ENGINEERING DESIGN CALCULATION - DENNIS KIRK ENGINEERING

Calculation of Gas Properties - GPSA Engineering Data Book - SI Units - 11th Edition 1998 Version 1.513

CALCULATION TITLE

SEAGas
Pipeline
Design - Uniformly
Minerva Normalised
mole % mole %
CH4 Methane 93.605 93.6050 %
C2H6 Ethane 2.24 2.2400 %
C3H8 Propane 0.81 0.8100 % R= 8.314510 kJ/mol.oK
C4H10 I-Butane 0.107 0.1070 % MW air= 28.9625 kg/kmol
C4H10 n-Butane 0.171 0.1710 % Zb air= 0.99958
C5H12 i-Pentane 0.057 0.0570 % Pb= 0 kPa(g) 0 0 psi(g)
C5H12 n-Pentane 0.052 0.0520 % Ps= 101.325 kPa(abs)
C6H14 n-Hexane 0.098 0.0980 % Pb= 101.325 kPa(abs)
o o
C7H16 n-Heptane 0.0000 % Tb= 15 C 15 59 F
o
C8H18 n-Octane 0.0000 % Ts= 273.15 K
o
C9H20 n-Nonane 0.0000 % Tb= 288.15 K
C10H22 n-Decane 0.0000 %
C6H6 Benzene 0.0000 %
CO Carbon Monoxide 0.0000 %
CO2 Carbon Dioxide 1.885 1.8850 %
H2S Hydrogen Sulfide 0.0000 %
N2+02 Air 0.0000 %
H2 Hydrogen 0.0000 %
O2 Oxygen 0.0000 %
N2 Nitrogen 0.972 0.9720 %
H2O Water 0.003 0.0030 %
100.0000 100.0000 %
MW 17.4749 kg/kmol 17.4797 from AGA8 GCM2 Method
SG ideal 0.6034 Specific Gravity 0.6035 from AGA8 GCM2 Method
SG real 0.6046 0.6046 from AGA8 GCM2 Method
Zb [15oC, 0 kPa(g)] 0.9975 Compressibility at base conditions 0.9978 from AGA8 GCM2 Method
3
HHV ideal 38.2125 MJ/Sm Higher Heating Value
3
HHV real 38.2975 MJ/Sm Wobbe Index 49.253544 38.2797 from AGA8 GCM2 Method
3
LHV ideal 34.4554 MJ/Sm Lower Heating Value
3
LHV real 34.5320 MJ/Sm
P 6900 kPa(g) Operating Pressure 1000.776 psi(g)
o o
T 69.8 C Operating Temperature 157.64 F
P 7001.325 kPa(abs)
o
T 342.95 K
Pc 4597.01 kPa(abs) Pseudo Critical Pressure includes Wichert & Aziz Correction for Sour Gas
o
Tc 195.60 K Pseudo Critical Temperature includes Wichert & Aziz Correction for Sour Gas
Vc 0.0058 m3/kg Pseudo Critical Specific Volume
Zc 0.2868 Pseudo Critical Compressibility
Pr (Pro) 1.5230 0.0220 Pseudo Reduced Pressure
Tr 1.7533 Pseudo Reduced Temperature
Z (MW<40, P<70MPa) 0.9248 Compressibility (Pr 0 to 15, Tr 1 to 3) 0.9295 from AGA8 GCM2 Method
3
d 46.3972 kg/m Density 46.0937 from AGA8 GCM2 Method
Cpo (T -25 to 150oC)
o o
38.8280 kJ/kmole. C Heat Capacity (Pconstant) 2221.9282 J/kg. C
o o
Cvo 30.5135 kJ/kmole. C Heat Capacity (T constant) 1746.131 J/kg. C
o o
ko=Cpo/Cvo 1.2725 Thermal Conductivity 0.0473265 W/m. C (MW>16, 20<T<200 C, Pr<8, 1<Tr<3)
o o
Cp 44.0491 kJ/kmole. C refer Redlich-Kwong 2520.7087 J/kg. C
o o
Cv 32.6013 kJ/kmole. C Equations of State 1865.6061 J/kg. C
k=Cp/Cv 1.3511 Velocity of Sound 438.67355 m/sec
w 0.0200 Acentric Factor
o
u (T -130 to 500 C) 0.0149 cP (mPa.s) Viscosity from Fig 23-23 (P 0 to 21 Mpa)
ua @101.325 kPa(a) 0.01206114 cP (mPa.s) or Viscosity from 23-22 (if Tr > 1.0)
u/ua 1.12063134 and pressure correction from 23-24
u 0.0135 cP (mPa.s) 0.0137468 from John M Campbell & Co
or if high levels of non hydrocarbons are present (eg 20%)
E 0.04532 Eq 23-20 (corrected)
E.ua 0.00056 Eq 23-21 (corrected) and Eq 23-22
ua @101.325 kPa(a) 0.01241 cP (mPa.s) for high levels of non hydrocarbons
u 0.0139 cP (mPa.s) with pressure correction from 23-24
H (T -30 to 480oC) 10890.7928 kJ/kmol Enthalpy (Pr 0.1 to 10, Tr 1 to 4) Note:H=0 for T=0oK and P=0 kPa(abs)
623.224831 kJ/kg Note: Values for Hexane, Heptane, Octane, Nonane, Decane are approximate only!
JT 2.8878889 oC/MPa JT Effect of Gas Expansion 2.8924 from AGA8 GCM2 Method
S (T -80 to 240oC) 181.128199 kJ/kmole.K Entropy (Pr 01 to 10, Tr 0.8 to 4) Note:S=0 for T=0oK and P=0 kPa(abs)
10.365 kJ/kg.K Note: Values for Hexane, Heptane, Octane, Nonane, Decane are not available!

GPSAGasProp.xls Gas Prop Calc SI 10/03/2003