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JEE Advanced Phase Test Guide

FIITJEE – Phase Test (JEE-Advanced) PHYSICS, CHEMISTRY & MATHEMATICS Pattern - CPT-1 QP Code: SET-A PAPER - 1 This 3-hour test contains 183 total marks across 3 sections: Physics, Chemistry, and Mathematics. Students are instructed to attempt all questions, mark answers on the OMR sheet using the provided code, and are not allowed to leave before the test ends. The test contains multiple choice and numerical questions across two parts for each subject. Part A contains multiple correct answer questions worth up to +4 marks and Part B contains single answer or numerical questions worth up to +3 marks, with negative marking

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0% found this document useful (0 votes)
598 views15 pages

JEE Advanced Phase Test Guide

FIITJEE – Phase Test (JEE-Advanced) PHYSICS, CHEMISTRY & MATHEMATICS Pattern - CPT-1 QP Code: SET-A PAPER - 1 This 3-hour test contains 183 total marks across 3 sections: Physics, Chemistry, and Mathematics. Students are instructed to attempt all questions, mark answers on the OMR sheet using the provided code, and are not allowed to leave before the test ends. The test contains multiple choice and numerical questions across two parts for each subject. Part A contains multiple correct answer questions worth up to +4 marks and Part B contains single answer or numerical questions worth up to +3 marks, with negative marking

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Adhyayan D
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FIITJEE – Phase Test (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

Pattern - CPT-1 QP Code: SET-A PAPER - 1

Time Allotted: 3 Hours Maximum Marks: 183

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
BATCH – 2022-24A01

OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each Part is further divided into Two Part : Part-A & Part B in OMR
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Parts.


(i) Part-A (01-07) – Contains seven (07) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: 1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B)
will result in 1 marks, as a wrong option is also darkened.

(i) Part-A (08-13) – Contains six (06) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.

(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+3 marks for correct answer and there will be no negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 2

PART –I (PHYSICS)
SECTION – A : (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE is correct.
1. The displacement (x) of a particle depends on time (t) as x   t 2   t 3 .
(A) The particle will return to its starting point after time /.
(B) The particle will come to rest after a time 2/3.
(C) The initial velocity of the particle was zero but its initial acceleration was not zero.
(D) No net force will act on the particle at t = /3.

2. A block of mass 2 kg is pressed against a rigid vertical wall by a


horizontal force of 100 N. If co-efficient of static and kinetic friction are
each equal to 0.3, then 2 kg
100 N
(A) the magnitude of friction is 20 N
(B) direction of frictional force on the block is vertically upward
(C) the magnitude of friction is 40 N
(D) direction of frictional force on the block is vertically downward

3. A simple pendulum has a bob of mass m and swings with an angular amplitude . The
tension in the thread is T. At a certain time, the string makes an angle  with the vertical (
 ).
(A) T = mg cos , for all values of .
(B) T = mg cos , only for  = .
1 
(C) T = mg, for   cos1  (2cos   1) .
3 
(D) T will be larger for smaller values of .

4. In the figure, the pulley P moves to the right with a constant B


P u
speed u. The downward speed of A is vA, and the speed of B to
the right is vB.
(A) vB = vA
(B) vB = u + vA A
(C) vB +u = vA
(D) The two block have acceleration of the same magnitude.

5. Velocity of a particle moving in a curvilinear path varies with time as V  2ti  t 2 j m / s .  
Where t is in sec.
At t = 1 sec
(A) acceleration of particle is 8m / s 2
6
(B) tangential acceleration of particle is m / s2
5
2
(C) Radial acceleration of particle is m / s2
5
5 5
(D) Radius of curvature to the paths is m
2
6. A block of mass m is attached to a horizontal spring of F
stiffness k. The other end of the spring is attached to a fixed
wall. The entire system lies on a horizontal surface and the
spring is at its natural length. The natural length of the spring
5
is 0. If the block is slowly lifted up vertically to a height 0
12
from its initial position, which of the following is correct?

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5
(A) The work done by the gravity = mg0
12
k  20
(B) The work done by the spring force = 
288
5 k 2
(C) The work done by the lifting force = mg 0  0
12 288
(D) The sum of works done by all the forces on the block is zero.

