27 JULY 21 ASSIGNMENT CHEMISTRY (XI 2021-23)

(XI) LALIT TUTORIALS (XI)

1. Which of the following ion will form most water soluble 22. Which of the following pair of atomic numbers
hydroxide ? represents s-block element ?
a) K+ b) Ni2+ c) Zn2+ d) Al3+ . a) 7, 15 b) 6, 12 c) 9, 17 d) 3, 20.
2. Which of the following has greatest tendency to lose 23. Atoms with high value of IE; always have
electron ? a) large atomic radius
a) F b) Fr c) S d) Be. b) small atomic radius
3. With which of the following configuration the lowest c) strongly bound valence electrons
value of first IE is associated d) loosely bound valence electrons.
a) 1s22s22p63s2 b) 1s22s22p5 24. The elements with atomic number 26 will be found in
c) 1s22s22p6 d) 1s22s22p63s23p2 group
4. Which of the following configuration is associated with a) 2 b) 8 c) 6 d) 10.
biggest jump between 2nd and 3rd IE ? 25. Among the following elements which one has the highest
a) 1s22s22p2 b) 1s22s22p63s1 value of first ionisation potential ?
c) 1s22s22p63s2 d) 1s22s22p1 a) Oxygen b) Argon c) Barium d) Cesium.
5. In the long form of the periodic table, the transition 26. Which of the following ion is not isoelectronic with O 2- ?
metals are placed in a) N3- b) Na+ c) F- d) Ti+.
a) s-block b) f-block 27. The lightest metal is
c) d-block d) s and p-block. a) Li b) Fe c) Cu d) Ag.
6. Which of the following metal requires radiation of 28. Among O, C, F, Cl, Br, the correct order of increasing radii
highest frequency to cause emission of electrons ? is
a) Na b) Mg c) K d) Ca. a) F O C Cl Br b) F C O Cl Br
7. Which of the following ions is smallest in size ? c) F Cl Br O C d) C O F Cl Br.
a) Cr b) Na+ c) Mg2+ d) S2- . 29. Which of the following gaseous ion contains maximum
8. Which of the following decreases in going down the number of unpaired electrons ?
halogen group ? a) Fe2+ b) Co3+ c) Co2+ d) Fe3+.
a) Ionic radius b) Atomic radius 30. Which of the following is isoelectronic with carbon atom
c) Ionisation potential d) Boiling point. a) Na+ b) Al3+ c) O2- d) N+.
9. Which of the following elements is/are not liquid at 30°C 31. The attraction that an atom exerts on a pair of electrons
a) Ga b) Hg c) Ge d) Cs. that are being shared with another atom for forming
10. Of the given alkali metals, the one with smallest size is covalent bond is referred to as its
a) Rb b) Cs c) K d) Na. a) Electron affinity b) Electronegativity
11. Which among the following elements has lowest value of c) Ionisation energy d) Valency.
ionisation potential ? 32. The element with atomic number 55 belongs to which
a) Mg b) Ca c) Ba d) Sr. block of the periodic table
12. Which among the following elements have lowest value a) s-block b) p-block
of IE1 ? c) d-block d) f-block.
a) Pb b) Sn c) Si d) C. 33. Which of the following ions are paramagnetic in
13. Which of the following pair of elements belongs to same character ?
period of the periodic table ? a) Zn2+ b) Cu+ c) Ni2+ d) Ag+.
a) P, Se b) Mg, Se c) Ag, Cl d) Ca,Zn. 34. Alkali metals in each period have
14. The first element of rare earth metals is a) smallest size b) lowest IE
a) Cerium b) Actinum c) highest IE d) highest electronegativity.
c) Uranium d) Lanthanum. 35. Which block of the periodic table contains the element
15. The oxide of which of the following elements will be with configuration
acidic in character 1s22s22p63s23p63d104s1
a) Mg b) Rb c) Li d) Cl. a) 5-block b) p-block c) d-block d) f-block.
