CHEMISTRY 962 / 3 – MARKING SCHEME

Section A (15 marks)

Question No Answer Question No Answer

1 C 9 B

2 D 10 C

3 C 11 C

4 D 12 D

5 B 13 B

6 C 14 B

7 A 15 A

8 B

Section B (15 marks)

No Suggested answer Marks

16 (a) 1

Structure formula S
16 (b) 1
1

16 (c) Stage II : hydrolysis 1

Stage III : oxidation 1

16 (d) Structure compoud P

1
1
and

Total 7 Marks
17 (a) (i) 1
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17 (a) (ii) 1

17 (a) (iii) 1

17 (a) (iv) 1

17 (b) (i) 1
1

17 (b) (ii) 1

17 (b) (iii) 1

17 (b) (iv) CH3CH2COONa + CH3NH2 1

TOTAL Marks 9
Max 8

SECTION C (30 marks)

Question Explanation Marks

No.
18 (a) (i) 1

1 arrow
1 label
Carbocati
on

1 arrow
1 major
product
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Question Explanation Marks

No.
18 (a) (ii) With acidified KMnO4
Product Phenylmethanol

1
structural
formula
Phenol no reaction

With Bromine water

Product Phenol

1
structural
formula

Phenylmethanol no reaction

18 (b)
1
1
1

Reaction of A with aqueous sodium hydroxide:

Reaction of C with alkaline iodine:

Reaction of A with ethanolic potassium hydroxide:

1
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Question Explanation Marks

No.

Reaction of D with bromine: 1

Oxidation of B by hot acidified potassium manganat(VII) 1

Total 15
Marks

19 (a) Structural isomers are compounds which have the same molecular formula but 1
different structural formulae.

Example:
1

Geometrical isomers are compounds which have the same molecular formula 1
but are different in their spatial arrangement due to the presence of a double
bond or a cyclic structure.

Example:

Optical isomers are compounds that have the same molecular formula
but are mirror images of one another and are not superimposable. 1

Example : 2-butanol

1
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Question Explanation Marks

No.

19 (b) 1
1
1

19 (b) (ii) W is a phenylamine: 1

TOTAL 15
Marks

20 (a) (i) (i) Reagent : I2 in NaOH(aq), Condition: heat. 1+1

Observation: CH3CH2OH would form yellow precipitate of CH13 while 1
no observable change for CH3CHCHO.
1
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Question Explanation Marks

No.

(or Na metal at room ternperature/PCl at room temperature)

(ii) Reagent : NaOH(aq), Condition: heat 1+1

Observation: CH3CONH, liberates an alkaline gas while 1
no observable change is observed for CH3CH2NH2,
1

20(b)(i) 1

20(b)(ii) 1
Reagent
&
condition

1
product

1 reagent
&
condition

1
product

20(b)(iii) Potassium manganate( VII) 1

TOTAL 15
Marks

END OF MARKING SCHEME