SAFETY DATA SHEET
1. Identification
TRANSPORTATION EMERGENCY
Covestro LLC CALL CHEMTREC: (800) 424-9300
1 Covestro Circle INTERNATIONAL: (703) 527-3887
Pittsburgh, PA 15205
USA
NON-TRANSPORTATION
Emergency Phone: Call Chemtrec
Information Phone: (844) 646-0545
Product Name: IMPRANIL C
Material Number: 00268836
Chemical Family: Aromatic Polyester Urethane Resin
Use: Raw material for coatings, adhesives, sealants, or elastomers in
industrial applications
Restrictions on use: Pesticides
2. Hazards Identification
GHS Classification
Reproductive toxicity: Category 2
GHS Label Elements
Hazard pictograms:
Signal word: Warning
Hazard statements: Suspected of damaging fertility or the unborn child.
If fine particles are generated during further processing, handling or
by other means, product may form combustible dust concentrations in
air.
Precautionary statements: Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and
understood.
Wear permeation resistant protective gloves and clothing. Wear eye
and face protection.
Response:
IF exposed or concerned: Get medical attention.
Storage:
Material Name: IMPRANIL C Material Number: 00268836
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Store locked up.
Disposal:
Dispose of contents and container in accordance with existing federal,
state, and local environmental control laws.
3. Composition/Information on Ingredients
Hazardous Components
Concentration Components CAS-No.
0.1 - 1% Toluene 108-88-3
The specific chemical identity and/or exact percentage of component(s) have been withheld as a trade
secret.
4. First Aid Measures
Most Important Symptom(s)/Effect(s)
Acute: May cause mechanical irritation of the respiratory tract, skin, and/or eyes. Eyes may become red,
feel scratchy and may tear., Contact with heated material can cause thermal burns.
Eye Contact
In case of contact, flush eyes with plenty of lukewarm water. Use fingers to ensure that eyelids are
separated and that the eye is being irrigated. Get medical attention if irritation develops.
Skin Contact
In case of skin contact, wash affected areas with soap and water. Wash clothing and shoes before reuse.
Inhalation
If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
respiration. Get medical attention if irritation develops.
Ingestion
If ingested, do not induce vomiting unless directed to do so by medical personnel. Get medical attention.
5. Firefighting Measures
Suitable Extinguishing Media: Water, Foam, Dry chemical
Unsuitable Extinguishing Media: Carbon dioxide (CO2)
Fire Fighting Procedure
Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic
and irritating fumes. Toxic and irritating gases/fumes may be given off during burning or thermal
decomposition. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture.
Hazardous Decomposition Products
By Fire and Thermal Decomposition: Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen
(NOx), dense black smoke, Isocyanate, Isocyanic Acid and other undetermined compounds., Hydrogen
Material Name: IMPRANIL C Material Number: 00268836
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cyanide
Unusual Fire/Explosion Hazards
Product is a granular solid. If ground into powder form, conditions may exist for a dust explosion. Avoid
dusting.
6. Accidental Release Measures
Spill and Leak Procedures
Avoid creating dusty conditions. Remove mechanically by a method that minimizes the generation of
airborne dust (vacuum cleaner, wet mopping, etc.) Collect and place in appropriately marked sealable
containers for disposal. If molten, allow material to cool and place into an appropriate marked container for
disposal. Wash spill area with soap and water.
7. Handling and Storage
Handling/Storage Precautions
Handle in accordance with good industrial hygiene and safety practices. Wash thoroughly after handling.
Keep container closed when not in use. Take precautionary measures against static discharges. Avoid
breathing dust. Material is hygroscopic and may absorb small amounts of atmospheric moisture.
Storage Period:
6 Months: after receipt of material by customer
Storage Temperature
Minimum: 20 °C (68 °F)
Maximum: 20 °C (68 °F)
Storage Conditions
Store in a dry place in original or waterproof containers. Minimize dust generation and accumulation.
Material can be stored safely at ambient temperatures. Store separate from food products.
