JEE Advanced Phase Test Guide
JEE Advanced Phase Test Guide
Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
BATCH – 2022-24A01
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each Part is further divided into Two Part : Part-A & Part B in OMR
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
(i) Part-A (08-13) – Contains six (06) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.
(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+3 marks for correct answer and there will be no negative marking.
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 2
PART –I (PHYSICS)
SECTION – A : (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE is correct.
1. The displacement (x) of a particle depends on time (t) as x t 2 t 3 .
(A) The particle will return to its starting point after time /.
(B) The particle will come to rest after a time 2/3.
(C) The initial velocity of the particle was zero but its initial acceleration was not zero.
(D) No net force will act on the particle at t = /3.
3. A simple pendulum has a bob of mass m and swings with an angular amplitude . The
tension in the thread is T. At a certain time, the string makes an angle with the vertical (
).
(A) T = mg cos , for all values of .
(B) T = mg cos , only for = .
1
(C) T = mg, for cos1 (2cos 1) .
3
(D) T will be larger for smaller values of .
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 3
5
(A) The work done by the gravity = mg0
12
k 20
(B) The work done by the spring force =
288
5 k 2
(C) The work done by the lifting force = mg 0 0
12 288
(D) The sum of works done by all the forces on the block is zero.
10. A particle A is projected with speed VA from a point, making an angle 600 with the
horizontal. At the same instant, second particle B (lie in the same horizontal plane) is
thrown vertically upwards from a point directly below the maximum height point of
parabolic path of A, with velocity VB. If the two particles collide then the ratio of VA/VB
should be
(A) 1 (B) 2 / 3 (C) 3 / 2 (D) 3
12. A person walking at the rate of 3km/hour, the rain appears to fall vertically when he
increase his speed to 6 km/hr it appears him coming at angle of 450 with vertical. The
speed of rain is
3
(A) 3 2 km / hr (B) km / hr
2
(C) 6 2 km / hr (D) 2 3 km / hr
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 4
ut
distance of AB is then k ____________ u
k
60 0
300
A C
5. Two particles A and B are located at points (0, 0) and (0, 103) respectively in xy plane.
They start moving simultaneously at time t = 0 with constant velocities v A 5iˆ m/s and
v 5 3ˆj m/s, respectively. Time when they are closest to each other is found to be K/2
B
second. Find K. All distances are given in meter.
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 5
3. The van der Waal’s equation for one mole of a real gas is given as follows:
a
P V 2 V b RT
Which of the following expression(s) is/are correct at extremely high pressure?
(A) The equation gets reduced to PV = RT + Pb
(B) a ~ 0 (a = van der Waal’s constant)
(C) Z > 1 (Z = compressibility factor)
PV
(D) 1
RT
7.
2p 2p
Which of the following statement(s) is/are correct for the above molecular orbital which is
formed by two 2p orbitals of two atoms of the same element?
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 6
9. Overlapping between which of the following half-filled atomic orbitals, results in the
formation of the strongest sigma covalent bond?
(A) 2s and 2s (B) 2p and 2p
(C) 3p and 3p (D) 2p and 3p
10. Which of the following property of an ideal gas decreases by increasing temperature?
(A) R.M.S velocity (B) Average kinetic energy
(C) Rate of effusion (D) No. of collisions
11. Boiling of hard water in a boiler is accompanied with formation of scales on the inner
surface of the boiler. The scales are produced due to deposition of:
(A) Ca(HCO3)2 (B) CaCO3
(C) CaSO4 (D) CaCl2
12. How many gram of magnesium can be completely dissolved in 400 mL of 0.1 M HCl
solution?
Mg 2HCl MgCl2 H2
(A) 4.8 g (B) 0.48 g
(C) 0.96 g (D) 9.6 g
2. A vessel contains equal number of moles of CH4 and SO2 gases at a particular
temperature. If the ratio of rates of effusion of CH4 to SO2 through an orifice made on the
vessel, is expressed as x : y, the value of (x + y) is:
3. CO2, SO2, XeF2, NF3, BF3, XeF4, PCl2F3, BeCl2, CHCl3, CO, SF2 and SF6.
How many molecule(s) of the above list has/have zero dipole moment.
5. The normality of a sample of H2O2 solution is 1.25. How much litre of O2 gas will be
liberated in litre unit by decomposing one litre of the sample solution at NTP?