16. The valency of noble gases, in general, is 36. The electronic configuration of the element is
a) Zero b) One c) Three d) Two 1s22s22p63s23p3.
17. Paulings electronegativity values for elements are useful What is the atomic number of the element which is just
in predicting below the above element in the periodic table ?
a) Polarity of bonds in molecules a) 33 b) 34 c) 31 d) 49.
b) Position of elements in electromotive series 37. The correct arrangement of increasing order of atomic
c) Co-ordination number radius among Na, K, Mg, Rb is
d) Dipole moment of various molecules. a) Mg < K < Na < Rb b) Mg < Na < K < Rb
18. The number of elements in the 4th period of periodic c) Mg < Na < Rb < K d) Na < K < Rb < Mg.
table is 38. The properties of the elements are the periodic function
a) 8 b) 10 c) 18 d) 32. of their atomic number. The statement is given by
19. Which period of the periodic table contains maximum a) N. Bohr b) J.W. Dobereiner
number of elements ? c) D;I. Mendeleev d) H.G.J. Moseley.
a) 7th b) 3rd c) 4th d) 5th. 39. The ionic radii of N3-, O2-, F-, N+ follows the order
20. In the second period of periodic table, the ionisation a) N3- > O2- > F- > Na+ b) N3- > Na+ > O2- > F-
potential of elements increases from left to right because c) Na > O > N > F
+ 2- 3- - d) O2- > F- > Na+ > N3-.
of 40. Among the elements given below, the one with highest
a) increase in densities electropositivity is
b) decrease in chemical reactivities a) Cu b) Cs c) Cr d) Ba.
c) decrease in atomic size 41. Collective name given to the elements with outer shell
d) decrease in electronegativities. configuration ns2np6 is
21. The valence shell electronic structure of an element is a) Chalcogens b) Alkaline earths
ns2np5. The element will belong to the group of c) Transition elements d) Noble gases.
a) Alkali metals b) Inert metals
c) Noble gases d) Halogens.
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27 JULY 21 ASSIGNMENT CHEMISTRY (XI 2021-23)

42. In the periodic table, the element with atomic number e) Br > F > Cl.
16 will be placed in the group 63. The correct order the increasing ionic character is
a) fourteen b) sixteen c) thirteen d) fifteen. a)BeCl2 < MgCl2 < CaCl2 < BaCl2
43. Ca2+ion is isoelectronic with b)BeCl2 < MgCl2 < BaCl2 < CaCl2
a) Mg2+ b) Na+ c) Ar d) Kr. c)BeCl2 < BaCl2 < MgCl2 < CaCl2
44. Which of the following configurations represent atoms d)BeCl2 < CaCl2 < MgCl2 < BaCl2
of elements having the highest second ionisation 64. Variable valency is characteristic of
energy ? a) Halogen b) Transition elements
a) 1s22s22p4 b) 1s22s22p6 c) Alkali metals d) Noble gas.
c) 1s22s22p63s1 d) 1s22s22p63s2 . 65. Which of the following has least electron affinity ?
45. Gradual addition of electronic shells in the noble gases a) O b) N c) Ar d) F.
causes a decrease in their 66. In the modern long form of the periodic table, elements
a) ionisation energy b) atomic radius are arranged in the increasing order of
c) boiling point d) density. a) Atomic mass b) Atomic number
46. The correct sequence of elements in the decreasing c) Mass number d) Isotopic number
order of first ionisation energy is 67. An element of atomic number 29 belongs to which of the
a) Na > Mg > Al > Si b) Mg > Na > Al > Si following block of the periodic table ?
c) Al > Mg > Na > Si d) Si > Mg > Al > Na. a) s-block b) p-block c) f-block d) d-block.
