Sec: SR.

IIT_CO-SC GTA-7(P-I) Date: 02-05-21

Time: 3HRS 2016_P1 Max. Marks: 186
KEY SHEET

PHYSICS
1 A 2 B 3 D 4 C 5 B

6 AD 7 ABC 8 ACD 9 ABC 10 AC

11 BD 12 AB 13 BC 14 2 15 6

16 4 17 6 18 5

CHEMISTRY
19 C 20 B 21 D 22 B 23 C

24 ABCD 25 ABD 26 ABC 27 ACD 28 AB

29 AC 30 D 31 ABD 32 5 33 3

34 9 35 8 36 7

MATHEMATICS
37 D 38 A 39 B 40 D 41 B

42 ABC 43 BD 44 AD 45 AC 46 AC

47 AD 48 AB 49 AC 50 0 51 9

52 2 53 4 54 6
Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL
SOLUTIONS
PHYSICS
1. Conceptual
2. Point A shall record zero magnetic field (due to -particle) is at position P and Q as shown in figure.
The time taken by -particle to go from P to Q is –
P

O 60º
A
60º

1 2 2
t= or  =
3  3t
3.

Net upward force

= 2 R2S + 2R1 S contact angle = 0°
 Capillary rise is given by
2S(R 1  R 2 )
h=
(R 22  R 12 )g

2S
=
(R 2  R 1 )g

4. The system can be redraw as

A
4m

4m
4mg g
a= = = 5 m/s2
8m 2
 v = u + at = 2 × 5 = 10 m/s
5. ac = k2 rt2
v2
or = k2 rt2
r
or v = krt
dv
Therefore, tangential acceleration, at = = kr or Tangential force,
dt
Ft = mat = mkr

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL
Only tangential force does work.
Power = Ft v = (mkr) (krt)
or Power = mk2 r2 t
6. Acceleration of cylinder is given by
mg sin  sin 
a =
mm
2
2g sin  sin  g
= =
3 6

 X



Y
friction along axis : fx = mg sin  cos 
mg sin  sin 
friction  to axis : fy =
3
7 mg
 friction = f x 2  f y 2 =
6
7. (A) Heat required is -
Q = nCpT = n(Cv + R)T
1000
= [5 + 2] × 120 = 30 × 103 cal
28
Q = 30 Kcal
(B) The increase in the internal energy is
1000
U = nCvT = × 5 × 120
28
= 21 Kcal
(C) Q = nCvT + PV
for constant volume V = 0
Q = nCvT = 21 Kcal
(D) external work done is
W = Q – U = 8.6 KCal
8. At t = 0, Rate of heat loss for two sphere is same as surface area and temperature of the two sphere is
same at t = 0. But rate of temperature loss
d dH 1 1
= × 
dt dt ms m

Hence more for hollow sphere. Thus at t > 0 temperature of hollow sphere is less than that of solid
sphere and hence at t > 0, rate of heat loss is more for solid sphere.
9. Conceptual-
dV d dA
10. = +
V  A

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL
0.2 d 0.004
= –
100  100

d 0.204
=
 100

11.

a
 eq. ckt.
8V 10

6V
 c
3 b
13V
11
Using Kirchoff's Law Solve the circuit.
12.
L


2L cos 
L a L
i = 2Lx cos × B
f = 2L2B
 = 2L2B [cos  – 1] L

 2LBx[cos   1]L
e= =
t 0 .1 L b L
2  1.5  0.3[0.5]  1.5
=
0 .1
= – 6.75 volt clockwise
v
13. m= =–4
u

v + u = 60
 u = 12, v = 48
y
1cm
x
Object
12cm 8cm
4 cm

40 cm

1 1 1 48
=   f= = 9.6 cm
f 48  12 5

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL
 
14. Angular fringe width  = =
D d
According to the given condition
 

d 180 60
6  10 7  180  60
d<

dmax = 2.06 × 10–3 m
dmax = 2.06 mm
15. vx = 8 2 m/s = relative velocity along x-axis
  x = (22 – 8 2 t)
vy = 6 2 m/s = relative velocity along y-axis
 y = (9 – 6 2 t)
r = x2  y2
For minimum r,
dr 23
= 0 t = s and rmin = 6.00 m
dt 10 2

16. The bob will execute SHM about a stationary axis passing through AB. If its effective length is '' then
'
T = 2
g'

' = = 2
sin 
g' = g cos = g / 2
2 2 4
T=2 = =
g 5 10

x = 4.
v
17. F = A
d

F1 v
= 1
F2 v2

800 2
=
2400 v2

v2 = 6 cm/s
18. Phase of particle at t = 0 = – /6
 Velocity of particle = vmax cos (–/6)
3
   A= 3 (By figure)
2
 A = 5 cm
2
= sec–1
50    10 – 3

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL
CHEMISTRY
19. Conceptual
20. VA group hydrides: (a) reducing properties increases down the group.
(b) Basic nature decreases down the group.
(c) Thermal stability decreases down the group.
(d) Bond angles decreases down the group.