Substances to Avoid
Strong oxidizing agents, Strong acids and strong bases, Isocyanates
8. Exposure Controls/Personal Protection
The recommendations in this section should not be a substitute for a personal protective equipment (PPE)
assessment performed by the employer as required by 29 CFR 1910 Subpart I.
Exposure Limits
Toluene (108-88-3)
US. ACGIH Threshold Limit Values, as amended
Time weighted average 20 ppm
US. OSHA Table Z-2 (29 CFR 1910.1000), as amended
Time weighted average 200 ppm
US. OSHA Table Z-2 (29 CFR 1910.1000), as amended
Ceiling Limit Value 300 ppm
Material Name: IMPRANIL C Material Number: 00268836
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US. OSHA Table Z-2 (29 CFR 1910.1000), as amended
Maximum concentration: 500 ppm (10 minutes)
US. ACGIH Threshold Limit Values, as amended
Hazard Designation: Group A4 Not classifiable as a human carcinogen.
Any component which is listed in section 3 and is not listed in this section does not have a known ACGIH
TLV, OSHA PEL or supplier recommended occupational exposure limit.
Industrial Hygiene/Ventilation Measures
Use local and general exhaust ventilation to control levels of exposure. Thermal processing operations
should be ventilated to control gases and fumes given off during processing.
Respiratory Protection
Maintain levels below the recommended exposure limits., During high-temperature processing and/or
circumstances where decomposition is suspected, a NIOSH-approved supplied air respirator is
recommended to protect against fumes and vapors.
Hand Protection
Ensure gloves remain in good condition during use and replace if any deterioration is observed.
Wear heat resistant gloves when handling molten material.
Eye Protection
Safety glasses with side-shields
Skin Protection
No special skin protection requirements during normal handling and use.
Additional Protective Measures
Employees should wash their hands and face before eating, drinking, or using tobacco products. Emergency
showers and eye wash stations should be available. Employee education and training in the safe use and
handling of this product are required under the OSHA Hazard Communication Standard 29 CFR
1910.1200. Store separate from food products.
9. Physical and Chemical Properties
State of Matter: solid
Appearance: flakes, granules
Color: Colorless
Odor: Odorless
Odor Threshold: No Data Available
pH: not applicable
Melting Point: ca. 115 °C (239 °F)
Boiling Point: No Data Available
Flash Point: > 93 °C (199.4 °F) @ 1,013 hPa
Evaporation Rate: No Data Available
Flammability: No Data Available
Lower Explosion Limit: Not Established
Upper Explosion Limit: Not Established
Vapor Pressure: No Data Available
Vapor Density: No Data Available
Density: No Data Available
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Relative Vapor Density: No Data Available
Specific Gravity: No Data Available
Solubility in Water: insoluble
Partition Coefficient: n- No Data Available
octanol/water:
Auto-ignition Temperature: No Data Available
Decomposition Temperature: No Data Available
Unblocking Temperature: No Data Available
Dynamic Viscosity: 40,000 mPa.s @ 23 °C (73.4 °F)
Kinematic Viscosity: No Data Available
Bulk Density: ca. 600 kg/m3
Molecular Weight: No Data Available
10. Stability and Reactivity
Hazardous Reactions
Hazardous polymerisation does not occur.
Stability
Stable
Materials to Avoid
Strong oxidizing agents, Strong acids and strong bases, Isocyanates
Conditions to Avoid
None known.
Hazardous Decomposition Products
By Fire and Thermal Decomposition: Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen
(NOx), dense black smoke, Isocyanate, Isocyanic Acid and other undetermined compounds., Hydrogen
cyanide
11. Toxicological Information
Likely Routes of Exposure: Inhalation
Skin Contact
Eye Contact
Ingestion
Health Effects and Symptoms
Acute: May cause mechanical irritation of the respiratory tract, skin, and/or eyes. Eyes may become red,
feel scratchy and may tear., Contact with heated material can cause thermal burns.
Chronic: Suspected of damaging fertility or the unborn child.
