Hychill Manual
Hychill Manual
MANUAL
CONTENTS
Warranty/Guarantee 2
BACKGROUND INFORMATION
About Us 3
Environmental Trends 4
Benefits of Hydrocarbons 6
The Market 8
Export 10
Distribution 10
Support 11
180713
WARRANTY ~ GUARANTEE
Where the customer believes there is a fault with the refrigerant, the remainder
of the refrigerant in the supplied container must be returned to HyChill in
order for the customer to be eligible for replacement or reimbursement.
Freight and insurance for the return of the refrigerant and container is at
the customers expense. If HyChill elects to replace the product, freight and
insurance of the replacement will be borne by HyChill..
HyChill Refrigerants
85A Canterbury Road, Kilsyth Vic 3137 Australia
Telephone: +61 (3) 9761 8788 Facsimile: +61 (3) 9761 8799
Email: [email protected]
Web: www.hychill.com
Please photocopy completed form and fax to HyChill Australia Pty Ltd on +61-3-9761 8799 4
ABOUT US
ABOUT US
BACKGROUND INFORMATION
From humble beginnings in 1995 when Colin Spencer and John Clark
pooled resources and “know how” to produce the first few hundred
cylinders of Australian made HC refrigerant, they have lead the way
in the development and promotion of hydrocarbon refrigerants,
culminating in the introduction of the HyChill brand in 1999.
5
ENVIRONMENTAL TRENDS
ENVIRONMENTAL TRENDS
In what is an industry first, the range of hydrocarbon refrigerants produced by HyChill Australia has been assessed and
accepted as compliant with the requirements of the "Good Environmental Choice" Label.
“The hydrocarbon product range by HyChill deserves market recognition and support for the significant environmental
opportunity that this product range promises in comparison to current refrigerants” said Petar Johnson, Chairman of
Good Environmental Choice Australia. "We are pleased to offer independent assurance to the market as to the high
quality, environmental preferability and market usability of the hydrocarbon product line."
HyChill's range of hydrocarbon refrigerants meets the high environmental expectations of Australians. The product
range offers products that have been formulated with environmental and human health considerations in mind and are
suitable for commercial and domestic uses in Australia.
The primary environmental impacts of HyChill Hydrocarbon refrigerant products assessed as part of the Good
Environmental Choice program include:
Fitness for Purpose
Ozone Depleting Potential
Global Warming Potential, and
Packaging Stewardship
BACKGROUND INFORMATION
6
ENVIRONMENTAL TRENDS
The Good Environmental Choice Aim ultimately to improve the quality of
Label is the national product life cycle the environment and to encourage the
independent environmental declaration sustainable management of resources.
in Australia (http://www.geca.org.au).
The organisation is an independent Following an independent audit
non-profit environmental research and against the recognition requirements
certification organisation recognised as of the Australian Ecolabel Program, the
the Australian member of an international following HyChill products have been
network of ecolabelling schemes under awarded the "Good Environmental
the Global Ecolabelling Network. The Choice" label for the Australian
Australian Environmental Labelling market. This Ecolabel is awarded to
Association Inc. (AELA) manages the those products that meet or exceed
Good Environmental Choice – Mark voluntary standards of environmental
of Conformity in conformance to ISO performance. The verification procedure
14 024 – International Standard for is managed via a Documented Quality
Third Party Environmental Labelling and Management System and Certification
Declaration. Program Manual which have made
significant use of the ISO 14 000
The objectives of The Good series.
Environmental Choice Labeling program HyChill’s entire line of Hydrocarbon
are to: Refrigerants have qualified for the
Provide a clear, credible and independent endorsement:
BACKGROUND INFORMATION
guide to consumers wishing to take HyChill Minus 30 (HR12)
account of environmental factors in Minus 30 is a blend of R600a and R290,
their purchasing decisions; two naturally occurring hydrocarbon
Encourage consumers to purchase refrigerant gases and is perfect for use
products which have lower in automotive air-conditioning systems
environmental impacts; and in refrigeration applications. It
Recognise genuine moves by companies replaces the Ozone Depleting R12 and
to reduce the adverse environmental high Global Warming R134a.
