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LOCTITE 567 Adhesive SDS

This document is a safety data sheet for LOCTITE 567 250ML 2/CASE M/L adhesive. It lists the product identifier and supplier contact information. The product contains reaction product: bisphenol-A-(epichlorhydrin); epoxy resin. It is classified as a skin sensitizer and the label contains precautionary statements to wear protective gloves and get medical advice if skin irritation occurs. The document provides the composition of the product listing hazardous components such as epoxy resin, cumene hydroperoxide, and various aromatic amines.

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0% found this document useful (0 votes)
137 views16 pages

LOCTITE 567 Adhesive SDS

This document is a safety data sheet for LOCTITE 567 250ML 2/CASE M/L adhesive. It lists the product identifier and supplier contact information. The product contains reaction product: bisphenol-A-(epichlorhydrin); epoxy resin. It is classified as a skin sensitizer and the label contains precautionary statements to wear protective gloves and get medical advice if skin irritation occurs. The document provides the composition of the product listing hazardous components such as epoxy resin, cumene hydroperoxide, and various aromatic amines.

Uploaded by

Edgar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 16

Safety Data Sheet according to (EC) No 1907/2006

Page 1 of 16
SDS No. : 153487
V005.0
LOCTITE 567 250ML 2/CASE M/L Revision: 18.05.2016
printing date: 27.05.2016
Replaces version from: 10.09.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
LOCTITE 567 250ML 2/CASE M/L

Contains:
Reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700)

1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Adhesive

1.3. Details of the supplier of the safety data sheet


Henkel Ltd
Wood Lane End
HP2 4RQ Hemel Hempstead

Great Britain

Phone: +44 1442 278000


Fax-no.: +44 1442 278071

[email protected]

1.4. Emergency telephone number


24 Hours Emergency Tel: +44 (0)1442 278497

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Classification (CLP):
Skin sensitizer Category 1
H317 May cause an allergic skin reaction.

2.2. Label elements

Label elements (CLP):

Hazard pictogram:

Signal word: Warning

Hazard statement: H317 May cause an allergic skin reaction.


MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 2 of 16
V005.0

Precautionary statement: ***For consumer use only: P101 If medical advice is needed, have product container or
label at hand. P102 Keep out of reach of children. P501 Dispose of waste and residues in
accordance with local authority requirements***

Precautionary statement: P280 Wear protective gloves.


Prevention

Precautionary statement: P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
Response

2.3. Other hazards


None if used properly.
Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.

SECTION 3: Composition/information on ingredients


3.2. Mixtures

General chemical description:


Anaerobic Sealant
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 3 of 16
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Declaration of the ingredients according to CLP (EC) No 1272/2008:

Hazardous components EC Number content Classification


CAS-No. REACH-Reg No.
Reaction product: bisphenol-A- 500-033-5 1- < 2,5 % Skin Irrit. 2
(epichlorhydrin); epoxy resin (number 500-033-5 H315
average molecular weight <= 700) 01-2119456619-26 Skin Sens. 1
25068-38-6 H317
Eye Irrit. 2
H319
Aquatic Chronic 2
H411

Cumene hydroperoxide 201-254-7 0,1- < 1 % Acute Tox. 4; Dermal


80-15-9 H312
STOT RE 2
H373
Acute Tox. 4; Oral
H302
Org. Perox. E
H242
Acute Tox. 3; Inhalation
H331
Aquatic Chronic 2
H411
Skin Corr. 1B
H314

N,N-dimethyl-o-toluidine 210-199-8 0,1- < 1 % Acute Tox. 3; Inhalation


609-72-3 H331
Acute Tox. 3; Dermal
H311
Acute Tox. 3; Oral
H301
STOT RE 2
H373
Aquatic Chronic 3
H412

N,N-Diethyl-p-toluidine 210-345-0 0,1- < 1 % Acute Tox. 3; Oral


613-48-9 H301
Acute Tox. 3; Dermal
H311
Acute Tox. 3; Inhalation
H331
STOT RE 2
H373
Aquatic Chronic 3
H412

