SAFETY DATA SHEET
Revision Date 17-Apr-2018 Version 8
1. IDENTIFICATION
Product identifier
Product Name Spray Nine Grez-Off® 1 gal
Other means of identification
Product Code 22701
Recommended use of the chemical and restrictions on use
Recommended Use Degreaser - General Purpose - Non-Aerosol.
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufacturer Address May Also Be Distributed by:
ITW Permatex ITW Permatex Canada
6875 Parkland Blvd. 101-2360 Bristol Circle
Solon, OH 44139 USA Oakville, ON Canada L6H 6M5
Telephone: (800) 924-6994
24-hour emergency phone number Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 2A
Serious eye damage/eye irritation Category 2A
Label elements
Emergency Overview
Signal word
Warning
Causes skin irritation
Causes serious eye irritation
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22701 - Spray Nine Grez-Off® 1 gal Revision Date 17-Apr-2018
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Appearance Orange Physical state Liquid Odor Citrus
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
- Not applicable
Unknown acute toxicity 1.4708 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance(s)
Chemical Name CAS No Weight-%
SODIUM METASILICATE 6834-92-0 1-5
Any concentration shown as a range is due to batch variation.
4. FIRST AID MEASURES
Description of first aid measures
General advice Get medical advice/attention if you feel unwell.
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician.
Take off contaminated clothing and wash before reuse.
Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Self-protection of the first aider Use personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
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Symptoms See section 2 for more information.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None.
Specific hazards arising from the chemical
None in particular.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel
into suitable containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep from freezing.
Incompatible materials Strong oxidizing agents
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
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Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wearpr
otect
i
venat
uralr
ubber
,ni
t
ril
erubber
,Neopr
ene™ orPVCgl
oves.
Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Liquid
Appearance Orange
Odor Citrus
Odor threshold No information available
Property Values Remar
ks •Met
hod
pH 8-11
Melting point / freezing point No information available
Boiling point / boiling range 100 °C / 212 °F
Flash point > 93 °C / > 200 °F Tag Closed Cup
Evaporation rate < 1 Butyl acetate = 1
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure 18 mm Hg
Vapor density >1 Air = 1
Relative density ~1.013 g/ml
Water solubility Soluble in water
Solubility in other solvents No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available
Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) <1%
Density No information available
Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity
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Stable under normal conditions
Chemical stability
Stable under recommended storage conditions
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Keep from freezing.
Incompatible materials
Strong oxidizing agents
Hazardous Decomposition Products
Carbon oxides
Nitrogen oxides (NOx)
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation May cause irritation of respiratory tract.
Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
Skin contact May cause skin irritation and/or dermatitis.
Ingestion Ingestion may cause irritation to mucous membranes.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
SODIUM METASILICATE = 1153 mg/kg ( Rat ) - -
6834-92-0
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 17322 mg/kg
ATEmix (dermal) 75518 mg/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity
3.2241 % of the mixture consists of component(s) of unknown hazards to the aquatic environment
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
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Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Do not reuse container.
US EPA Waste Number Not applicable
14. TRANSPORT INFORMATION
DOT
Proper shipping name: Not regulated
IATA
Proper shipping name: Not regulated
IMDG
Proper shipping name: Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Not determined
ENCS Not determined
IECSC Complies
KECL Complies
PICCS Not determined
AICS Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard No
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Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not intentionally contain any chemicals known by the State of California to cause cancer and/or birth defects
U.S. State Right-to-Know Regulations
U.S. EPA Label Information
EPA Pesticide Registration Number Not applicable
WHMIS Hazard Class
D2B - Toxic materials
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 1 Flammability 1 Instability 0 -
HMIS Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date 17-Apr-2018
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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