Arm & HammerTM Carpet Deodorizer - All Versions and

Fragrances
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Revision Date: 04/21/2015 Date of issue: 04/21/2015 Supersedes Date: 11/11/2013 Version: 1.0

SECTION 1: IDENTIFICATION
Product Identifier
Product Form: Mixture
TM
Product Name: Arm & Hammer Carpet Deodorizer - All Versions and Fragrances
Intended Use of the Product
Deodorizer, Allergen Reducer.
Name, Address, and Telephone of the Responsible Party
Company
Church & Dwight
500 Charles Ewing Blvd
Ewing Township, NJ 08628
T 1-800-524-1328
www.churchdwight.com
Emergency Telephone Number
Emergency Number : For Medical Emergency: 1-888-234-1828, For Chemical Emergency: 1-800-424-9300 (CHEMTREC)
SECTION 2: HAZARDS IDENTIFICATION
This product is labeled in accordance with regulations administered by the Consumer Product Safety Commission (CPSC). The use
pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of the
Occupational Safety and Health Administration applicable to this SDS differ from the labeling requirements of the CPSC and, as a
result, this SDS may contain additional health hazard information not pertinent to consumer use and not found on the product label.
Classification of the Substance or Mixture
Classification (GHS-US)
Not classified
Label Elements
GHS-US Labeling No labeling applicable
Other Hazards
Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. Prolonged contact with dust can produce
mechanical irritation. May aggravate an existing allergic or asthmatic condition.
Unknown Acute Toxicity (GHS-US) Not available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Name Product Identifier % (w/w) Classification (GHS-US)
Sodium bicarbonate (CAS No) 144-55-8 60 - 100 Not classified
Calcium silicate (CAS No) 1344-95-2 0.1 - 1 Not classified
Quaternary ammonium compounds, ethylbis (hydroxyethyl) (CAS No) 68071-95-4 0.1 - 1 Skin Irrit. 2, H315
tallow alkyl, ethoxylated, ethyl sulfates (salts) Eye Irrit. 2A, H319
The specific chemical identity and/or exact percentage of composition have been withheld as a trade secret [29 CFR 1910.1200].
A range of concentration as prescribed by the Controlled Products Regulations has been used where necessary, due to varying
composition.
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
Description of First Aid Measures
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice.
Inhalation: When symptoms occur: go into open air and ventilate suspected area.

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Arm & HammerTM Carpet Deodorizer - All Versions and Fragrances
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Skin Contact: Brush off loose particles from skin. Rinse immediately with plenty of water. Obtain medical attention if irritation
develops or persists.
Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do so. Continue
rinsing. Obtain medical attention if irritation persists.
Ingestion: Rinse mouth. Do NOT induce vomiting. Seek medical attention if a large amount is swallowed.
Most Important Symptoms and Effects Both Acute and Delayed
General: None expected under normal conditions of use.
Inhalation: Prolonged inhalation of dust may cause respiratory irritation.
Skin Contact: Skin contact with large amounts of dust may cause mechanical irritation.
Eye Contact: Contact may cause irritation due to mechanical abrasion.
Ingestion: Ingestion of small amounts is not likely to be harmful. If a large quantity has been ingested: May cause gastrointestinal
irritation.
Chronic Symptoms: None expected under normal conditions of use.
Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention.
SECTION 5: FIRE-FIGHTING MEASURES
Extinguishing Media
Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: For surrounding fire. Use of heavy stream of water may spread fire.
Special Hazards Arising From the Substance or Mixture
Fire Hazard: Not flammable.
Explosion Hazard: Product is not explosive.
Reactivity: Hazardous reactions will not occur under normal conditions.
Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be
present.
Firefighting Instructions: Exercise caution when fighting any chemical fire.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: Yields Carbon oxides (CO, CO2) at temperatures over 200 °F (93.3 °C), and Sodium oxides if
exposed to temperatures above 1500 °F (815.6 °C).
Reference to Other Sections
Refer to section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Do not breathe dust or fumes. Avoid skin and eye contact.
For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods,
protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.
Environmental Precautions
Prevent entry to sewers and public waters. Avoid release to the environment.
Methods and Material for Containment and Cleaning Up
For Containment: Contain and collect as any solid.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Avoid generation of dust during clean-up of spills.
Keep in suitable, closed containers for disposal. Contact competent authorities after a spill.
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection. For further information refer to section 13.