1,4-Naphthalenedione 204-977-6 100- < 250 PPM Acute Tox. 3; Oral


130-15-4 H301
Skin Irrit. 2; Dermal
H315
Skin Sens. 1; Dermal
H317
Eye Irrit. 2
H319
Acute Tox. 1; Inhalation
H330
STOT SE 3; Inhalation
H335
Aquatic Acute 1
H400
Aquatic Chronic 1
H410
M factor (Acute Aquat Tox): 10

For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 4 of 16
V005.0

SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Move to fresh air. If symptoms persist, seek medical advice.

Skin contact:
Rinse with running water and soap.
Obtain medical attention if irritation persists.

Eye contact:
Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist.

Ingestion:
Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed
Prolonged or repeated contact may cause eye irritation.

May cause an allergic skin reaction.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media:
Foam, extinguishing powder, carbon dioxide.

Extinguishing media which must not be used for safety reasons:


High pressure waterjet

5.2. Special hazards arising from the substance or mixture


Do not expose to direct heat.
Trace amounts of toxic and/or irritating fumes may be released and the use of breathing apparatus is recommended.

5.3. Advice for firefighters


Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Additional information:
In case of fire, keep containers cool with water spray.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Ensure adequate ventilation.

6.2. Environmental precautions


Do not let product enter drains.

6.3. Methods and material for containment and cleaning up


For small spills wipe up with paper towel and place in container for disposal.
For large spills absorb onto inert absorbent material and place in sealed container for disposal.
Dispose of contaminated material as waste according to Section 13.

6.4. Reference to other sections


See advice in section 8

SECTION 7: Handling and storage


MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 5 of 16
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7.1. Precautions for safe handling


Use only in well-ventilated areas.
Gloves and safety glasses should be worn
Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation.
Avoid skin and eye contact.
See advice in section 8

Hygiene measures:
Good industrial hygiene practices should be observed.
Do not eat, drink or smoke while working.
Wash hands before work breaks and after finishing work.

7.2. Conditions for safe storage, including any incompatibilities


Keep away from heat and direct sunlight.
Keep container in a well ventilated place.

7.3. Specific end use(s)


Adhesive
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 6 of 16
V005.0

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits

Valid for
Great Britain

Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list
category / Remarks
Titanium dioxide 10 Time Weighted Average EH40 WEL
13463-67-7 (TWA):
[TITANIUM DIOXIDE, TOTAL
INHALABLE]
Titanium dioxide 4 Time Weighted Average EH40 WEL
13463-67-7 (TWA):
[TITANIUM DIOXIDE, RESPIRABLE]
Silicon dioxide 6 Time Weighted Average EH40 WEL
112945-52-5 (TWA):
[SILICA, AMORPHOUS, INHALABLE
DUST]
Silicon dioxide 2,4 Time Weighted Average EH40 WEL
112945-52-5 (TWA):
[SILICA, AMORPHOUS, RESPIRABLE
DUST]
Cumene 50 250 Short Term Exposure EH40 WEL
98-82-8 Limit (STEL):
[CUMENE]
Cumene Skin designation: Can be absorbed through the EH40 WEL
98-82-8 skin.
[CUMENE]
Cumene 25 125 Time Weighted Average EH40 WEL
98-82-8 (TWA):
[CUMENE]
Cumene 50 250 Short Term Exposure Indicative ECTLV
98-82-8 Limit (STEL):
[CUMENE]
Cumene 20 100 Time Weighted Average Indicative ECTLV
98-82-8 (TWA):
[CUMENE]