impacts of their products;
7
THE BENEFITS OF HC REFRIGERANTS
BACKGROUND INFORMATION
8
THE BENEFITS OF HC REFRIGERANTS
Use of existing charging equipment: • Granherne P/L - Risk Assessment
The equipment currently used for existing Study Engineers
refrigerants requires no modification or change • Maclaine-cross, I. L., Usage and Risk
for charging hydrocarbon refrigerants. of Hydrocarbon Refrigerants in Motor
Cars for Australia and the United States,
Since no retrofitting is required, HyChill June 2004, International Journal of
refrigerants are the perfect "drop in" solution Refrigeration, Volume 27, No. 4, pages
for systems, which previously used gases 339-345
such as CFC R12, HFC R134a, HCFC
R22, R502, R11 and others. Conclusions of these organisations support
the continued growth in the use and
Less Energy Use acceptance of hydrocarbon refrigerants.
Hydrocarbon refrigerants in refrigeration
or car air-conditioning systems use less Scientific papers published by various
energy than fluorocarbon refrigerants. organisations in Australia and overseas,
repeatedly attest to the efficiency and
This provides a number of benefits: safety of hydrocarbon refrigerants across a
• Operating costs are lower. wide range of applications.
• Compressor loads are reduced, which
reduces wear and tear, extending Great Heat Conductors
component life and reducing leakage. Hydrocarbons are also 50% more efficient
• Less energy consumed means less conductors of heat than fluorocarbons.
fossil fuel burned resulting in lower
global warming. In practical terms this means that the
BACKGROUND INFORMATION
hydrocarbon molecule rejects heat faster
Increased Safety than a fluorocarbon molecule.
Most importantly, the safety of hydrocarbon
refrigerants is assured when the application For example, a Coca Cola or Pepsi
complies with relevant safety standards, drink cabinet which uses HyChill
such as International Standards ISO 5149, Minus 30 hydrocarbon refrigerant
BS 4434-1995, and Australia/New Zealand instead of HFC R134a, chills
Standard AS/NZS 1677-1998. the cans to the desired temperature
approximately 15% to 30% faster. In the
Research summer time with higher volume store
Hydrocarbon refrigerants have been traffic, this is a definate advantage for the
the subject of detailed studies by many store owner, as well as for the manufacturer
organisations including: of the products being sold.
9
THE MARKET
Not only are HyChill’s products more efficient and cost effective, but they also
perform even better than the current market place alternatives. HCFC’s and HFC’s
THE MARKET
were developed to replace CFC’s, but still contain blends of gases with a high Global
Warming Potential. In general, they have been found to be poor substitutes under
extreme conditions.
10
In general, HFC refrigerants were advanced very quickly in the face of a
found to be a poor substitute for CFC great deal of obstruction by fluorocarbon
THE MARKET
refrigerants, as extensive modifications refrigerant manufacturers and distributors.
to, or replacement of, existing systems
were necessary to facilitate their use. This In August 1992, the German mail order
costly exercise was called retrofitting. company "Neckermann" placed an initial
Furthermore, HFC's were found to be poor order with Foron for 20,000 Greenfreeze
performers under extreme conditions. refrigerators. Within three months, the
quantity on order exceeded 50,000 units.
As these original HFC gases were found
to be unsuitable in many refrigeration By the end of 1993, after enthusiastic
applications, it then became necessary acceptance of Foron "Greenfreeze
to create a large number of HFC/HCFC Technology" at Europe’s most important
combinations and other blends. homewares exhibition, most of Germany's
major refrigerator manufacturers announced
The importance of hydrocarbon refrigerants that their production lines would adopt
had been extolled by Greenpeace under the hydrocarbon technology as a matter
name "Greenfreeze Technology" for more of urgency.
than twenty years. As each application
BACKGROUND INFORMATION
for alternative refrigerants was properly By 1996, almost 100% of refrigerators
studied, it was found that a hydrocarbon made for the German market were designed
refrigerant was available as the perfect to utilise "Greenfreeze Technology".
alternative. Often, no changes to system
design were required. It’s no surprise therefore that an increasing
number of refrigeration systems are
As a result, in 1991, Foron, a minor being charged with HyChill hydrocarbon
German manufacturer of refrigerators, refrigerants. The combination of first class
was sponsored by Greenpeace to develop products and environmental responsibility
a small refrigerator, which utilized the best has propelled HyChill to grow in demand
possible solutions for foam expansion and - from distributors and suppliers, to
in the refrigeration system. This project technicians and consumers.
