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 Chemistry
Sample Question Paper-1

Time- 3 Hours Max. Marks: 70

General Instruction:
1. Question 1 is of 20 marks having four sub parts, all of which are compulsory.
2. Question numbers 2 to 8 carry 2 marks each, with two questions having internal choice.
3. Question numbers 9 to 15 carry 3 marks each, with two questions having internal choice.
4. Question numbers 16 to 18 carry 5 marks each, with an internal choice.
5. All working, including rough work, should be done on the same sheet as, and adjacent to the
rest of the answer.
6. The intended marks for questions or parts of questions are given in brackets [].
7. Balanced equations must be given wherever possible and diagrams where they are helpful.
8. When solving numerical problems, all essential working must be shown.
9. In working our problems, use the following data:
Gas constant R = 1.987 cal deg-1 mol-1 = 8.314 JK-1 mol-1 = 0.0821 dm3 atm K-1 mol-1
1 l atm = 1 dm3 atm = 101.3 J. 1 Faraday = 96500 Coulombs.
Avogadro’s number = 6.023 × 1023 mol-1.

1. Question 1: (a) Fill in the blanks by choosing the appropriate word/ words from those
given in the brackets:
[4]
(Ketones, aldehydes, cationic, Acidic, CaCl2, Ammonic, Al4C3, alkaline, -M, +I, -I, +M,
Normality, Molality, Mole fraction, Molarity, Less, More)

(i) ________ and ___________ temperature independent mode of concentration representation.

(ii) Aqueous solution of NH4Cl will be _________ due to _______ hydrolysis.
(iii) _________ on hydrolysis give ethyne while _______ on hydrolysis gives methane.
(iv) Trichloracetic acid is _________ acidic than acetic acid due to _________ effect.

(b) Complete the following statements by selecting the correct alternative from the choices
given:
[4]

(i) The electronic configuration of outer most shell of the second most electromagnetic element
is:
1
(a) ns2np3
(b) ns2np4
(c) ns2np5
(d) ns2np6

(ii) Which of the following species is diamagnetic in nature?

(a) H2-
(b) H2
(c) He2-
(d) H2+

(iii) The volume of ‘ 20 vol’ H2O2 required to liberate 500mL of O2 at NTP is:
(a) 50mL
(b) 125mL
(c) 25mL
(d) 100mL

(iv) The compound which is isometric with dimethyl ether is:

(a) Methyl n- proplyl ether
(b) 1- Butanol
(c) 2- methyl propen-2-ol
(d) Butanone

(c) Match the laws given in Column I with expressions given in Column II. [4]

Column I Column II
A. Optical Isomerism 1. Magnetic quantum
number
B. Sodium Carbonate 2. Boron halides
C. Orientation of the orbital 3. Lactic acid
D. Lewis acid 4. Solvay’s Process

(d) Answer the following questions: [4×2]

(i) (a) Give reason why a molecule in which Nb =Na is more stable.

(b) Name the bond which is formed by the sidewise overlapping of p- orbitals.

(ii) (a) Glyoxals are produced by the reductive ozonolysis of which alkyne?

(b) Name the gas which is produced by the dehydrohalogenation of ethyl iodine.

2
(iii) (a) What is temperature at which the entropy of crystalline substance can be taken as zero?

(b) In case of an exothermic reactions with mordant entropy the sign of G will ether positive or
negative.

(iv) (a) Alkali metals the considered as good reducing agent. Why?

(b) An alkaline earth metal is deepening related with Aluminium. Name the element.

Solution 1:

(a) (i) molality and mole fraction

(ii) more and -I effect

(iii) acidic and cationic

(iv) CaC2 and Al4C3

(B) (i) (3) ns2np5

(ii) (2) H2
(iii) Volume of 10 mole of H2O2 required to liberate 500ml of O2 at NTP is

2H2O2   H2O + H2

10 mol

10ml of O2 liberated from 1ml

Volume of H2O2

500
So , 500ml of oxygen liberated from  50ml volume of H 2 O 2solution
10

(iv) (2) 1-butanol

(C) (i) (c)

(ii) (d)

(iii) (a)
(iv) (b)

(D) (i)
1. If NA = Nb , then formation of the molecule will not take place
3
 2.  Bond

(ii) (1) alkyne on reductive ozonolysis will produce glyoxal only is acetylene.
(2) HI gas is produced on dehydrohalogenation on of ethyl iodide.
(iii) (1) At 0 Kelvin
(2) G = -ve So, entropy is increased.

