hazards: Dust explosion possible.
5.5 Common Extinguishing Methods:
• Powder.
• Foam, AFFF.
• CO2.
• Water, water spray.
Inappropriate extinguishing means: No restriction.
5.6 Fire Fighting Procedures
Specific hazards: Formation of dangerous gas/vapors in case of decomposition (see Section 10).
Possible buildup of electrical charges which could cause a fire by electrical discharge.
Protective measures in case of intervention:
• Evacuate all non
essential personnel.
®

• Intervention only by capable personnel who are trained and aware of the hazards of the
product.
• Wear self
contained breathing apparatus when in close proximity or in confined spaces.
Other precautions:
• If safe to do so, remove exposed containers, or cool with large quantities of water.
• As with any fire, clean and ventilate room before reentry.

6. Accidental Release Measures

6.1 Precautions:
• Observe the protective measures given in Section 8.
• Spilled material may cause slipping hazard.
6.2 Cleanup methods:
Solid:
• Collect the product with suitable means avoiding dust formation.
• Place material into a closed, labeled container compatible with the product.
• Place the container in a safe and isolated place.
• For disposal methods, refer to Section 13.

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 3/9 www.solvaychemicals.us 1.800.765.8292
CAPA Polycaprolactones
CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

Molten Solid:
• If possible dam large quantities of molten solid with sand or earth and allow to solidify.
• Place into a closed, labeled container compatible with the product.
• Place the container in a safe and isolated place.
• For disposal methods, refer to Section 13.
• Clean the spill area with large quantities of water.
6.3 Precautions for protection of the environment:
• Avoid discharges into the environment (sewers, rivers, soils, etc.) and take any measure
required by applicable federal, state and local laws.
• Immediately notify the appropriate authorities in case of significant discharge or if required by
applicable federal, state or local laws.

7. Handling and Storage

7.1 Handling:
• Use electrically conductive materials for piping circuits and equipment.
• Avoid heating product above decomposition temperature (see Section 9).
7.2 Storage:
• Keep in the original packaging, closed.
• Store in dry area.
• Keep away from ignition and heat sources.
7.3 Specific Uses: See Section 1.2.
®

7.4 Other precautions:

• Use grounded equipment.
• No open flames or sparks. No smoking.
• Prevent electrostatic discharge.
• Avoid dust and formation of dust clouds.
• Warn personnel of the dangers of the product.
• Follow protective measures given in Section 9.
7.5 Packaging:
• Paper bags.
• Polypropylene sacks.

8. Exposure Controls/Personal Protection

This material does not have established exposure limits.
8.1 Exposure Limit Values
Authorized limit Values OSHA PEL
PNOC (Particulates not 15 mg/m3
total dust
otherwise classified) 5 mg/m3
resp. frac.

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 4/9 www.solvaychemicals.us 1.800.765.8292
CAPA Polycaprolactones
CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

8.2 Exposure Controls:

8.2.1 Occupational Exposure Controls:
8.2.1.1 Ventilation: Provide local ventilation suitable for the emission risk (see Section 9).
8.2.1.2 Respiratory protection: Use appropriate respiratory protection in case of dust
or dust formation.
8.2.1.3 Hand protection: Where contact is likely, wear chemical
resistant gloves (PVC).
8.2.1.4 Eye protection:
• Wear safety glasses with side shields.
• Wear chemical splash goggles and face shield, if risk of splashing.
8.2.1.5 Skin protection:
• Where contact is likely, wear chemical
resistant gloves, a chemical suit and boots.
• Recommended materials are PVC, neoprene or rubber.
• Wear appropriate thermal protection when handling hot material.
• Wear chemical protective clothing in dusty areas.
8.3 Other precautions:
• Provide a shower and eyewash station.
• Consult your industrial hygienist or safety manager for the selection of personal
protective equipment suitable for the working conditions.

9. Physical and Chemical Properties

®

9.1 Appearance:
• CAPA® 6100, 6400 (640), 6430, 6500 (650), 6500C (651), 6800 (680): pellets.
• CAPA® 6106S, 6109S, 6406 (646), 6501, 6501S, 6502S, 6503, 6505 (655), 6506 (656), 6506S,
6806 (686): powder.
• CAPA® 6100, 6250: solid.
Color: White.
Odor: Odorless.
9.2 Important Health, Safety and Environmental information:
pH: Not applicable.
Change of state:
Melting point: 136
140°F (58
60°C).
Boiling point: Not determined.
Decomposition Temperature: 392°F (200°C).
Flash Point:
• CAPA® 6100, 6106S, 6109S, 6250, 6400 (640), 6406 (646), 6430, 6500 (650), 6501,
6501S, 6502S, 6500C (651), 6505 (655), 6506 (656), 6506S: 527°F (275°C).
• CAPA® 6800 (680) and 6806 (686): No data.
Flammability: Non
flammable.

