Material Safety Data Sheet
Revision Date: 02/14/2008 Issue date: 02/14/2008
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Kit Number: AS9174000
Product name: HYSOL EA 934NA PART B 8 OZ Item No. : AB9174014 / IDH No. 936945
Product type: Adhesive for the Aerospace Industry Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 925.458.8000 Fax : 925.458.8030.
2850 Willow Pass Road Emergency Telephone: 860.571.5100.
Bay Point, California 94565 Internet www.aerospace.henkel.us
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Amine adduct 60-100 None None None
68082-29-1
Diethylene triamine 10-30 1 ppm TWA None None
111-40-0 (skin)
Triethylenetetramine 1-5 None None 1 ppm, skin TWA, (WEEL)
112-24-3
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: 2
Color: Amber FLAMMABILITY: 1
Odor: Ammoniacal PHYSICAL HAZARD: 1
Personal Protection: See Section 8
WARNING: CAUSES EYE AND SKIN BURNS.
CAUSES RESPIRATORY TRACT IRRITATION.
Relevant routes of exposure: Skin, Inhalation, Eyes
Potential Health Effects
Inhalation: Vapors and mists will irritate nose and throat and possibly eyes.
Skin contact: This material is corrosive to eyes and skin. Brief contact may cause chemical burns. Repeated or
prolonged skin contact may result in allergic sensitization.
Eye contact: Severe eye irritation.
Ingestion: Not expected under normal conditions of use.
Existing conditions aggravated by Determining whether product ingredients will aggravate a pre-existing medical condition requires case-
exposure: by-case consideration of the exposed workers` medical condition and the nature of the exposures
expected to occur in the specific workplace where the worker will be employed.
See Section 11 for additional toxicological information.
Item No. : AB9174014 / IDH No. 936945 Product name: HYSOL EA 934NA PART B 8 OZ
1 of 5
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If discomfort persists seek medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Get medical attention if symptoms occur.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion: Drink water as a precaution. Get medical attention immediately.
Notes to physician: Treat symptomatically and supportively.
5. FIRE-FIGHTING MEASURES
Flash point: Decomposes before flashing.
Autoignition temperature: Not determined
Flammable/Explosive limits-lower %: Not determined
Flammable/Explosive limits-upper %: Not determined
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Cartridge
respirators do not provide adequate protection for fire fighters or exotherm mitigation.
Unusual fire or explosion hazards: May liberate large quantities of dense, foul-smelling smoke which may contain unidentified toxic
gasses.
Hazardous combustion products: Oxides of carbon and nitrogen, aldehydes, acids and undetermined organics.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: No information available
Clean-up methods: Wear protective clothing, gloves and safety glasses. Soak up with inert absorbent. Store in a closed
container until ready for disposal.
7. HANDLING AND STORAGE
Handling: For the Part A plus Part B adhesive mixture, follow curing schedule as recommended in product
literature. Do not heat Part B at temperatures greater than 100 ºC (212 ºF). This material may self-
react at higher temperatures and cause an exotherm. The exotherm has the potential for release of
excessive energy and toxic gasses. Empty containers retain product residue, so obey hazard
warnings and handle empty containers as if they were full. Do not cut, grind, weld, or drill on or near
this container.
Storage: For safe storage, store at or below 25°C (77°F). Keep container closed.
Incompatible products: Keep away from strong oxidizing agents, strong Lewis or mineral acids.
For information on product shelf life, please review labels on container or check the Technical Data Sheet.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Work should be done in an adequately ventilated area (i.e., ventilation sufficient to maintain
concentrations below one half of the PEL and other relevant standards). Local exhaust ventilation is
recommended when general ventilation is not sufficient to control airborne contamination.
Respiratory protection: When workplace hazards warrant the use of a respirator, appropriate respirators must be used, and a
program that follows 29 CFR 1910.134 must be followed.
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to
prevent skin contact.