7. A body moves along an uneven horizontal road surface with B


constant speed at all points. The normal reaction of the road on the
A
body is C
(A) maximum at A (B) maximum at B
(C) minimum at B (D) the same at A, B and C

SECTION – A : (Multi Correct Answer Type)


This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLYONE is correct.
     
8 There are three vectors P, Q and R . The angle between Pand Q is 60º and R is
 
perpendicular to the plane containing the vectors Pand Q . Which of the following relation is
possibly correct ?
    
(A) P  Q  R  0 (B) P  Q  R
  
(C) P R  Q (D) All of these
9. Two weights W 1 and W 2 in equilibrium and at rest, are suspended
W
as shown in figure. Then the ratio 1 is
W2
(A) 5/4 (B) 4/5
(C) 8/5 (D) None of these

10. A particle A is projected with speed VA from a point, making an angle 600 with the
horizontal. At the same instant, second particle B (lie in the same horizontal plane) is
thrown vertically upwards from a point directly below the maximum height point of
parabolic path of A, with velocity VB. If the two particles collide then the ratio of VA/VB
should be
(A) 1 (B) 2 / 3 (C) 3 / 2 (D) 3

11. A particle initially at rest starts moving from point A on the


surface of a fixed smooth hemisphere of radius r as shown.
The particle looses its contact with hemisphere at point B.
C is centre of the hemisphere. The equation relating  and
 is
(A) 3 sin  2cos  (B) 2 sin   3 cos  (C) 3 sin   2cos  (D) 2 sin   3cos 

12. A person walking at the rate of 3km/hour, the rain appears to fall vertically when he
increase his speed to 6 km/hr it appears him coming at angle of 450 with vertical. The
speed of rain is
3
(A) 3 2 km / hr (B) km / hr
2
(C) 6 2 km / hr (D) 2 3 km / hr

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 4

13. If wedge is moving with acceleration a as shown in the


figure then value of net force on m is
(A) ma (B) 2 ma a
M
(C) mg +ma (D) zero M m
M

PART – B (Numerical Answer Type)


This section contains 05 questions. The answer to each question is a Numerical type, which may
be positive or negative. The correct digit below the question number in the ORS is to be bubbled.

1. Two blocks of masses m1 and m2 are connected by


inextensible massless strings as shown in the figure.
Neglecting the masses of pulleys and assuming friction in
any point of the system to be absent. Then, find the ratio of
m2
for equilibrium of the system. m2
m1
m1

2. A block of mass m is placed on another block of mass M lying on


a smooth horizontal surface as shown in the figure. The co-
m
efficient of friction between the blocks is . Find the maximum
horizontal force F (in Newton) that can be applied to the block M M F
so that the blocks move together? (M = 3 kg, m = 2 kg,  = 0.1, g
= 10 m/s2)
  
3. If vectors A  2iˆ  2ˆj  mkˆ , B  3iˆ  ˆj  2kˆ and C  ˆi  ˆj  kˆ are coplanar, then find the value of
‘m’.

4. The time taken by a projectile to reach from A to B is t then the B

ut
distance of AB is then k  ____________ u
k
60 0
300

A C

5. Two particles A and B are located at points (0, 0) and (0, 103) respectively in xy plane.

They start moving simultaneously at time t = 0 with constant velocities v A  5iˆ m/s and

v  5 3ˆj m/s, respectively. Time when they are closest to each other is found to be K/2
B
second. Find K. All distances are given in meter.

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 5

PART –II (CHEMISTRY)


SECTION – A : (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE is correct.
1. Which of the following statement is/are correct for carbon atom?
(A) It follows Hund’s rule in ground state electron configuration.
(B) It’s electron gain enthalpy(electron affinity) is higher than that of nitrogen.
(C) In ground state it accommodates its electrons in five atomic orbitals.
(D) It can exhibit sp, sp2 and sp3 hybridization.

