A New Technique For Simultaneous Water and Energy Minimisation in Process Plant
A New Technique For Simultaneous Water and Energy Minimisation in Process Plant
Zainuddin Abdul Manan ∗ , Swee Yin Tea, Sharifah Rafidah Wan Alwi
Process Systems Engineering Centre, Faculty of Chemical and Natural Resources Engineering, Univesiti Teknologi Malaysia, 81310 UTM
Skudai, Johor, Malaysia
a b s t r a c t
This paper presents a new technique for simultaneous minimisation of water and energy in process plants through
a combination of numerical and graphical tools. The technique consists of three steps, namely, setting the minimum
water and wastewater targets; design of minimum water utilisation network, and finally, heat recovery network
design. This technique offers two key advantages over current state-of-the art techniques. Firstly, it is applicable to
mass transfer based and non-mass transfer based water-using operations. Secondly, it introduces a new graphical
visualisation tool through a plot of temperature versus stream flowrate, termed as heat surplus diagram to guide
water and energy reduction simultaneously. The heat surplus diagram provide insights on the energy demand as
well as on stream matching scenarios during design of a maximum water and energy recovery network. A case study
on a paper mill plant demonstrates that significant reductions in water and energy consumption can be achieved
using this approach.
© 2009 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
Keywords: Water minimisation; Energy minimisation; Pinch analysis; Process integration; Heat surplus diagram;
Heuristics
∗
Corresponding author. Tel.: +60 7 5535609; fax: +60 7 5581463.
E-mail address: [email protected] (Z.A. Manan).
Received 14 January 2009; Received in revised form 24 April 2009; Accepted 29 April 2009
0263-8762/$ – see front matter © 2009 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
doi:10.1016/j.cherd.2009.04.013
1510 chemical engineering research and design 8 7 ( 2 0 0 9 ) 1509–1519
2. Methodology
Nomenclature
C0 equipment cost of heat exchanger (USD) 2.1. Step 1: water and wastewater targeting
S0 heat transfer area
m contaminant loads (kg/h) Savulescu and Smith introduced a technique for simultaneous
Tlm Log mean temperature energy and water minimisation that focuses on heat recov-
A heat exchanger area (m2 ) ery (Savulescu and Smith, 1998; Savulescu et al., 2005a,b).
BC base cost (USD) Reduction of cooling water is achieved indirectly when the
C concentration (ppm) temperature of wastewater is reduced. In fact, for a water-
Cpinch pinch concentration (ppm) intensive industry that utilises water in processes on top
D demand/sink of those required by a cooling water circuit, more savings
DIP de-inking plant and benefits can be achieved when water reduction becomes
MF module factor the main consideration followed by heat recovery, as demon-
MNI Malaysian Newsprint Industry strated in this work. Various water targeting approaches are
MPF material and pressure factor available to generate the maximum water recovery targets
ppm parts per million applicable for both MTB and NMTB systems such as source
Q heat duty (MW) sink composite curves (El-Halwagi et al., 2003; Prakash and
RCF recycle fiber plant Shenoy, 2005) and water cascade analysis (WCA) (Manan et
S source al., 2004). In this work, the WCA is used to target the mini-
S heat transfer area of a particular heat mum water and wastewater targets due to its versatility and
exchanger capability to yield accurate results.
SWE simultaneous water and energy
TDS total dissolved solids 2.2. Step 2: water network design
TSS total suspended solid
UF updated factor Once the water and wastewater targets are established, water
WCA water cascade analysis utilisation network is designed using the improved cleanest
to cleanest rule by Wan Alwi and Manan (2008) that takes
into consideration both ‘flowrate deficit cases’ and ‘mass load
deficit cases’. In order to achieve the fresh water and wastewater
combines numerical and graphical visualisation tools. This
flowrate targets, it is necessary to observe the pinch division
approach offers two key advantages over current state-of-
and some well-established water network design rules which
the art techniques. Firstly, it is applicable to mass transfer
specify that water sources above the pinch may not be fed
based (MTB) and non-mass transfer based (NMTB) water-using
to demands below the pinch, and may not be mixed with
operations (i.e. global water operations) not considered in pre-
sources that are below the pinch concentration. Exceptions
vious studies (Savelski and Bagejewicz, 1997; Savulescu and
apply for the sources at the pinch concentration where part
Smith, 1998; Savulescu et al., 2002, 2005a,b; Zheng et al., 2003;
of these sources can be used to satisfy demands below the
Feng et al., 2008). Note that a resilient analysis tool should
pinch.