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 5/9 www.solvaychemicals.us 1.800.765.8292
CAPA Polycaprolactones
CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

Explosive Properties: Dust explosion possible.

Oxidizing Properties: Non
oxidizer.
Vapor Pressure: No data.
Relative Density:
Specific gravity (H2O=1): • CAPA® 6100, 6106S, 6109S, 6250, 6400 (640), 6406 (646), 6430,
6500 (650), 6500C (651), 6501, 6501S, 6502S, 6503, 6505 (655),
6506 (656), 6506S: 1.10 @ melting point.
• CAPA® 6800 (680), 6806 (686): No data.
Solubility:
Water: Insoluble in water.
Fat: Not Applicable.
Soluble in aromatic solvents and chlorinated hydrocarbons.
Partition coefficient: P (n
octanol/water): Not determined.
Viscosity:
• CAPA® 6100, 6106S, 6109S: 9300 mPa.s @ 212°F (100°C).
• CAPA® 6400 (640), 6406 (646): 315000 mPa .s @ 212°F (100°C).
• CAPA® 6250, 6500 (650), 6500C (651), 6501, 6501S, 6502S, 6505 (655), 6506 (656), 6506S:
1.5 million mPa.s @ 212°F (100°C).
• CAPA® 6800 (680), 6806 (686): 8 million mPa .s @ 212°F (100°C).
• CAPA® 6430: 1000 mPa .s @ 212°F (100°C).
• CAPA® 6501, 6503: 80 mPa .s @ 212°F (100°C).
®

Vapor Density (air=1): Not determined.

Evaporation Rate: Not Applicable.
9.3 Other Information: None.

10. Stability and Reactivity

Stability:
• Stable under normal conditions of use (see Section 7).
• Moisture.
• Excessive temperatures.
10.2 Materials and substances to avoid:
• Acids.
• Alkalis.
10.3 Hazardous decomposition products:
• Carbon monoxide and carbon dioxide when involved in a fire.
• Particulates of carbon.
• Caprolactone / monomer.
10.4 Hazardous Polymerization: Will not occur.
10.5 Other information: None.

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 6/9 www.solvaychemicals.us 1.800.765.8292
CAPA Polycaprolactones
CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

11. Toxicological Information

11.1 Acute toxicity:
Inhalation: No data.
Oral: No data.
Dermal: No data.
Irritation: No data.
Sensitization: No data.
Comments: None.
11.2 Chronic toxicity: No data.
11.3 Carcinogenic Designation: Not listed.

12. Ecological Information

12.1 Acute ecotoxicity: No data.
12.2 Chronic ecotoxicity: No data.
12.3 Mobility: No data.
12.4 Degradation: No data.
Abiotic: No data.
®

Biotic: No data.
12.5 Potential for bioaccumulation: No data.
12.6 Other adverse effects/Comments: Ingestion of pellets by wildlife and fish may cause
satiation (fullness) or bowel constriction. Consult the Society of the Plastics Industry’s Clean
Sweep Program to assure minimal impact to the environment.

13. Disposal Considerations

13.1 Waste treatment: CAPA® 6100, 6106S, 6502S, 6109S, 6250, 6400 (640), 6406 (646),
6430, 6500 (650), 6500C (651), 6501, 6501S, 6502S, 6503, 6505 (655), 6506 (656), 6506S,
6800 (680), and 6806 (686) are not considered hazardous waste under Federal Hazardous
Waste Regulations (40 CFR 261). Please be advised, however, that federal laws may change
and that state and local requirements for waste disposal may be more restrictive or otherwise
different from federal regulations. Consult current federal, state and local regulations regarding
the proper disposal of this material and its emptied containers.
13.2 Packaging treatment: Consult current federal, state and local regulations regarding
the proper disposal of emptied containers.
13.3 RCRA Hazardous Waste: Not listed.

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 7/9 www.solvaychemicals.us 1.800.765.8292
CAPA Polycaprolactones
CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

14. Transport Information

Mode DOT IMDG IATA
UN Number Not a regulated Not a regulated Not a regulated
hazardous material hazardous material hazardous material
Other It is recommended that ERG Guide # 111 be used for all non
DOT
regulated material.