47. Which of the following statements is correct ? 68. The ionisation potential is lowest for the
a) X- ion is larger in size than X atom a) Halogens b) Inert gases
b) X+ ion is larger in size than X atom c) Alkaline earth metals d) Alkali metals.
c) X+ ion is larger in size than X- ion 69. The element with highest electron affinity among the
d) X+ and X- ions are equal in size. halogens is
48. The correct order of electron affinity of B, C, N, O is a) F b) Cl c) Br d) I.
a) O > C > N > B b) B > N > C > O 70. Which of the following sets of atomic number belong to
c) O > C > B > N d) 0 > B > C > N. that of alkali metals ?
49. Which of the following electronic configurations is of a) 1, 12, 30, 4, 62 b) 37,19,3,55
transition elements ? c) 9, 17, 35, 53 d) 12, 20, 56, 88
a) 1s22s22p63s23p64s2 71. Ionisation energy is highest in
b) 1s22s22p63s23p63d104s24pl a) [NeJ3s1 b) [Ne]3s23p3
c) 1s22s22p63s23p63d104s24p6 c) [Ne]3d 4s 4p
10 2 3 d) [Ne] 3s23p4.
d) 1s22s22p63s23p63d24s2. 72. The atomic radius increases as we move down a group
50. With reference to ionisation potential which one of the because
following sets is correct ? a) Effective nuclear charge increases
a) Li < K < Cs b) B > Li > K b) Atomic mass increases
c) Cs > Li > B d) Cs < Li < K. c) Additive electrons are accommodated in new
51. Which of the following species has the highest ionization electron level
potential ? d) Atomic number increases.
a) Ne b) AL+ c) Mg+ d) Li+. 73. Which of the following pairs of atomic numbers
52. The radii of the F, F-, O and O2- are in the order represents elements belonging to the same group ?
a) O2- > O > F- > F b) F- > O2- > F > O a) 11 and 20 b) 12 and 30
c) O > F > F > O
2- - d) O2- > F- > O > F. c) 13 and 31 d) 14 and 33.
53. Which of the following has highest first ionization 74. Consider the following changes
potential ? A ⎯⎯ → A+ +e-;E1 and A+ ⎯⎯ → A2+ +e-:E2
a) Carbon b) Oxygen c) Nitrogen d) Boron. The energy required to pull out the two electrons are E 1
54. Which of the following has the smallest size? and E2 respectively. The correct relationship between
a) Na+ b) Mg2+ c) Al3+ d) P5+ . two energies would be
55. Which of the following element has the maximum
a) E1 < E2 b) E1 = E2 c) E1 > E2 d) E  E2
electron affinity ?
75. Which of the following isoelectronic ions has the lowest
a) F b) S c) I d) Cl.
ionisation energy ?
56. Which of the following order for ionization energy is
a) K+ b) Ca2+ c) Cl- d) S2-.
correct ?
76. The decreasing order of the ionisation potential of the
a) Be > B > C > N > O b) B < Be < C < O < N
following elements is
c) B < Be < C < N < O d) B < Be < N < C < O.
a) Ne > Cl > P > S > Al > Mg
57. Which of the following is most electronegative ?
b) Ne > Cl > P > S > Mg > Al
a) Carbon b) Silicon c) Lead d) Tin.
c) Ne > Cl > S > P > Mg > Al
58. Which of the following are isoelectronic species ?
+
d) Ne > Cl > S > P > Al > Mg.
I − CH3 , II − NH 2− , III − NH 4+ , IV − NH3 77. Which of the following does not exhibit the periodicity in
a) I, II, III b) II, III, IV c) I, II, IV d) II and I. properties of the elements ?
59. Among the following groupings which represents the a) Ionisation energy b) N/P ratio
collection of isoelectronic species ? c) Electronegativity d) Atomic radius.