be able to handle global water operations which include the
During water network design and retrofit, it is quite com-
MTB and NMTB operations. An MTB operation involves the
mon to encounter more than one heat recovery match options.
preferential transfer of species from a rich stream to a lean
To simultaneously consider energy reduction during water
stream (a mass separating agent, MSA). A typical example of
network design, it is best to observe Heuristic SWE as follows:
such operation is ammonia used as an absorbent to recover
H2 S from a sour gas stream. On the other hand, the NMTB
operation covers function of water other than as a mass Heuristic SWE: Favour matches with closer heat load.
separating agent, including water fed as a raw material, or
being withdrawn as a product or by-product in a chemical Matching the units or streams with closer heat loads can
reaction. keep the number of heat exchanger units to a minimum.
The second contribution of this technique is introduction
of the heat surplus diagram (HSD) which is a new graphical 2.3. Step 3: heat recovery network design
visualisation tool used to guide water and energy reduction.
The heat surplus diagram, which is a plot of temperature (T) Heat recovery can be maximised and the minimum energy
versus water stream heat capacity flowrate (FCP, assumed as consumption targets can be achieved by considering direct
constant) is used together with design heuristics to provide and indirect heat transfer. The optimal water network mix-
insights on the minimum energy demand as well as on stream ing scheme is first identified to cater for direct heat transfer
matching scenarios during design of a maximum water and through isothermal mixing. This is done using the heat sur-
energy recovery network. plus diagram as described next. Then, a heat recovery system
Section 2 describes the methodology for simultaneous is designed using heat pinch design method to consider indi-
water and energy (SWE) reduction which consists of three rect heat transfer via heat exchangers.
steps, namely, setting the minimum water and wastewa- The source and demand streams are plotted on a new
ter targets, design of minimum water utilisation network graphical tool introduced in this work called “heat surplus
and heat recovery network design. The effectiveness of diagram” in order to explore the potential water and energy
the approach for energy and water reduction is demon- savings. Heat surplus diagram is a plot of stream tempera-
strated via a case study on a paper mill plant (Section ture versus water flowrate to identify the optimal isothermal
3). mixing scheme for a water utilisation network.
chemical engineering research and design 8 7 ( 2 0 0 9 ) 1509–1519 1511
Table 1 – Demand streams limiting data for MNI paper mill case study.
Demand Type F (t/h) Cmax,in (ppm) Mass load of contaminant, m (kg/h) T (◦ C)
the extracted stream data for the paper mill process which 13.3% wastewater flowrates from the existing network’s water
include twelve demands and five sources. The data extracted consumption. Next, a maximum water recovery network was
include water flowrate, contaminant concentration and tem- designed to achieve the water targets.
perature data for source and demand streams.
Total suspended solids (TSS) measured in parts per million 3.3. Step 2: water utilisation network design
(ppm) was selected as the dominant water quality parameter
and the limiting contaminant for water re-use in this work. A water utilisation network was designed for the case study
The TSS lumps together various types of contaminants sus- using the improved cleanest to cleanest rule from Wan
pended in water into a pseudo single-contaminant system. Alwi and Manan (2008). The demands and sources listed in
Fig. 5 shows the existing process flow diagram of MNI water Tables 1 and 2 are divided into regions above and below the
utilisation network. Table 3 shows the existing heaters and pinch concentration of (Cpinch ) 150 ppm. Table 4 shows the list
cooler duties of the paper mill water utilisation network. of demands and sources for regions above and below Cpinch .
