Question:
Describe the preparation of
(a) 500 mL of 0.0750 M AgNO3 from the solid reagent.
(b) 1.00 L of 0.285 M HCl, starting with a 6.00 M
solution of the reagent.
(c) 400 mL of a solution that is 0.0810 M in K+,
starting with solid K4Fe(CN)6.
(d) 600 mL of 3.00% (w/v) aqueous BaCl2 from a
0.400 M BaCl2 solution.
(e) 2.00 L of 0.120 M HClO4 from the commercial
reagent [71.0% HClO4 (w/w), sp gr 1.67].
(f) 9.00 L of a solution that is 60.0 ppm in Na+, starting
with solid Na2SO4.
Answer :
a) Given:
Molarity of
Volume of the
Molar mass of
Mass of in 500 mL of solution can be calculated as
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Mass of
Therefore, 0.0750 M solution can be prepared by dissolving
of in water and diluting to 500 mL.
b) Given:
Molarity of the given
Molarity of the prepared
Volume of the prepared
Here, we have to calculate the volume of the concentrated and this can be
obtained by dividing the number of moles of required by the molarity of the
given solution:
Number of moles
Volume of concentrated reagent
Therefore, solution can be prepared by diluting of
concentrated to 1 L.
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c) Molarity of
Molarity of
Volume of the prepared
Therefore, in can be prepared by dissolving of
in water and then diluting to 400 mL.
Mass of in 400 mL solution can be calculated as
Mass of
Therefore, 0.02025 M solution can be prepared by dissolving
of in water and diluting to 400 mL.
d) Given:
Molarity of the given
Volume of the prepared
Concentration of
To obtain the volume of concentrated , we have to first determined the
number of moles of and then divide it by the molarity of the concentrated
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(given) solution.
Number of moles of
Volume of concentrated solution
Therefore, 3.00% (w/v) of can be prepared by diluting of the given
solution to 600 mL.
e)
Given:
Molarity of the prepared
Specific gravity of concentrated
Concentration of
Volume of the prepared
Calculation of molarity of concentrated
Now, to obtain the volume of the concentrated solution, we have to first calculate
the number of moles of and then divide it by the molarity of the
concentrated solution.
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Number of moles of
Volume of the concentrated solution
Therefore, solution can be prepared by diluting of
concentrated solution to 2.00 L.
f) Given:
Concentration of
Volume of the prepared
Molar mass of
To determine the molar concentration of from the given ppm value, we have to
convert ppm into molarity.
For an aqueous solution 1ppm is given as
So,
Now, divide by the molar mass of in order to
determine the molar concentration of .
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Molar concentration of
Thus, the molar concentration of
The mass of in 9.00 L solution can be calculated as
Mass of
Therefore, 60 ppm in solution can be prepared by dissolving of
in water and then diluting to 9.00 L.
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