11
EXPORT
EXPORT / DISTRIBUTION
Utilizing a strong network of distributors, HyChill trades with countries from every
corner of the globe and can supply in cylinders or bulk containers.
DISTRIBUTION
HyChill’s unique production process, combined with an accomplished distribution
network enable HyChill to maintain a leading position for supplying hydrocarbon
refrigerants. The customised process allows high volume production of quality
product, and every batch is tested to stringent standards. All orders are
processed and packed in-house for distribution using efficient distribution systems.
No matter where you are located, HyChill can supply top quality natural
refrigerants.
BACKGROUND INFORMATION
EUROPE
USA
TEXAS CHINA
MIDDLE EAST GCC
FLORIDA
TAIWAN
INDIA THAILAND
MALAYSIA
SINGAPORE
12
SUPPORT
SUPPORT
What makes HyChill unique, apart from its range of products, is the standard of after-
care support - that famous HyChill service. It’s all about customer satisfaction!
Friendly staff and experienced representatives are on hand for advice and always
ready to assist. Comprehensive information is readily available for both the trade and
consumers. These include:
• Product information brochures and leaflets.
• Information Manual covering all technical requirements.
• Interactive CD Roms
• A comprehensive website covering everything from products, to environmental
trends, research and technical data. Check out www.hychill.com.au
You can rely on HyChill to set new industry standards in total customer
satisfaction.
BACKGROUND INFORMATION
JAPAN
PHILIPPINES
INDONESIA
13
It’s all about ‘Customer Satisfaction’
When you service your customers’ air conditioner with highly efficient
Minus 30 hydrocarbon refrigerant from HyChill, you are enhancing the most
important component of your business: ‘Customer Satisfaction.’
Minus 30 refrigerant is a highly efficient heat transfer medium; it uses about 30%
less energy to produce a faster result. On really hot days, Minus 30 will put a
smile on your customers’ face. Contented customers guarantee the growth of
your business.
We supply product at an attractive price - it’s easy to see that Minus 30 is the
lowest cost alternative to HFC refrigerants when you are only required to use 1/3
of R134a’s charge weight, or about 85% by volume.
Each standard 22 litre cylinder will hold 9kgs of Minus 30 as opposed to 20kgs for
R134a, this means you are only paying for 9kgs of refrigerant and not 20kgs.
Furthermore, each 9kgs of Minus 30 will charge 30 or more systems whereas
20kgs of R134a will only charge about 25 systems.
You can use your normal equipment; Minus 30 is suitable for all systems. It
doesn’t matter whether it is an old R12 system, or a new R134a system, Minus 30
is compatible with all oils, O Rings, Seals and Gaskets. We highly recommend the
use of modern service equipment, scales and diagnostic tools, they save time and
money, and, they help to build your customers’ confidence. We also recommend
HyChill SRO 500 Synthetic Refrigerant oil, in systems and in your vacuum pump.
It is non hygroscopic and is compatible with all refrigerants.
‘Customer Satisfaction’
HyChill Refrigerants, the Natural Alternative
14
Minus 30 - PRODUCT DETAILS
TECHNICAL INFORMATION
High Efficiency Medium Temperature Hydrocarbon Refrigerant
Minus 30
to charge weight section.
operation are achievable by replacing • Digital scales recommended – they save
fluorocarbon refrigerants with Minus 30. a great deal of time and also help to
prevent refrigerant wastage.
• Minus 30 is compatible with any
refrigerant lubricant, however we strongly
recommend a system flush and use of
SRO500 oil in all systems
Safe, natural, and environmentally
benign, the HyChill range of natural organic Effect on Systems
refrigerants is suitable for a wide range of air • Lower Head Pressures reduce load
conditioning and refrigeration applications. on compressor
• Less heat at compressor
Since no retro-fitting is required, HyChill
• Less engine drain at idle and when running
refrigerants are the prefered "drop in"
• Positive liquid head at TX valve or restrictor
solution for systems which previously used
• Quicker pull down temperature at vent
gases such as CFC R12 and HFC R134 and
• Lower vent temperature at all times
others.