2. MnO4  C2O24  H   Mn2  CO2  H2O


Choose the correct statement(s) regarding above reaction.
(A) One mole of MnO4 ion can completely oxidise 2.5 mole of C2O42 .
Ionic mass
(B) The equivalent mass of C2O24  .
2
(C) The n-factor of CO2 is 1.
(D) nfactor of MnO4 is 5

3. The van der Waal’s equation for one mole of a real gas is given as follows:
 a 
 P  V 2   V  b   RT
 
Which of the following expression(s) is/are correct at extremely high pressure?
(A) The equation gets reduced to PV = RT + Pb
(B) a ~ 0 (a = van der Waal’s constant)
(C) Z > 1 (Z = compressibility factor)
PV
(D) 1
RT

4. Which of the following statement(s) is/are correct for CO2?


(A) The central atom undergoes sp-hybridization.
(B) Two  bonds are present in the molecule.
(C) It contains polar as well as non-polar covalent bonds.
(D) It’s bond order is 2

5. The values of some successive ionization energies of a non-transition metal M is


12.7, 18.6, 24.9, 1206.6, 1508.9 eV respectively. Choose correct statement(s) regarding
the metal?
(A) It is from 13th group.
(B) It’s second ionization energy is higher than the first ionization energy.
(C) This element can formed trihalide
(D) It exhibits +3 oxidation state in its oxide.

6. Which of the following is/are disproportionation reaction?


(A) P4  3NaOH  3H2O   PH3  3NaH2PO2
(B) 2KClO3  2KCl  3O2
(C) 2H2O2 
 2H2O  O 2
(D) 2H2S  SO2  3 S  2H2O

7.
2p 2p
Which of the following statement(s) is/are correct for the above molecular orbital which is
formed by two 2p orbitals of two atoms of the same element?

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(A) It is a sigma antibonding(*) molecular orbital.


(B) It has three nodal planes.
(C) Electrons of this orbital reduce bond order.
(D) The energy of this orbital is higher than that of the corresponding * antibonding orbital.
PART – A : (Multi Correct Answer Type)
This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLYONE is correct.
8. The formula of the chloride of a non-transition element(E) is ECl3. The probable group
number(s) of the element may be:
(A) 12 or 16 (B) 13 or 15
(C) 14 or 15 (D) 15 or 17

9. Overlapping between which of the following half-filled atomic orbitals, results in the
formation of the strongest sigma covalent bond?
(A) 2s and 2s (B) 2p and 2p
(C) 3p and 3p (D) 2p and 3p

10. Which of the following property of an ideal gas decreases by increasing temperature?
(A) R.M.S velocity (B) Average kinetic energy
(C) Rate of effusion (D) No. of collisions

11. Boiling of hard water in a boiler is accompanied with formation of scales on the inner
surface of the boiler. The scales are produced due to deposition of:
(A) Ca(HCO3)2 (B) CaCO3
(C) CaSO4 (D) CaCl2

12. How many gram of magnesium can be completely dissolved in 400 mL of 0.1 M HCl
solution?
Mg  2HCl  MgCl2  H2
(A) 4.8 g (B) 0.48 g
(C) 0.96 g (D) 9.6 g

13. Best conductor of electricity in aqueous solution is


(A) Li+ (B) Na+
(C) Cs+ (D) K+

PART – B (Numerical Answer Type)


This section contains 05 questions. The answer to each question is a Numerical type, which may
be positive or negative. The correct digit below the question number in the ORS is to be bubbled.
1. A mixture containing 0.2 mole of Na2CO3, 0.6 mole of NaOH and 0.2 mole of NaHCO3
requires 400 mL of HCl solution for complete reaction with phenolphthalein indicator. What
is the molarity of HCl solution?

2. A vessel contains equal number of moles of CH4 and SO2 gases at a particular
temperature. If the ratio of rates of effusion of CH4 to SO2 through an orifice made on the
vessel, is expressed as x : y, the value of (x + y) is:

3. CO2, SO2, XeF2, NF3, BF3, XeF4, PCl2F3, BeCl2, CHCl3, CO, SF2 and SF6.
How many molecule(s) of the above list has/have zero dipole moment.

4. How many of the following element(s) show(s) paramagnetism in atomic as well as


molecular form?
Nitrogen, Fluorine, Oxygen, Hydrogen and Chlorine

5. The normality of a sample of H2O2 solution is 1.25. How much litre of O2 gas will be
liberated in litre unit by decomposing one litre of the sample solution at NTP?

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 7

PART –III (MATHEMATICS)


(Multi Correct Choice Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE OR MORE may be correct.