Occupational Exposure Limits

Valid for
Ireland

Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list
category / Remarks
Titanium dioxide 4 Time Weighted Average IR_OEL
13463-67-7 (TWA):
[TITANIUM DIOXIDE, RESPIRABLE
DUST]
Titanium dioxide 10 Time Weighted Average IR_OEL
13463-67-7 (TWA):
[TITANIUM DIOXIDE, TOTAL
INHALABLE DUST]
Silicon dioxide 6 Time Weighted Average IR_OEL
112945-52-5 (TWA):
[SILICA, AMORPHOUS, TOTAL
INHALABLE DUST]
Silicon dioxide 2,4 Time Weighted Average IR_OEL
112945-52-5 (TWA):
[SILICA, AMORPHOUS, RESPIRABLE
DUST]
Cumene 20 100 Time Weighted Average Indicative OELV IR_OEL
98-82-8 (TWA):
[ISOPROPYL BENZENE]
Cumene 50 250 Short Term Exposure Indicative OELV IR_OEL
98-82-8 Limit (STEL):
[ISOPROPYL BENZENE]
Cumene Skin designation: Can be absorbed through the IR_OEL
98-82-8 skin.
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 7 of 16
V005.0

[ISOPROPYL BENZENE]
Cumene 50 250 Short Term Exposure Indicative ECTLV
98-82-8 Limit (STEL):
[CUMENE]
Cumene 20 100 Time Weighted Average Indicative ECTLV
98-82-8 (TWA):
[CUMENE]

Predicted No-Effect Concentration (PNEC):

Name on list Environmental Exposure Value Remarks


Compartment period
mg/l ppm mg/kg others
Reaction product: bisphenol-A- aqua 0,006 mg/L
(epichlorhydrin); epoxy resin (number (freshwater)
average molecular weight <= 700)
25068-38-6
Reaction product: bisphenol-A- aqua (marine 0,001 mg/L
(epichlorhydrin); epoxy resin (number water)
average molecular weight <= 700)
25068-38-6
Reaction product: bisphenol-A- aqua 0,018 mg/L
(epichlorhydrin); epoxy resin (number (intermittent
average molecular weight <= 700) releases)
25068-38-6
Reaction product: bisphenol-A- sewage 10 mg/L
(epichlorhydrin); epoxy resin (number treatment plant
average molecular weight <= 700) (STP)
25068-38-6
Reaction product: bisphenol-A- sediment 0,996
(epichlorhydrin); epoxy resin (number (freshwater) mg/kg
average molecular weight <= 700)
25068-38-6
Reaction product: bisphenol-A- sediment 0,1 mg/kg
(epichlorhydrin); epoxy resin (number (marine water)
average molecular weight <= 700)
25068-38-6
Reaction product: bisphenol-A- soil 0,196
(epichlorhydrin); epoxy resin (number mg/kg
average molecular weight <= 700)
25068-38-6
Reaction product: bisphenol-A- oral 11 mg/kg
(epichlorhydrin); epoxy resin (number food
average molecular weight <= 700)
25068-38-6
.alpha.,.alpha.-Dimethylbenzyl aqua 0,0031 mg/L
hydroperoxide (freshwater)
80-15-9
.alpha.,.alpha.-Dimethylbenzyl aqua (marine 0,00031 mg/L
hydroperoxide water)
80-15-9
.alpha.,.alpha.-Dimethylbenzyl aqua 0,031 mg/L
hydroperoxide (intermittent
80-15-9 releases)
.alpha.,.alpha.-Dimethylbenzyl Sewage 0,35 mg/L
hydroperoxide treatment plant
80-15-9
.alpha.,.alpha.-Dimethylbenzyl sediment 0,023
hydroperoxide (freshwater) mg/kg
80-15-9
.alpha.,.alpha.-Dimethylbenzyl sediment 0,0023
hydroperoxide (marine water) mg/kg
80-15-9
.alpha.,.alpha.-Dimethylbenzyl soil 0,0029
hydroperoxide mg/kg
80-15-9
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 8 of 16
V005.0

Derived No-Effect Level (DNEL):

