Material Safety Data Sheet

NFPA HMIS Personal Protective Equipment

Health Hazard
2
2 Fire Hazard
2 0 2
Reactivity
0 See Section 15.

Section 1. Chemical Product and Company Identification Page Number: 1

Common Name/ Naphthalene

Trade Name

Manufacturer Zhejiang Province,China(Mainland)

Commercial Name(s) Moth Balls; Moth Flakes; Naphthalin; Naphthaline;

Naphthene; Tar camphor; White tar
Synonym Not available.

Chemical Name Not available.

Chemical Family Not available.

Chemical Formula C10H8

Supplier Happy Deer Zhejiang Province,China(Mainland)

Section 2.Composition and Information on Ingredients

Exposure Limits
3
Name CAS # TWA (mg/m ) STEL (mg/m3) CEIL (mg/m3) % by Weight

1) Naphthalene 91-20-3 50 15 100

Toxicological Data Naphthalene:

on Ingredients ORAL (LD50): Acute: 490 mg/kg [Rat]. 316 mg/kg [Mouse]. 1200 mg/kg [Guinea pig].
DERMAL (LD50): Acute: >20000 mg/kg [Rabbit]. >2500 mg/kg [Rat].

Section 3. Hazards Identification

Potential Acute Health Effects Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Slightly hazardous in case of
skin contact (permeator), of inhalation. Severe over-exposure can result in death.
Potential Chronic Health CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC. A4 (Not classifiable for human) by
Effects ACGIH.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance may be toxic to blood, kidneys, liver, skin.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to
a highly toxic material may produce general deterioration of health by an accumulation in one or many human
organs.

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 Naphthalene Page Number: 2

Section 4. First Aid Measures

Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient.
Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.

Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention immediately.
Serious Inhalation Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth
resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen
tight clothing such as a collar, tie, belt or waistband.
Serious Ingestion Not available.

Section 5. Fire and Explosion Data

Flammability of the Product Flammable.

Auto-Ignition Temperature 526°C (978.8°F)

Flash Points CLOSED CUP: 79°C (174.2°F). OPEN CUP: 88°C (190.4° F).

Flammable Limits LOWER: 0.9% UPPER: 5.9%

Products of Combustion These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Flammable in presence of open flames and sparks, of heat.
Various Substances

Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
of Various Substances Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media Flammable solid.

and Instructions SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray or fog. Cool containing vessels with water jet in order to prevent pressure
build-up, autoignition or explosion.

Special Remarks on May form explosive mixtures with air.

Fire Hazards Naphthalene can accumulate static electrical charges and may ignite its own vapors.
Special Remarks on Explosion Naphthalene can react explosively with dinitrogen pentaoxide and chromic anhydride..
Hazards Naphthalene dust and vapors may form explosive mixtures when mixed with air due to its flammability
properties.

Section 6. Accidental Release Measures

Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container.

Large Spill Flammable solid.

Stop leak if without risk. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent
entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for
assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check
TLV on the MSDS and with local authorities.

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 Naphthalene Page Number: 3

Section 7. Handling and Storage

Precautions Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
ingest. Do not breathe dust. Wear suitable protective clothing. If ingested, seek medical advice immediately
and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such
as oxidizing agents.
Storage Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use.
Avoid all possible sources of ignition (spark or flame).

Section 8. Exposure Controls/Personal Protection

Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
exposure to airborne contaminants below the exposure limit.
Personal Protection Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be
a Large Spill used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a
specialist BEFORE handling this product.
Exposure Limits TWA: 10 (ppm) from OSHA (PEL) [United States]
TWA: 50 from OSHA (PEL) [United States]
STEL: 15 from NIOSH
STEL: 75 (mg/m3) from NIOSH
TWA: 10 STEL: 15 (ppm) from ACGIH (TLV) [United States]
TWA: 10 STEL: 15 (ppm) [Canada]
TWA: 52 STEL: 79 (mg/m3) [Canada]
TWA: 10 STEL: 15 (ppm) [United Kingdom (UK)]

Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties

Physical state and appearance Solid. (Crystalline solid.) Odor Aromatic.

Taste Not available.

Molecular Weight 128.19 g/mole
Color White.
pH (1% soln/water) Not available.

Boiling Point 218°C (424.4°F)

Melting Point 80.2°C (176.4°F)

Critical Temperature Not available.

Specific Gravity 1.162 (Water = 1)

Vapor Pressure Not applicable.

Vapor Density 4.42 (Air = 1)

Volatility Not available.

Odor Threshold 0.3 ppm

Water/Oil Dist. Coeff. The product is more soluble in oil; log(oil/water) = 3.3

Ionicity (in Water) Not available.

Dispersion Properties See solubility in water, methanol, diethyl ether.

Solubility Easily soluble in diethyl ether.

Partially soluble in methanol.
Very slightly soluble in cold water, hot water.
Very soluble in hydronaphthalenes, in fixed and volatile oils, 1,3-Dichloromethane.
Soluble in Ethylene Dichloride, alcohol, acetate, benzene, toluene, chloroform, carbon tetrachloride
Solubility in Water: 30 mg/ml

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 Naphthalene Page Number: 4

Section 10. Stability and Reactivity Data

Stability The product is stable.

Instability Temperature Not available.

Conditions of Instability Heat, ingniton sources (flames, sparks, static), incompatible materials

Incompatibility with various Reactive with oxidizing agents.

substances
Corrosivity Non-corrosive in presence of glass.

Special Remarks on It will react violently wity chromic anhydride, aluminum chloride + benzoyl chloride.
Reactivity Naphthalene will volatize at room temperature and emit a moth ball odor.
Special Remarks on May attack some forms of rubber and plastic
Corrosivity
Polymerization Will not occur.