78. Which one of the following is an incorrect statement ?
a) NO+, C22 − ,O2, CO b) N2, C22 − ,CO, NO
a) The ionisation potential of nitrogen is greater than
c) CO, N2, CN-, C22 − d) NO, CN-, N2, O2− that of oxygen
60. A compound contains atoms of three elements A, B and b) The electron affinity of fluorine is greater than that of
C. If the oxidation number of A = +2, B = +5 and C = -2, chlorine
the possible formula of the compound is c) The ionization potential of beryllium is greater than
a) A3(BC4)2 b) A3(B4C)2 c) ABC2 d) A2(BC3)2. that of boron
61. The valence shell of transition element consists of d) The electronegativity of fluorine is greater than that
a) nd orbitals b) (n - 1) d-orbitals of chlorine.
c) ns-np-nd orbitals d) (n -1)d ns np orbitals 79. The electronic configuration of elements A, B and C are
e) ns. nd orbitals. [He] 2s1, [Ne] 3s1 and [Ar] 4sl respectively. Which one of
62. The correct order of electron affinity among the the following order is correct for IE1 (in kJ mol-1) of A, B
following is and C ?
a) F > Cl > Br b) Br > Cl > F a) A > B > C b) C > B > A c) B > C > A d) C > A > B.
c) Cl > F > Br d) F > Br > Cl
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27 JULY 21 ASSIGNMENT CHEMISTRY (XI 2021-23)

80. Which among the following species has the highest b) decreases one by one from IA to VIIA
ionisation energy ? c) increases one by one from IA to IVA and then
a) Ne b) F c) Li d) B. decreases from VA to VIIA one by one
81. Eka-aluminium and Eka-silicon are known as d) decreases one by one from IA to IVA and then
a) Gallium and germanium increases from VA to VIIA one by one
b) Aluminium and silicon e) changes randomly.
c) Iron and sulphur 98. For electron affinity of halogens which of the following is
d) Proton and silicon correct ?
82. Which of the following order is wrong ? a) Br > F b) F > Cl c) Br > Cl d) F > I.
a) NH3 < PH3 < AsH3...Acidic character 99. The elements with atomic numbers 9, 17, 35, 53, 85 and
b) Li < Be < B < C......1E1 all
c) Al2O3 < MgO < Na2O < K2O .... Basic character a) noble gases b) halogens
d) Li+ < Na+ < K+ < Cs+....Ionic character. c) heavy metals d) light metals.
83. Which is true about the electronegativity order of the 100. In a given shell, the order of screening effect is
following ? a) s > p > d > f b) f > d > p > s
a) P > Si b) C > N c) Br > Cl d) Sr > Ca. c) p < d < s < f d) d>f<s>p (e)f>p > s > d,
84. Element with atomic number 56 belongs to which block 101. Correct order of radii is
a) s (e)p c) d d) f a) N < Be < B b) F- < O2- < N3-
85. Which of the following order is correct for the first c) Na < Li < K d) Fe3+ < Fe2+ < Fe4+.
ionisation potential of B, C and N ? 102. Which one of the following sets of ions represents the
a) B > C> N b) N > C > B collection of isoelectronic species ?
c) N > C < B d) N < C < B. a) K+ ,Ca2+, Sc3+, Cl- b) Na+, Mg2+ , Al3+ , Cl-
86. Electron affinity depends on c) K+, Cl-, Mg2+, Sc3+ d) Na+,Ca2+, Sc3+ , F2.
a) Atomic size (Atomic Nos. : F = 9, Cl = 17, Na = 11, Mg = 12, Al=13, K
b) Nuclear charge = 19, Ca = 20, Sc = 21)
c) Atomic number 103. The formation of the oxide ion O2- (g) require first an
d) Atomic size and nuclear charge both. exothermic and then an endothermic step as shown
87. Which of the following is not isoelectronic ? below :
a) Na+ b) Mg2+ c) O2- d) Cl-. O (g) + e- ⎯⎯ → O- (g)-; ∆H° = -142 kJ mol-1
88. The ions O , F , Na , Mg and Al3 + are isoelectronic.
2- - + 2+
O- (g) + e- ⎯⎯ → O2- (g); ∆H° = 844 kJ mol-1
Their ionic radii show
This is because :
a) a decrease from O2- to F- and then increase rom Na+ to
a) Oxygen is more electronegative
Al3+
b) O- ion has comparatively larger size than oxygen
b) a significant increase from O2- to Al3+
atom
c) a significant decrease from O2 to Al3+
c) O- ion will tend to resist the addition of another
d) an increase from O2- to F- and then decrease from
electron
Na+ to Al3+ .
d) Oxygen has high electron affinity.