Item No. : AB9174014 / IDH No. 936945 Product name: HYSOL EA 934NA PART B 8 OZ
2 of 5
Eye/face protection: Wear appropriate goggles, face shields or other PPE which will be effective under the circumstances if
the possibility of contact exists. A program meeting 29 CFR 1910.133 requirements must be followed
when PPE is necessary.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Amber
Odor: Ammoniacal
Vapor pressure: Less than 1 mm Hg at 20ºC (68ºF)
pH: Not determined
Boiling point/range: 207°C (405°F)
Melting point/range: Not determined
Specific gravity: 0.96
Vapor density: Not determined
Evaporation rate: Not determined
Solubility in water: Completely soluble
Partition coefficient (n-octanol/water): Not determined
VOC content: <10 g/l (estimate) per SCAQMD Rule 1124 [EPA Test Method 24/304-91]
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: May occur.
Hazardous decomposition products: Oxides of carbon and nitrogen, aldehydes, acids and undetermined organics.
Incompatability: Keep away from strong oxidizing agents, strong Lewis or mineral acids.
Conditions to avoid: Avoid mixing resin (Part A) and curing agent (Part B) in batches greater than 1 pound(s) (.454 kg)
unless you plan to use immediately. Do not heat mixed adhesive above 52ºC (125ºF) unless curing
surfaces to be bonded. Failure to observe these precautions may result in excessive heat build-up
causing an exotherm. The exotherm has the potential for release of toxic gasses.
11. TOXICOLOGICAL INFORMATION
Product toxicity data: Loctite is not aware of any toxicity data on the specific mixture of chemical components contained in
this product.
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Amine adduct No No No
68082-29-1
Diethylene triamine No No No
111-40-0
Triethylenetetramine No No No
112-24-3
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Amine adduct No Records
68082-29-1
Diethylene triamine Allergen, Eyes, Irritant
111-40-0
Triethylenetetramine Allergen, Developmental, Irritant, Mutagen, Corrosive
112-24-3
12. ECOLOGICAL INFORMATION
Item No. : AB9174014 / IDH No. 936945 Product name: HYSOL EA 934NA PART B 8 OZ
3 of 5
Ecological information: No specific studies have been conducted by Henkel on the ecotoxicity or environmental fate of this
material; however, commonly available data on the material indicate that uncontrolled releases to soil,
groundwater, or surface waters could entail acute and/or chronic ecological effects, depending on the
quantity and concentration of such releases. Releases of volatile components to the atmosphere are
not believed to entail significant ecological consequences provided such releases are within the
exposure levels set forth in this document. Accordingly, all appropriate measures should be taken to
avoid uncontrolled releases to the environment, and any spills or other uncontrolled releases which
may occur should be contained and cleaned up immediately in accordance with Section 6.
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Legal disposition of wastes is the responsibility of the owner/generator of the waste. Applicable
federal, state and/or local regulations must be followed during treatment, storage, or disposal of waste
containing this product.
EPA hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Amines, liquid, corrosive, n.o.s. ( Diethylenetriamine / Triethylenetetramine )
Hazard class or division: 8
Identification number: UN 2735
Packing group: II
Marine pollutant: None
International Air Transportation (ICAO/IATA):
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. ( Diethylenetriamine / Triethylenetetramine )
Hazard class or division: 8
Identification number: UN 2735
Packing group: II
WaterTransportation (IMO/IMDG):
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. ( Diethylenetriamine / Triethylenetetramine )
Hazard class or division: 8
Identification number: UN 2735
Packing group: II
Marine pollutant: None
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None.
CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard
CERCLA/SARA 313: None.
California Proposition 65: No California Proposition 65 listed chemicals are known to be present.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: D.2.A, D.2.B, E
Item No. : AB9174014 / IDH No. 936945 Product name: HYSOL EA 934NA PART B 8 OZ
4 of 5
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 2, 11, 15
Prepared by: Environment, Health & Safety Department - Bay Point, CA
For Safety and Regulatory Information contact:
Product Safety and Regulatory Affairs,
Rocky Hill, CT.
860-571-5204
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from
sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
Item No. : AB9174014 / IDH No. 936945 Product name: HYSOL EA 934NA PART B 8 OZ
5 of 5