1. The points (2, 3), (0, 2), (4, 5) and (0, t) are concyclic if the value of t is
(A) 1 (B) 2
(C) 17 (D) 3

2. The line 4y  3x +  = 0 touches the circle x2 + y2  4x  8y  5 = 0, the value of  is


(A) 29 (B) 15
(C) 35 (D) none the these

3. If the lines y x = 5, 3x + 4y = 1 and y = mx+3 are concurrent then the value of 19 m is


5
(A) greater than 1 (B)greater than
2
(C) less than 3 (D) less than 6

4. If 4a2  9b2  c 2  12ab  0, then the family of straight lines ax  by  c  0 is concurrent at


(A) (2, 3) (B) (–2, –3)
(C) (–3, –4) (D) (3, –4)

sin  sin3 sin9


5. If k1  tan 27  tan  and k 2    , then
cos 3 cos 9 cos 27
(A) k1  2k 2 (B) k1  k 2
k  k2 k  k2
(C) 1 1 (D) 1 2
2k1  k 2 2k1  k 2


6. Let fn     tan
2

1  sec  1  sec 21  sec 4     1  sec 2n  , then 
     
(A) f2    1 (B) f3    1
16
   32 
     
(C) f4    1 (D) f5   1
 64   128 

7. Equation of a circle with centre (4, 3) touching the circle x2 + y2 = 1 is


(A) x2 + y2 – 8x – 6y – 9 = 0 (B) x2 + y2 – 8x – 6y + 11 = 0
2 2
(C) x + y – 8x – 6y – 11 = 0 (D) x2 + y2 – 8x – 6y + 9 = 0

(Single Correct Choice Type)


This section contains 6 multiple choice questions. Each question has four choices (a), (b), (c)
and (d) out of which ONLY ONE is correct.

log  x 1
8. The set of real values of x for which 2 2
 x  5 is
(A)  , 1   4,   (B)  4, 
(C)  , 1 (D)  1,4 

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 8

9. If sin x  sin2 x  1, then cos8 x  2cos6 x  cos 4 x is equal to


(A) – 1 (B) 0
(C) 1 (D) 2

10. The point A (2, 1) is translated parallel to the line x  y  3 by a distance of 4 units. If the
new position A ' is in the third quadrant, then the coordinates of A ' are

(A) 2  2 2, 1  2 2  
(B) 2  2,  1  2 2 
(C)  2  2 2, 1  2 2 (D) none of these

11. If a, c and b are in G.P with common ratio 2, then the family of lines ax + by + c= 0 always
passes through point
(A) (–1, 2) (B) (2,– 1)
(C) (1, 2) (D) none of these

(x  1)(x  2)2 (x  4)
12. Solution set of 0
(x  2)(x  3)
(A) (, 4]  ( 2,1]  {2}  (3, ) (B) (4,2]  [1,2]  (3, )
(C) (, 4]  {2}  (3,  ) (D) None of these

13. Equation of line through the point (-4,-3) and perpendicular to the line joining points (1,3)
and (2,7) is ax + by + 16 = 0, then the value of a + b =
(A) 3 (B) 4
(C) –1 (D) 5

PART – B
(Numerical Based)
This section contains 5 Numerical Based Questions. Answer of which may be numbers of
decimals. (e.g. 6.25, 7.00, -0.33, -0.30, 30.27, -127.30)
2 3
 x  2  2x  3   x  6 
1. The number of integral values of x satisfying 4
 0 is __________
 x  5
2. The value of log4 3 4 3 240 is ___________

3. Tangents are drawn to the circle x 2  y 2  12 at the points where it is met by the circle
x2  y2  5x  3y  2  0 . The x – coordinate of the point of intersection of these tangents is
________

4. If f(x) = x3 – 5x2 + sinx + 4x then the value of f (0)

5. The numerical value of 3 cos ec20  sec 20 is equal to

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 9

FIITJEE COMMON TEST


BATCHES: Two Year CRP(2022-24) A-Lot_PT1
PAPER-I
JEE ADVANCED LEVEL
SETA
ANSWER KEY

PART – I (PHYSICS) PART – II (CHEMISTRY) PART – III (MATHS)

PART – A PART – A PART – A


1. ABCD 1. ABD 1. BC
2. AB 2. ABC 2. BC
3. BCD 3. ABC 3. ABD
4. BD 4. ABD 4. AB
5. BCD 5. ABCD 5. AC
6. BCD 6. AC 6. ABCD
7. AC 7. ABCD 7. CD
8. B 8. B 8. B
9. A 9. B 9. C
10. B 10. C 10. C
11. C 11. B 11. B
12. A 12. B 12. A
13. B 13. C 13. D
PART – B PART – B PART – B
1. 2 1. 2 1. 3
2. 5 2. 3 2. 5
3. 2 3. 6 3. 6
4. 3 4. 1 4. 5
5. 3 5. 7 5. 4