89. According to the Periodic Law of elements, the variation
104. Which of the following ion has the highest value of ionic
in properties of elements is related to their
radius ?
a) atomic masses
a) Li+ b) F- c) O2- d) B3+ .
b) nuclear masses
105. Ionic radii are
c) atomic numbers
a) directly proportional to square of effective nuclear
d) nuclear neutron-proton number ratios.
charge
90. Which one of the following groupings represents a
b) inversely proportional to effective nuclear charge
collection of isoelectronic species ?
c) inversely proportional to square of effective nuclear
(At. Nos. : Cs = 55, Br = 35)
charge
a) Na+,Ca2+,Mg2+ b) N3-, F-, Na+
d) directly proportional to effective nuclear charge.
c) Be, Al , Cr
3+ d) Ca2+, Cs+ Br.
106. Four successive members of the first row transition
91. Arrange in order of increasing I.P.
elements are listed below with their atomic numbers.
a) Mg < Al < Si < P b) Al < Si < P < Mg
Which one of them is expected to have the highest third
c) Si < P < Mg < Al d) Al < Mg < Si < P.
ionisation energy ?
92. Number of elements present in 5th period is
a) Vanadium (Z = 23) b) Chromium (Z = 24)
a) 8 b) 18 c) 32 d) 24.
c) Iron (Z = 26) d) Manganese (Z = 25).
93. What is the general outer electronic configuration
107. Which of the following oxides is amphoteric in character
of the coinage metals ?
a) CaO b) CO2 c) SiO2 d) SnO2.
a) ns2np6 b) (n - 1)d10 ns1
108. In which of the following arrangements, the order is not
c) (n -1)d ns
10 2 d) (n - 1)d9 ns2.
according to the property indicated against it ?
94. How does the ionisation energy of 1st group elements
a) Al3+ < Mg2+ < Na+ < F- Increasing ionic size
vary ?
b) B < C < N < O Increasing first ionisation energy
a) increases down the group
c) I < Br < F < Cl Increasing electron gain enthalpy
b) decreases down the group
(without negative sign)
c) remains unchanged
d) Li < Na < K < Rb Increasing metallic radius.
d) variation is not regular.
109. Which one of the following arrangements represents the
95. The electron affinity values (in kJ mol-1) of three
correct order of electron gain enthalpy (with negative
halogens, X, Y and Z are respectively -349, -333 and -
sign) of the given atomic species
325. Then X, Y and Z are respectively
a) Cl < F< S < O b) O < S < F < Cl
A) F2, Cl2 and Br2 b) Cl2, F2 and Br2
c) S < O < Cl < F d) F < Cl < O < S.
c) Cl2, Br2 and F2 d) Br2, Cl2 and F2.
110. The order of first ionisation energies of the elements Li,
96. An atom with high electronegativity has
Be, B, Na is
a) large size b) high ionization potential
a) Li > Be > B > Na b) Be > B > Li > Na
c) low electron affinity d) low ionization potential
c) Na > Li > B > Be d) Be > Li > B > Na.
e) high ionic potential.
e) B > Be > Li > Na. (Kerala Engg. 2005)
97. In any period of the periodic table, valency of an element
111. Which of the following is an inert gas ?
with respect to oxygen
a) H2 b) O2 c) N2 d) Argon.
a) increases one by one from IA to VIIA

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112. In the following, the element with the highest ionization 125. Correct sequence of increasing order of ionization
energy is energy is
a) [Ne] 3s23p1 b) [Ne] 3s23p3 a) I < Br < Cl b) Cl < Br < I c) Cl < I < Br d) I < Cl < Br.
c) [Ne] 3s 3p
2 2 d) [Ne] 3s2 3p4. 126. Which of the following has the highest electron affinity ?
