PYQ 1
Previous Year Questions
States Of Matter
Ashwani Tyagi
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PYQ 1
Previous Year Questions
States Of Matter
Ashwani Tyagi
Points I, II and III in the
following plot respectively
correspond to (νmp: most
probable velocity)
10 April, 2019 (2)
A. νmp of H2 (300 K); νmp of N2 (300 K); νmp of O2 (400 K)
B. νmp of O2 (400 K); νmp of N2 (300 K); νmp of H2 (300 K)
C. νmp of N2 (300 K); νmp of O2 (400 K); νmp of H2 (300 K)
D. νmp of N2 (300 K); νmp of H2 (300 K); νmp of O2 (400 K)
Consider the following table.
a and b are van der Waals’ Gas a/(k Pa dm6 mol–1) b/(dm3 mol–1)
constants. The correct statement
about the gases is A 642.32 0.05196
10 April, 2019 (1) B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382
A. Gas C will occupy lesser volume than gas A; gas B will be lesser
compressible than gas D
B. Gas C will occupy more volume than gas A; gas B will be more
compressible than gas D
C. Gas C will occupy more volume than gas A; gas B will be lesser
compressible than gas D.
D. Gas C will occupy more volume than gas A; gas B will be lesser
compressible than gas D
At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate
from ideal gas behaviour. Their equation of state is given as,
Here, b is the van der Waals’ constant. Which gas will exhibit steepest
increase in the plot of Z (compression factor) vs p?
9 April, 2019 (2)
A. Xe
B. Ar
C. Kr
D. Ne
Consider the van der Waals’ constants, a and b, for the following
gases.
Gas Ar Ne Kr Xe
a/(atm dm6 mol–2) 1.3 0.2 5.1 4.1
9 April, 2019 (1)
b/(10–2 dm3 mol–1) 3.2 1.7 1.0 5.0
Which gas is expected to have the highest critical temperature?
A. Kr
B. Xe
C. Ar
D. Ne
The combination of plots which does not represent isothermal
expansion of an ideal gas is 12 Jan, 2019 (2)
A. A and C
B. B and C
C. B and D
D. A and D
An open vessel at 27°C is heated until two fifth of the air (assume as
an ideal gas) in it has escaped from the vessel. Assuming that the
volume of the vessel remains constant, the temperature at which the
vessel has been heated is
12 Jan, 2019 (2)
A. 750 K
B. 500 K
C. 750°C
D. 500°C
The volume of gas A is twice than that of gas B. The compressibility
factor of gas A is thrice than that of gas B at same temperature. The
pressures of the gases for equal number of moles are
12 Jan, 2019 (1)
A. pA = 2pB
B. 2pA = 3pB
C. pA = 3pB
D. 3pA = 2pB
A 10 mg effervescent tablet containing sodium bicarbonate and oxalic
acid releases 0.25 mL of CO2 at T = 298.15 K and p = 1 bar. If molar
volume of CO2 is 25.0 L under such condition, what is the percentage
of sodium bicarbonate in each tablet?
11 Jan, 2019 (1)
[Molar mass of NaHCO3 = 84 g mol–1]
A. 8.4
B. 0.84
C. 16.8
D. 33.6
0.5 moles of gas A and x moles of gas B exert a pressure of 200 Pa in
a container of volume 10 m3 at 1000 K. Given R is the gas constant in
JK–1 mol–1, x is
9 Jan, 2019 (1)
A.
B.
C.
D.
Two closed bulbs of equal volume (V) containing an ideal gas initially
at pressure pi and temperature T1 are connected through a narrow
tube of negligible volume as shown in the figure below. The
temperature of one of the bulbs is then raised to T2. The final
pressure pf is JEE 2016
A.
B.
C.
D.
If Z is a compressibility factor, van der Waals’ equation at low
pressure can be written as
JEE 2014
A.
B.
C.
D.
For gaseous state, if most probable speed is denoted by C*, average
–
speed by C and root square speed by C, then for a large number of
molecules, the ratio of these speeds are
JEE-2013
–
A. C* : C : C = 1.225 : 1.128 : 1
–
B. C* : C : C = 1.128 : 1.225 : 1
–
C. C* : C : C = 1 : 1.128 : 1.225
–
D. C* : C : C = 1 : 1.225 : 1.128
For one mole of a van der Waals’ gas when b = 0 and T = 300 K, the
pV vs 1/V plot is shown below. The value of the van der Waals’
constant a (atm L mol–2)
JEE-2012
A. 1.0
B. 4.5
C. 1.5
D. 3.0
The term that corrects for the attractive forces present in a real gas
in the van der Waals’ equation is
JEE-2009
A. nb
B. n2a/V2
C. –(n2a/V2)
D. –nb
The given graph represents the variations of Z (compressibility factor
(Z) = pV/nRT) versus p, for three real gases A, B and C. Identify the
only incorrect statement.
JEE-2006
A. For the gas A, a = 0 and its
dependence on p is linear at all
pressure
B. For the gas B, b = 0 and its
dependence on p is linear at all
pressure
C. For the gas C, which is typical real gas for which neither a nor
b = 0. by knowing the minima and the point of intersection, with
Z = 1, a and b can be calculated.
D. At high pressure, the slope is positive for all real gases
If helium and methane are allowed to diffuse out of the container
under the similar conditions of temperature and pressure, then the
ratio of rate of diffusion of helium to methane is
JEE-2005
A. 2.0
B. 1.0
C. 0.5
D. 4.0
For a monatomic gas kinetic energy = E. The relation with rms
velocity is
JEE 2004
A.
B.
C.
D.
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