Toxicity Data for: IMPRANIL C
Acute Inhalation Toxicity
Acute toxicity estimate: 29.72 mg/l, 4 h, vapour (Calculation method)
Acute Dermal Toxicity
Acute toxicity estimate: > 5,000 mg/kg (Calculation method)
Material Name: IMPRANIL C Material Number: 00268836
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Toxicity Data for: Toluene
Acute Oral Toxicity
LD50: 5,580 mg/kg (rat, male) (Directive 67/548/EEC, Annex V, B.1.)
Acute Inhalation Toxicity
LC50: 28.1 mg/l, 4 h, vapour (rat, male/female) (OECD Test Guideline 403)
Acute Dermal Toxicity
LD50: > 5,000 mg/kg (rabbit, male)
Skin Irritation
rabbit, Exposure Time: 4 h, irritating
Eye Irritation
rabbit, OECD Test Guideline 405, slight irritant
Sensitization
ambiguous (Guinea pig)
non-sensitizer (rat)
Skin sensitisation according to Magnusson/Kligmann (maximizing test):: negative (Guinea pig)
Repeated Dose Toxicity
13 weeks, Inhalation: NOAEL: 312 mg/kg, (rat, Male/Female, 6 hrs/day 5 days/week)
Chronic exposure damages the brain and the central nervous system.
Mutagenicity
Genetic Toxicity in Vitro:
Ames: Negative results were reported in various in vitro studies. (Salmonella typhimurium, Metabolic
Activation: with/without)
Mammalian cell - gene mutation assay: Negative results were reported in various in vitro studies. (Mouse
lymphoma cells (L5178Y/TK), Metabolic Activation: with/without)
Genetic Toxicity in Vivo:
Dominant Lethal Assay: positive, negative (Mouse, male)
positive, negative
Sister Chromatid Exchange: negative, Negative results were reported in various in vivo studies. (rat, )
negative, Negative results were reported in various in vivo studies.
Cytogenetic assay: negative (rat, )
negative
Carcinogenicity
rat, Male/Female, inhalation, 18 months, 6 hrs/day 5 days/week negativeMouse, Male/Female, inhalation, 2
years, 6 hrs/day 5 days/week negative
Toxicity to Reproduction/Fertility
Fertility Screening, inhalation, 6 hrs/day 5 days/week, (Mouse, male) NOAEL (parental): 400 ppm,
Reproductive effects have been observed in animal studies.Two generation study, inhalation, (rat,
Male/Female) NOAEL (parental): 500 ppm, NOAEL (F1): 500 ppm, NOAEL (F2): 500 ppm Two
generation study, inhalation, 6 hrs/day 7 days/week, (rat, Male/Female)
Material Name: IMPRANIL C Material Number: 00268836
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Developmental Toxicity/Teratogenicity
rabbit, inhalation, gestation, 6 hrs/day 7 days/week, NOAEL (teratogenicity): 1.14 mg/l, NOAEL
(maternal): 1.14 mg/kg, No Teratogenic effects observed at doses tested.rat, female, inhalation, gestation, 6
hrs/day 5 days/week, NOAEL (teratogenicity): 400 ppm, NOAEL (maternal): 400 ppm No fetotoxicity
observed at doses tested.rat, female, Inhalative, pregnancy, 6 hours/day 7 days/week, NOAEL
(teratogenicity): 4500 mg/m³, NOAEL (maternal): 2250 mg/m³ Fetotoxicity has been observed in animal
studies.
Other Relevant Toxicity Information
May cause drowsiness or dizziness.
May be fatal if swallowed and enters airways.
Carcinogenicity:
No carcinogenic substances as defined by IARC, NTP and/or OSHA
12. Ecological Information
Ecological Data for: IMPRANIL C
No data available for this product.
