Material Safety Data Sheet
Revision Date: 04/10/2007 Issue date: 04/10/2007
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Kit Number: AS9354000
Product name: Hysol EA9309.3 NA Part B Bulk Item No. : AB9354000
Product type: Adhesive for the Aerospace Industry Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 925.458.8000 Fax : 925.458.8030.
2850 Willow Pass Road Emergency Telephone: 860.571.5100.
Bay Point, California 94565 Internet www.aerospace.henkel.us
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Diethylene glycol Di-(3- 60-100 None None None
aminopropyl)ether
4246-51-9
Substituted Piperazine 10-30 None None None
Proprietary
Diethylene triamine 1-5 1 ppm TWA None None
111-40-0 (skin)
Phenol 0.1-1 5 ppm TWA 19 mg/m³ TWA None
108-95-2 (skin) 5 ppm TWA
(skin)
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Gel HEALTH: 2
Color: Blue FLAMMABILITY: 1
Odor: Ammoniacal PHYSICAL HAZARD: 1
Personal Protection: See Section 8
DANGER: CAUSES EYE AND SKIN BURNS.
CAUSES RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY BE HARMFUL IF SWALLOWED OR ABSORBED THROUGH SKIN.
Relevant routes of exposure: Skin, Inhalation, Eyes
Potential Health Effects
Inhalation: Respiratory tract burns.
Skin contact: May cause skin burns. Repeated or prolonged skin contact may result in allergic sensitization.
Eye contact: Severe eye irritation. Possible burns to eyes.
Ingestion: Not expected under normal conditions of use. May be harmful if swallowed. Aspiration may occur
during swallowing or vomiting, resulting in lung damage.
Existing conditions aggravated by Eye, skin, and respiratory disorders.
exposure:
Item No. : AB9354000 Product name: Hysol EA9309.3 NA Part B Bulk
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See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If discomfort persists seek medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Get medical attention if symptoms occur.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion: Drink water as a precaution. Get medical attention immediately.
Notes to physician: Treat symptomatically and supportively. This material is an aspiration hazard. Potential danger from
aspiration must be weighed against possible oral toxicity when deciding whether to induce vomiting.
5. FIRE-FIGHTING MEASURES
Flash point: Greater than 93ºC (200ºF) (estimated)
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not determined
Flammable/Explosive limits-upper %: Not determined
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Cartridge
respirators do not provide adequate protection for fire fighters or exotherm mitigation.
Unusual fire or explosion hazards: May liberate large quantities of dense, foul-smelling smoke which may contain unidentified toxic
gasses.
Hazardous combustion products: Oxides of carbon and nitrogen, aldehydes, acids and undetermined organics.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: No information available Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Clean-up methods: Wear protective clothing, gloves and safety glasses. Soak up with inert absorbent. Store in a closed
container until ready for disposal.
7. HANDLING AND STORAGE
Handling: For the Part A plus Part B adhesive mixture, follow curing schedule as recommended in product
literature. Do not heat Part B at temperatures greater than 100 ºC (212 ºF). This material may self-
react at higher temperatures and cause an exotherm. The exotherm has the potential for release of
excessive energy and toxic gasses. Empty containers retain product residue, so obey hazard warnings
and handle empty containers as if they were full. Do not cut, grind, weld, or drill on or near this
container.
Storage: For safe storage, store at or below 25°C (77°F). Keep container closed.
Incompatible products: Keep away from strong oxidizing agents, strong Lewis or mineral acids.
For information on product shelf life, please review labels on container or check the Technical Data Sheet.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Item No. : AB9354000 Product name: Hysol EA9309.3 NA Part B Bulk
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Engineering controls: Use local ventilation if general ventilation is insufficient to maintain vapor concentration below
established exposure limits.
Respiratory protection: When workplace hazards warrant the use of a respirator, appropriate respirators must be used. Use a
NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists.
Observe OSHA regulations for respiratory use (29 CFR 1910.134).
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to
prevent skin contact.
Eye/face protection: Wear appropriate goggles, face shields or other PPE which will be effective under the circumstances if
the possibility of contact exists.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Gel
Color: Blue
Odor: Ammoniacal
Vapor pressure: Not determined
pH: Not determined
Boiling point/range: Not determined
Melting point/range: Not determined
Specific gravity: 1.0
Vapor density: 8.45
Evaporation rate: Not determined
Solubility in water: Negligible.
Partition coefficient (n-octanol/water): Not determined
VOC content: <10 g/l (estimate) per SCAQMD Rule 1124 [EPA Test Method 24/304-91]
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: May occur.
Hazardous decomposition products: Oxides of carbon and nitrogen, aldehydes, acids and undetermined organics.
Incompatability: Keep away from strong oxidizing agents, strong Lewis or mineral acids.
Conditions to avoid: Failure to observe these precautions may result in excessive heat build-up causing an exotherm. The
exotherm has the potential for release of toxic gasses. Avoid mixing resin (Part A) and curing agent
(Part B) in batches greater than 1 pound(s) (.454 kg) unless you plan to use immediately. Do not heat
mixed adhesive above 24ºC (75ºF) unless curing surfaces to be bonded.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Diethylene glycol Di-(3- No No No
aminopropyl)ether
4246-51-9
Substituted Piperazine No No No
Proprietary
Diethylene triamine No No No
111-40-0
Phenol No No No
108-95-2
Literature Referenced Target Organ & Other Health Effects
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Hazardous components Health Effects/Target Organs
Diethylene glycol Di-(3- Corrosive
aminopropyl)ether
4246-51-9
Substituted Piperazine Irritant, Corrosive, Allergen
Proprietary
Diethylene triamine Allergen, Eyes, Irritant
111-40-0
Phenol Blood, Cardiac, Corrosive, Developmental, Eyes, Irritant, Kidney, Liver, Mutagen, Nervous System, Skin,
108-95-2 Vascular
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Legal disposition of wastes is the responsibility of the owner/generator of the waste. Applicable
federal, state and/or local regulations must be followed during treatment, storage, or disposal of waste
containing this product.
EPA hazardous waste number: U188: Phenol
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Amines, liquid, corrosive, n.o.s. ( Diethyleneglycol diaminopropyl ether / Substituted Piperazine )
Hazard class or division: 8
Identification number: UN 2735
Packing group: II
DOT reportable quantity (lbs): Phenol is reportable at 1000 pounds (454 kg).
International Air Transportation (ICAO/IATA):
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. ( Diethyleneglycol diaminopropyl ether / Subsitiuted
Piperazine )
Hazard class or division: 8
Identification number: UN 2735
Packing group: II
WaterTransportation (IMO/IMDG):
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. ( Diethyleneglycol diaminopropyl ether / Substituted
Piperazine )
Hazard class or division: 8
Identification number: UN 2735
Packing group: II
Marine pollutant: None
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15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Not evaluated , Immediate Health Hazard, Delayed Health Hazard
CERCLA/SARA 313: Phenol (CAS# 108-95-2) .
California Proposition 65: No California Proposition 65 listed chemicals are known to be present.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: D.2.B, E
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: First issue.
Prepared by: C.J. Michaels, Manager, Regulatory Affairs
For Safety and Regulatory Information contact:
Product Safety and Regulatory Affairs,
Rocky Hill, CT.
860-571-5204
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
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