Next, the source-demand matching process was carried
3.2. Step 1: water and wastewater targeting out. Since all the matches represent the ‘flowrate deficit case’,
demands at the lowest concentration were matched with the
The first step of the SWE minimisation technique is to estab- sources at the lowest concentration. Note that S2 and S3 were
lish the fresh water and wastewater consumption targets selected to be matched with D7 since both sources existed at
using the water cascade analysis (WCA) technique by Manan the same limiting concentration. Looking at the temperatures,
et al. (2004). The WCA technique yields the minimum fresh however, S2 existed at 40 ◦ C and S3 at 46 ◦ C. According to the
water and wastewater flowrate targets of 377.5 and 377.5 t/h, new SWE heuristic, matches with closer temperature are to be
respectively and a pinch concentration at 150 ppm. The tar- preferred. In line with this heuristic, S3 was matched with D7
gets represent potential reductions of 13.3% freshwater and in order to simultaneously improve heat transfer and energy
Table 2 – Source streams limiting data for MNI paper mill case study.
Source Type F (t/h) Cmax,out (ppm) Mass load of contaminant, m (kg/h) T (◦ C)
Fig. 6 – Water network design that achieves the minimum fresh water consumption and wastewater generation for region
above Cpinch .
Fig. 7 – Water network design that achieves the minimum fresh water consumption and wastewater generation for region
below Cpinch .
3.4.3. Non-isothermal mixing Note that, for the same duty supplied to Heaters A and B,
Since none of the indirect heat transfer techniques can be the fresh water temperature rises from 30 to 38 ◦ C. This would
applied for heat recovery in this work, non-isothermal mixing reduce the hot utility of fresh water in the subsequent pro-
process was used. cesses. Referring to Table 6, the duty of Heater D is 2.73 MW.
Through non-isothermal mixing, S1 which was used to sat- was added here to achieve the task. The temperature of the
isfy the demands D1, D2 and D3 at a total flowrate of 43.2 t/h mixture became 45 ◦ C. To reduce the mixture temperature to
(25.2 t/h + 10.8 t/h + 7.2 t/h) was mixed with fresh water sent to 37 ◦ C, 0.78 MW heat duty was removed from Cooler I.
D1 and D2 at a total flowrate of 143.9 t/h (100.8 t/h + 43.1 t/h). For the matches that needed to be cooled down like S4-D8
The temperature of the mixture is 39 ◦ C. In order to increase and S4-D9, new coolers were added in order to satisfy the tem-
the mixture temperature to the target temperature for D1 and perature requirement of each demand. Portions of S4 which
D2 at 50 ◦ C, the duty of Heater D had to be raised to 2.77 MW. were sent to D8 (676.8 t/h) and D9 (154.8 t/h) were cooled using
Heater C has a duty of 2.14 MW. 7.2 t/h of S1 which was previ- Cooler G with a total duty of 2.91 MW. Note that the cold utility
ously heated to 50 ◦ C was then sent to D3. S1 was mixed with for wastewater was also reduced due to wastewater flowrate
28.8 t/h of fresh water before being sent to Heater C for further reduction. 5.73 MW of cold utility for Cooler F was needed to
temperature increase. It was calculated that only 1.71 MW was cool down 377.5 t/h of wastewater to the targeted temperature
needed for Heater C to increase the water temperature to 81 ◦ C of 35 ◦ C. Tables 6 and 7 show the new duties for the existing
compared to 2.14 MW before isothermal mixing. and the newly added heaters and coolers. Fig. 11 shows the
In order to achieve the target temperature of D4, Cooler I final minimum water and energy network.
was added to reduce the temperature of S1 from 43 to 37 ◦ C.
25.1 t/h fresh water and 58.4 t/h of S2 was sent to D6. Fresh 3.4.4. Summary of the energy recovery
water and S2 were mixed before sending to D6. In this way, Table 8 summarises the savings from heat recovery from the
only cold utility was needed to cool down the mixed streams application of SWE minimisation technique. Note that the cold
in order to satisfy the heat load requirement of D6. Cooler H utility is increased by 5.5% in the effort to reduce the hot utility.
Table 6 – Hot duty of heat exchangers before and after the application of SWE minimisation.