Name on list Application Route of Health Effect Exposure Value Remarks


Area Exposure Time
Reaction product: bisphenol-A- Workers dermal Acute/short term 8,33 mg/kg bw/day
(epichlorhydrin); epoxy resin (number exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- Workers Inhalation Acute/short term 12,25 mg/m3
(epichlorhydrin); epoxy resin (number exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- Workers dermal Long term 8,33 mg/kg bw/day
(epichlorhydrin); epoxy resin (number exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- Workers Inhalation Long term 12,25 mg/m3
(epichlorhydrin); epoxy resin (number exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- general dermal Acute/short term 3,571 mg/kg bw/day
(epichlorhydrin); epoxy resin (number population exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- general dermal Long term 3,571 mg/kg bw/day
(epichlorhydrin); epoxy resin (number population exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- general Inhalation Acute/short term 0,75 mg/m3
(epichlorhydrin); epoxy resin (number population exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- general Inhalation Long term 0,75 mg/m3
(epichlorhydrin); epoxy resin (number population exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- general oral Acute/short term 0,75 mg/kg bw/day
(epichlorhydrin); epoxy resin (number population exposure -
average molecular weight <= 700) systemic effects
25068-38-6
Reaction product: bisphenol-A- general oral Long term 0,75 mg/kg bw/day
(epichlorhydrin); epoxy resin (number population exposure -
average molecular weight <= 700) systemic effects
25068-38-6
.alpha.,.alpha.-Dimethylbenzyl Workers inhalation Long term 6 mg/m3
hydroperoxide exposure -
80-15-9 systemic effects

Biological Exposure Indices:


None

8.2. Exposure controls:

Engineering controls:
Ensure good ventilation/extraction.

Respiratory protection:
Ensure adequate ventilation.
An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly
ventilated area
Filter type: A (EN 14387)
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 9 of 16
V005.0

Hand protection:
Chemical-resistant protective gloves (EN 374).
Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes
permeation time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time
as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy
with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably
shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g.
temperature). If signs of wear and tear are noticed then the gloves should be replaced.

Eye protection:
Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing.
Protective eye equipment should conform to EN166.

Skin protection:
Wear suitable protective clothing.
Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts.

Advices to personal protection equipment:

The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be
conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions.
Personal protective equipment should conform to the relevant EN standard.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Appearance paste
white
Odor mild
Odour threshold No data available / Not applicable

pH Not determined
Initial boiling point > 149 °C (> 300.2 °F)
Flash point > 93,3 °C (> 199.94 °F)
Decomposition temperature No data available / Not applicable
Vapour pressure < 27 mbar
(27 °C (80.6 °F))
Vapour pressure < 300 mbar
(50 °C (122 °F))
Density 1,14 g/cm3
()
Bulk density No data available / Not applicable
Viscosity No data available / Not applicable
Viscosity (kinematic) No data available / Not applicable
Explosive properties No data available / Not applicable
Solubility (qualitative) Slight
(Solvent: Water)
Solubility (qualitative) Not determined
(Solvent: Acetone)
Solidification temperature No data available / Not applicable
Melting point No data available / Not applicable
Flammability No data available / Not applicable
Auto-ignition temperature No data available / Not applicable
Explosive limits No data available / Not applicable
Partition coefficient: n-octanol/water No data available / Not applicable
Evaporation rate No data available / Not applicable
Vapor density No data available / Not applicable
Oxidising properties No data available / Not applicable
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 10 of 16
V005.0

9.2. Other information

No data available / Not applicable

SECTION 10: Stability and reactivity


10.1. Reactivity
Acids.
Oxidizers.
Alkali metals
Reaction with reducing agents.
Free radical initiators.
Peroxides.

10.2. Chemical stability


Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions


See section reactivity

10.4. Conditions to avoid


No decomposition if used according to specifications.
Protect from direct sunlight.

10.5. Incompatible materials


See section reactivity

10.6. Hazardous decomposition products


carbon oxides.

SECTION 11: Toxicological information


11.1. Information on toxicological effects

General toxicological information:


The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for
mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.

Oral toxicity:

May cause irritation to the digestive tract.

Inhalative toxicity:
May cause irritation to respiratory system.