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Arm & HammerTM Carpet Deodorizer - All Versions and Fragrances
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

SECTION 7: HANDLING AND STORAGE

Precautions for Safe Handling
Additional Hazards When Processed: When heated, material emits irritating fumes.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking, or smoking and again when leaving work.
Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Ensure all national/local regulations are observed.
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Store away from
incompatible materials.
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Water. Lime.
Specific End Use(s)
Deodorizer, Allergen Reducer.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or
the Mexican government
Calcium silicate (1344-95-2)
USA ACGIH ACGIH TWA (mg/m³) 10 mg/m³ (synthetic nonfibrous-particulate matter containing
no asbestos and <1% crystalline silica)
USA ACGIH ACGIH chemical category Not Classifiable as a Human Carcinogen synthetic nonfibrous
USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (total dust)
5 mg/m³ (respirable fraction)
USA NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ (total dust)
5 mg/m³ (respirable dust)
Alberta OEL TWA (mg/m³) 10 mg/m³ (synthetic, nonfibrous)
British Columbia OEL TWA (mg/m³) 10 mg/m³ (total particulate matter containing no Asbestos and
<1% Crystalline silica-total particulate)
3 mg/m³ (particulate matter containing no Asbestos and <1%
Crystalline silica-respirable particulate)
Manitoba OEL TWA (mg/m³) 10 mg/m³ (synthetic nonfibrous, particulate matter containing
no Asbestos and <1% Crystalline silica)
New Brunswick OEL TWA (mg/m³) 10 mg/m³ (particulate matter containing no Asbestos and <1%
Crystalline silica)
Newfoundland & Labrador OEL TWA (mg/m³) 10 mg/m³ (synthetic nonfibrous, particulate matter containing
no asbestos and <1% crystalline silica)
Nova Scotia OEL TWA (mg/m³) 10 mg/m³ (synthetic nonfibrous, particulate matter containing
no Asbestos and <1% Crystalline silica)
Nunavut OEL TWA (mg/m³) 5 mg/m³ (respirable mass)
10 mg/m³ (total mass)
Northwest Territories OEL TWA (mg/m³) 5 mg/m³ (respirable mass)
10 mg/m³ (total mass)
Ontario OEL TWA (mg/m³) 10 mg/m³ (synthetic nonfibrous, containing no Asbestos and
<1% Crystalline silica)
Prince Edward Island OEL TWA (mg/m³) 10 mg/m³ (synthetic nonfibrous; particulate matter containing
no Asbestos and <1% Crystalline silica)
Québec VEMP (mg/m³) 10 mg/m³ (synthetic, containing no Asbestos and <1%
Crystalline silica-total dust)
Saskatchewan OEL STEL (mg/m³) 20 mg/m³ (nonfibrous)
Saskatchewan OEL TWA (mg/m³) 10 mg/m³ (nonfibrous)
Yukon OEL TWA (mg/m³) 30 mppcf

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Arm & HammerTM Carpet Deodorizer - All Versions and Fragrances
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
10 mg/m³
Exposure Controls
Appropriate Engineering Controls: For occupational/workplace settings: Emergency eye wash fountains and safety showers should
be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all
national/local regulations are observed.
Personal Protective Equipment: For occupational/workplace settings and bulk quantities: Gloves. Safety glasses. Dust formation:
dust mask.

Materials for Protective Clothing: For occupational/workplace settings: Chemically resistant materials and fabrics.
Hand Protection: For occupational/workplace settings: Chemically resistant gloves are recommended, but not required.
Eye Protection: For occupational/workplace settings: Chemical goggles or safety glasses.
Skin and Body Protection: For occupational/workplace settings: In case of dust production: dustproof clothing.
Respiratory Protection: If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn.
Other Information: When using, do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties
Physical State : Solid
Appearance : White, granular powder
Odor : As per label
Odor Threshold : Not available
pH : 8.2 (1% SOLN. w/v)
Evaporation Rate : Not available
Melting Point : Not applicable
Freezing Point : Not available
Boiling Point : Not applicable
Flash Point : Not applicable
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : Not available
Relative Vapor Density at 20 °C : Not available
Relative Density : Not available
Specific gravity / density : 1.0 g/cc
Specific Gravity : 1.0
Solubility : 8.5 g/ml @ 20 °C (68 °F) in water
Partition Coefficient: N-Octanol/Water : Not available
Viscosity : Not available
Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact
Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge

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Arm & HammerTM Carpet Deodorizer - All Versions and Fragrances
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

