4 Chemical Dehumidifying Process
4 Chemical Dehumidifying Process
Air can be dehumidified by passing it over chemicals that have an affinity for moisture. Usually in so doing
the moisture is condensed and gives up its latent heat, raising the dry bulb temperature of the air. The air
leaves drier and warmer. The wet bulb temperature may increase or decrease. Units employing such chemical
are used in some comfort air conditioning installations but mainly for industrial air conditioning. Since the air
leaving-air temperature is usually higher than wanted, it is necessary to add a sensible cooling process to get
the desired final air condition.
The moisture contained in humid air partially condenses in the chemical desiccant: it is adsorbed because of
the vapour partial pressure difference between process air and desiccant surface. So the process air temperature
increases because of the conversion in sensible heat of both condensation heat and heat due to the adsorption
chemical process. Therefore, process air specific humidity decreases while temperature increases (Fig. 34).
For this reason, before supplying to the space, process air must be cooled (Fig. 34b) by means of one or more of
the following components: direct expansion or chilled liquid cooling coil.
Figure. 34: Air dehumidification by (a) cooling coil and (b) chemical dehumidification
1.) Air at 24oC dry bulb and 15oC wet bulb temperatures enters a dehumidifier and leaves at 41oC dry bulb and
19oC wet bulb temperatures. How much moisture has been removed per kilogram of dry air?
Solution:
From the pschrometric chart: at td1 = 24oC and tw1 = 15oC, W1 = 0.0070 kg/kg d.a.
At td2 = 41oC and tw2 = 19oC, W2 = 0.0048 kg/kg.d.a.