Skin irritation:
Prolonged or repeated contact may cause skin irritation.

Eye irritation:
Prolonged or repeated contact may cause eye irritation.

Sensitizing:
May cause an allergic skin reaction.
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 11 of 16
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Acute oral toxicity:

Hazardous components Value Value Route of Exposure Species Method


CAS-No. type application time
Reaction product: LD50 > 5.000 mg/kg oral rat Not specified
bisphenol-A-
(epichlorhydrin); epoxy
resin (number average
molecular weight <= 700)
25068-38-6
Cumene hydroperoxide LD50 550 mg/kg oral rat
80-15-9
1,4-Naphthalenedione LD50 190 mg/kg oral rat
130-15-4

Acute dermal toxicity:

Hazardous components Value Value Route of Exposure Species Method


CAS-No. type application time
Reaction product: LD50 23.000 mg/kg dermal rabbit
bisphenol-A-
(epichlorhydrin); epoxy
resin (number average
molecular weight <= 700)
25068-38-6
Cumene hydroperoxide LD50 1.200 - 1.520 dermal
80-15-9 mg/kg

Skin corrosion/irritation:

Hazardous components Result Exposure Species Method


CAS-No. time
Reaction product: slightly irritating 4h rabbit OECD Guideline 404 (Acute
bisphenol-A- Dermal Irritation / Corrosion)
(epichlorhydrin); epoxy
resin (number average
molecular weight <= 700)
25068-38-6
Cumene hydroperoxide corrosive rabbit Draize Test
80-15-9

Serious eye damage/irritation:

Hazardous components Result Exposure Species Method


CAS-No. time
Reaction product: not irritating rabbit OECD Guideline 405 (Acute
bisphenol-A- Eye Irritation / Corrosion)
(epichlorhydrin); epoxy
resin (number average
molecular weight <= 700)
25068-38-6

Respiratory or skin sensitization:

Hazardous components Result Test type Species Method


CAS-No.
Reaction product: sensitising Mouse mouse OECD Guideline 429 (Skin
bisphenol-A- local Sensitisation: Local Lymph
(epichlorhydrin); epoxy lymphnod Node Assay)
resin (number average e assay
molecular weight <= 700) (LLNA)
25068-38-6
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 12 of 16
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Germ cell mutagenicity:

Hazardous components Result Type of study / Metabolic Species Method


CAS-No. Route of activation /
administration Exposure time
Reaction product: negative bacterial reverse OECD Guideline 472 (Genetic
bisphenol-A- mutation assay (e.g Toxicology: Escherichia coli,
(epichlorhydrin); epoxy Ames test) Reverse Mutation Assay)
resin (number average
molecular weight <= 700)
25068-38-6
Cumene hydroperoxide positive bacterial reverse without OECD Guideline 471
80-15-9 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
Cumene hydroperoxide negative dermal mouse
80-15-9

Repeated dose toxicity

Hazardous components Result Route of Exposure time / Species Method


CAS-No. application Frequency of
treatment
Cumene hydroperoxide inhalation: 6 h/d5 d/w rat
80-15-9 aerosol

SECTION 12: Ecological information


General ecological information:
The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for
mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.

12.1. Toxicity

Ecotoxicity:
Do not empty into drains / surface water / ground water.
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 13 of 16
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Hazardous components Value Value Acute Exposure Species Method