Ecological Data for Toluene
Biodegradation
Aerobic, 86 %, Exposure time: 20 d
Biochemical Oxygen Demand (BOD)
2,150 mg/l
Chemical Oxygen Demand (COD)
2,520 mg/g
Bioaccumulation
Golden orfe (Leuciscus idus), Exposure time: 3 Days, 90 BCF
Acute and Prolonged Toxicity to Fish
LC50: 13 mg/l (Goldfish (Carassius auratus), 96 h)
LC50: 26 mg/l (Fathead minnow (Pimephales promelas), 96 h)
LC50: 24 mg/l (Rainbow (Donaldson)Trout (Oncorhynchus mykiss), 96 h)
Acute Toxicity to Aquatic Invertebrates
EC50: 11.5 mg/l (Water flea (Daphnia magna), 48 h)
Toxicity to Aquatic Plants
EC50: > 433 mg/l, (Green algae (Selenastrum capricornutum), 96 h)
Toxicity to Microorganisms
EC0: 29 mg/l, (Pseudomonas putida, 16 h)
Material Name: IMPRANIL C Material Number: 00268836
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13. Disposal Considerations
Waste Disposal Method
Waste disposal should be in accordance with existing federal, state and local environmental control laws.
Empty Container Precautions
Recondition or dispose of empty container in accordance with governmental regulations. Empty containers
retain product residue; observe all precautions for product.
14. Transportation Information
Land transport (DOT)
Non-Regulated
Sea transport (IMDG)
Non-Regulated
Air transport (ICAO/IATA)
Non-Regulated
15. Regulatory Information
United States Federal Regulations
US. Toxic Substances Control Act: Listed on the Active Portion of the TSCA Inventory.
No substances are subject to TSCA 12(b) export notification requirements.
US. EPA CERCLA Hazardous Substances (40 CFR 302) Components:
None
SARA Section 311/312 Hazard Categories:
Refer to hazard classification information in Section 2.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A) Components:
None
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required Components:
None
US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes
and Appendix VIII Hazardous Constituents (40 CFR 261):
Under RCRA, it is the responsibility of the person who generates a solid waste, as defined in 40 CFR
261.2, to determine if that waste is a hazardous waste.
State Right-To-Know Information
The following chemicals are specifically listed by individual states; other product specific health and safety
data in other sections of the SDS may also be applicable for state requirements. For details on your
regulatory requirements you should contact the appropriate agency in your state.
Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists:
Material Name: IMPRANIL C Material Number: 00268836
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Concentration Components CAS-No.
>=1% Polyurethane Resin CAS# is a trade secret
1 - 5% Talc (non-asbestos form) 14807-96-6
New Jersey Environmental Hazardous Substances List and/or New Jersey RTK Special Hazardous
Substances Lists:
Concentration Components CAS-No.
0.1 - 1% Toluene 108-88-3
California Proposition 65 List:
Concentration Components CAS-No.
0.1 - 1% Toluene 108-88-3
CFATS (Chemical Facility Anti-Terrorism Standards) Chemicals
To the best of our knowledge, this product does not contain Appendix A Chemicals of Interest (COI), at or
above the Screening Threshold Quantity (STQ), as defined by the Department of Homeland Security
Chemical Facility Anti-terrorism Standard (CFATS, 6 CFR Part 27).
Based on information provided by our suppliers, this product is considered “DRC Conflict Free” as defined
by the SEC Conflict Minerals Final Rule (Release No. 34-67716; File No. S7-40-10; Date: 2012-08-22).
16. Other Information
The method of hazard communication for Covestro LLC is comprised of product labels and safety data
sheets. Safety data sheets for all of our products and general product declarations are available for
download at www.productsafetyfirst.covestro.com.
This product, or any part of the product, is not approved for and should not be used in the formulation of
a pesticide or pesticide product, as those terms are defined in 40 CFR 152.3.
Contact: Product Safety Department
Telephone: (412) 413-2835
Version Date: 05/06/2021
SDS Version: 4.5
Information contained in this SDS is believed to be accurate but is furnished without warranty, express or
implied, including warranties of merchantability or fitness for a particular purpose. The information relates
only to the specific material designated herein. Covestro LLC. assumes no legal responsibility for use of or
reliance upon the information in this SDS and such information shall in no case be considered a part of our
terms and conditions of sale. The user is responsible for determining whether the Covestro product is
suitable for user’s method of use or application. Covestro is not liable for any failure to observe the
precautionary measures described in this SDS or for any misuse of the product.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.
Material Name: IMPRANIL C Material Number: 00268836
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