21. 1.  Co  en  2 Cl 2  Geometrical, only cis form optical

2.  Co  NH 3 3 Cl3  Geometrical, No optical

3.  Co  H 2 O 4 Cl 2  Cl Geometrical, no optical.

22. Conceptual
23. Neoprene is the polymer of chloroprene
24. a) Strong acid & weak base, at 25C
1 1
pH  7  pKb  log C
2 2
1 1
5  7   4.4  log C
2 2
0.4  log C
C = 0.4
80 1
0.4  
 F.wt XY 2
40
 F.wt XY   100 g / mol
0.4

b) X   H 2O  XOH  H 
CCh Ch Ch

 H    Ch
 

105  0.4  h

h  2.5  105

c) 3a  2  rX   rY  

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL

2 160  186.4
a  400 pm
1.732
1100
d) d 
 
3
6 1023  4 108

100
d  2.6 g / cm3
6  6.4
25. a)

b) B.C & E.C are octahedral voids

between two body centres distance is ‘a’
between two edge centres distance is ‘a’

2a a
between B.C & E.C distance is 
2 2
a
c) Distance between two nearest TVS is
2
26. Conceptual

27. (A) Cl2O6 contain ClO 2 ClO 4 , ClO 2 is planar

(B) Due to the back bonding N(SiH3)3 weak base
(C) Both HNO2 and HClO3 disproportanal on heating
(D) In both NO2 and ClO2 central atoms are in sp2 hybridisation

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL

28. Conceptual
29. Conceptual
30.

31. Conceptual
32. Conceptual
33. in (c) N 2O is released
In (e) H 2 is released
In (f) NH3 is released
34. C g   2H 2 g   CH 4 g 

75  717  4  218  4x

4x  1664  x  416
416
  9.04  9
46
35. There are three different centers which can show optical isomerism
36.

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL
MATHS
37. f  x    2 x  a  2 x  c    2 x  b 
a c
f    a b So f    cb
2 2
a c
Now f   . f     a  b  c  b   0
2 2
c a
Hence exactly one root lies between   and  
2 2
38. z1 z1  1 , z2 z2  4 , z3 z3  9
Now, 12  z3 z3 z1 z2  z1 z1 z2 z3  z2 z2 z3 z1


 z1 z2 z3 z1  z2  z3 
2 2 2 2
16m  8   12   16   20 
39.              ... to 10 terms
5 5  5   5   5 
42
 2  22  32  ....  112  12  12 
5
 m  101
40. Solving centre C = (1,1)
 a 2  7a  11, a 2  6a  6   1,1  a  5
x 2  y 2  2 x  2 y   b3  1  0
Now r  0  b  1
41. n1  7  D7  3186
n2  7 3 c1 6  3 c2 5  3 c3 4  3216
n2  n1  30
x2 y2
42.  1
 2a2 a2
1
e1  1  2 , e2  2

 ae1  ae2
 3
e1 1

e2 3
43. f  x 3  1  t  f '  x 3  1 .3x 2 dx  dt

 
x 2 f  x 3  1 f '  x 3  1 dx   3x 2dx  0
2 2
0 0

  g  t  dt   x 3   0   g  t  dt  24
1 10 2 10

3 2 0 2

  g 1  x  dx  168
20

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL

 f  t  dt  x  f  t  dt   t f  t  dt  1  e
x x x
x
44.
0 0 0

f  x    f  t  dt  xf  x   xf  x   e …………….. (1)
x
x
0

 f  0   1
Again from (1)
f '  x   f  x   e x
d x
dx
 e .f  x    1  e x f  x   x  c

f  0   1  c  1  f  x    x  1 e x
f '  x    x  1  e  x   e  x
 e2tx  2tx  1 
45. g  x   Lim tan  2   tan x
2
t 0
 2t 

L  Lim
tan x  x
2 2 4

 tan x  x 2   tan x 2  x 2 
2

x 0 x8 x6 x2
2
L
3
46. p  0 head or 2 heads or 4 heads 
q  p 4  6p 2 1  p   1  p 
2 4

1   2p  1
4


2
cos    4sin 2   4 cos 2    
47. h ,k  &  sin 2   2 cos   1  0     ,  
 sin  4sin  2
2 
48. ax  by  cz  0
2a  2b  c 8a  b  4c

3 9
Only A & B satisfy
49. Tgt at B
x-6y+18=0
Solving with y   x  9
2

 y 2    6y  18  9
 y 2  6y  9  0  y  3  3 2  x  36  18 2
 3 15
Solving x - 6y + 18 = 0 and x + 9 = 0   9 ,       
 2 2
3
1 9 1 27 81
Area  2  27  
2 9 2 2 4
3

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL
 2

I1   cos  sin x dx

2
50.
0
Use king
 2

I1   cos  cos x dx

2

0
On adding
 2  2
   
2 I1   cos  sin x   cos  cos x dx   2cos   2 .cos  2 cos 2 x  dx  0
2 2

0 0
 I1  0 …(1)
 2  2 
1
I2   cos 1  cos 2 x  dx   
0 0
cos  cos 2 x  dx    cos  cos t  dt [Put 2x = t]
20
 2
2

2  cos  cos t  dt
0
 2

I 2    cos  sin t  dt
0
 I 2  I 3  0 …(2)
Hence, I1  I 2  I 3  0 ]
51.  CD  DE   AD.DB
AD b bc ac
And,   AD  & DB 
DB a ab ab
ab c 2 4ab c2
Hence, CD.DE  c2   9
a  b 4  a  b 2 4
2

Given A  A and B  B
2 2
52.

 A  B  A  B   A  B
det  A  B  .det  A  B   det  A  B  …(1)
det  A  B   0 or det  A  B   1

and  A  B   A  B   AB  BA   A  B  A  B
2 2 2 2 2

det. A  B   det  A  B 
2

If det. A  B   1 then det  A  B   1

 det  A  B   0, 1, 1 Ans]

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Narayana IIT Academy 02-05-21_Sr.IIT_CO-SC _JEE-Adv_GTA-7(P-I)_KEY&SOL

53. Let r  xi  y j  zk

r.  r.

 2i  j  2i  j 
 r.k
5 5

 2 x  y  2 x  y  5 z
  5 1   5 1   5 2  5 2
 r   0, , , 0, ,  , ,0, , ,0, 
 6 6   6 6   3 3   3 3 

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