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 7
1. The points (2, 3), (0, 2), (4, 5) and (0, t) are concyclic if the value of t is
(A) 1 (B) 2
(C) 17 (D) 3
6. Let fn tan
2
1 sec 1 sec 21 sec 4 1 sec 2n , then
(A) f2 1 (B) f3 1
16
32
(C) f4 1 (D) f5 1
64 128
log x 1
8. The set of real values of x for which 2 2
x 5 is
(A) , 1 4, (B) 4,
(C) , 1 (D) 1,4
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 8
10. The point A (2, 1) is translated parallel to the line x y 3 by a distance of 4 units. If the
new position A ' is in the third quadrant, then the coordinates of A ' are
(A) 2 2 2, 1 2 2
(B) 2 2, 1 2 2
(C) 2 2 2, 1 2 2 (D) none of these
11. If a, c and b are in G.P with common ratio 2, then the family of lines ax + by + c= 0 always
passes through point
(A) (–1, 2) (B) (2,– 1)
(C) (1, 2) (D) none of these
(x 1)(x 2)2 (x 4)
12. Solution set of 0
(x 2)(x 3)
(A) (, 4] ( 2,1] {2} (3, ) (B) (4,2] [1,2] (3, )
(C) (, 4] {2} (3, ) (D) None of these
13. Equation of line through the point (-4,-3) and perpendicular to the line joining points (1,3)
and (2,7) is ax + by + 16 = 0, then the value of a + b =
(A) 3 (B) 4
(C) –1 (D) 5
PART – B
(Numerical Based)
This section contains 5 Numerical Based Questions. Answer of which may be numbers of
decimals. (e.g. 6.25, 7.00, -0.33, -0.30, 30.27, -127.30)
2 3
x 2 2x 3 x 6
1. The number of integral values of x satisfying 4
0 is __________
x 5
2. The value of log4 3 4 3 240 is ___________
3. Tangents are drawn to the circle x 2 y 2 12 at the points where it is met by the circle
x2 y2 5x 3y 2 0 . The x – coordinate of the point of intersection of these tangents is
________
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 9
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 10
HINT / SOLUTIONS
Physics
2 3
1. x = t - t
2 3 2
x = 0 t - t = 0 t ( - t) = 0
t = 0,
dx
Velocity v= = 2t - 3t2
dt
v = 0, t(2 - 3t) = 0
2
t = 0,
3
dv
acceleration a= 2 6t
dt
dv
a=0 2 6t t
dt 3
2.
f
2g
25l20 l
6. increase in length of spring l l l0 l02 l0
144 5l0/12
13l0 l0 l0
l l0
2 12
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 11
5l0
Work done by gravity = mg
12
2
1 l0 kl02
Work done by spring = k
2 12 288
Work done by all forces = KE
WF Wg Wsp 0
10. To collide velocity of A with respect to B should be along the line joining the two.
So vertical component of velocities of both should be same
v A sin60 v B
vA 2
vB 3
11. COE
r cos 1
mgr cos sin mv 2
r sin 2
at B
mv 2
mgsin
r
12. v m 3i v r v 1i v 2 j
v rm v r v m v 1 3 i v 2 j
Falling vertically down v1 3 0 v1 3
v m 6i v rm v 1 6 i v 2 j
v2
tan 45
v1 6
v 2 3
13. Fx ma
FY ma
Part – B
2. fmax mg 0.1 2 10 2N
m
M F
fmax
Acc. Of upper block a 1m / s 2 .
m
F fmax M.a
F = 5N
5. v A 5i
A
v B 5 3j
v BA 5 3j 5i vBA
v BA 10
B
5 3
tan
5
60º
Distance of closest approach x = 10 3 sin60 15
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 12
15 3
Time to approach t
10 2
Chemistry
Part – A
1. ABD
Sol. The ground state(1s22s22p2) and excited state (1s22s12p3) configuration follows Hund’s
rule.
Electron affinity C > N
‘C’ acquires a half-filled configuration and N destroys a half – filled configuration by gaining
one electron.
It needs four orbitals (1s, 2s, 2px, 2py) to accommodate its electron.
It can exhibit sp, sp2 and sp3 hybridization.
2. ABC
Sol. The balanced equation is
2MnO4 5 C2O42 8H
2Mn2 10CO2 4H2O
n-factor of C2O42 is 2
n-factor of CO2 is 1
3. ABC
Sol. At high pressure, repulsive force dominates. Hence, ‘a’ is assumed to be zero.