Heat exchanger Existing water utilisation After SWE minimisation % difference, Q (MW)
network, QH (MW) technique, QH (MW)
A 2.68 2.68 –
B 0.59 0.59 –
C 2.14 1.71 −20.0%
D 2.73 2.77 +1.4%
Table 7 – Cold duty of heat exchangers before and after the application of SWE minimisation.
Heat exchanger Existing water utilisation After SWE minimisation % difference, Q (MW)
network, QC (MW) technique, QC (MW)
E 2.37 – –
F 6.61 5.73 −13.3%
G – 2.91 –
H – 0.78 –
I – 0.05 –
Table 8 – Comparison of utility usage for MNI paper mill case study before and after implementation of SWE
minimisation technique.
Without using With NEW technique % of utility reduction
NEW technique
Direct heat transfer Indirect heat transfer
4. Results and discussion results show that the new water utilisation network has
potential to save 13.4% of both fresh water and wastewater
4.1. Utility cost savings costs.
(b) Energy cost saving.
The previous sections reported the reductions in water and In the paper mill water utilisation network, the main
energy consumption achieved using the new SWE minimi- energy costs comprised of the cost live steam, electric
sation technique. In this section, the utility cost savings are
calculated. The paper mill operates 24 h a day and 330 days a
year. Table 9 shows the cost of water, wastewater and energy Table 10 – Fresh water and wastewater cost comparison
for the mill. (with and without using SWE technique).
Before After using
(a) Water and wastewater cost savings. using SWE SWE
Table 10 compares the fresh water and wastewater costs
Fresh water (t/h) 436 377.5
of the existing and the new water utilisation network
Cost of fresh water (USD/year) 156,591 135,580
designed using the SWE minimisation technique. The Savings of fresh water (USD/year) 0 21,010
% fresh water savings 0 13.4
Table 11 – Load of exchangers before and after SWE Table 13 – Base cost for heat exchangers.
minimisation.
Types
Existing water utilisation New SWE minimisation C0 = USD 300
network, QH (MW) technique, QH (MW) S0 = 5.5 ft2
˛ 0.024
A 2.68 2.68
UF(2002) 3.62
B 0.59 0.59
MPF 0.80
C 2.14 1.71
MF 1.83
D 2.73 2.77
Total 8.98 9.47 Q is the heat duty derived from energy balance, A is the
required area, and Tlm is the log mean temperature (see Eq.
(2))
power (to drive pumps) and cooling water cost. Table 11 [(T1 − t2 ) − (T2 − t1 )]
Tlm = (2)
shows the duties of heat exchangers for cases before and ln ((T1 − t2 )/(T2 − t1 ))
after applying SWE technique. Here, low pressure steam
was used as hot utility and cooling water as cold utility. The overall heat transfer coefficient was estimated as
The cost of each utility is shown in Table 9. As mentioned U = 1000 Btu/ft2 h ◦ F or 5678 W/m2 K.
in Section 3, the hot utility supply for Heater A and Heater The base cost for each heat exchanger is obtained using the
B came from the recycled heat of flash steam or condensed following equations:
moisture. Therefore, the duties for these two heaters were
not included in the overall water network hot utility cost. S a
Note that, while the hot utility was reduced from 8.14 to BC = C0 (3)
S0
7.75 MW, the cold utility increased by about 2.86 MW for
the network (see Table 11). Table 12 shows the total cost C0 is the equipment cost of heat exchanger, S0 is the heat
of the hot and cold utilities before and after applying the transfer area, ˛ is the exponent of the equation. S represents
SWE technique. Note that the cold utility had increased the heat transfer area of a particular heat exchanger.
by 5.5% in the effort to reduce the hot utility. When this is The updated bare module cost can be obtained from Eq.
translated into cost savings, the modifications resulted in (4) once the update factor (UF), material and pressure factor
an annual cold utility increment of about USD 0.12 million. (MPF), and module factor (MF) are determined.
However, this loss was compensated for the significant
annual savings of hot utility of about USD 1.13 million.
updated bare module cost = UF (BC) (MPF + MF − 1) (4)
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