SAFETY DATA SHEET

Revision date 15-Nov-2019 Version 8 Supersedes Date: 28-Aug-2019

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
Product identifier
Product Code MC01.C01

Product Name ALUMINUM EFFECT KOSMIC KROME

Other means of identification

No information available

Recommended use of the chemical and restrictions on use

Tint, colorant

Details of the supplier of the safety data sheet

See section 16 for more
information

The Valspar Corporation

PO Box 1461
Minneapolis, MN 55440

E-mail address [email protected]

Emergency telephone number

United States of America 1-888-345-5732

Section 2: HAZARDS IDENTIFICATION

Classification

Skin corrosion/irritation Category 2

Serious eye damage/eye irritation Category 2
Carcinogenicity Category 2
Reproductive toxicity Category 2
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
Aspiration toxicity Category 1
Flammable liquids Category 2

Label elements

Product Code MC01.C01 Page 1 / 10 AGHS - USA OSHA SDS

Signal word DANGER

HAZARD STATEMENTS
Highly flammable liquid and vapor
Causes skin irritation
Causes serious eye irritation
Suspected of causing cancer
Suspected of damaging fertility or the unborn child
May cause drowsiness or dizziness
May be fatal if swallowed and enters airways
May cause damage to the following organs through prolonged or repeated exposure: Nervous System, Ears

PREVENTION
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective
gloves/protective clothing/eye protection/face protection. Wash face, hands and any exposed skin thoroughly after handling. Do not
breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. P210 - Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use
explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static
discharge.

RESPONSE
IF exposed or concerned: Get medical advice/attention.
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin
If skin irritation occurs: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower. Wash contaminated clothing before reuse.
Inhalation
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Ingestion
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction.

STORAGE
Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.

DISPOSAL
Dispose of contents/containers in accordance with local regulations.

HAZARDS NOT OTHERWISE CLASSIFIED (HNOC)

No information available.

OTHER HAZARDS
Not applicable.

UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Product Code MC01.C01 Page 2 / 10 AGHS - USA OSHA SDS

 Chemical Name CAS No weight-%
n-Butyl acetate 123-86-4 25 - 50
Acetone 67-64-1 10 - 25
Toluene 108-88-3 10 - 25
Ethyl acetate 141-78-6 5 - 10
Xylenes 1330-20-7 5 - 10
Solvent naphtha, petroleum, light aromatic 64742-95-6 1-3
Isopropyl acetate 108-21-4 1-3
1,2,4-Trimethylbenzene 95-63-6 1-3
Ethylbenzene 100-41-4 1-3

*The exact percentage (concentration) of composition has been withheld as a trade secret.

Section 4: FIRST AID MEASURES

First Aid Measures

General advice
IF exposed or concerned: Get medical advice/attention.

Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.

Skin Contact
If skin irritation occurs: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower. Wash contaminated clothing before reuse.

Inhalation
IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Ingestion
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.

Most important symptoms and effects, both acute and delayed

Symptoms No information available.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

Section 5: FIRE FIGHTING MEASURES

Suitable extinguishing media
Dry chemical, CO2, water spray or alcohol-resistant foam.

Not to be used for safety reasons: Strong water jet

Specific hazards arising from the chemical

Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe
fumes.

Special protective equipment for fire-fighters

Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is
out. Do not allow run-off from fire-fighting to enter drains or water courses.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions

Product Code MC01.C01 Page 3 / 10 AGHS - USA OSHA SDS

Avoid breathing vapors or mists. Remove all sources of ignition. Use personal protective equipment as required. Avoid contact with
skin, eyes or clothing. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Take precautionary
measures against static discharges.

For emergency responders

Use personal protection recommended in Section 8.

Environmental precautions

Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform
appropriate authorities in accordance with local regulations. Prevent further leakage or spillage if safe to do so. Local authorities
should be advised if significant spillages cannot be contained.

Methods and material for containment and cleaning up

Methods for containment

Prevent further leakage or spillage if safe to do so.

Methods for cleaning up

Dispose of waste product or used containers according to local regulations. Clean with detergents. Avoid solvent cleaners. Dam
up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to
properly labeled containers. Clean contaminated surface thoroughly.

Section 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling

Prevent the creation of flammable or explosive concentrations of vapor in air and avoid vapor concentration higher than the
occupational exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Use personal protection recommended in Section 8. Never use pressure to empty container. Comply with the health and safety at
work laws. Prevent product from entering drains. Vapors are heavier than air and may spread along floors. Vapors may form
explosive mixtures with air. Use only with adequate ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. Use only in
well-ventilated areas. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. All
equipment used when handling the product must be grounded.

General Hygiene Considerations

When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Avoid contact with skin, eyes or clothing.

Conditions for safe storage, including any incompatibilities

Storage Conditions
Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage. Keep container tightly closed in a dry and
well-ventilated place. Keep tightly closed in a dry and cool place.

Incompatible materials
Strong oxidizing agents.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Limits
If S* appears in the OEL table, it indicates this chemical contains a skin notation.

