Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Super60 PTA-14 Date: 19-12-2021
Time: 09:00Am to 12:00 2018_P1 Max.Marks:180

KEY SHEET
PHYSICS

1 ABD 2 ABD 3 AD 4 ACD 5 BD

6 AD 7 4.40-4.50 8 8 9 10 10 4
11 2.20-2.25 12 0.7-0.8 13 11.6-11.8 14 1.73 15 D
16 A 17 D 18 B

CHEMISTRY

19 ACD 20 ABD 21 ABCD 22 ABCD 23 ABC

24 BCD 25 35 26 3 27 0 28 2
29 4 30 3 31 6 32 6 33 B
34 A 35 C 36 C

MATHEMATICS

37 ABC 38 CD 39 BCD 40 BD 41 ABCD

42 BCD 43 24.0 44 39.0 45 3.0 46 10
47 6.0 48 4.0 49 8.0 50 540 51 A
52 D 53 D 54 A
Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
SOLUTIONS
PHYSICS
1. From graph clearly there are 10 intersection points including the intersection of lines
of A and B also ; So there are total 10 collisions.
Now by exchanging the slope of line at each intersection we can easily find that final
velocity of A, C and D are
VA = + 1.5 m/s
VC  0
10
VD   m/s
9
2. Just before point A,
N1  mg
Just after point A,
mV 2 mv2
N 2  mg   N 2  mg 
R R
4  16
 N1  40 and N 2  40   104
1
Applying work energy theorem,
1 1
mgh  mv | 2  mv2
2 2
1 1 1
 4  10    4  V | 2   4  16
2 2 2
|
 V  6 m/s
R
From geometry, R  R cos  
2
1
 cos      600
2

3.
3
v x  v2 sin 2  v 2 sin 370  v2 …..…… (i)
5
4
v y  v1 sin 1  v1 sin530  v1 …..…… (ii)
5
Using conservation of momentum of system along horizontal direction.

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 
m 2 v2  m1v1  m v x sin 2  v y sin 1  0
 9 16 
16v2  9v1  25  v2  v1  0
 25 25 
25v 2  25v1
 v1  v 2
Velocity of cylinder,
v 2 2
v  v 2x  v2y  1  3   4
5
 v  v1  v 2 …..…… (iii)
Now, using conservation of energy of the system
1 1 1
mgh  m1v12  m 2 v 22  mv 2
2 2 2
1
mgh   m1  m 2  m v2
2
1
25gh   50v 2
2
 v  gh  10  0.4  2 m / s
 v  v1  v 2  2 m / s
1 1
4. (1) 2m1 cos   m (2) m  2. m12
2 2
nd / 2
(3) sin   (4) m  2m. 1 cos 
d
 = 45 and n  2 (for A to stop)

5. Friction at the horizontal surface will be impulsive in nature  momentum of the

system will not be conserved in horizontal direction.
Momentum of the system (M + m) will be conserved in the direction  to the net
impulsive (normal + friction) force.
6. Initially there will be n collisions. Exchange of velocity takes place between two
colliding blocks. The two extreme blocks will move out and never encounter any

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
other collision. Remaining (2n–2) blocks will further have (n–1) collisions and so
n  n  1
on. This way total no. of collisions = n+(n–1)+(n–2)+(n–3)+.......+3+2+1= .
2
7. F  12  5.2  62.4
12  5.2
  0.39
16  10
0.39
62.4   40
a1  2
12
= 4.55
a 2  1.95
a rel  4.55  1.95
= 2.6
w  fr  Srel
2.6
 7.8  10 
4.55
= 44.57
loss
 4.46
10

8.
Change in momentum per collision = 2mV cos
Particles colliding per second on dA drea = 2mV 2 cos 2  d A n
 /2
F  4mV 2 cos3   1Rd n
0
/ 2
= 4nmV R 2
 1  sin  cos  d
2

0
1
8nmV 2R

 4nmV 2R  1  t 2 d t   3
0
K=8
9. Srel  5 m
2u y u y
T 
g 5
40  v1  40 v 2  80  8
v1  v 2  16 m / s  v 2  16  v1

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
5 25 25
v1  8    v1  8 
T uy uy
50
v1  v 2  v rel x  2v1  16  16   16
uy
vrel y  u y
502
vrel  2
 u 2y
uy
502
vrelmin xy y  20
u 3y
u 4y  502
u y  50  5 2
v rel  50  50  10 m / s

