page 23-9
Liquid Volume Fraction Calc
Given: Total pounds mass = 825,3
Component mole fraction (x) MW x•MW
Carbon Dioxide 0.0011 44.01 0.048411
Methane 0.0214 16.043 0.3433202
Ethane 0.3897 30.07 11.718279
Propane 0.3648 44.097 16.0865856
Iso-butane 0.0294 58.123 1.7088162
Normal-butane 0.0877 58.123 5.0973871
Iso-pentane 0.0171 72.15 1.233765
Normal-pentane 0.0182 72.15 1.31313
Hexanes + 0.0706 87.436 6.1729816
TOTAL 1 43.7226757
page 23-9
Liquid Volume Fraction Calculation
ven: Total pounds mass = 825,300 Lbm
mass fraction (M) lbm FIG. 23-2 (lbm/gal) gal v
0.0011072287 913.79582 6.8199 133.989622 0.00065135
0.007852223 6480.43965 2.5 2592.17586 0.01260115
0.2680137666 221191.762 2.9696 74485.3723 0.36209019
0.3679231736 303646.995 4.2268 71838.5055 0.34922317
0.0390830655 32255.254 4.6927 6873.49585 0.03341361
0.1165845186 96217.2032 4.8691 19760.7778 0.0960616
0.0282179665 23288.2878 5.2058 4473.52718 0.02174682
0.0300331574 24786.3648 5.2614 4710.98278 0.02290115
0.1411849001 116519.898 5.591 20840.6185 0.10131095
1 825300 205709.445 1
specific volume (V)
1.5
Fig. 24-27 f(T,P)
density (ρ) 0.6666666667
MW 44.1
T 200
P 100
gas constant (R) 10.73
Z-factor 0.9359706775
page 23-11
Pure Component Properties
ft3/lbm SRK91 equation
lbm/ft3
°F
psia
(psia ft3)/(°R lbmol)
Calculation of Pseudo-critical Te
FIG. 23-2
Component
Mole
Critical
Component Fraction,
Temperature,
yi
Tci, °F
CH4 0.8319 -116.66
C2H6 0.0848 89.92
C3H8 0.0437 205.92
iC4H10 0.0076 274.41
nC4H10 0.0168 305.55
iC5H12 0.0057 369
nC5H12 0.0032 385.8
nC6H14 0.0063 453.8
TOTAL 1
page 23-11
Calculation of Pseudo-critical Temperature and Pressure for a Natural Gas Mixture
FIG. 23-2
Component Component
Pseudocritical Pseudocritical
Critical Critical
Temperature, Pressure,
Temperature, Pressure,
Tpc, °R Ppc, psia
Tci, °R Pci, psia
342.01 284.518119 666.4 554.37816
548.59 46.520432 706.5 59.9112
664.59 29.042583 616 26.9192
733.08 5.571408 527.9 4.01204
764.22 12.838896 550.6 9.25008
827.67 4.717719 490.4 2.79528
844.47 2.702304 488.6 1.56352
912.47 5.748561 436.9 2.75247
Tpc = Ppc=
391.660022 661.58195
specific gravity or relative density (gas densit
FIG. 23-2
Component Mixture
Molecular Molecular
Weight, Weight,
MW yi •MW
16.043 13.3461717
30.07 2.549936
44.097 1.9270389
58.123 0.4417348
58.123 0.9764664
72.15 0.411255
72.15 0.23088
86.177 0.5429151
MWm=
20.4263979
ic gravity or relative density (gas density)
G=
0.7063069813
page 23-17
Determine the Z-factor for the sour natural g
Mole
Component Fraction,
yi
H2S 0.2
CO2 0.07
T 100 °F
P 1000 psia.