• No upgrading to existing processing
equipment required.
• No change to repairers procedures
while installing
15
A GUIDE TO AIR CONDITIONING
SERVICE AND DIAGNOSIS
TECHNICAL INFORMATION
The following pages are designed to assist in the step by step servicing and
diagnosis of air conditioning systems.
SAFETY PRECAUTIONS
Refrigerants have a very low boiling point. Extreme care must be taken when
they are being handled. Always observe the following safety precautions:
PREPARATION
The following preliminary checks should be carried out prior to any service or
diagnosis of an air conditioning system:
• Ensure the condenser fins are not blocked with debris such as insects,
leaves etc. and that the fins are straight
• Ensure that the condenser fan operates and runs in the correct direction
• Check that the engine and radiator are at the correct operating temperature
and are not overheating
• Inspect the drive belts for damage and correct tension
• Ensure that the engine viscous fan engages at the correct temperature.
• The compressor should cycle on and off
• Make sure the evaporator drain hose is not blocked
• The heater is turned off and in the full cold mode position
• The air mix door is fully closed
• A/C switch fully illuminates when engaged
• There are no vacuum hose leaks
• The dash vents should open and close fully
• There must be no air leaks between the evaporator case and the heater case
• The blower fan should be operational on all speeds
• Check for any evidence of refrigerant leakage and oil staining at components
and connections
16
HOW A SYSTEM SHOULD OPERATE
TECHNICAL INFORMATION
LEGEND
50 60 250
40 200 300
70
30 LOW 150 HIGH
The gauge readings for Minus 30
80 350
20 90
refrigerant should be approx 150kPa
100 400
10 100 (20 psi) on the low side, and 620-
50 450
0 110 1200kPa (90 to 180 psi) on the high
-10 120 0 500
PSI PSI side, depending on the ambient
temperature, good condenser, air
flow and an suitably sized condenser
- these items contribute to variations
in the high pressure gauge reading.
On larger commercial systems,
2 BAR 6.2-12 BAR pressures can be much lower.
Minus 30
200 kPa 620-1200 kPa
30 psi 90-180 psi
17
TECHNICAL INFORMATION
ahead position.
5. Insert thermometer probe approximately 50mm Leave valves A, C & F Blockage or leak evident
open. Slowly open high in system. Find cause
into the centre vent louvre. side valves B & D. and rectify
6. Set the controls to:
A. Recirculate air position (use fresh air
position on cold days when charging) Evacuate system to 6 kPa absolute.
Close valves A, B & F. System must maintain 6 kPa
B. Maximum cooling absolute for a minimum of 15 minutes
C. A/C on.
7. Start engine, bring engine speed to 1700 RPM
Low pressure gauge Low pressure gauge
then allow pressure gauge needles to stabilise. needle steady needle rises
8. Take pressure and temperature settings.
Compare these to the manufacturers
Continue evacuation for
performance charts found in the appropriate GO TO STEP 2
Minus 30
30 minutes.
workshop manuals.
The performance test described here puts increased Check for leakage using an
load on the A/C system. If the A/C system can electronic leak detector.
18
LEGEND
TECHNICAL INFORMATION
D High pressure a/c sys connection
E Recovery system
F Vacuum pump
G Refrigerant supply
H Refrigerant recovery unit
Minus 30
Set controls to maximum cooling and high fan speed.
Close all valves and taps. Remove high and low filling hoses,
make sure valves C & D are closed. Connect high side filling
Continue with evacuation and charging procedure hose to recovery unit inlet side. Open valves
as per steps 1 - 3. A, B & D. Switch on recovery machine and remove all
refrigerant from filling hoses. (Refer Fig. 2)
19
DIAGNOSTIC TIP - CHECKING FOR
A BLOCKAGE IN THE CONDENSER
TECHNICAL INFORMATION
A change of state, where high pressure vapour forms into a high pressure liquid
during the movement through the condenser takes place within approximately
the first 1/3 of the condenser. With this change of state a slight temperature
change takes place. This will vary depending on ambient temperature.
