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DPP-3 Redox Reaction

The document provides examples of balancing redox reactions using oxidation number and ion-electron methods. It includes sample problems balancing equations like Cu + HNO3 → Cu(NO3)2 + NO2 + H2O and NH4OH + Br2 → NH4Br + H2O + N2. The document also asks multiple choice questions testing the ability to balance reactions and determine stoichiometric coefficients using redox concepts.

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Ramacharyulu
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269 views32 pages

DPP-3 Redox Reaction

The document provides examples of balancing redox reactions using oxidation number and ion-electron methods. It includes sample problems balancing equations like Cu + HNO3 → Cu(NO3)2 + NO2 + H2O and NH4OH + Br2 → NH4Br + H2O + N2. The document also asks multiple choice questions testing the ability to balance reactions and determine stoichiometric coefficients using redox concepts.

Uploaded by

Ramacharyulu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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DPP-3

Redox reaction
“Failure is the opportunity to begin again more intelligently.”

Mohit Ryan Sir


Balance the following reaction by the oxidation number method :
Cu + HNO3 → Cu(NO3)2 + NO2 + H2O
Solution:
Balance the following reaction by the oxidation number method :
MnO4- + Fe2+ → Mn+2 + Fe+3
Solution:
Balance the following reaction
V + H2O → H4V6O17 + H2
Solution:
Balance the following reaction
NH4OH + Br2 → NH4Br + H2O + N2
Solution:
In the reaction
x HI + y HNO3 → NO + I2 + H2O

A x = 3, y = 2

B x = 2, y = 3

C x = 6, y = 2

D x = 6, y = 1
In the reaction
x HI + y HNO3 → NO + I2 + H2O

A x = 3, y = 2

B x = 2, y = 3

C x = 6, y = 2

D x = 6, y = 1
Solution:
For the redox reaction
MnO4- + C2O42- + H+ → Mn2+ + CO2 + H2O
The correct stoichiometric coefficients of MnO4-, C2O42- and H+ are
respectively.

A 2, 5, 16

B 16, 5, 2

C 5, 16, 2

D 2, 16, 5
For the redox reaction
MnO4- + C2O42- + H+ → Mn2+ + CO2 + H2O
The correct stoichiometric coefficients of MnO4-, C2O42- and H+ are
respectively.

A 2, 5, 16

B 16, 5, 2

C 5, 16, 2

D 2, 16, 5
Solution:
During the disproportionation of iodine to iodide and iodate ions,
the ratio of iodate and iodide ions formed in alkaline medium is

A 1:5

B 5:1

C 3:1

D 1:3
During the disproportionation of iodine to iodide and iodate ions,
the ratio of iodate and iodide ions formed in alkaline medium is

A 1:5

B 5:1

C 3:1

D 1:3
Solution:
Balance the following equation by ion electron method.

FeCl3 H2S → FeCl2 + HCl + S


Solution:
FeCl3 +H2S ⟶ FeCl2 + HCl + S
Ionic equation, Fe3+ + H2S ⟶ Fe2+ + H+ + S
1 Step. Splitting the redox reaction into two half reactions,
H2S ⟶ 2H+ + S Fe3+ ⟶ Fe2+
(oxidation half reaction) (Reduction half reaction)

2nd step. Adding electrons to the side deficient in electrons,


H2S ⟶ 2H+ + S + 2e
Fe3+ + e ⟶ Fe2+
3rd step. Balancing electrons in both the half reactions,
H2S ⟶ 2H+ + S + 2e
2Fe3+ 2e ⟶ 2Fe2+
Solution:
4th Step. Adding both the half reaction,
H2S + 2Fe3+ ⟶ 2H+ + S + 2Fe2+
Converting it into molecular form,
H2S + 2Fe3+ + 6Cl- ⟶ 2H+ + 2Cl- + S + 2Fe2+ + 4Cl-
Or H2S + 2FeCl3 ⟶ 2HCl + S + 2FeCl2
Balance the following equation by ion electron method.

Cu + HNO3 → Cu(NO3)2 + NO + H2O


Solution:

Cu + HNO3 ⟶ Cu(NO3)2 + NO + H2O


Ionic equation,
Cu + H+ +NO3- ⟶ Cu2+ + NO + H2O
Ist step. Splitting into half reaction
Cu ⟶ Cu2+ ; NO3- + H+ ⟶NO+ H2O
(oxidation half reaction) (Reduction half reaction)
2nd Step. Adding H+ ions to the side deficient in hydrogen,
Cu ⟶ Cu2+ ; NO3- + 4H+ ⟶ NO + 2H2O
Solution:

4th step. Balancing electrons in both half reactions,


3Cu ⟶3Cu2+ +6e; 2NO3- + 8H+ + 6e ⟶ 2NO+ 4H2O
5th Step. Adding both the half reactions,
3Cu ⟶ 2NO3- + 8H+ + 6NO3- ⟶ 3Cu2+ + 6NO3- + 2NO+ 4H2O
Or 3Cu + 8HNO3 ⟶ 3Cu(NO3)2 + 2NO + 4H2O
Balance the following equation by ion electron method.

KI + Cl2 → KCl + I2
Solution:

KI + Cl2 ⟶ KCl + I2
Ionic equation, I- + Cl2 ⟶ Cl- + I2
Splitting into two half reactions,
I- ⟶ I2 ; Cl2 ⟶ Cl-
(oxidation) (Reduction)
Making number of atoms equal,
2I- ⟶ I2 ; Cl2 ⟶ 2Cl-
Adding electrons to the sides deficient in electrons,
2I- ⟶ I2 +2e ; Cl2+ 2e ⟶ 2Cl-
Adding both the half reactions
2I- +Cl2 ⟶ I2 + 2Cl-
Converting it into molecular form,
2K+ + 2I- + Cl2 ⟶ I2 + 2Cl- +2 K+
or 2KI + Cl2 ⟶ I2 +2KCl
Balance the following equation by ion electron method.

H2S + HNO3 → H2SO4 + NO2 + H2O


Solution:

H2S + HNO3⟶ H2SO4 + NO2 +H2O


Ionic equation,
H2S +NO3- ⟶ NO2 +H2O
1st step. Splitting into two half reactions,
H2S ⟶ SO42- ; NO3- ⟶ NO2 +H2O
(oxidation half reaction) (Reduction half reaction)
2nd step. Add water to the side deficient oxygen
H2S + 4H2O ⟶ SO42- + 10H+
3rd step. Add H+ ions to the side deficient in hydrogen,
NO3- + 2H+ ⟶ NO2 +H2O
4th step. Add electrons to the side deficient in electrons,
H2S + 4H2O ⟶ SO42- + 10H+ + 8e
NO3- + 2H+ + e- ⟶ NO2 +H2O
Solution:

5th step. Balancing electrons in both the half reactions,


H2S + 4H2O ⟶ SO42- + 10H+ + 8e
[NO3- + 2H+ + e ⟶NO2 + H2O]×8
6th step. Adding Both the half reactions,
H2S +4H2O +8NO3- +6H+ ⟶SO42- +8NO2 +8H2O
or H2S +8NO3- +6H+ ⟶ SO42- +8NO2 +4H2O
Converting it into molecular form
H2S +8HNO3 ⟶ H2SO4 +8NO2 +4H2O
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