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 10

HINT / SOLUTIONS
Physics
2 3
1. x = t - t
2 3 2
x = 0  t - t = 0  t ( - t) = 0

 t = 0,

dx
Velocity v= = 2t - 3t2
dt
v = 0,  t(2 - 3t) = 0
2
t = 0,
3
dv
acceleration a=  2  6t
dt
dv 
a=0  2  6t t 
dt 3

2.
f

fmax = N = 0.3 × 100 = 30 N.


N 100 N To stap the block f = 20 N

2g

3. Equation of circular motion


mv 2
T-mg cos = ………. (1)
L
 l
For    velocity = 0
T
T = mg cos  v
Conservation of energy
mg l(cos  - cos ) mg cos
For T = mg  v2 lg(1 - cos) from equation 1.

5. v  2tiˆ  t 2 ˆj m/s

a  2iˆ  2tjˆ
 
  av
at = Tangential acceleration = projection of a on v   = a cos 
v
ac = radial acceleration = a sin 
v2
Radius of cunature R 
ac

25l20 l
6. increase in length of spring l  l  l0  l02   l0
144 5l0/12
13l0 l0 l0
l   l0 
2 12

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 11

5l0
Work done by gravity = mg
12
2
1  l0  kl02
Work done by spring =  k    
2  12  288
Work done by all forces = KE
WF  Wg  Wsp  0
10. To collide velocity of A with respect to B should be along the line joining the two.
So vertical component of velocities of both should be same
v A sin60  v B
vA 2

vB 3

11. COE


r cos 1
 mgr  cos   sin    mv 2 
r sin  2
at B
mv 2
mgsin  
r
12. v m  3i v r  v 1i  v 2 j
v rm  v r  v m   v 1  3  i  v 2 j
Falling vertically down v1  3  0  v1  3
v m  6i  v rm   v 1  6  i  v 2 j
v2
tan 45 
v1  6
v 2  3
13.  Fx  ma
 FY  ma
Part – B
2. fmax  mg  0.1 2  10  2N
m
M F

fmax
Acc. Of upper block a   1m / s 2 .
m
F  fmax  M.a
F = 5N
5. v A  5i
A
v B  5 3j

v BA  5 3j  5i vBA 
v BA  10
B
5 3
tan  
5
  60º
Distance of closest approach x = 10 3 sin60  15

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 12

15 3
Time to approach t  
10 2

Chemistry
Part – A
1. ABD
Sol. The ground state(1s22s22p2) and excited state (1s22s12p3) configuration follows Hund’s
rule.
Electron affinity C > N
‘C’ acquires a half-filled configuration and N destroys a half – filled configuration by gaining
one electron.
It needs four orbitals (1s, 2s, 2px, 2py) to accommodate its electron.
It can exhibit sp, sp2 and sp3 hybridization.

2. ABC
Sol. The balanced equation is
2MnO4  5 C2O42  8H 
 2Mn2  10CO2  4H2O
n-factor of C2O42 is 2
n-factor of CO2 is 1

3. ABC
Sol. At high pressure, repulsive force dominates. Hence, ‘a’ is assumed to be zero.

4. ABD
Sol. It contains only polar covalent bonds.

5. ABCD
Sol. The metal belongs to aluminium group.

6. AC

7. ABCD
Sol. A P B

B Q C
The nodal planes pass through the lines AB, PQ & BC)

8. B
Sol. The elements of gr-13 and gr-15 display +3 oxidation states.

9. B
Sol. p-orbitals overlap better than s-orbitals. p-orbitals of lower value of ‘n’ overlap in a better
way than that with higher value of ‘n’.

10. C
1
Sol. Effusion  , other properties  temperature.
T

11. B

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 13

Sol. Hard water contains Ca(HCO3)2 which on heating produces insoluble CaCO3.