10.
Centre of mass must lie on line L1
x y
 1
 
2 2
2x + 2y = 
a+b=4
11. P=t
t2 1
  1  V2
2 2
V=t
a  an  1
t2
aN  2
2
a 5
12. FV  2mu sin 2  uSn cos 
sin 2  cos 
2sin  cos2   sin3   0
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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
FVmax

u 4
 nmu 2s
3 3


2
tan 2   2 sin  
3
1
tan  2 cos 
3
    
13. r 1  t i  t 2 j m
 r 2  t 2 i  2t j
 ac  a  at
   10 
v1  i  2t j m / s
  v2  2ti  2j  2i  2j    i  4j
   
 17 
   24i 6j
a1  2j m / s 2
  a 2  2i ac  
17 17
at t = 1 sec.
    24   6
2 2
r 21  r 2  r1  0i  3 j m   ac      
 17   17 
 1
v 21  2i  2j  i  2j  i  4j m / s a c 
     612
17
  V2 
 

a 21  2i  2 j m / s 2
 R 
 ac 

  
 21 V
 21 V  i  4j

a t  a 21 .V 
  i  4ˆj    i  4j 
=  2i  2 j .    V  17
  17    17 
 
  2  8   i  4j  10  17 
i  4j
at    
 17   17  17     R
1 
 612 
 17 
   17 
2
at  ac  a R m
612
14. Denoting the angles with (*) for the CM system transformation of angles for CMS to
LS is given by
sin *
tan   ............ (1)
* m
cos  
M
* *
But         2

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
*
 sin   sin    2  sin 2
cos *  cos    2   cos 2
(i) becomes
sin 2
tan  
m
 cos 2
M
sin  sin 2
Further more 
cos  m  cos 2
M
Cross-multiplying and rearranging
m
sin   sin  cos 2  cos  sin 2  sin    2
M
m sin  2   
 
M sin 

15.
Loss in PE = Gain in KE
Loss in PE = 10 g . 1 . sin 530  5g 1 / 2 sin
370  65J
Gain in KE =
2 2
1 1 V   V  
 5  V02   5   r cos37 0  V0    r  sin 370 
2 2 2   2  
1  2 2
  
  10   Vr cos530  V0  Vr sin 530 
2 
 
Momentum is conserved along horizontal axis
V 
0  5  V0   5  r cos370  V0   10  Vr cos530  V0 
2 
5
Vr  V0 ........ (2)
2
Solving equation (1) & (2)
2080
V0  m/s
805

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s

16.
a 
0  5a 0  5  r cos370  a 0   10  a r cos530  a 0 
2 
 5a 
ar   0 
 2 
a 
10 a r sin 530   5  r sin 370 
a cmg  2 
20
 13a 
a cmg   0 
 16 
20g  N  20a cmg
 3200  260a 0 
N 
 16
F
17. a cm 
2m
1 1 F  2
Scm  u cm t  a cm t 2  0   t
2 2  2m 

18.
In centre of mass frame
m1x1  m 2 x 2
mx1  mx 2
x1  x 2 .......... (1)
and x1  x 2  x 0 .......... (2)
From equation (1) and (2)
x
x2  0
2
Displacement of right block in ground frame x 2  Scm
x F 2
= 0 t
2 4m

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
CHEMISTRY
19. AC 3  H 2O  A  OH  3  HC
Dense white vapours with moisture.
3
 A  H 2O  is octahedral complex ion.
 6
A to T  +3 oxidation state stability decreases.
A  HC   AC 3  H 2
A  NaOH  NaAO 2  H 2  H 2 O .
20.
NaOH 
A  NaOH  A  OH    A  OH 4 

HC

A3  C  H2O


A  OH  3   A 2O3  H 2O
21. Octahedral geometry is special case of square bipyramid, with equilateral triangles.
22. CO 2 is most acidic oxid in 14 group elements Pb 2 ions are commonly available
and stable Silicon and Germanium are used as semiconductors
 SnO 2  H 2  .
Sn  H 2 O Steam 
23. Dangling bonds can be present on non clean surface of any lattice. Fullerens have
discrete molecular units and does not have dangling bonds.
24. As almost each oxygen of Silicate is shared by our tetrahedral silicate unit, it is
called Silicate.
25. 3NaBH 4  4BF3   2B2H6  3NaBF4
76gms 170
g
38gms 68
= 2.00 2.50
BF3 is limiting reagent
4 moles BF3 
 2 moles of B 2 H 6
2.50
2.50 moles of BF3    2 moles of B 2 H 6 = 1.25
42
Mass of B2H 6  1.25  28  35gms

26.