(iv) (1) Alkali metals are used as reducing agents because they have low ionization energy
which decrease down the
group. So, Can easily lose there valance e-.
(2) Be (Berylium)

Question 2: An organic compound of 0.250g gives 0.141g of AgBr. Calculate the percentage of
bromine compound by Carious method. (Given: atomic weight of Ag = 108, Br = 80)
OR
An organic compound of 0.234g, given 0.334g of Barium sulphate in Carious method of
estimation. Calculate the percentage of sulphate in the given compound. (Given:
At. Wt. of Ba = 137, S = 32, O =16)
Solution 2:
Carious method
(a) Carious method
Organic compound (w)= 0.250g
AgBr x= 0.141g
AgBr = 80+108 = 188gm
80 x
% of Br =   100
108 w

80 0.141
=  100
108 0.250

8 141
=
47

= 24% Br
OR
4
(b) BaSO4 (x) = 0.334g
Organic compound (w)= 0.234
BaSO4 =137+32+16 X 4 = 233

32 x
Percentage of sulphur =  100
231 w

32 0.334
=   100
231 0.234

= 19.72%
= 20%
Question 3: Complete the following reactions and then balance them:

(i) Fe2SO3 +H2O2 + H2SO4 

 _______ + ___________

(ii) H2O2 + Ag2O 

 __________ + __________ + ____________

Solution 3:

(i) 2Fe2SO3 +H2O2 + H2SO4 

 Fe2(SO24)3 +H2O

(ii) H2O2 + Ag2O 

 2Ag + H2O +O2

Question 4: Calculate the molecular weight of a gas which is measured 280 ml at 307K and 750
mm of Hg.
Solution 4:
Given :-
V= 280ml = 280  10-10
P=750mmHg = 105 pa
T =307 K
W= 0.344g
PV = nRT

PV
n=
RT

5
 2801010 105
= = 0.011 moles
8314  305

mass
n=
molarmass

mass 0.344
M= = = 31.2 g
n 0.011 mol

Question 5: Write the structural formula of the following IUPAC Names-

(i) 5-methyl hept-3-enal
(ii) 3- hydroxyl 6,6 dimethyl hept 4-ene-1-oic acid
Solution 5:
(i)5- methyl hept-3-enal
OHC-CH2-CH-CH=CH-CH-CH2-CH3
CH3
(ii) 3- hydroxyl 6,6 dimethyl hept 4-ene-1-oic acid
CH3
HOOC-CH2-CH-CH=CH-C-CH3
OH CH3

Question 6: Give the reason why the first ionization enthalphy of nitrogen is more than oxygen
but the second ionization of oxygen is more than nitrogen. Explain. ( at. No. of N = 7 and O =
8)
Solution 6:
I.E N>O
N (7)= 1s22s22p3
O (8)= 1s22s22p4
I.E N>O
N+ (6)= 1s22s22p2

6
 O+ (7)= 1s22s22p3

Question 7: (a) Name the alkenes which give only following compound on reductive ozonalysis:
(i) Ethanol
(ii) Propanone

OR
(b) Give the preparation of following compounds:
(i) Ethene from ethyl alcohol
(ii) 2- Bromopropane from propene.
Solution 7:
(A)

(i) CH3CH=CHCH3 

Ozonolysis
 CH3CHO + CH3CHO

But-2-ene

(ii) CH3-C=CH-CH3 
 CH3-C=O + CH3-CHO

CH3 CH3
2-methyl but-2-ene
OR
(B)
(i) Ethyl alcohol to ethene

CH2-CH3-OH 
H 2 SO4
433 K
 CH2=CH2

(ii) propene to 2-bromopropane

Br

CH3-CH=CH2  
HBr
 CH3-CH-CH3

7
Question 8: Explain the structure of allotropies of Carbon which are diamond and graphite and
give the reason of their hardness based on this structure.
Solution 8:
Structure of diamond and graphite:-
Diamond has giant molecular structure. Each Carbon atom is covalently to Sour other Carbon
atoms. The bond present in diamond is covalent bond.
Graphite on the other hand has flat layers of carbon atoms held by weak van der waal’s forces.
On the basis of hardness:-

 Diamond is used in making cutting and grinding tools.