4. ABD
Sol. It contains only polar covalent bonds.
5. ABCD
Sol. The metal belongs to aluminium group.
6. AC
7. ABCD
Sol. A P B
B Q C
The nodal planes pass through the lines AB, PQ & BC)
8. B
Sol. The elements of gr-13 and gr-15 display +3 oxidation states.
9. B
Sol. p-orbitals overlap better than s-orbitals. p-orbitals of lower value of ‘n’ overlap in a better
way than that with higher value of ‘n’.
10. C
1
Sol. Effusion , other properties temperature.
T
11. B
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 13
Sol. Hard water contains Ca(HCO3)2 which on heating produces insoluble CaCO3.
12. B
400 0.1
Sol. Moles of HCl 0.04
1000
Moles of Mg to be dissolved = 0.02 mole
Mass of Mg = 0.02 24 = 0.48 g
13. C
Sol. Due to strongest p - p back bond in (C).
14. 2
Sol. At phenolphthalein indicator NaOH and Na2CO3 will react with HCl, NaHCO3 will not react.
Mole of NaOH + mole of Na2CO3(n - factor -1) = Moles of HCl
15. 3
Sol. When the moles are same
rCH4 MSO2 64
4 2
rSO2 MCH4 16
x:y=2:1x+y=3
16. 6
Sol. The molecules are: CO2, XeF2, BF3, XeF4, BeCl2 and SF6.
17. 1
Sol. Only O(2s22p4) and O2 *1 *1
y z
are paramagnetic.
18. 7
Sol. Vol. strength = 5.6 N = 5.6 1.25 = 7.
Mathematics
Part – A
1. BC M110801
Sol. Equation of the circle through (2, 3), (0, 2) and (4, 5) is x 2 y2 5x 19y 34 0 .
The point (0, t) lies on this circle. Therefore, 0 t 2 0 19t 34 0
t = 2, 17
2. B, C
Line 4y 3x + = 0 touches the circle
So perpendicular distance from centre will be equal to radius
4 4 32
5
5
+ 10 = 25
= 35, 15
3. ABD M111404
4. AB M110725
Sol. 4a2 9b2 c 2 12ab 0
2
c 2 4a2 9b2 12ab 2a 3b
c 2a 3b
Given family of lines is ax by c 0 .
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 14
ax by 2a 3b 0
a x 2 b y 3 0
x 2 0, y 3 0
i.e. (–2, –3) and (2, 3)
5. AC M11412
Sol. k1 tan 27 tan tan 27 tan9 tan 9 tan3 tan3 tan
sin2 2 sin
Now, tan 3 tan
cos 3 cos cos 3
2 sin 3
Similarly, tan 9 tan 3
cos 9
2sin9
and tan 27 tan9
cos 27
sin 9 sin 3 sin
k1 2 2k 2
cos 27 cos 9 cos 3
6. A, B, C, D
fn tan
2
1 sec 1 sec 21 sec 4 1 sec 2n
tan 1 sec
2
1 cos
tan
2 cos
sin 2cos2
2 2 tan
cos
cos
2
similar tan(1 + sec2) = tan2
fn() = tan(2n)
f2 1, f3 1
16 32
f4 1, f5 1
64
428
8. B M110202
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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 15
y
x 2 y 1
Sol. o
4 A (2, 1)
cos 45 sin 45o
o x-y=3
45
x 2 2 2, y 1 2 2
O (3, 0)
x 2 2 2, y 1 2 2
A’
(0, –3)
11. B
Solution : Put the values of b and c in ax + by + c = 0 we get x + 4y + 2 = 0
Pt (2, -1) satisfies it.
12. A
Using wavy curve
13. D
PART-C
1. 3 M110109
Sol. x 2,6
2. 5 M110202
40 / 3
Sol. log4 3 4 3 240 log28 /3 240/3 5
8/3
3. 6 M110809
Sol. The equation of the common chord is 5x 3y 10 0 . This common chord is the chord of
contact of tangents.
4. 5
5. 4 M111407
3 cos 20 sin 20 2 sin 60 cos 20 sin 20
Sol. 3 cos ec20 sec 20
sin 20 cos 20 1
sin 40
2
2 sin 80 sin 40 sin 20 2 2 sin 30 cos 50 sin 40 2 sin 40 sin 40
4
sin 40 sin 40 sin 40
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