113. The successive ionization energy values for an element X a) F- b) O- c) O d) Na.
are given below : 127. The first ionisation potentials of Na, Mg, Al and Si are in
(1) 1st ionization energy = 410 kJ mol-1 the order :
(2) 2nd ionization energy = 820 kJ mol-1 a) Na < Mg > Al < Si b) Na > Mg > Al > Si
(3) 3rd ionization energy = 1100 kJ mol-1 c) Na < Mg < Al > Si d) Na > Mg > Al < Si.
(4) 4th ionization energy = 1500 kJ mol-1 128. What is the correct decreasing order of ionic radii of
(5) 5th ionization energy = 3200 kJ mol-1 following ions ? N3-, O2-, F-, Na+, Mg2+
Find out the number of valence electrons for the atom X a) N3- > O2- > F- > Mg2+ > Na+
a) 4 b) 3 c) 5 d) 2 e) 1. b) N3- > O2- > F- > Na+ > Mg2+
114. Which of the following species has the highest electron c) N3- > O2- > Mg2+ > Na+ > F-
affinity ? d) Na+ > F > O2- > Mg2+ > N3-.
a) F- b) O c) O- d) Na+ 129. The correct order of decreasing ionic radii among the
115. Which electronic configuration of an element has following isoelectronic species is
abnormally high difference between second and third a) K+ > Ca2+ > Cl- > S2- b) Ca2+ > K+ > S2- > Cl
ionization energy ? c) Cl > S > Ca > K
- 2 2+ + d) S > Cl- > K+ > Ca2+.
a) 1s22s22p63s1 b) 1s22s22p63s23p1 130. Among the following, the third ionisation energy is
c) 1s22s22p6 d) 1s22s22p63s2. highest for
116. The electronic configuration of four elements are given a) Magnesium b) Boron c) Beryllium d) Aluminium
below. Arrange these elements in the correct order of 131. Which of the element is expected to have lowest first
the magnitude (without sign) of their electron affinity ionisation enthalpy
(i) 2s22p5 (ii) 3s23p5 (iii) 2s2 2p4 (iv) 3s2 3p4. a) Sr b) Al c) Xe d) S.
Select the correct answer using the codes given below 132. Generally, the first ionisation energy increases along a
a) (i) < (ii) < (iv) < (iii) b) (ii) < (0 < (iv) < (iii) period. But there are some exceptions one which is not
c) (i) < (iii) < (iv) < (ii) d) (iii) < (iv) < (ii) < (i) an exception is
117. The electronic configuration of the atom having a) N and O b) Na and Mg c) Mg and Al d) Be and B.
maximum difference in first and second ionization 133. The highest electron affinity is shown by
energies is a) O b) F- c) Cl2 d) F2
a) 1s22s22p63s1 b) 1s22s22p63s2 134. The electronic configuration of two elements X and Y are
c) 1s 2s 2p
2 2 1 d) 1s22s22p63s23s3 given below
118. The electronic configuration of the element with X = 1s2 2s1 2p6 3s2 3p6 4s2 ; Y =1s2 2s2 2p6 3s2 3p5
maximum electron affinity is The formula of the ionic compound can be formed
a) 1s2 2s2 2p3 b) 1s2 2s2 2p6 between these elements is
c) 1s2 2s2 2p6 3s2 3p5 d) 1s2 2s2 2p6 3s2 3p3 a) xy b) xyz c) xzy d) xy3
119. The first ionization energy of oxygen is less than that of 135. In the periodic table, the basic character of oxides
nitrogen. Which of the following is the correct reason for a) increases from left to right and decreases from top to
this observation ? bottom
a) Lesser effective nuclear charge of oxygen than b) decreases from right to left and increases from top to
nitrogen bottom
b) Lesser atomic size of oxygen than nitrogen c) decreases from left to right and increases from top to
c) Greater interelectron repulsion between two bottom
electrons in the same p-orbital counter balances the d) decreases from left to right and increases from
increase in effective nuclear charge on moving from bottom to top.