Tc 433.9 °R
Pc 826.9 psia
age 23-17
ctor for the sour natural gas
ε 29.8 °F Fig. 23-8
Tc' 404.1 °R
Pc' 761.738467 psia
Tr' 1.38497897
Pr' 1.31278653
Z 0.831 Fig. 23-4
page 23-36
Calculation of Viscosity of a Gas Mixture
FIG. 23-2 FIG. 23-2
Component Component Component
Mole
Molecular Molecular Critical
Component Fraction,
Weight, Weight, Pressure,
yi
MW MW Pci, psia
CH4 0.8 16.043 12.8344 667
N2 0.15 28.013 4.20195 492.8
CO2 0.05 44.01 2.2005 1069.5
1 19.23685
e 23-36
ity of a Gas Mixture
FIG. 23-2 FIG. 23-2
Component Component Component
Critical Critical Critical Vci Vci Vci
Temperature, Temperature, Temperature, ft3/lb ft /lb mole
3
ft /lb mole
3
Tci, °F Tci, °R Tci, °R
-116.66 342.01 273.608 0.0988 1.5850484 1.26803872
-232.53 226.14 33.921 0.051 1.428663 0.21429945
87.76 546.43 27.3215 0.0342 1.505142 0.0752571
334.8505 1.55759527
Zci Zci
ft3/lb ft3/lb
0.2880911 0.2304728766
0.29015054 0.0435225814
0.27455162 0.0137275809
0.2877230389
page 23-24
Calculation of Liquid Density of a Mixture at 120°F and 1760 p
FIG. 23-2 FIG. 23-2
Component
Mole
Molecular Relative density
Component Fraction, Weight, lb
Weight, of liquid 60°F
yi
MW
Methane 0.20896 16.043 3.35234528
Carbon Dioxide 0.3973 44.01 17.485173 0.82203
Ethane 0.01886 30.07 0.5671202
Propane 0.02387 44.097 1.05259539 0.50738
n-Butane 0.03586 58.123 2.08429078 0.58408
n-Pentane 0.02447 72.15 1.7655105 0.63113
n-Hexane 0.01844 86.177 1.58910388 0.66404
n-Heptane 0.02983 100.204 2.98908532 0.68819
n-Octane 0.02995 114.231 3.42121845 0.70698
n-Decane 0.18208 142.285 25.9072528 0.73406
n-Tetradecane 0.03038 198.394 6.02720972
TOTAL 1
age 23-24
y of a Mixture at 120°F and 1760 psia
References
Density (60°F) Volume
lb/cu ft cu ft Ludwig’s Applied Process Design for Chemical and Petroch
0 A 0.22827
51.2289096 895.746347 B 0.2724
0 T 288.7055 K
31.6199216 33.2829837 TC 425.18 K
36.3998656 75.8679043 n 0.2863
39.3320216 69.4410971 density 0.58396492 g/mL
41.3829728 65.7618426 density 36.4394107 lb/cu ft
42.8880008 128.195894
44.0589936 150.735442
45.7466192 1185.16923
47.815 288.191033
for Chemical and Petrochemical Plants
Appendix C
Appendix C
Appendix C
Appendix C
page 24-10
Example Enthalpy Calculation
FIG. 23-2 FIG. 23-2
Component Component Component
Mole
Molecular Critical Critical
Component Fraction,
Weight, Temperature, Temperature,
yi
MW Tci, °F Tci, °R
Methane 0.901 16.043 -116.66 342.01
Carbon Dioxide 0.0106 44.01 87.9 546.57
Ethane 0.0499 30.07 89.92 548.59
Propane 0.0187 44.097 205.92 664.59
i-Butane 0.0065 58.123 274.41 733.08
n-Butane 0.0045 58.123 305.55 764.22
i-Pentane 0.0017 72.15 369 827.67
n-Pentane 0.0019 72.15 385.8 844.47
Hexane 0.0052 86.177 453.8 912.47
MWm=
TOTAL 1
2055.64
ge 24-10
e Enthalpy Calculation
FIG. 23-2 FIG. 23-2
?
Component
Pseudocritical Pseudocritical Ideal Gas
Critical Acentric
Temperature, Pressure, Enthalpy
Pressure, Factor
Tpc, °R Ppc, psia Btu/lb
Pci, psia
308.15101 667 600.967 0.0108 292
5.793642 1069.5 11.3367 0.2667 100
27.374641 706.5 35.25435 0.0972 189
12.427833 616 11.5192 0.1515 162
4.76502 527.9 3.43135 0.1852 151
3.43899 550.6 2.4777 0.1981 162
1.407039 490.4 0.83368 0.2286 151
1.604493 488.6 0.92834 0.251 158
4.744844 436.9 2.27188 0.299 139
Tpc = Ppc=
369.707512 669.0202