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

n-Butyl acetate STEL: 150 ppm TWA: 150 ppm IDLH: 1700 ppm
123-86-4 TWA: 50 ppm TWA: 710 mg/m3 TWA: 150 ppm
TWA: 710 mg/m3
STEL: 200 ppm
STEL: 950 mg/m3
Acetone STEL: 500 ppm TWA: 1000 ppm IDLH: 2500 ppm
67-64-1 TWA: 250 ppm TWA: 2400 mg/m3 TWA: 250 ppm

Product Code MC01.C01 Page 4 / 10 AGHS - USA OSHA SDS

 TWA: 590 mg/m3
Toluene TWA: 20 ppm TWA: 200 ppm IDLH: 500 ppm
108-88-3 Ceiling: 300 ppm TWA: 100 ppm
TWA: 375 mg/m3
STEL: 150 ppm
STEL: 560 mg/m3
Ethyl acetate TWA: 400 ppm TWA: 400 ppm IDLH: 2000 ppm
141-78-6 TWA: 1400 mg/m3 TWA: 400 ppm
TWA: 1400 mg/m3
Xylenes STEL: 150 ppm TWA: 100 ppm
1330-20-7 TWA: 100 ppm TWA: 435 mg/m3
Isopropyl acetate STEL: 200 ppm TWA: 250 ppm IDLH: 1800 ppm
108-21-4 TWA: 100 ppm TWA: 950 mg/m3
1,2,4-Trimethylbenzene TWA: 25 ppm TWA: 25 ppm
95-63-6 TWA: 125 mg/m3
Ethylbenzene TWA: 20 ppm TWA: 100 ppm IDLH: 800 ppm
100-41-4 TWA: 435 mg/m3 TWA: 100 ppm
TWA: 435 mg/m3
STEL: 125 ppm
STEL: 545 mg/m3

Appropriate engineering controls

Engineering Controls
Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear
suitable respiratory equipment.

Individual protection measures, such as personal protective equipment

Eye/face protection
Wear safety glasses with side shields (or goggles).

Skin and body protection

Wear suitable protective clothing. Personnel should wear anti-static clothing made of natural fiber or of high temperature
resistant synthetic fiber.

Hand Protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of
chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on
breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage,
maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance
or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance. Wear protective gloves.

Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Thermal Protection
No information available

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state liquid

Appearance No information available
Odor Solvent
Color Aluminum
Odor Threshold No information available
pH value No information available
Melting point/freezing point No information available
Boiling point / boiling range 56.05 °C / 133 °F
flash point -16 °C / 3 °F
evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air

Product Code MC01.C01 Page 5 / 10 AGHS - USA OSHA SDS

 Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor Pressure No information available
vapor density No information available
Density (lbs per US gallon) 7.31
specific gravity .88
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available

Other information

Section 10: STABILITY AND REACTIVITY

Reactivity No information available.

Chemical stability Stable under normal conditions.

Possibility of Hazardous Reactions None under normal processing.

Hazardous polymerization None under normal processing.

Conditions to avoid Heat, flames and sparks.

Incompatible materials Strong oxidizing agents.

Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Chlorine gas.

Section 11: TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Eye contact
Causes serious eye irritation
Skin Contact
Causes skin irritation
Ingestion
May be fatal if swallowed and enters airways
Inhalation
May cause drowsiness or dizziness

Numerical measures of toxicity - Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

n-Butyl acetate = 10768 mg/kg ( Rat ) > 17600 mg/kg ( Rabbit ) = 390 ppm ( Rat ) 4 h
123-86-4
Acetone = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m3 ( Rat ) 8 h
67-64-1
Toluene = 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h
108-88-3
Ethyl acetate = 5620 mg/kg ( Rat ) > 20 mL/kg ( Rabbit ) > 18000 -
141-78-6 mg/kg ( Rabbit )
Xylenes = 3500 mg/kg ( Rat ) > 1700 mg/kg ( Rabbit ) > 4350 = 5000 ppm ( Rat ) 4 h = 29.08
1330-20-7 mg/kg ( Rabbit ) mg/L ( Rat ) 4 h
Solvent naphtha, petroleum, light = 8400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 3400 ppm ( Rat ) 4 h
aromatic
64742-95-6
Isopropyl acetate = 3000 mg/kg ( Rat ) > 17436 mg/kg ( Rabbit ) = 50600 mg/m3 ( Rat ) 8 h
108-21-4
1,2,4-Trimethylbenzene = 3280 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) = 18 g/m3 ( Rat ) 4 h
95-63-6
Ethylbenzene = 3500 mg/kg ( Rat ) = 15400 mg/kg ( Rabbit ) = 17.4 mg/L ( Rat ) 4 h

Product Code MC01.C01 Page 6 / 10 AGHS - USA OSHA SDS

100-41-4

Numerical measures of toxicity - Product Information

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (dermal) 18701 Mg/kg
ATEmix (inhalation-dust/mist) 18.2 mg/l
ATEmix (inhalation-vapor) 134 mg/l

UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Chemical Name ACGIH IARC NTP OSHA

Ethylbenzene A3 Group 2B X
100-41-4
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen.
IARC (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans.
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present.