nitrogen to oxygen. 136. Which of the following orders regarding ionisation
d) Greater effective nuclear charge of oxygen than energy is correct ?
nitrogen. a) N > O > F b) N < O < F c) N > O < F d) N < O > F.
120. The number of unpaired electrons in gaseous species of 137. Among the following which one has the highest cation to
Mn3+, Cr3+ and V3+ respectively are .............. and most anion size ratio ?
stable species is a) Csl b) CsF c) LiF d) NaF.
a) 4, 3 and 2 and V3+ is most stable 138. The diagonal partner of Be is
b) 3, 3 and 2 and Cr3+ is most stable a) Li b) Al c) Si d) Mg.
c) 4, 3 and 2 and Cr3+ is most stable 139. The correct decreasing order of first ionisation
d) 3, 7 and 3 and Mn3+ is most stable. enthalpies of five elements of second period is
121. Which is not the correct order of the stated property ? a) Be > B > C > N > C b) N > F > C > B > Be
a) Ba > Sr > Mg ; Atomic radius c) F > N > C > Be > B d) N > F > B > C > Be
b) F > O > N ; first ionization energy 140. The second ionization energies of Li, Be, B and C are in
c) Cl > F > I ; electron affinity the order
d) O > Se > Te ; electronegativity. a) Li > C > B > Be b) Li > B > C > Be
122. Lattice energy of an ionic compound depends upon c) B > C > Be > Li d) Be > C > B > Li.
a) Charge on the ion only 141. Identify the wrong statements in the following
b) Size of the ion only a) Amongst isoelectronic species, smallar the positive
c) Charge on the ion and size of the ion charge on cation, smaller is the ionic radius
d) Packing of the ions only. b) Amongst iso electronic species, greater is the negative
123. Which one of the following order is correct for the first charge on the anion, larger is the ionic radius.
ionization energies of the elements? c) Atomic radius of the elements increases as one moves
a) B < Be < N < O b) Be < B < N < O down the first group of the periodic table.
c) B < Be < O < N d) B < O <Be < N. d) Atomic radius of the elements decreases as one
124. Which one of the following statements is correct ? moves across from left to right in the second period of
a) Ionic radius of Fe3+ is greater than Fe2+ the periodic table.
b) Atomic radius of chlorine atom is greater than ionic 142. The element with positive electron gain enthalpy is
radius of chloride ion a) Hydrogen b) Sodium
c) Electron affinity of phosphorus is greater than nitrogen c) Oxygen d) Neon.
d) Cs2O is strongly acidic in nature.

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143. The correct order of electronegativities of N, O, F and P 160. The correct order of electron affinity of the elements of
is oxygen family in the periodic table is
a) F > N > P > O b) F > O > P > N a) O > S > Se b) S > O > Se
c) F > O > N > P d) N > O > F > P. c) S > Se > O d) Se > O > S.
144. Which of the following sets of ions represents a 161. The statement that is not correct for the periodic
collection of isoelectronic species. classification of element is
a) K+, Cl-, Mg2+, Si3+ b) Na+,Ca2+, Si3+ , F- a) The properties of the elements are the periodic
c) K+,Ca2+, Si3+ ,Cl- d) Na+,Mg2+, Al3+,Cr. function of their atomic numbers
145. Which of the following represents the correct order of b) Non-metallic elements are lesser in number than the
increasing first ionisation enthalpy for Ca, Ba, S, Se and metallic elements
Az ? c) The first ionisation energies of elements along a
a) Ca < Ba < S < Se < Ar b) Ca < S < Ba < Se < Ar period do not vary in a regular manner with increase in
c) S < Se < Ca < Ba < Ar d) Ba < Ca < Se < S < Ar. atomic number
146. The first ionisation potential of Na is 5.1 eV. The value of d) For transition elements the rf-subshells are filled with
electron gain enthalpy of Na+ will be the electrons monotonically with increase in atomic
a) + 2.55 eV b) – 2.55 eV number.