 On the other hand graphite there are flat layers of carbon atoms.

Question 9:
(i) Give the reason why Fe3+ if more paramagnetic than Fe2+.
(ii) The atomic number of Mn is 25. What is the number of unpaired electrons inM2+ ion?
Solution 9:
(i) Fe (26) =1s2 2s2 2p6 3s2 3p6 3d6 4s2
Fe2+ = 1s2 2s2 2p6 3s2 3p6 3d6 4s
Fe3+ = 1s2 2s2 2p6 3s2 3p6 3d5 4s0
Fe3+ is more paramagnetic because it contain five unpaired e-.
(ii) Mn(25) =1s2 2s2 2p6 3s2 3p6 3d5 4s2
Mn2+ =1s2 2s2 2p6 3s2 3p6 3d5 4s0
Unpaired e- = 5
Question 10:
(a) 0.36 gm of relative substance displaces air moisture 140mL at STP in a Viene Meyer’s
Experiment. What will the vapour density and molecular weight of the substance. If 1 Live of H2
gas weighs 0.09g at STP.
OR
(b) If 1200 ml of O2 gas is taken in a vessel has pressure equal to 1450 mmg of Hg, whereas 750
ml of the H2 gas is taken in another vessel has pressure equal to 900 mm of Hg. If both the gases
8
are mixed in a vessel of capacity of 1000ml. Calculate the total pressure exerted by the mixture
of both the gases when both are non- reacting gases.
Solution 10:
(a)
PV = nRT
m m
N= , PV = RT
M M

mRT
M=
PV

At STP :- m = 0.36
R = 0.08314 barLK-1ml-1
T =273.15 K
P = 1 bar
140
Volume = 140ml = = 0.14 l
1000

0.36  0.08314  273 8.1709

M= = = 58.36 g
1 0.14 0.14

Vaapour density = 2  molecular weight

=2  58.36 = 116.72
OR
(b) To Calculate partial pressure of nitrogen
Given condition
Volume, V1=750ml V2=1500ml
Pressure, P1 =900 mmHg P2=? mm
P1P2 = V1 V2
900  750 = P2  1000
900  750
P2 =
1000

9
 P2 = 675mm
To calculate partial pressure of oxygen:-
Given condition
Volume, V1=1200ml V2=1000ml
Pressure, P1 =1450 mmHg P2=? mm
P1P2 = V1 V2
1450  1200 = P2  1000
1450  1200
P2 =
1000

P2 = 1740mm
Final pressure of gaseous mixture according to Dalton’s law of partial pressure,

P = PN 2  Po2

= 657 + 1750
=2415mm
Question 11: Write balanced equations for-
(i) Dilute Hydrochloric acid is reacted to Sodium thiosulphate.
(ii) Silver nitrate solution is reacted with sodium thiosulphate.
(iii) Sodium thiosulphate is reacted to Iodine solution.
Solution 11:
(i) 2 HCl  Na2 S2O3  2 NaCl  S  SO2  H 2O
(ii) I 2  2 Na2 S2O3  2 NaI  Na2 S4O6
(iii) 2 AgNO3  Na2 S2O3  Ag 2 S2O3  2 NaNO3

Question 12: (i) What do you mean by heat of neutralization?

(ii) Write the criteria for the spontaneity in the terms of free energy change?
(iii) Among the gaseous and liquid substance, which have higher entropy.

10
Solution 12:
(a)
(i) Heat of neutralization: - Heat released in neutralization of 1 mole of acid or base.

Acid + Base 
 Salt + H2O

(ii) The criteria for spontaneity in terms of free energy change:-

 If  G is –ve, the process is spontaneous.

 If  G is +ve, the process is non - spontaneous.

 If  G = 0, the process is in equilibrium.

(iii)
1. Gaseous substances possesses higher entropy
(i) Dilute hydrochloric acid is added to sodium thiosulphate solution

N a2 S2 O3( a )q 2 HC l ( a q

)  N2a C l a( q ) 2 + H
O 2+ SO + S (s)

(ii) Silver Nitrate Solution is treated with sodium Thiosulphate solution.