SECTION 10: STABILITY AND REACTIVITY

Reactivity: Hazardous reactions will not occur under normal conditions.
Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Exposure to moisture or moist air. Temperatures above 200 °F (93.3 °C).
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Water. Lime.
Hazardous Decomposition Products: Yields Carbon oxides (CO, CO2) at temperatures over 200 °F (93.3 °C), and Sodium oxides if
exposed to temperatures above 1500 °F (815.6 °C).
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects - Product
Acute Toxicity: Not classified
LD50 and LC50 Data:
TM
Arm & Hammer Carpet Deodorizer - All Versions and Fragrances
LD50 Oral Rat 7.3 g/kg
LC50 Inhalation Rat > 4.7 mg/l/4h
Skin Corrosion/Irritation: Not classified
pH: 8.2
Serious Eye Damage/Irritation: Not classified
pH: 8.2
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not classified
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: Prolonged inhalation of dust may cause respiratory irritation
Symptoms/Injuries After Skin Contact: Skin contact with large amounts of dust may cause mechanical irritation
Symptoms/Injuries After Eye Contact: Contact may cause irritation due to mechanical abrasion
Symptoms/Injuries After Ingestion: Ingestion of small amounts is not likely to be harmful. If a large quantity has been ingested: May
cause gastrointestinal irritation
Chronic Symptoms: None expected under normal conditions of use
Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data:
Sodium bicarbonate (144-55-8)
LD50 Oral Rat 4220 mg/kg
Calcium silicate (1344-95-2)
LD50 Oral Rat 3400 mg/kg

SECTION 12: ECOLOGICAL INFORMATION

Toxicity Not classified
TM
Arm & Hammer Carpet Deodorizer - All Versions and Fragrances
LC50 Fish 1 7100 mg/l Bluegill
EC50 Daphnia 1 4100 mg/l
LC 50 Fish 2 7700 mg/l Rainbow Trout
Sodium bicarbonate (144-55-8)
LC50 Fish 1 8250 - 9000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
EC50 Daphnia 1 2350 mg/l (Exposure time: 48 h - Species: Daphnia magna)

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Arm & HammerTM Carpet Deodorizer - All Versions and Fragrances
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Persistence and Degradability
TM
Arm & Hammer Carpet Deodorizer - All Versions and Fragrances
Persistence and Degradability Not established.
Bioaccumulative Potential
TM
Arm & Hammer Carpet Deodorizer - All Versions and Fragrances
Bioaccumulative Potential Not established.
Mobility in Soil Not available
Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial
and international regulations.
SECTION 14: TRANSPORT INFORMATION
In Accordance with DOT Not regulated for transport
In Accordance with IMDG Not regulated for transport
In Accordance with IATA Not regulated for transport
In Accordance with TDG Not regulated for transport
SECTION 15: REGULATORY INFORMATION
US Federal and international regulations
Sodium Bicarbonate (144-55-8)
Regional Legislation
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on the Canadian DSL (Domestic Substances List)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Calcium Silicate (1344-95-2)
Regional Legislation
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on the Canadian DSL (Domestic Substances List)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Quaternary Ammonium Compounds, Ethylbis(Hydroxyethyl)Tallow Alkyl, Ethoxylated, Ethyl Sulfates (Salts) (68071-95-4)
Regional Legislation
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on the Canadian DSL (Domestic Substances List)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) inventory

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Arm & HammerTM Carpet Deodorizer - All Versions and Fragrances
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
US State Regulations
Calcium silicate (1344-95-2)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Canadian Regulations
TM
Arm & Hammer Carpet Deodorizer - All Versions and Fragrances
WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Sodium bicarbonate (144-55-8)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Calcium silicate (1344-95-2)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Uncontrolled product according to WHMIS classification criteria
Quaternary ammonium compounds, ethylbis(hydroxyethyl)tallow alkyl, ethoxylated, ethyl sulfates (salts) (68071-95-4)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS
contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 04/21/2015
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200. This product is labeled in accordance
with regulations administered by the Consumer Product Safety Commission (CPSC). The use
pattern and exposure in the workplace are generally not consistent with those experienced
by consumers. The requirements of the Occupational Safety and Health Administration
applicable to this SDS differ from the labeling requirements of the CPSC and, as a result,
this SDS may contain additional health hazard information not pertinent to consumer use
and not found on the product label.
GHS Full Text Phrases:
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
Party Responsible for the Preparation of This Document
Church & Dwight
500 Charles Ewing Blvd
Ewing Township, NJ 08628
T 1-800-524-1328

This Product Safety Data Sheet is offered solely for your information, consideration and investigation. Church & Dwight Co., Inc.
provides no warranties; either expressed or implied, and assumes no responsibility for the accuracy or completeness of data contained
herein. Church & Dwight Co., Inc. urges persons receiving this information to make their own determination as to the information
suitability for their particular application.

North America GHS US 2012 & WHMIS 2

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