c) -5.1eV d) -10.2 eV. 162. Which one of the following has largest size ?
147. The correct order of electron gain enthalpy with a) Na b) Na+
negative sign of F, Cl, Br and I, having atomic number 9, c) Na - d) None of these.
17, 35 and 53 respectively is 163. The decreasing order of the second ionization energy of
a) I > Br > Cl > F b) F > Cl > Br > I K, Ca and Ba is (At. Nos. K = 19, Ca = 20, Ba = 56)
c) Cl > F > Br > I d) Br > Cl > I > F. a) K > Ca > Ba b) Ca > Ba > K
148. Among the elements B, Mg, Al and K the correct order of c) Ba > K > Ca d) K > Ba > Ca.
increasing metallic character is 164. The incorrect statement among the following is
a) B < Al < Mg < K b) B < Mg < Al < K a) The first ionization potential of Al is less than the first
c) Mg < B < Al < K d) Mg < Al < B < K ionization potential of Mg
149. The correct order of second ionisation potential of b) The second ionization potential of Mg is greater than
carbon, nitrogen, oxygen and fluorine is the second ionization potential of Na
a) C > N > O > F b) O > N > F > C c) The first ionization potential of Na is less than the first
c) O > F > N > C d) F > O > N > C. ionization potential of Mg
150. The correct order of IE1 potential C, N, O and F is d) The third ionization potential of Mg is greater than
a) C > N > O > F b) O > N > F > C the third ionization potential of Al.
c) O > F > N > C d) F > N > O > C.
151. Atomic radii of Fluorine and Neon (in Angstrom units)
respectively are given as
a) 0.72, 1.60 b) 1.60, 1.60
c) 0.72, 0.72 d) None of these.
152. The electronegativity of the following elements
increases in the order
a) C, N, Si, P b) N, Si, C, P
c) Si, P, C, N d) P, Si, N, C.
153. Which of the following values in electron volt per atom
represent the first ionisation energies of oxygen and
nitrogen atom respectively ?
a) 41.6, 13.6 b) 13.6, 14.6
c) 13.6, 13.6 d) 14.6, 14.6.
154. Which of the following is the smallest in size ?
a) N3- b) O2- c) F- d) Na+.
155. Which of the following statement is not true about the
long form of periodic table ?
a) It reflects the sequence of filling of electrons in order
of sub-energy levels s, p, d and f
b) It helps to predict the stable valency states of the
elements
c) It reflects trends in physical and chemical properties
of the elements
d) It helps to predict the relative ionicity of the bond
between any two elements.
156. The first ionisation potential of Na, Mg, Al and Si are in
the order
a) Na > Mg > Al > Si b) Na < Mg < Al < Si
c) Na < Si < Al < Mg d) Na < Al < Mg < Si.
157. The outermost electronic configuration of the element
with highest value of electron affinity is
a) ns2np3 b) ns2np5
c) ns2np4 d) ns2np6.
158. Amongst the following elements (whose electronic
configurations are given below), the one having the
highest ionisation energy is
a) [Ne] 3s23p1 b) [Ne] 3s23p3
c) [Ne] 3s 3p3 2 d) [Ar] 3d104s24p2 .
159. Which one of the following is correct order of increase of
size ?
a) Mg < Na+ < F- < Al b) Na+ < Al < Mg < F-
c) Na+ < F < Al < Mg
- d) Na+ < F- < Mg < Al.

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