Chemistry Basics for Students
Chemistry Basics for Students
Let's Map It
Can beseparated into
Can be broken down into elements
its components
or
simpler compounds by chemical
processes (e.g. electrolysis) Have similar chemical
properties as the
Have different
properties from the components
elements that form it
Cannot be broken down Are formed with little
Are formed with an
energy change or no energy change
Have a fixed into simpler substances by
composition chemical processes Have variable compositions
general
general general
properties U properties properties
Atoms
chemically
Combine to form
Metals Non-metals
Molecules
Let's Review
Section A: Multiple-choice Questions 6 When a green solid X is heated, it forms a black solid
What is the total number of atoms present in one unit and a gas.Therefore, X
of chromium(l) suliate, Cr(SO,),? A does not contain a metal.
A B is a compound made up of at least two elements.
Let'sReview
Section B:
Short-answer and Structured (d) Urea is a mixture of elements. [11
Questions
1 Look at
(e)The molecule contains carbon monoxide. [1
Figure 2.16. f) Urea has the formula CO(NH). [11
4 Three students looking at a colourless substance
are
Figure 2.17
Which substance, R, S, Tand U, is most lik to be
Determine which statements are true and which are (a) a noble gas: (1
false. Correct the false statements. (b) carbon;01
(a) The molecule contains four elements. [ (c)acompound? [1]
(b) There are eight atoms in the molecule. [1]
(c) One of the elements present in the molecule is sodium. [
3 Atomic Structure
C CHEM WATCH
iodine-131.
Discuss.
(?)QUESTIONS
Suggest why there are no auroras on
The picture shows an aurora in Iceland. Auroras are coloured lights seen the Moon.
in the night sky at areas near the North and South poles. Scientists have Why is there more blue light than
green-yellow or red light in the auroras?
discovered that auroras occur due to tiny particles in an atom called
Do you think all electrons in an atom have
electrons! The Sun emits charged particles that contain a large amount of
the same energy level? Explain.
energy. When these particles collide with nitrogen and oxygen gas in the
Earth's atmosphere, they transfer energy to the electrons of the nitrogen
and oxygen atoms. Soon after, the electrons release the absorbed energy
as light. The green-yellow or red light is due to the emission from oxygen,
while the blue light is due to the emission from nitrogen. In which part of
the atom are electrons found?
33
Chapter 3
A proton
has a relative charge of +1;
has a relative mass of 1;
Ihe protons and neutrons
is represented by the symbol p.
are tightly packed
together in the centre of
A neutron
CHEM WATCH has a relative charge of 0;
an atom;
together form the
has a relative mass of 1;
Scan this page to watch nucleus of the atorn
is represented by the symbol n.
a clip on on the size of
atoms.
An electron
What can you conclude?
has a relative
charge of -1; Theelectrons move fapidly
Figure 3.1Structure of an has a relative mass of
atom (The relative sizes of around the nucleus.
1840
the particles are not drawn is represented by the symbol e.
to scale.)
HELPFULNOTES
Imagine placing a pea in
the middle of the field in
an empty stadium. The
pea represents the nucleus
of an atom. Ihe stadium
represents the space
where electrons are found.
34 Atomic Structure
Chapter3
3.2 The Proton Number and Nucleon
Number
In this section, you will learn the following:
Define proton number and atomic number.
Define mass number and nucleon number.
Interpret and use symbols for atoms and ions.
ENRICHMENT
THINK
Figure 32 shows the atomic structures of helium, lithium and beryllium atoms. Use the Internet to
search for Rutherford's
experiment on the
discovery of the proton
Helium (He) Lithium (Li) Beryllium (Be) If Rutherford had used
lithium instead of qold,
would he have discovered
the proton
Key:
o electron
neutron
proton
The number of electrons in an atom is the same as the number of protons. Therefore,
the negative charges cancel out the positive charges;
an atom is electrically neutral.
Proton number
The proton number of an atom is the number of protons in the nucleus of an atom. wORD ALERT
Atomic Structure 35
Chapter 3
numbers
Diferent elements have different proton atoms with this
This means that other no elerment nas
a n elenment has a unique proton number.
proton
numbers (igure 33)
have different
O O n nurmber. For example, carbon and oxygen
Oxygen (0)
Carbon (C)
nucleus
nucleus
neutron
neutron
proton
proton
Some elements can exist in different forms. For instance, graphite and diamonds appear very
different, but they are made up of carbon atoms with the pr:on number 6 (Figure 34).