Using your finger, follow the tube(s) of the condenser (avoid burning your
skin), you should be able to feel where the change takes place. This change
will be quite subtle, however if you feel the difference in temperature before
approximately the first 1/3, a blockage may be present.
20
WHY DO COMPRESSORS FAIL?
TECHNICAL INFORMATION
In most cases the reason you are fitting a reconditioned and guaranteed compressor
is that the old or original compressor has "GONE DOWN", therefore you must ask
yourself why did this happen?
Compressors do not fail for unexplained reasons so be assured that if you fit a
compressor without answering the "WHY" question and without following the
correct installation procedure this compressor will also "GO DOWN" causing you
unnecessary losses in both time and money. So, why did the old unit fail?
3. LACK OF REFRIGERANT
1. EXCESSIVE HEAD PRESSURE 2. LACK OF OIL
(COMPRESSOR OVERHEATS)
In the case of excessive head pressure In the case of lack of oil the two reasons Slow leaks allow the system to run with
the three reasons for this are: for this are: low liquid supply to tx valve. The suction
BLOCKAGE IN SYSTEM - Check dryer, return gas to the compressor is not cold
SYSTEM BLOCKAGE -
T.X. Valve, Condenser (internally) enough to cool the compressor parts
restrictive flow of oil back to the
OVERCHARGE IN THE SYSTEM - compressor (i.e. tx valve, receiver/dryer, internally. Shaft seals harden and leak,
Some compressors are extremely oil deteriorates and metal parts fail.
condenser, freezing evaporator)
susceptible to this
OVERPRESSURE IN THE SYSTEM SYSTEM LEAK - allowing the oil to
- Inadequate car cooling system, clogged escape from the system.
condenser fins (external), defective thermo
fan or fan clutch, excessive moisture in
system, a cocktail of refrigerants.
Once you have found and rectified the reason for the old compressor failure, follow
Minus 30
this procedure for the installation of the new unit to ensure trouble free running.
21
GAUGE AND SYSTEM DIAGNOSIS
TECHNICAL INFORMATION
Compressor malfunction
(CCTXV/CCOT system) Discharge hose: Cool
Minus 30
22
TECHNICAL INFORMATION
PROBLEM CONDITION CAUSE
Low side gauge: Low to vacuum • Orifice tube filter screen blocked
with debris such as aluminium
particles.
High side gauge: Low
0 BAR 1 BAR
0 kPa 100 kPa Orifice tube: Frost build up
0 psi 14 psi
Minus 30
Low side gauge: Low to vacuum • Expansion valve (TX) jammed
closed, insufficient refrigerant
flow to suction side of the
High side gauge: Low compressor.
• This is normally related to the
TXV sensing bulb malfunction,
Discharge air: Slightly cool disconnected from tube, foreign
material in TXV or moisture
0 BAR 0 BAR
entry causing rust formations.
0 kPa 0 kPa Expansion valve: Sweating or
0 psi 0 psi
frost build up
Expansion valve (TX) remains closed
(CCTXV system)
23
GAUGE AND SYSTEM DIAGNOSIS (CONTINUED)
TECHNICAL INFORMATION
24
TECHNICAL INFORMATION
PROBLEM CONDITION CAUSE
• Refrigerant undercharge.
Discharge air: Cool
0 BAR 10 BAR
0 kPa 1000 kPa Accumulator: Warm
0 psi 145 psi
Refrigerant loss
(CCOT system)
Minus 30
Low side gauge: Low • Foreign material causing blockage
between compressor outlet and
evaporator inlet (high side).
ie. Entry to compressor may be
High side gauge: Low blocked. Receiver may be blocked
by debris from compressor.
• No or very little refrigerant flow to
Discharge air: Slightly cool suction (low) side of compressor.
0.8 BAR 9 BAR
80 kPa 900 kPa
11 psi 130 psi High side tubes: Cool and showing • Note - Compressor noisy, fast
cycling depending if the high
Restriction in high side of system signs of sweating or moist build up pressure switch is before or after
(CCTX/CCOT system) after the point of restriction. the restriction.