Skin corrosion/irritation Causes skin irritation

Serious eye damage/eye irritation Causes serious eye irritation
Skin sensitization Not applicable
Respiratory sensitization Not applicable
Germ cell mutagenicity Not applicable
Carcinogenicity Suspected of causing cancer
Reproductive Toxicity Suspected of damaging fertility or the unborn child
Specific target organ toxicity (single exposure) May cause drowsiness or dizziness
Specific target organ toxicity (repeated exposure)
May cause damage to the following organs through prolonged or repeated exposure: Nervous System Ears
Aspiration hazard May be fatal if swallowed and enters airways

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity
Environmental precautions Prevent product from entering drains.

Persistence and degradability

No information available

Bioaccumulation
No information available

Mobility
No information available

Other adverse effects No information available

Section 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty
containers must be scrapped or reconditioned.

Section 14: TRANSPORT INFORMATION

Product Code MC01.C01 Page 7 / 10 AGHS - USA OSHA SDS

 DOT IMDG IATA
14.1 UN/ID no UN1263 UN1263 UN1263
14.2 Proper shipping name Paint related material Paint related material Paint related material

14.3 Hazard Class 3 3 3

14.4 Packing Group II II II
14.5 Environmental hazard
14.6 Special Provisions 149, B52, IB2, T4, TP1, TP8, TP28, 163, 367 A3, A72, A192
367 EmS-No
Emergency Response Guide F-E, S-E
Number
128
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available

The supplier may apply one of the following exceptions: Combustible Liquid (49 CFR 173.150(f)); Consumer Commodity (49 CFR 173.150(c),
ICAO/IATA SP A112); Limited Quantity (49 CFR 173.150(b), ICAO Part 3 Chapter 4, IATA 2.7, IMDG Chapter 3.4); Viscous Liquid (49 CFR
173.121(b), IMDG 2.3.2.2, IATA 3.3.3.1.1, ICAO 3.2.2, ADR 2.2.3.1.5); Does Not Sustain Combustion (49 CFR 173.120(a), IATA 3.3.1.3, ICAO
3.1.3, IMDG 2.3.1.3, ADR 2.2.3.1.1 Note 1); or others as allowed under hazardous materials/dangerous goods regulations.

Section 15: REGULATORY INFORMATION

International Inventories
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt
from listing.
DSL - Canadian Domestic Substances List All components are listed or exempt
from listing

US Federal Regulations

Chemical Name SARA 313 - Threshold Values Metals Hazardous air pollutants
% (HAPs) content
Toluene 1 Present
108-88-3
10 - 25
Xylenes 1 Present
1330-20-7
5 - 10
1,2,4-Trimethylbenzene 1
95-63-6
1-3
Ethylbenzene 0.1 Present
100-41-4
1-3

Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
n-Butyl acetate 5000 lb X
123-86-4
Toluene 1000 lb X X X
108-88-3
Xylenes 100 lb X
1330-20-7
Ethylbenzene 1000 lb X X X
100-41-4

Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

n-Butyl acetate 5000 lb RQ 5000 lb final RQ
123-86-4 RQ 2270 kg final RQ
Acetone 5000 lb RQ 5000 lb final RQ
67-64-1 RQ 2270 kg final RQ
Toluene 1000 lb RQ 1000 lb final RQ
108-88-3 RQ 454 kg final RQ
Ethyl acetate 5000 lb RQ 5000 lb final RQ
141-78-6 RQ 2270 kg final RQ
Xylenes 100 lb RQ 100 lb final RQ

Product Code MC01.C01 Page 8 / 10 AGHS - USA OSHA SDS

 1330-20-7 RQ 45.4 kg final RQ
Ethylbenzene 1000 lb RQ 1000 lb final RQ
100-41-4 RQ 454 kg final RQ

US State Regulations

Rule 66 status of product

Photochemically reactive.

California Proposition 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

U.S. EPA Label information

EPA Pesticide registration number Not applicable

U.S. State Right-to-Know Regulations

Chemical Name
n-Butyl acetate .
123-86-4
Acetone .
67-64-1
Toluene .
108-88-3
Ethyl acetate .
141-78-6
Xylenes .
1330-20-7
Solvent naphtha, petroleum, light aromatic .
64742-95-6
Isopropyl acetate .
108-21-4
1,2,4-Trimethylbenzene .
95-63-6
Ethylbenzene .
100-41-4

Section 16: OTHER INFORMATION

HMIS
Health hazards 3*
* = Chronic Health Hazard
Flammability 3
Physical hazards 0
Personal Protection X

Supplier Address
Valspar Coatings Valspar Automotive
701 Shiloh Rd. 600 Nova Drive S.E.
Garland, TX 75042 Massillon, OH 44646
972-276-5181 330-830-6000

Prepared By Product Stewardship

Revision date 15-Nov-2019

Revision Note No information available
Disclaimer
The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national
legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and
control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS
should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS

Product Code MC01.C01 Page 9 / 10 AGHS - USA OSHA SDS

SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND
DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL,
INCIDENTAL OR CONSEQUENTIAL DAMAGES.

End of Safety Data Sheet

Product Code MC01.C01 Page 10 / 10 AGHS - USA OSHA SDS