Nucleon number
ryeor fatsr The nucleon number of an atom is the total number of protons and neutrons in the nucleus of
an atom.
The nucleon number is represented by the symbol A. The nucleon number is also called the mass
number. This is because the mass of an atom depends on the numbers of protons and neutrons in
the atom's nucleus. The mass of electrons in the atom is said to be
negligible.
Nucleon number (A) number of protons+ number
=
of neutrons
26 Atomic Structure
Chapter 3
Figure 3.5 General symbol for an atom, with nucleon and proton numbers
Fr exampie a sodium atom has 12 neutrons and 11 protons.Thus, sodium can be represented by Na.
comvenience, it is sometimes represented using onlythe nucleon number, sodium-23 or Na.
Worked Example3A
Deduce the numbers of protons, neutrons and electrons in an atom of uranium-235 (U).
Solution
Number of protons = proton number (Z) = 92
= 143
(a) Deduce
(i) the number of electrons in an atom of Y;
(ii) the nucleon number of Y.
the proton and nucleon numbers.
(b) Represent Y by writing the chemical symbol, including
TWB LINK
Atomic Structure 37
Chapter 3
ElectronsinAtoms
Arrangement of
5.3 learn the following:
Inthis section, you will numbersI to 20
the electronicconfiquration of
elements with proton
Letermine full outer shel. to VI.
State that Group Vll noble gases haveelectrons
a
is equal to the group
number in GroupsI
outer shell
dte that the number of
number.
HELPFUL NOTES
First shell
The layers of an onion is closest to the nucleus;
level;
can be a simple model corresponds to the lowest energy
of how electrons occupy can hold a maximum of
two electrons;
first.
the space surrounding is always filled
the nucleus. Imagine that
electrons exist in layers
around the nucleus. There Second and third shells
are a hixed number of have increasing energy levels (e.g. the third
electrons in each layer shell has higher energy th the second shel);
and each electron can usually hold up to eio ons each;
move only within its layer. are filled in order Lnesecond shell is
fully filled before th shell.
38 Atomic Structure
Chapter 3
atomicsymbol
element- Hydrogen (H) |
proton number Period
VIll number
arrangement of electrons
Helium (He)
electronicconfiguration 2
Group
number
V 2
Lithium (Li) Beryllium (Be) Boron (B) Carbon (C) Nitrogen (N) Oxygen (0 Fluorine (F) Neon (Ne)
9 10
6
(
2,1 2, 2 2,3 2,4 2,5 2, 6 2, 7 2,8
Silicon (Si) Phosphorus (P) Sulfur (S) Chlorine (CI) Argon (Ar)
Sodium (Na) Magnesium
12
(Mg) Aluminium
13
(A) 14 15 16 17 18
2,8,8,1 2, 8,8, 2
relative sizes
Figure 3.9 The arrangement ofelectrons in elements with proton numbers 20. (The
I to
of atoms are not drawn to scale.)
LINK
Atomic Structure 39
Chapter 3
O T e that elements that have the same number of outer shell electrons are in the same grour
QUICK CHECK e
up.
chemial properties of an element depend on the number of outer shell electrons. Thus,the
An eenis im the same group have similar chemical properties. For example, sodium (2, 8, 1) and
eloment with tha
POsSum ,8,8,) have similar chemical have one outer shell
eletroni niGnation
o has tw
because
properties they each electo
hlls nd
aupid
thre eler
in ioute shell. tions
rue talse?
LINK
Worked Example 3B
17X 9Y, and Z are three elements in the Periodic Ta
HELPFUL NOTES (a) What is the order of these elements in the
Perioc Teason for your answer.
(b) i)Which element is a noble gas?
To find out which period (i) Which element is in period 4? Explainn your answer
and group an element
Deiongs to, write Solution
down the electronic
confguration of the (a) X, Z,Y
element. The number of (b) ) Z
outer shell electrons will Y
tell you the group, while
the number of shells will
tell you the period.
Atomic Structure
40
Chapter 3
3.4 Isotopes
In this section, you will learn the following:
Define isotopes.
State that isotopes of the same element have the same chemical properties and electronic
configuration.