25
GAUGE AND SYSTEM DIAGNOSIS (CONTINUED)
FEEL TEST
TECHNICAL INFORMATION
There will be times when the pressures registering on the gauges will not make sense. When
this occurs, a handy diagnostic tip is to carry out a 'feel test'. Feeling the hoses and tubing
may indicate the location of a possible blockage. The location of charge port will have to be
considered when attempting this test, as the pressure gauge readings will vary, depending
on which side of the charge port the blockage is located.
• Compressor noisy
• High side hose very hot before blockage
• High side hose very cool to warm after blockage
26
TECHNICAL INFORMATION
Blockage - low side (before charge port)
27
PRODUCT COMPARISON CHART
HC HFC CFC
Class (HydroCarbon) (HydroFluoroCarbon) (ChloroFluoroCarbon)
Refrigerant + Lubricant
Yes Yes Yes
Flammability
Atmosphere Lifetime
<1 ~16 ~130
(Years)
Minus 30
Cooling Performance
Excellent Marginal Very Good
@ 40˚C
28
PRESSURE TEMPERATURE CHART
TECHNICAL INFORMATION
˚C ˚F kPa psi kPa psi kPa psi
-40 -40 -6.4 -0.9 -35.5 -5.2 -47.5 -6.9
-38 -36 1.3 0.2 -29.2 -4.2 -41.9 -6.1
-36 -33 9.5 1.4 -22.5 -3.3 -35.8 -5.2
-34 -29 18.3 2.6 -15.3 -2.2 -29.2 -4.2
-32 -26 27.5 4.0 -7.6 -1.1 -22.1 -3.2
-30 -22 37.3 5.4 0.6 0.1 -14.4 -2.1
-28 -18 47.7 6.9 9.4 1.4 -6.2 -0.9
-26 -15 58.7 8.5 18.8 2.7 2.7 0.4
-24 -11 70.4 10.2 28.9 4.2 12.3 1.8
-22 -8 82.6 12.0 39.5 5.7 22.5 3.3
-20 -4 95.6 13.9 50.9 7.4 33.5 4.9
-18 0 109.3 15.9 62.9 9.1 45.2 6.6
-16 3 123.7 17.9 75.7 11.0 57.8 8.4
-14 7 138.8 20.1 89.3 13.0 71.2 10.3
-12 10 154.7 22.5 103.6 15.0 85.5 12.4
-10 14 171.5 24.9 118.8 17.2 100.7 14.6
-8 18 189.0 27.4 134.8 19.6 116.8 17.0
-6 21 207.5 30.1 151.7 22.0 134.0 19.4
-4 25 226.8 32.9 169.5 24.6 152.2 22.1
-2 28 247.0 35.9 188.3 27.3 171.5 24.9
0 32 268.2 38.9 208.0 30.2 192.0 27.9
2 36 290.3 42.1 228.8 33.2 213.6 31.0
4 39 313.5 45.5 250.6 36.4 236.5 34.3
6 43 337.6 49.0 273.4 39.7 260.7 37.8
8 46 362.8 52.7 297.4 43.2 286.1 41.5
10 50 389.1 56.5 322.5 46.8 313.0 45.4
12 54 416.5 60.5 348.8 50.6 341.3 49.5
14 57 445.1 64.6 376.3 54.6 371.0 53.8
16 61 474.8 68.9 405.1 58.8 402.3 58.4
18 64 505.7 73.4 435.1 63.2 435.1 63.2
20 68 537.9 78.1 466.5 67.7 469.6 68.2
Minus 30
22 72 571.3 82.9 499.2 72.4 505.7 73.4
24 75 605.9 87.9 533.2 77.4 543.6 78.9
26 79 641.9 93.2 568.7 82.5 583.2 84.6
28 82 679.3 98.6 605.6 87.9 624.7 90.7
30 86 718.0 104.2 644.0 93.5 668.0 97.0
32 90 758.1 110.0 683.9 99.3 713.3 103.5
34 93 799.6 116.1 725.4 105.3 760.6 110.4
36 97 842.6 122.3 768.4 111.5 809.9 117.5
38 100 887.1 128.8 813.1 118.0 861.3 125.0
40 104 933.1 135.4 859.4 124.7 914.9 132.8
42 108 980.7 142.3 907.3 131.7 970.7 140.9
44 111 1029.8 149.5 957.0 138.9 1028.7 149.3
46 115 1080.6 156.8 1008.4 146.4 1089.1 158.1
48 118 1132.9 164.4 1061.7 154.1 1151.8 167.2
50 122 1187.0 172.3 1116.7 162.1 1216.9 176.6
52 126 1242.7 180.4 1173.5 170.3 1284.6 186.4
54 129 1300.1 188.7 1232.3 178.8 1354.7 196.6
56 133 1359.3 197.3 1292.9 187.6 1427.5 207.2
29
MDS No: 1012 Page 1 of 2
HYCHILL AUSTRALIA PTY LTD
85A Canterbury Road Kilsyth VIC 3137
Phone +61 3 9728 5055 Fax +61 3 9761 8799
Emergency Phone Number +61 3 9728 5055
TECHNICAL INFORMATION
USE: A flammable gas used as refrigerant, normally stored under pressure in liquid form.