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
O
S S
= One d   p = Two d   p 
O O O O
27.
28. In  & In 3 are diamagnetic In I In IIIC 4  InC 2
29. CsC, MgC 2 , BaC 2 and KC
30. K,CaH 2 , Mg,Ca, LiH
31. B3 N 3H 6  H 3BO 3  NH 3  H 2
32. NCERT (Boric acid)
33&34
H H H
B B
BF3  LiAH 4  B2 H 6 H H H

BF3  H2O  H3BO3  H2O  BF4

35&36
H O CO 20000 C CO
Ca  2   2aq 
2  H  Ca OH 2  CaCO 
3
2  CaCO
 CaC2  3

Li CO 2

LiH 
H O
 LiOH  H 2 Ca  HCO3  2
2

MATHEMATICS
37. Image of A 1,2,3 in the plane x  y  z  12 is 5,6,7 
x5 y 6 z 7
 Equation of BC is  
2 1 2
 B is  -7,0,19
A(1,2,3) C(3,5,9)

B(–7,0,19)

(5,6,7)

x 1 y  2 z  3
Now, equation of AB is  
8 2 16
Equation of plane containing the incident and reflected ray is
x 1 y  2 z  3
2 3 6 0
8 2 16
i.e., 3 x  4  z  2  0

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  
38. As, If AAT  I , so a b c are orthogonal unit vectors.
i j 
k
   1

c   a  b  
49
2  3 6
6 2 3


c
3i  6 j  2k 
  

7
  

[Note that a  1  b & a  b
    
So, a  b  a b sin
 
2
 a  b  1 is also a unit vector.]


 t cos kt dt
39. (C) ak  

 cos2 kt dt
N r is zero as t cos kt is an odd function.
Hence, ak  0
(D)
2sin x  sin 2 x 2cos x  2cos 2 x 2sin x  4sin 2 x 0  0
Lim 2
 Lim  Lim  0
x0 x x0 2x x0 2 2
40. Conceptual
41. a1  a2 cos 2 x  a3 sin 2 x  0x  R
  
a1  a2 1  2sin 2 x  a3 sin 2 x  0x  R
  a1  a2   sin 2 x  a3  2a2   0x R
So, a1  a2  0
and a3  2a2 must hold simultaneously.
a a a
So, 1  2  3     0
1 1 2
  a1, a2 , a3    , ,2  x  R0
42. Let R be circum radius of pentagon
 2
A1 A2  2R sin and A5 A3  2R sin
5 5
   
 A A  2cos A A  ka
5 3 5 3
5
     
A2 A5  b  ka, A2 A4  k  k 2 a  kb ,  

A3 A4  1 
b
  
 ka , A5 A4  1 a 
b


k  k  

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43. Since the 2 planes are  to each other therefore a  2b  c  0 .................1

x 1 y 1 z  3
Since the plane is containing the line  
1 2 4
 a  2b  4c  0 ...... 2
Point 1, 1,3 also lies on plane ax  by  c  4  0
a  b  3c  4  0 ...................3
Solving (1), (2) and (3) we get
12 16
a  8; b  ;c 
5 5
 2a  10b  5c  16  24 16  24
44. Any plane through the second line is given by
3x  y  2 z  4  1 2 x  y  z  1  1
3  2  x   1 y     2 z   4     0
If this plane is parallel to first line then its normal must be at right angles to first line
3  2  2    1 4     2  0    0
equation of plane through the second line and parallel to first line is
3x  y  2 z  4  0
Shortest distance  distance of a point 1,3, 2 on the first line to the plane
3x  y  2 z  4  0
3 3 4  4 8 64 32 a
S.D.     
32  12  22 14 14 7 b
a  32; b  7
  a  b  39
45. The lines
x 2 y 3 z  4 x 1 y  4 z  5
  and   are co-planer if
1 1 k k 2 1
1 2 4  3 5  4 1 1 1
1 1 k  0  1 1 k  0
k 2 1 k 2 1