Section 11. Toxicological Information

Routes of Entry Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR
EXPOSURE.
Acute oral toxicity (LD50): 316 mg/kg [Mouse].
Acute dermal toxicity (LD50): >2500 mg/kg [Rat].
Acute toxicity of the vapor (LC50): 340 1 hours [Rat].
Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC. A4 (Not classifiable for human) by
ACGIH.
May cause damage to the following organs: blood, kidneys, liver, skin.
Other Toxic Effects on Hazardous in case of skin contact (irritant), of ingestion.
Humans Slightly hazardous in case of skin contact (permeator), of inhalation.

Special Remarks on Not available.

Toxicity to Animals

Special Remarks on May affect genetic material (mutagenic).

Chronic Effects on Humans May cause adverse reproductive effects and birth defects (teratogenic) based on animal test data.
May cause cancer based on animal test data.
Special Remarks on other Acute Potential Health Effects:
Toxic Effects on Humans Skin: Causes skin irritation. It can be absorbed through the skin and cause systemic effects
Eyes: Causes eye irritation. Direct contact may cause conjunctivitis, corneal damage.
Inhalation: Inhalation of vapor or dust may produce respiratory tract irritation and signs and symptoms similar
due to ingestion or dermal absorption.
Ingestion: Harmful if swallowed. It can cause flushing, nausea, abdominal cramps, vomiting, diarrhea,
malaise. It can affect the blood (anemia, hemolysis), liver (hepatomegaly, hepatic necrosis, liver damage),
kidneys (dysuria, albuminuria, oliguria, hemoglobinuria, hematuria, acute renal failure, kidney damage),
behavior/central nervous system (CNS depression, headache, lethargy, somnolence, restlessness,
convulsions, coma), cardiovascular system(hypotension, tachycardia). It can induce methemoglobinemia. It
may cause hyperkalemia, metabolic acidosis, visual changes, skin tingling.
Chronic Potential Health Effects:
Ingestion: Prolonged or repeated ingestion may affect the blood (hemolytic anemia), spleen (spleenomegaly),
liver (jaundice, liver damage), behavior/central nervous system (tremors, restlessness, hallucinations, extreme
apprehension and cause cataracts.
Skin: Prolonged or repeated contact may cause skin allergy.

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 Naphthalene Page Number: 5

Section 12. Ecological Information

Ecotoxicity Ecotoxicity in water (LC50): 1.6 mg/l 96 hours [Trout].

BOD5 and COD Not available.

Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products
may arise.
Toxicity of the Products The products of degradation are less toxic than the product itself.
of Biodegradation

Special Remarks on the Not available.

Products of Biodegradation

Section 13. Disposal Considerations

Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental
control regulations.

Section 14. Transport Information

DOT Classification CLASS 4.1: Flammable solid.

Identification : Naphthalene, refined UNNA: 1334 PG: III

Special Provisions for Not available.

Transport
DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms

Federal and State California prop. 65: This product contains the following ingredients for which the State of California has found
Regulations to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute:
Naphthalene
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause cancer which would require a warning under the statute: Naphthalene
Connecticut hazardous material survey.: Naphthalene
New York release reporting list: Naphthalene
Pennsylvania RTK: Naphthalene
Minnesota: Naphthalene
Massachusetts RTK: Naphthalene
Massachusetts spill list: Naphthalene
New Jersey: Naphthalene
New Jersey spill list: Naphthalene
Louisiana spill reporting: Naphthalene
California Director's List of Hazardous Substances: Naphthalene
TSCA 8(b) inventory: Naphthalene
TSCA 4(a) proposed test rules: Naphthalene
TSCA 8(a) PAIR: Naphthalene
TSCA 8(d) H and S data reporting: Naphthalene: Effective date: 06/01/87; Sunset date: 06/01/97
SARA 313 toxic chemical notification and release reporting: Naphthalene
CERCLA: Hazardous substances.: Naphthalene: 100 lbs. (45.36 kg)

California California prop. 65: This product contains the following ingredients for which the State of California has
Proposition 65 found to cause cancer which would require a warning under the statute: Naphthalene
Warnings California prop. 65: This product contains the following ingredients for which the State of California has
found to cause birth defects which would require a warning under the statute: No products were found.
Other Regulations

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 Naphthalene Page Number: 6

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS
No. 202-049-5).
Canada: Listed on Canadian Domestic Substance List (DSL).
China: Listed on National Inventory.
Japan: Listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Listed on National Inventory (PICCS).
Australia: Listed on AICS.

Other Classifications WHMIS (Canada) CLASS B-4: Flammable solid.

CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC) R22- Harmful if swallowed. S36/37- Wear suitable protective clothing and
R40- Limited evidence of a gloves.
carcinogenic effect. S46- If swallowed, seek medical advice
R50/53- Very toxic to aquatic immediately and show this container or label.
organisms, may cause long-term S60- This material and its container must be
adverse effects in the aquatic disposed of as hazardous waste.
environment. S61- Avoid release to the environment. Refer
to special instructions/Safety data sheets.

Health Hazard
HMIS (U.S.A.) 2 National Fire Protection Flammability
Fire Hazard Association (U.S.A.)
2
2
Reactivity
Health 2 0 Reactivity
0
Personal Protection Specific hazard
E
WHMIS (Canada)
(Pictograms)

DSCL (Europe)
(Pictograms)

TDG (Canada)
(Pictograms)

ADR (Europe)
(Pictograms)

Protective Equipment Gloves.

Lab coat.

Dust respirator. Be sure to use an

approved/certified respirator or
equivalent. Wear appropriate
respirator when ventilation is
inadequate.
Splash goggles.