Scribd
Upload
150 views10 pages

24.04.22 - SR - STAR CO-SC - Jee - Adv - 2019 - P1 - GTA-2 (P1) - KEY & SOL

1. The document provides a key sheet for a physics, chemistry, and mathematics exam containing multiple choice questions and numerical questions with solutions. 2. It includes the question numbers and correct answer options for physics, chemistry, and math questions. Short solutions are also provided for some of the physics questions. 3. The chemistry section provides more detailed step-by-step solutions for some questions involving concepts like chemical equilibrium, hydrolysis of phosphates, and calculation of freezing point depression constant.

Uploaded by

Gadde Gopala Krishna
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
150 views10 pages

24.04.22 - SR - STAR CO-SC - Jee - Adv - 2019 - P1 - GTA-2 (P1) - KEY & SOL

1. The document provides a key sheet for a physics, chemistry, and mathematics exam containing multiple choice questions and numerical questions with solutions. 2. It includes the question numbers and correct answer options for physics, chemistry, and math questions. Short solutions are also provided for some of the physics questions. 3. The chemistry section provides more detailed step-by-step solutions for some questions involving concepts like chemical equilibrium, hydrolysis of phosphates, and calculation of freezing point depression constant.

Uploaded by

Gadde Gopala Krishna
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 10

Sec: SR.

IIT_*CO-SC GTA-2(P1) Date: 24-04-22


Time: 3HRS 2019_P1 Max. Marks: 186
KEY SHEET
PHYSICS
1 C 2 B 3 D 4 A 5 ABD
6 AD 7 AD 8 BD 9 ABCD 10 AD
11 AB 12 ACD 13 9 14 6.82 15 1.10
16 3 17 0.6 18 5

CHEMISTRY
19 C 20 A 21 B 22 A 23 ABC

24 ABC 25 BCD 26 C 27 AB 28 AD

29 ABCD 30 ABD 31 6 32 2 33 9
12 to
34 35 6 36 5
13

MATHEMATICS
37 C 38 C 39 C 40 B 41 BC

42 ABD 43 BC 44 AB 45 BD 46 ABC
0.70 2.71
47 BD 48 AD 49 83 50 TO 51 TO
0.71 2.72
52 2 53 5 54 –3
Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
SOLUTIONS
PHYSICS
1.

2. B due to entire long solenoid   0 n


 n
B due to half solenoid  0
2
 M  M2 R
3. Td    Rd   2  R  T 
 2R  2
M R 2 2
L  
 yA  YA
 
 2R 
A 2h R 2 2  H  R 2 H
4. t  2   
a g r g  2  r2 g
5. As the photoelectrons get ejected, the conductor acquires positive potential and gradually increases
to stopping potential.
6.

7. Both move together


20  0.25  5 10
 a sys   1.5m / s 2
5
 f block  1.5N

SR.IIT_*CO-SC Page NO: 2


Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
8.

9.

10.

11.

SR.IIT_*CO-SC Page NO: 3


Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
12.

13.

14.

15.

SR.IIT_*CO-SC Page NO: 4


Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
16. T = 2T
T0
aA  aB  g
17.

18.

SR.IIT_*CO-SC Page NO: 5


Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
CHEMISTRY
+4
18. Pb is oxidising and I- is reducing agent.
19. Trans 1,2-dimethylcyclohexane.
21. At equilibrium
R1  OH  CH 3COOH  CH 3COOR1  H 2O  KC1 
1 x 1 x  y x  x y 
R2  OH  CH 3COOH  CH 3COOR2  H 2O  KC2 
1 y 1 x  y y  x y 
x 3
 x  y  0.8
y 2
3y
2x  3y  y  0.8
2
y  0.32
x  0.48
x. x  y  0.48  0.8
K C1    3.69
1  x 1  x  y  0.52  0.2
3
22. Hydrolysis of PO 4 will take place
 k 
PO 43  H 2O  HPO 42  OH   k h1  w 
 x  y z 
 c x   xy  k3 
 k 
HPO 42  H 2O  H 2 PO 4  OH   k h 2  w 
 x  y z 
 xy  yz   k2 
 k 
HPO 4  H 2O  H 3PO 4  OH   k h3  w 
 x  y z 
 yz  z  k1 
 OH    x  y  z
 OH    x
x  y  z

k h1 
 x  y  z  x  y 
c  x 
kw x.x.

k3 c  x 
x2
2.2  102 
 0.1  x 
on solving x  3.73  102 molar
23. The given ionic radius order is correct.
24. Conceptual
25. No vacant orbitals for boron.
26. Conceptual
27. Acylsubstitution followed by decomposition of azide into isocyanate.
28. Cu and Pb
29. Conceptual

