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Alkyl Halides 2nd Year Chapter10

This document contains questions from the topic of Alkyl Halides from the Chemistry chapter 10 for class 2nd year. There are multiple choice questions testing the understanding of key concepts like reactivity order of alkyl halides, mechanisms of substitution and elimination reactions, properties of primary, secondary and tertiary alkyl halides. Short answer questions define alkyl halides and important terms, ask for IUPAC names, drawing structures and explaining preparation methods. Extensive questions require explaining the mechanism of nucleophilic substitution and beta-elimination reactions in detail.

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447 views2 pages

Alkyl Halides 2nd Year Chapter10

This document contains questions from the topic of Alkyl Halides from the Chemistry chapter 10 for class 2nd year. There are multiple choice questions testing the understanding of key concepts like reactivity order of alkyl halides, mechanisms of substitution and elimination reactions, properties of primary, secondary and tertiary alkyl halides. Short answer questions define alkyl halides and important terms, ask for IUPAC names, drawing structures and explaining preparation methods. Extensive questions require explaining the mechanism of nucleophilic substitution and beta-elimination reactions in detail.

Uploaded by

mshahbaz bwp123
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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KIMS Acadmy Bahawalpur

Name 2nd year Chemistry Chapter 10 Alkyl Halides

CHOOSE THE RIGHT OPTION (1×10=10) Max .marks 40

i) In primary alkyl halides, the halogen atom is attached to a carbon which is

further attached to how many carbon atoms.

(a) Two (b) Three (c) One (d) Four

ii) The reactivity order of alkyl halides for a particular alkyl group is:

(a) Fluoride > Chloride > Bromide > Iodide (b) Chloride > Bromide > Fluoride > Iodide

(c) Iodide > Bromide > Chloride > Fluoride(d) Bromide > Iodide > Chloride > Fluoride

iii) When CO2 is made to react with ethyl magnesium iodide, followed by acid

hydrolysis, the product formed is:

(a) Propane (b) Propanoic acid (c) Propanal (d) Propanol

iv)SN2 reactions can be best carried out with:

(a) Primary alkyl halides (b) Secondary alkyl halides (c) Tertiary alkyl halides (d) All the three

v) Elimination bimolecular reactions involve:

(a) first order kinetics (b) second order kinetics

(c) third order kinetics (d) zero order kinetics

vi) For which mechanisms, the first step involved is the same.

(a) E1 and E2 (b)E2andSN2 (c)SN1andE2 (d) E1 and SN1

vii) Alkyl halides are considered to be very reactive compounds towards nucleophiles, because: (a) they
have an electrophilic carbon (b) they have an electrophilic carbon and a good leaving group(c) they have
an electrophilic carbon and a bad leaving group (d) they have a nucleophilic carbon and a good leaving
group

viii)The rate of E1 reaction depends upon:

(a) the concentration of substrate (b) the concentration of nucleophile

(c) the concentration of substrate as well as nucleophile (d) None of the above

ix) Which one of the following is not a nucleophile :(a) H2O (b) H2S (c) BF3 (d) NH3
x) In tertiary alkyl halides the halogen atom is attached to a carbon which is

further attached to __________ carbon atoms directly.

(A) 1 (b) 2 (c) 3 (d) 4

Short Questions (2×7=14)

1)Define alkyl halide. Which is the best method of preparing alkyl halides?

2)Give IUPAC names to the following compounds.

(i) CH3CH2CH2CHClCH3 (ii) CH3CCl2CH2CH3

3) Write down the formula of following compound

(i) 2-chloro ,2 -bromo,4-methly -pentane (ii)3,3 dibromo, 5,5 dimethly heptane

4) Define nucliphile & electrophile with example

5) What do you know about leaving group

6) How will you prepare TEL from alkyl halides

7) Write Wurtz synthesis reaction for preparation of symmetrical Alkane.

Extensive Question (10+6+=16)

Q.1 Write a detailed note on the mechanism of nucleophilic substitution reaction

Q.10. What do you understand by the term B-elimination reaction. Explain brief-E1 &E2 mechansim

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