PHYSICAL DESCRIPTION/PROPERTIES:
Appearance: Rapidly evaporating liquid or gas with rotten cabbage - like odour
Initial boiling point: -30°C to 0°C Vapour Pressure at 20°C: 540kPag
Melting Point: Not Applicable Flash Point: -104 to 60°C
Density @ 15°C: Approximately equal to 0.53 Solubility in Water: Very slight
Lower Flammability Limit: 1.9% in air Upper Flammability Limit: 9.5% in air
OTHER PROPERTIES:
Evaporation Rate: Rapid Vapour Density: 1.5 to 2.0 air = 1
Auto Ignition Point: ~460°C - ~470°C % Volatilise: 100%
INGREDIENTS:
Chemical Entity CAS Number Proportion
C3 H8 0074-98-6 0 to 70%
CH(CH3)3 75-28-5 0 to 50%
Minus 30 contains odourant ethyl mercaptan unless otherwise authorised. (recommended 25 mg/kg). This is detectable to 20% of its lower flammability limit.
FIRST AID
Inhaled: Avoid breathing vapours and fumes as much as possible. If someone is overcome by fumes, remove them to fresh air immediately. Rescuers
should avoid becoming a casualty by wearing suitable respiratory protection. If the affected individual is not breathing, administer artificial respiration.
Seek medical advice promptly in serious cases of over exposure.
Eye: Avoid contact with the product. Remove any contact lenses carefully. Hold eyelids open and flush eyes with tepid water for 15 minutes. Seek
medical advice immediately for all eye contact.
Where significant splashing of Minus 30 liquid may occur, eyewash facilities stations should be installed.
Skin: Avoid skin contact with the liquid. Remove contaminated clothing and wash the exposed areas with plenty of soap and water. Seek medical
advice if irritation or frostbite (see below) occurs.
Swallowed: Unlikely to be a problem, owing to high evaporation rate.
Frostbite: Obtain medical assistance. If medical advice is not available immediately, place casualty in a warm area as soon as possible and allow the
injured area to warm gradually (further damage may occur if the area of injury warms too rapidly). DO NOT EXPOSE THE INJURED AREA TO
EXCESS HEAT OR COLD (such as heat lamps, hot water, snow or ice). Gently cover or drape the injured area with clean material, such as dressing or
sheet. To relieve pain, immerse the injured area in water which is near or at body temperature (35-40°C). If possible, get the casualty to exercise the
injured area gradually. Give them something warm to drink, BUT NO ALCOHOL. Seek medical advice as soon as possible.
30
Page 2 of 2
ADVICE TO DOCTOR
No specific treatment recommended. Treat symptomatically. Show a copy of this material safety data sheet to medical personnel dealing with cases of
over exposure
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
Worksafe Australia has established comments and exposure Standards for the following ingredients of this product:
TECHNICAL INFORMATION
Minus 30: Simple asphyxiant 800ppm (1900 mg/m³) as an 8-hour Time Weighted Average.
Minus 30 is odourised before transport handling and is detectable to 20% of its LEL. If no stenching agent has been added, Minus 30 has a high odour
threshold (in the order of 10-25 times the exposure standard).