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s

 
  1  2k   1 1  k 2  1 2  k   0
1  2k  1 k 2  2  k  0
k 2  3k  0  k  0, 3
    6  0 3 6  3
46. 10  a bc  d  2  b cd  a
x  0 y 1 z  0 x 1 y  0 z  0
47. L1 :     ;L 2 :   
1 1 1 2 1 1
Hence any point on L1 and L 2 can be   ,   1,   and  2  1, ,  
2  1       1   
  
2 1 1
Solving   1 and   3
A = (3, 2, 3) and B = (1, 1, 1)
(0,0,0)

 
v d = | v | sin 


(1,1,1)

c = (2,1,2)
x 1 y 1 z 1
Hence equation of line AB is  
2 1 2
  2 2  2
vc
d  
v c  v.c

  
 3 9  25

2
c c 3 3
2
 27d 2  27  6
9
48. Given line is parallel to the line of intersection of two planes x + y + 0z = 2 and
 
0x + 0y + z = 0 so it is long n1  n 2  i  j
(0, 0, 0)

x–2 y–0 z–p 

= = =
 + 2, –, p 1 –1 0
 a  1,b  1,c  0
2
    2   2  p 2  18
 2  0
  1 & p = 4

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
2 ab ac
      a
a .a a .b a .c 2 2
  2       ab bc a 2 b 2c 2
49. a
 b c   b . a b . b
b .c  b2 
      2 2 2
c .a c .b c . c ca cb
c2
2 2
 abc 1    abc
 a b c    V   a b c  
2 6 6 2
Now, applying A.M.  G.M.
1
4a 2  3b2  2c2
3
 4a 2 .3b2 .2c2  3

3

 48  4.3.2.36.2.V 2 
V8
D

4 M

50. C 3 B
5
Mid point of BD is such that MD = MB = MC = . So if we take A directly above
2
M, such that AM = h, then A will be equidistant from the remaining vertices.
2
 5 2 5 3 1 34 5 3
h  5      Volume  . .
 2 2 3 2 2
     
  a  b a  c a  d   30 3
         
K  6a  b  2c  3d b  3d  4c b  2c  3a 
               
          
= a  b  2 a  c  3 a  d 4 a  c  a  b  3 a  d b  a  2 c  a 
    
1 2 3
     
= 1 4 3 a  b a  c a  d 
1 2 0
=18  30 3  540 3
51&52              
Au  v  p  a1i  b1 j  c1 k ; q  a 2 i  b 2 j  c 2 k and r  a 3 i  b 3 j  c3 k
(i) A is orthogonal  A = 1 or –1
  
Volume =  p q r   1
        
(ii) A is orthogonal  p  q  r  1 and p . q  q . r  r . p  0

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Sri Chaitanya IIT Academy 19-12-2021_Sr.Super60_Jee-Adv(2018-P1)_PTA-14_Key & Sol’s
  
 angle between p and q is .
2
53&54
Putting x = z = 0 and y = 3 in the planes.
k = 2 and  = 12
P1 : 3x + 4y – 12 = 0 and P2 : –3x – 2y + 6 = 0
But points (0, 0, 0) and (0, –4, 0) lie on opposite sides of both the plane.
 Putting x = 0 = z = 0 and y = –3 in the planes, k = –2 and  = –12
 P1 : 3x + 4y = –12 and P2 : –3x + 2y + 6 = 0

(–4,0,0) (2,0,0)

(0,–3,0)
(i) Required plane is P1  tP2  0
3x + 4y + 12 + t (–3x + 2y + 16) = 0
Putting (2, 3, 1), get t = –5
18x – 6y – 18 = 0
 3x – y – 3 = 0
(ii) Plane perpendicular to the plane P1 and parallel to z–axis is 4x – 3y + q = 0
  2  2 
 2 , 3 ,0 , lies on the plane
 

2  2   2  q  0 
 2  2  q  2  0
For exactly one real value of 
D=0
 4 – 4 (q – 2) = 0  q = 3
4x – 3y + 3 = 0
8x – 6y + 6 = 0  8x + by + cz + d = 0
b + c + d = 0

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