9 Calculate the relative atomic mass ofan element from the relative masses and abundances
of its isotopes.
Look at the models of hvdrogen atoms shown in Figure 3.10.What is the same or different about them?
ENRICHMENT
INFO
Key:
Uses of Isotopes
Oelectron
Isotopes have many uses:
neutron lodine-131 is used
in the treatrment of
proton thyroid disorder.
Carbon-14 is used to
estimate the age of
things that contain
carbon.
.Uranium-238 is used
to estimate the age of
rocks.
Contains Contains Contains
They have the
same number of
1 proton 1 proton 1 proton
protons.
2 neutrons
They have
O neutron 1 neutron different numbers
of neutrons.
Figure 3.10 Hydrogen atoms AA smoke
detector contains
americium-241,
which emits
radiation. Smoke
These hydrogen atoms are known as isotopes. entering the snoke
detector absorbs this
have the number of protons but
Isotopes are different atoms of the same element that same
radiation. This sets
different numbers of neutrons. off an alarrm in the
element have the same number of protons. Thus, isotopes have the same smoke detector.
Isotopes of the same
numbers.
proton number but different nucleon
Atomic Structure 41
Chapter 3 chlorine consists of two
example,
naturally as a mixture
of isotopes. For however, do not have isotopes
elements occur
OSt chlorine-37 (Fiqure 3.1).
A few elements,
Sotopes: chlorine-35 and contain five neutrons
and four protons.
rO example, all atoms of beryllium
17e
17e
17p 17p
20n
18n
As we saw in Figure 3.5 on page 37, we can represent atoms and ions u' ir: ,these
ENRICHMENT isotopes can be represented as l and yCl. Chloride isotope ions ale t and
THINK
Fluoride, the ion of the
element fluorine, is
added to our tap water Properties of isotopes
for dental health. All
fluorine atoms contain
Isotopes have the same chemical properties because they have the same electronic configuration.
ten neutrons. How many
However, they have slightly different physical properties (Figure 3.12).
ISotopes of tiuorine are
there in tap water?
Isotopes
have
Example Example
.Both chlorine-35 and chlorine-37
Hydrogen-2 has a slightly
react with sodium to produce
sodium chloride.
higher boiling point and
density than hydrogen- 1.
Atomic Structure
42
Chapter 3
Calculating the relative atomic masses of
QUicK CHECx
an element
boron e\IStS IS [W
Look at the Periodic Table at the front of the book. Did you notice that the relative atomic masses ISutopes A SamOie
(the numbers below the names of the elements) of some elements are not whole numbers? boron ha SOo of
These elements exist as mixtures of isotopes. The relative atomic masses of these elements are and20o
The reltive J t o i Im
calculated basedon the relative
percentages of the isotopes. Of boron1Is l0
For example, chlorine exists as chlorine-35 and chlorine-37. A typical sample of chlorine has 75o ot Iue or fale
chlorine-35 and 25% of chlorine-37 atoms.
o0
Hence, the relative atomic mass =
7535)* 100
of chlorine (100 x35) ( x37
= 2625 +9.25
= 35.5
Worked Example 3C
Bromine has two types of
atoms: Br and Br
(a) What is the difference between the two atoms?
(b) F,7Cl and Br are in the same group of the Periodic Table Using Figure 39 onpage 9
deduce the number of outer shell electrons an atorn ot brornine has ( ENRICHMENT
THINK
Solution look up Dalton's Atornic
(a) They have different numbers of neutrons. Br Theory How did the
atorms have 44 neutrons but Br atorn, have discoveryof subatornic
46 neutrons. Br and Br are two isotopes of bromine
particles and isotopes
(b) Seven affect Dalton's theories?
Let's Practise3.4
1 Complete the table for carbon-12 and carbon-14
Per atom
Isotope
Nucleon number
Atomic number
Number of protons
Number of neutrons
Number of electrons
Electronic configuration
2 (a) What are the symbols for the three isotopes of magnesium- magnesium-24;
magnesium-25 and magnesium-26?
(b) How are these three isotopes similar?