ENGINEERING CONTROLS
Ensure there is good ventilation of the area in which the product is used to keep concentrations below the exposure standard or lower explosive limit.
While dilution by air may be sufficient in most cases, an exhaust ventilation may be required. In such cases use spark proof equipment, if possible. A
ventilation velocity of a least 0.3m/s is recommended.
PERSONAL PROTECTION
Avoid contact with eyes and skin. Overalls or a long sleeved shirt and closed in shoes or safety footwear should be worn as a general precaution.
Eye Protection: Eye protection is required (faceshield, chemical safety glasses or side shield glasses) where splashing is likely. Eye protection should
comply with AS 1336/1337.
Gloves: Impervious oil and cold resistant gloves should be worn when using this product. Gloves made of PVC are preferred, although gloves made of
nitrile and chloroprene should also be satisfactory. Any such gloves should comply with AS 2161.
Respiratory Protection: If ventilation of the area is not sufficient, respiratory protection may be required. This should be at least approved air supplied or
self contained breathing apparatus where the exposure standard is likely to be exceeded or if work is required close to large gas leaks. Respiratory
protection should comply with AS 1715/1716.
FLAMMABILITY
Minus 30 is gaseous and highly flammable at normal temperatures and pressures. The gas is normally stored under pressure in the liquid form. Release
of pressure is associated with rapid cooling, the intensity of which is dependent on the rate of release. Containers of Minus 30 are explosive hazards,
when exposed to excessive heat.
SAFE HANDLING
STORAGE AND TRANSPORT
Minus 30 is classified under the Australian Code for the Transportation of Dangerous Goods by Road and Rail as a FLAMMABLE GAS (Class 2.1).
Storage: Minus 30 should be stored in approved areas only. Minimum conditions of storage include dry, cool, secure storage away from heat, sources of
ignition and oxidising substances. Keep containers closed and upright when not in use.
Transport: Minus 30 must be transported in accordance with the latest edition of the Australian Dangerous Goods Code, (ADG Code). Large volumes
must be transported in approved tankers, and smaller volumes in approved pressure containers.
FIRE/EXPLOSION HAZARD
Hazchem Code: 2WE
Minus 30
Extinguishers: Water spray or BC fire extinguisher.
Procedures: Stay out of gas or vapour. Use water to disperse unignited gas or vapour. Allow to burn out if possible.
Special Precautions: Fire-fighters should wear full protection and breathing apparatus.
Minus 30 is heavier than air, and vapours will tend to flow downwards and accumulate in low-lying areas such as drains and pits at ground level.
Containers: Cool fire exposed containers with water spray. If ignition has occurred and water is not available, tank metal may weaken from overheating.
Reactivity: Stable
Incompatibilities: Oxidisers
Combustion Products: Hazardous combustion products of carbon dioxide (carbon monoxide under poor conditions of combustion) and smoke may be
produced.
Hazardous polymerisation will not occur.
31
PRESSURE/ENTHALPY CHART FOR A TYPICAL HYDROCARBON BLEND (MINUS 30)
150.0
100.0
50
0
30
60
40
20
20.0
-20
T = -40˚C
20
15
10.0
m3
7.0 p = 10 kg /
7.0
0.5
0.9
0.8
0.7
0.6
0.4
0.3
0.2
0.1
Pressure (bar)
4.0 5.0
x=
3.0
2.0
E
2.0
LIN
LINE
INT
1.5
PO
1.0
80
60
40
20
200
180
160
140
120
100
E-
OINT
L
T = 0˚C
-P
1.0
BB
0.7
BU
DEW
K
3.6
3.4
3.2
3.0
2.8
2.6
2.4
2.0
2.2
1.8
1.6
1.2
1.4
0.8
0.4
g = 1.0 kJ / kg
0.3
100 200 300 400 500 600 700 800 900 1000
Enthalpy (kJ/kg)
HyChill Australia Pty Ltd
85a Canterbury Rd, Kilsyth,
Victoria, Australia 3137
Ph: +61 3 9728 5055
Fax: +61 3 9761 8799
Email: [email protected]
Web: www.hychill.com.au
140624
Disclaimer: Every effort has been made to ensure the contents of this publication were accurate and up to date at the time of going to press (Sept 2007).