SR.IIT_*CO-SC Page NO: 6


Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
1 2
30. A) mv  q.V
2
v  4  106 m/sec
2 KZe 2
B) v
nh
v  4.38  106 m/sec
h
C) 
mv
v  1.09  106 m/sec
hc  c
D)  K.E max  
 0
1
 K.E max  mv 2
2
v  1.55  106 m/sec
31. Octahedral structure
32. Two lone pairs and four bond pairs.
33. Conceptual
RTf2 M
34. Kf 
H fusion
8.314   273  18
2

Kf 
1000  6  103
 K f  1.86K. Kg mol-1
Now Tf  K f  m
T  273  271
m  f   1.07 moles/Kg
Kf 1.86
moles of solutes
But m 
weight of solvent (in Kg)
 0.9  18  2
moles of solute  1.07     1.74  10
 1000 
760  700
Also X solute   0.079
760
mole of solute
X solute 
total moles
1.74  102
 Total moles   0.22
0.079
Moles of solvent  H 2 O   0.2026
 Mass of ice separated out   0.9  0.2026   18  12.55 gm
1 1 8RT P
35. Z  u aV  N*    Constant
4 4 M kT
SR.IIT_*CO-SC Page NO: 7
Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
P
or,  Constant  P  V 1  Constant
T
R 5 R
 C m  C V1m   R  3R
1 x 2 1   1
 6 cal/K mol
36. 2NH 3  g   N 2  g   3H 2  g 
3 0 0-initially
3  2x  x 3x -after time  t 
1 d  NH 3 
Rate of Reaction    0.1
2 dt
 d  NH 3 
  0.2  k
dt
For Zero Order Reaction P  P 0  Kt
3  2 x  3  0.2 10
3  2x  1
x 1
Ptotal   3  2x 
 5 atm

MATHS
37. Matrix A can be formed in 6 ways
Matrix A can be formed in 8 ways
So, A and B both can be formed in 48 ways
In only 4 of these combination A  B possible.
4 1
 Required probability  
48 12
38. 2 xy 4 e y dx  x 2 y 4 e y dy  2 xy 3d  x 2 y 2 dy  ydx  3dy  0
2 xy 3dx  x 2 y 2 dy y 3dx  3xy 2 dy

Divide whole equation with y 4 , d x 2 e y   y4

y6
0

 x2   x 
d  x 2e y   d    d  3   0
 y y 
41.

Area of parallelogram ACBD is least


= Area of ABC is least
In ABC , h  2 when base is AC

SR.IIT_*CO-SC Page NO: 8


Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
Ac = 2  cot   tan   is least when   45 0

42. Conceptual
43. Conceptual
44. Conceptual
45. a) Lt g  f  x  Lt g  x  does not exists
x1 x0
b) Lt g  f  g  x   Lt g  f  x   Lt g  x   0
 x 0 x 2
x
2
f  g  x 
c) Lt 0
x 2 f  x  2
g 2  x 1  cos x 1
d) Lt 2
 Lt 
x 0  2  x  2 x O x2 2
1
 2
3
46. tan   2 
1 2 4

1 20
 PC  PB sin   2  BD 
2 3
Which rule APB
2
AB  58
3
dPB which rule
2
BC  10
3
47. Conceptual
49.  ,  2 are the roots of the equation  2  px  1  0
 2  1   i 
Again  2 ,  are the roots of the equation  2  px  1  0
 2   8   ii 
From (i) and (ii)
 3  3  8    2   iii 
1
From (i) and (iii) 
2
From (ii) and (iii)  4
1 17
Now p     2  4  
4 4
1 33
q   2    16  
2 2
r
 is A.M of p and q
8
r pq  17 33 
  r  4     83
8 2  4 2 

SR.IIT_*CO-SC Page NO: 9


Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL

50.  a.x  0   i 
   
 
Again x  b x  a   ii 
      
 
 x a  b a  x a  a
       
   
 x  a  b  a  x.a a  a.a .x
   
 x  b  b  a  x [from (ii) and (i)
   
 2x  b  b  a
 1
x 
2
51. Conceptual
z2  z  1
52. z
z2  z  1
z2  1 z  1
   z  1
2 z 2 z  1 
1
 z  must be purely real
z
 e i  
 In  rei   0
 r 
sin 
 r sin    0    0 as r  1
r
x2  x 1
 2  x  for x  0 1 solution
x  x 1
for x < 0 no solution
sin 60 sin 60
53. tan12  tan 48  tan 84  tan120  tan156    tan120
cos12 cos 48 cos 24 cos 84
2sin 60 2sin 60
   35 3
cos 60  cos 36 cos108  cos 60
 x
1 cos 2sin 2 
 4
54. Lt 1
x0 2m x n
4sin 4 x 4
Lt 2
x0 2m x n
2
 n  4, 8m
 1  m  7
2
 m  n  3

SR.IIT_*CO-SC Page NO: 10

You might also like