15. Regulatory Information

National Regulations (US)
TSCA Inventory 8(b): Yes.
SARA Title III Sec. 302/303 Extremely Hazardous Substances (40 CFR 355): No.
SARA Title III Sec. 311/312 (40 CFR 370): No.
SARA Title III Sec. 313 Toxic Chemical Emissions Reporting (40 CFR 372): No.
CERCLA Hazardous Substance (40 CFR Part 302)
Listed: No.
Unlisted Substance: No.
State Component Listing:
State Comment: None identified.
®

National Regulations (Canada)

Canadian DSL Registration: Yes # 11183.
WHMIS Classification: Not a controlled product.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations, and the
MSDS contains all the information required by the Controlled Products Regulations.

16. Other Information

16.1 Ratings:
NFPA (NATIONAL FIRE PROTECTION ASSOCIATION)
Health = 0 Flammability = 1 Instability = 0 Special = None
HMIS (HAZARDOUS MATERIAL INFORMATION SYSTEM)
Health = 0 Fire = 1 Reactivity = 0 PPE = Supplied by User; dependent on local conditions
16.2 Other Information:
The previous information is based upon our current knowledge and experience of our product and
is not exhaustive. It applies to the product as defined by the specifications. In case of combinations
or mixtures, one must confirm that no new hazards are likely to exist. In any case, the user is not
exempt from observing all legal, administrative and regulatory procedures relating to the product,
personal hygiene, and integrity of the work environment. (Unless noted to the contrary, the technical
information applies only to pure product).

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 8/9 www.solvaychemicals.us 1.800.765.8292
CAPA Polycaprolactones
CAPA® 6100, 6106S, 6109S, 6250, 6400, 6406, 6430, 6500, 6500C,
6501, 6501S, 6502S, 6503, 6505, 6506, 6506S, 6800, and 6806
Material Safety Data Sheet

To our actual knowledge, the information contained herein is accurate as of the date of this
Perstorp Polyols, Inc.
document. However, neither Solvay Chemicals, Inc. nor any of its affiliates makes any warranty,
express or implied, or accepts any liability in connection with this information or its use. This
information is for use by technically skilled persons at their own discretion and risk and does not
relate to the use of this product in combination with any other substance or any other process.
This is not a license under any patent or other proprietary right. The user alone must finally
determine suitability of any information or material for any contemplated use, the manner of use
and whether any patents are infringed. This information gives typical properties only and is not
to be used for specification purposes. SolvayPerstorp Polyols
Chemicals, Inc. reserves the right to make
additions, deletions or modifications to the information at any time without prior notification.
Suitability of Caprolactone Resins in Medical Applications: Solvay Perstorp Polyols
Chemicals, Inc. does not claim
Perstorp Polyols
suitability of caprolactone products for any specific medical applications. Solvay Chemicals will
not knowingly sell (unless so specified in a written contractual agreement) into medical applications
involving long term contact with internal bodily fluids, cardiac prosthetic devices, critical components
Perstorp
sustaining human life, or involving human reproduction and pregnancy. In addition, Solvay Chemicals
reserves the right at any time in its sole discretion not to sell into other medical applications not
listed above.
Prior to purchasing Solvay Chemicals caprolactone products for use in any of the above medical
applications, customers will be required to sign appropriate documentation agreeing to accept full
responsibility for, and indemnify Solvay Chemicals against, any and all liability associated with the
use of such products in such medical applications.
In all instances, it is the responsibility of the medical device or pharmaceutical manufacturer to
determine that the Solvay Chemicals product is safe, lawful and technically suitable for the intend

®

ed use. SOLVAY CHEMICALS MAKES NO WARRANTIES, EXPRESS OR IMPLIED, CONCERNING

THE SUITABILITY OF ANY SOLVAY CHEMICALS PRODUCT FOR USE IN MEDICAL APPLICATIONS.
Trademarks and/or other Solvay Chemicals, Inc. products referenced herein are either trademarks
or registered trademarks of Solvay Chemicals, Inc. or its affiliates, unless otherwise indicated.
16.3 Reason for revision:
Supersedes edition: Solvay Chemicals, Inc. MSDS# CAPA
6500
0805 dated 08/20/05
Purpose of revision: Add CAPA® 6502S.

MSDS No. CAPA 6500
0307 Revised 03
21
07

Copyright 2007, Solvay Chemicals, Inc.
All Rights Reserved.
Page 9/9 www.solvaychemicals.us 1.800.765.8292