2 Ag NO
3 + a2 S2 O3 
N  Ag
2 S 2O 3 + 2 Na3NO

(iii) Iodine Solution is treated with Sodium thiosulphate solution

2 N a2 S2 O3 + I2 
 N a2 S4 O6 + 2 Na I

Question 13: Answer the following questions:

(i) In Bhopal Gas Tragedy which gas leaked from the storage tank of the Union carbide Plant?
(ii) What do you mean by acid rain? What are the consequence of its formation?
(iii) What happen of ozone layer get depleted? Mention its two effects.
Solution 13:
(i) MIC (Methyl isocynate)
(ii) Acid rain is one of the consequences of air pollution. It occur when emissions from factories,
Cars or heating boilers contact with water in the atmosphere.
These emission contain nitrogen oxides, sulphur dioxide which when mixed with H2O become
sulphuric acid, nitric acid.
11
(iii) Two effects of ozone layer depletion are:-
 Damage to DNA and leads to mutation.
 Damage skin cells
 Snow blindness
 Cataract
Question 14:
(a) Explain the process of optical isomerism by taking the example of lactic acid.
(b) Why a compound of type aac=cab cannot show geometrical isomerism?
Solution 14:
(i) Optically isomerism of lactic acid:-
1. Presence of asymmetrical carbon atom.
2. Non-superimposable mirror image structure:-
COOH COOH
H C OH HO C H
CH3 CH3
D or (+) lactic acid l or (-) lactic acid
3. Racemic mixture and its optically inactive.
(ii) No, Compound aaC = Cab do not show geometrical isomerism because if one of two doubly
bonded carbon atoms carries two identical groups then the molecule doesn’t exhibits geometric
isomerism.
a a
C=C
a b
No geometric isomerism

12
Question 15: Give the molecular orbital configuration of nitrogen. Predicts its magnetic
behavior along with bond order.
Solution 15:

N2 (14) =  1s2  *1s2  2s2  *2s2 π2p2x = π2p2y  2p2z

Nb  N a
Bond order =
2

10  4 6
= = =3
2 2

Question 16:
(a) Give the balanced chemical equations of the following reactions by oxidation number
method.
(i)

1. Mn O4  Fe2  H  Mn 2  Fe3  H2O

2. Mn O4 + SnO22 + H2O 

 Mn O2 +SnO32 + HO

(ii) Find the oxidation number of underlined element in following compounds:

(1) NaS4O6
(2) K2Cr2O7
(3) K2MnO4
(4) Fe3O4
(b) (i) Give balanced chemical equations of the following reactions by oxidation number method:

1. Cu + HNO3   Cu ( NO3 ) 2 + e  + H 

n
oxyd

2. K2Cr2O7 + HCl 
 KCl + CrCl3 + H2O  Cl2

(ii) (a) Give reasons why HNO2 acts as oxidizing as well as reducing agent whereas HNO3 only
acts an oxidizing agent.
(b) Give reasons why Chlorine liberate iodine from the solution of potassium iodide.

13
Solution 16:
(a) (i)

Mn O4  Fe 2  H  
 Mn 2  Fe 3
8H  + 5e  + Mn O4   Mn 2  4 H 2O
n
red
1.
Fe 2   Fe3  e 
n
oxyd

Here, we get that Fe 2 get oxidised and become Fe3 And Mn O4 shows reduction to
Mn2+

Mn O4  Fe2  H 
 Mn 2  Fe3

8H  5e  + Mn O4   Mn 2 
n
red
+ 4 H 2O
Mn O4 + SnO 22 + H 2O 
 Mn O2 +SnO 32 + HO 
H 2O + SnO 22   SnO32  2e  + 2n 
n
oxyd

6e  + 2Mn O4 
 Mn O4 + 4 H 2O
3H 2O + 3SnO 22 
 3SnO32 +6e  + 6H 

F e2 o  F3e  

n
xyd
e

8H  5e  + Mn O4   Mn 2 
n
red
+ 4 H 2O

F e2 o  F3e  

n
xyd
e

5 F e2  
 5 F3 e  
5e

Mn O4 + 5Fe2  H  
 Mn 2
 5Fe  2
 4H2O

(2) Mn O4 + SnO22 + H2O 

 Mn O2 +SnO32 + HO

Here, we get that SnO22 get oxidised and become SnO32 And Mn O4 shows reduction to
Mn O2 .