12. B
400  0.1
Sol. Moles of HCl   0.04
1000
 Moles of Mg to be dissolved = 0.02 mole
Mass of Mg = 0.02  24 = 0.48 g

13. C
Sol. Due to strongest p - p back bond in (C).

14. 2
Sol. At phenolphthalein indicator NaOH and Na2CO3 will react with HCl, NaHCO3 will not react.
 Mole of NaOH + mole of Na2CO3(n - factor -1) = Moles of HCl

15. 3
Sol. When the moles are same
rCH4 MSO2 64
   4 2
rSO2 MCH4 16
x:y=2:1x+y=3

16. 6
Sol. The molecules are: CO2, XeF2, BF3, XeF4, BeCl2 and SF6.
17. 1
Sol. Only O(2s22p4) and O2 *1 *1
y  z  
are paramagnetic.

18. 7
Sol. Vol. strength = 5.6  N = 5.6  1.25 = 7.
Mathematics
Part – A
1. BC M110801
Sol. Equation of the circle through (2, 3), (0, 2) and (4, 5) is x 2  y2  5x  19y  34  0 .
The point (0, t) lies on this circle. Therefore, 0  t 2  0  19t  34  0
 t = 2, 17

2. B, C
Line 4y  3x +  = 0 touches the circle
So perpendicular distance from centre will be equal to radius
4 4 32  
5
5
  + 10 =  25
 = 35, 15

3. ABD M111404

4. AB M110725
Sol. 4a2  9b2  c 2  12ab  0
2
 c 2  4a2  9b2  12ab   2a  3b 
 c    2a  3b 
Given family of lines is ax  by  c  0 .

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 14

 ax  by   2a  3b   0
 a  x  2  b  y  3  0
 x  2  0, y  3  0
i.e. (–2, –3) and (2, 3)
5. AC M11412
Sol. k1  tan 27  tan    tan 27  tan9    tan 9  tan3    tan3  tan  
sin2 2 sin 
Now, tan 3  tan   
cos 3 cos  cos 3
2 sin 3
Similarly, tan 9  tan 3 
cos 9
2sin9
and tan 27  tan9 
cos 27
 sin 9 sin 3 sin  
 k1  2      2k 2
 cos 27 cos 9 cos 3 

6. A, B, C, D

fn     tan
2

1  sec  1  sec 21  sec 4     1  sec 2n  

 tan 1  sec  
2
  1  cos  
tan 
2  cos  
 
sin 2cos2
2  2  tan 
 cos 
cos
2
similar tan(1 + sec2) = tan2
 fn() = tan(2n)
     
f2    1, f3    1
 16   32 
     
f4    1, f5   1
64
   428 

8. B M110202

log  x 1 log 2 2


Sol. 2 2
 x5   x  1 2
 x 5   x  1 x5
2
 x  3x  4  0  x  1 or x  4
Also, x  1  0 for logarithm to be defined. Hence, x  4 .
9. C M111402

Sol. sin x  sin2 x  1  sin x  1  sin2 x  sin2 x  cos4 x


 1  cos2 x  cos 4 x  cos4 x  cos2 x  1
Squaring both sides, we get cos8 x  cos4 x  2cos6 x  1
10. C 110715

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Two Year CRP(22-24)-PT-1_JEE (Paper-1)-PCM-IITJEE/ADV 15

y
x 2 y 1
Sol. o
  4 A (2, 1)
cos 45 sin 45o
o x-y=3
45
 x  2  2 2, y  1  2 2
O (3, 0)
 x  2  2 2, y  1  2 2
A’

(0, –3)

11. B
Solution :  Put the values of b and c in ax + by + c = 0  we get x + 4y + 2 = 0
Pt (2, -1) satisfies it.

12. A
Using wavy curve

13. D

PART-C
1. 3 M110109
Sol. x   2,6 

2. 5 M110202
40 / 3
Sol. log4 3 4 3 240  log28 /3 240/3  5
8/3

3. 6 M110809
Sol. The equation of the common chord is 5x  3y  10  0 . This common chord is the chord of
contact of tangents.
4. 5

5. 4 M111407
3 cos 20  sin 20 2 sin 60 cos 20  sin 20
Sol. 3 cos ec20  sec 20  
sin 20 cos 20 1
sin 40
2
2  sin 80  sin 40  sin 20  2  2 sin 30 cos 50  sin 40  2  sin 40  sin 40 
   4
sin 40 sin 40 sin 40

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