LINK
3 Bromine exists as two isotopes. A typical sample of bromine contains 50% ofBr and S0
of Br.What is the relative atomic mass of naturally oCCurring bromine? Exercses
Mind Map Construct your own mind map for the concepts that you have learnt in this section
Eerse8eslere
Atomic Structure 43
Chapter 3
Let's Maplt
ATOMS
consist of consist ot
subatomic subatomic
particles in particles n
dby
are Called
9Same chemlcal propertles
Different physlcal propertles
Atomic Structure
44
Let's Review
Section A: Multiple-choice Questions 8 Which diagram shows the arrangement of
1 His a/an electrons in oxygen (proton number 8)?
A atomn
B molecule
C neutron
D proton
2 Which atom has the largest number of neutrons?
A D
A H
3 He 9 Thallium-204 is used in the manufacturing industry to
C He regulate the thickness of paper. How many protons
D Li neutrons and electrons are there in an atom of
thallium-204?
3 Which statement about X and Y is false?
A They Number of Number of Number of
are isotopes. protons neutronsS electrons
B They are the same element.
31 123 81
C They have the same number of electrons.
B1 204 81
D They have the same number of neutrons.
123 123 123
4 Which atom has more protons than neutrons? 123 204 81
A C
B H
10 Table 31 shows the structures of five atoms.
C He Table 3.1
D $Li
Atom Number of Number of Number of
5 What is the number obtained when the proton number electrons neutrons protons
is subtracted from the nucleon number?
A Number of neutrons in the nucleus 6
Which symbol correctly represents X? 11 A naturally occurring sample of neon gas has two
A X B X isotopesNe and 7Ne. 90% of the sample is "Ne. What
is the relative atomic mass of naturally ocCurring neon?
C X D X
A 55
7 Which element is not found in the same period in the B 20.0
Periodic Table as the others? C 202
AO B F D 218
C Ne D Na
Atomic Structure 45
Chapter 3
Let's Review
Section B:
Short-answer and Structured (b) Figure 3.15 shows the nucleus from an atom of another
Questions element.
Table 3.2 shows the
atomic and mass numbers of some 8p
elements. 8n
Table 3.2
Figure 3.15
Element Atomic number Mass number
Carbon (i) Complete the diagram to show the electronic
6
12
Fluorine arrangement of this atom. [2
9
19 (ii) Write the electronic contiguration of the element. [|
Chlorine 17
35.5
5 One
Iron
26 s6
ofthe isotopes of nitrogen is N
(a) How many protons, neutrons and electrons are there
(a) How many protons are there in an in an atom of N? [1]
atom of fluorine?
(6) How many neutrons are there in an atom of [ (b) What is the electronic c
iron? [0 N [
(c) Which element has the same number of (c) State the symbol of an t'ogen that has
and protons
neutrons in an atom? [ one less neutron tha
(d) Explain why the mass number of chlorine is nota whole
6 (a) Complete the tabie.
number. [2]
Type of atom 09
47 Ag
2 Table 3.3 shows some information on element P Relative percentage pre
Table 3.3
Protons in one atom
19 R 20 T
(b) What is the narme given to represent these two types of
silver atoms? [1]
(a) ldentify element P. []
7 Two isotopes of lithium are
(b) What are the values of R, S and T? B] Li and ,Li.
An element E has the electronic configuration 2, 8, 8, 2.
(a) State two ways in which these isotopes are similar. |21
3
(b) State one way in which the isotopes differ. [21
It has a nucleon number of 40.
8 Deuterium, an isotope of hydrogen, is represented in
(a) State the group which E belongs to in the Periodic Table. [1]
Table. [ symbolsas D. Another isotope of hydrogen is tritiun (I)
(b) State the period which E belongs to in the Periodic (a) (i) Tritium has two neutrons. Write the ymtl
How many protons are there in an atom of E? [
(c)) for an atom of tritium, as has teen vrtttr
How many neutrons are there in an atom of E? [11
(ii) deuterium. [1]
an electron, 'n'a neutron and
4 In Figure 3.14, e' represents (ii) Write the formula of the compaund forrm d
p'a proton. between tritium and oxygen. (1
(b) Give the number of
(i) electrons in HD; [1]
(ii) protons in D; [1]
(ii) neutrons in DT. [1]
9 SCopper occurs naturally as two isotopes69.14
Figure 3.14
ofCu and 30.9% of Cu.What is the relative atomi
mass of copper, correct to one decimal place? [2
an atom of helium.
(a) Figure 3.14 shows
is the proton
number of the atom? [1]
(i) What
is its mass number? []
(ii) What
Atomic Structure
46