3e  MOn4   2 n
n
red
+ OM H2 O2
14
 H 2O + SnO 22   SnO32  2e + 2n 
n
oxyd

3e  MOn4   2 n
n
red
+ OM H2 O2

H 2O + SnO 22   SnO32  2e + 2n 

n
oxyd

6e + 2Mn O4 

 Mn O4 + 4 H 2O
3H 2O + 3SnO22 
 3SnO32 +6e + 6H 

2MnO4 + 3SnO22 3H2O 

 Mn O4  3SnO32 +4H2O + 6H

(ii)
1. S in NaS4O6
2(1) + 4x +6(-2) = 07
4x = 0

10 5
x= =
4 2

2. Cr in K2Cr2O7
2(1) + 2x + 7 (-2) = 0
12
2x = =6
2

3. Mn in K2MnO4
2(1) +X + 4(-2) = 0
2 + x – 8 =0
x=6
4. Mn in K2MnO4
2(1) + x + 4(-2) = 0
2+x–8=0
x=6

15
5. Fe in Fe3O4
3x + 4(-2) = 0
3x = 8

8
x=
3

OR
(b)
(1)

Na2 S2O3 (aq )  2HCl(aq) 2 NaCl (aq) + H 2O + SO 2 + S (s)

2AgNO3 + Na2 S 2O3 
 Ag 2 S 2O3 + 2NaNO3
2 Na2 S2O3 + I 2 
 Na2 S 4O6 + 2NaI

Cu + 2HNO3   Cu ( NO3 ) 2 + 2e  + 2H 

n
oxyd

HNO3 + 3e  + 3H    NO 2  2H 2O
n
red

Cu + 2HNO3   Cu ( NO3 ) 2 + 2e    3

n
oxyd
 

 HNO3 + 3e  + 3H    NO 2  2H 2O   3
n
red
 
3Cu + 6HNO3   3Cu ( NO3 ) 2 + 6e 
n
oxyd

2HNO3 + 6e  + 6H    2NO 2  4H 2O

n
red

3Cu + 8HNO3 + 6H 

 3Cu( NO3 )2 + 2NO2  4H2O

(2)

K2Cr2O7 + HCl 
 KCl + CrCl3 + H2O  Cl2

Here, we get that K 2Cr2O7 get oxidised and become CrCl3 And HCl shows reduction to Cl2.

  Cl2 + 2e  + 2n 
n
oxyd
2HCl

K2Cr2O7 + 6e  4HCl 

 2CrCl3 + KCl
16
2HCl  Cl2 + 2e  + 2n    3


6HCl  6Cl2 + 62e  + 6n 



K2Cr2O7 + 6e  4HCl 

 2CrCl3 + KCl

 2CrCl3 + 6Cl2  KCl + 6H

K2Cr2O7 + 10HCl 

Question 17: (a) (i) Give reason why:

(1) The Boeyer’s reagent becomes colourless when it is treated with an alkene.
(2) Alkyne and alkenes do not form geometric isomeric compounds.
(iii)Give the conversion of following reactions:
(1) Methane from Sodium acetate.
(2) Butane from ethane.
(3) Toluene from benzene
OR
(b) (i) Identify the compound X and Y in following equations:

1. C6H5COONa + NaOH 

CaO
 X 
conc , HNO3
conc , H 2 SO4
Y

2. C2H6 
Br2
 X 
Alc.KOH

Y

(ii) Give the specific chemical test used to distinguish between the following pairs of
compounds:
1. Ethene and Ethyne
2. But -1- ene and but-2-ene

Solution 17:
17
(i)
1. The colour of baeyer’s reagent gets discharged when treated with an alkene because
Bayer’s reagent is oxidizing agent.