CAS-No. type Toxicity time
Study
Reaction product: bisphenol- LC50 1,75 mg/l Fish 96 h Oncorhynchus mykiss (reported OECD Guideline
A-(epichlorhydrin); epoxy as Salmo gairdneri) 203 (Fish, Acute
resin (number average Toxicity Test)
molecular weight <= 700)
25068-38-6
Reaction product: bisphenol- EC50 9,4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline
A-(epichlorhydrin); epoxy 201 (Alga, Growth
resin (number average Inhibition Test)
molecular weight <= 700)
25068-38-6
NOEC 2,4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline
201 (Alga, Growth
Inhibition Test)
Reaction product: bisphenol- NOEC 0,3 mg/l chronic 21 d Daphnia magna OECD 211
A-(epichlorhydrin); epoxy Daphnia (Daphnia magna,
resin (number average Reproduction Test)
molecular weight <= 700)
25068-38-6
Cumene hydroperoxide LC50 3,9 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline
80-15-9 203 (Fish, Acute
Toxicity Test)
Cumene hydroperoxide EC50 18 mg/l Daphnia 48 h Daphnia magna OECD Guideline
80-15-9 202 (Daphnia sp.
Acute
Immobilisation
Test)
Cumene hydroperoxide ErC50 3,1 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline
80-15-9 201 (Alga, Growth
Inhibition Test)
Cumene hydroperoxide EC10 70 mg/l Bacteria 30 min
80-15-9
1,4-Naphthalenedione EC50 0,011 mg/l Algae 72 h Dunaliella bioculata OECD Guideline
130-15-4 201 (Alga, Growth
Inhibition Test)

12.2. Persistence and degradability

Persistence and Biodegradability:


The product is not biodegradable.

Hazardous components Result Route of Degradability Method


CAS-No. application
Reaction product: bisphenol- aerobic 5% OECD Guideline 301 F (Ready
A-(epichlorhydrin); epoxy Biodegradability: Manometric
resin (number average Respirometry Test)
molecular weight <= 700)
25068-38-6
Cumene hydroperoxide no data 0% OECD Guideline 301 B (Ready
80-15-9 Biodegradability: CO2 Evolution
Test)
1,4-Naphthalenedione no data 0 - 60 % OECD 301 A - F
130-15-4

12.3. Bioaccumulative potential / 12.4. Mobility in soil

Mobility:
Cured adhesives are immobile.

Bioaccumulative potential:
No data available.

Hazardous components LogKow Bioconcentration Exposure Species Temperature Method


CAS-No. factor (BCF) time
Cumene hydroperoxide 9,1 calculation OECD Guideline 305
80-15-9 (Bioconcentration: Flow-
through Fish Test)
Cumene hydroperoxide 2,16
80-15-9
1,4-Naphthalenedione 1,71
130-15-4
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 14 of 16
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12.5. Results of PBT and vPvB assessment

Hazardous components PBT/vPvB


CAS-No.
Reaction product: bisphenol-A-(epichlorhydrin); Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
epoxy resin (number average molecular weight Bioaccumulative (vPvB) criteria.
<= 700)
25068-38-6
Cumene hydroperoxide Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
80-15-9 Bioaccumulative (vPvB) criteria.

12.6. Other adverse effects

No data available.

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Product disposal:
Dispose of in accordance with local and national regulations.
Contribution of this product to waste is very insignificant in comparison to article in which it is used

Disposal of uncleaned packages:


After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an
authorised legal land fill site or incinerated.
Disposal must be made according to official regulations.

Waste code
08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances

SECTION 14: Transport information


14.1. UN number

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.2. UN proper shipping name

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.3. Transport hazard class(es)

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.4. Packing group

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.5. Environmental hazards

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.6. Special precautions for user

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 15 of 16
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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC content <3%
(2010/75/EC)

15.2. Chemical safety assessment


A chemical safety assessment has not been carried out.
MSDS-No.: 153487 LOCTITE 567 250ML 2/CASE M/L Page 16 of 16
V005.0

SECTION 16: Other information


The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
H242 Heating may cause a fire.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular
properties.

Label elements (DPD):

Xi - Irritant

Risk phrases:
R43 May cause sensitisation by skin contact.

Safety phrases:
S24 Avoid contact with skin.
S37 Wear suitable gloves.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.

Additional labeling:
Contains epoxy constituents. See information supplied by the manufacturer.
For consumer use only: S2 Keep out of the reach of children.
S46 If swallowed, seek medical advice immediately and show this container or label.

Contains:
Reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700)

Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document.
Corresponding text is displayed in a different color on shadowed fields.

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