CH  CH  H O  O 
 C H  C H
2 2 2 | 2 | 2
OH OH
[Baeyer’s reagent in oxidised form is KmNO4]
2.Alkanes and alkynes do not show geometrical isomerism because in alkanes  - bonds can
rotate around and shift .This makes isomers of non-sustituted alkanes impossible beacause the
atoms can shift back and alkynes are linear and can’t have a substituted atom branching off
carbon can form no more than four bonds.
(ii) (1) Sodium acetate to methane

CH2COONa + NaOH + CaO 

 CH4 + Na2CO3

(2)Ethane to butane

CH3-CH2-Br Na
Dry ether
 CH3-CH2-CH2-CH3

(3)Benzene to toluene

??????? + CH3-Cl 

AlCl3
 ??????????

OR
(b) 1.

C6H5COONa + NaOH 

CaO
 C6H6 + NaCO3 
conc , HNO3
conc , H 2 SO4

(A) (B)
2.

C2H6 
Br2
 CH3-CH2-Br 
Alc. KOH

 CH2=CH2

(A) (B)

(ii) 1. Ethane is a saturated compound and don’t under halogenation reaction while ethyne being
unsaturated compound undergo halogenation reaction .
18
 CH3-CH3 + Br2 
 CH2-CH2

Br Br
2. Chemical test for differentiate:-
This step involves two steps:-
i. Ozonolysis
ii. Isoform test
 But-1-ene on ozonolysis gives propioaldehyde and formaldehyde
CH3-CH2-CH2=CH2 + 2[O] 
 CH3-CH2-CHO +HCHO

 on ozonolysis gives 2 molecule of acetaldehyde ,

CH3-CH2=CH-CH2 + 2[O] 
 2CH3CHO

 But-1-ene to isoform test do not give any colour.

 But-2-ene to isoform test gives yellow colour.
Question 18: (i) 20 moles of H2 in mixed with 15 mole of N2 in a vessel of 8 Libe and 5.6 moles
of ammonia is formed as result of chemical reaction of N2 and H2. Calculate the Ke for the
equation given below:
N2(g) + 3H2(g) 


 2NH3(g) + heat

(ii) Calculate the solubility of AgCl in 0.1mg of NaCl if the solubility product of Agcl is
1 10 10 at 25oC.

(b) (i) What is Le Chatelier’s Principle. State the conditions which are necessary to obtain
maximum yield of SO3 in the given reaction:

2SO2 ( g )  O2( g ) 2SO3 ( g ) ; H  42Kcal

(ii) When 5% of 0.01 m CH3COOH is dissociated in solution than find its pH value.
Solution 18:
(i) Given: - 15 moles of N2 is mixed with 20 moles of H2 in an 8 litre vessel.
5.6 ammonia is formed

N2(g) + 3H2(g) 


 2NH3(g) + heat

Initial 1mole 3mole 2mole

19
At equilibrium 15mole 20mole 5.6 mole

15 20 5.6
Concentration
Vol. Vol. Vol.

15 20 5.6
8 8 8

[ NH 3 ]2
Kc =
[ N 2 ][ H 2 ]3

 5.6 
 8 
= 3
15   20 
 8   3 

2007.04
=
120000

= 0.0167
(ii) Ksp of AgCl = 1  10-10
T = 25˚c

 Na+ +
NaCl 
 Cl-

Since they are showing common ion effect


 Ag+ +
AgCl 
 Cl-


 Ag+ +
AgCl 
 Cl-

S S
1  10-10 = [5] [5+0.1]
Since, Ksp of AgCl is very small as compared to 0.1M of NaCl that’s why ‘s’ will be
ignored.
10-10 = S  0.1

1010
=S
0.1
S = 10-9

20
 OR
(b) Le Chateleir’s principle
(i) If a system is subjected to a change of concentration, temperature and pressure at
equilibrium shift such a way which undo the effect of change:-

2SO2(g) + O2(g) 


 2SO3(g) ,  H= -42K cal

Conditions for obtaining the maximum yield of SO3 are:-

 By increasing temperature reaction shift towards the forward direction and yield
maximum.

 If either O2 or SO2 is added the reaction shift towards the forward direction.
(ii) CH3COOH 


 CH3COO- + H+

Initially 1mole 0 0

1 5
At equilibrium 1 0.05 0.05
100

= 1 - 0.05
=0.95
Ph = -log[H+]
= -log[5  10-2]
= -log5 + 2log10
=0.698+2
=2.69

21
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