Miscellaneous

Topic: Normality , Molality, Mole fraction, ppm and Law of Chemical reaction.

1- A Fresh H2O2 solution is labelled 11.2 V. This solution has the same concentration as a solution which
is

a) 3.4 % (w/w) b) 3.4 % (v/v) c) 3.4 % (w/v) d) None

Answer: c

2- 100 mL of N/5 NaOH will neutralize

(a) 0.06184 g of H3BO3 (b) 0.1855 g of H3BO3 (c) 1.2368 g of H3BO3 (d) 0.03092 g of H3BO3

3- 0.5 g of an iron wire was dissolved in 75 mL of bench H2SO4, and the volume was increased to 250 mL
with water. 25 mL of this solution reduced 8.5 mL of of N/10 KMnO4 solution. The amount of pure iron
present was (atomic weight of Fe =56)

(a) 0.500 g (b) 0.252 g (c) 0.238 g (d) 0.476 g

4- A sample of 1.0 g of solid Fe2O3 of 80% purity is dissolved in a moderately concentrated HCl solution
which is reduced by zinc dust. The resulting solution required 16.7 mL of a 0.1-M solution of the oxidant.
Calculate the number of electrons taken up by the oxidant (the atomic weights of Fe and O are 56 and
16 respectively).

(a) 2 (b) 4 (c) 6 (d) 5

5- How many grams of copper will be replaced in 2 L of a 1.50 M CuSO4 solution if the latter is made to
react with 27.0 g of aluminium? (Al= 27.0 Cu= 63.5)

(a) 190.50 g (b) 95.25 g (c) 31.75 g (d) 10.65 g

6- What would be the normality of a 0.1 M K2Cr2O7 solution used as a precipitating agent for Pb2+?

(a) 0.1 N (b) 0.6 N (c) 0.4 N (d) 0.2 N

7- A solution of H2O2 is titrated against a solution of KMnO4. The reaction is

If it requires 46.9 mL of 0.145 M KMnO4 to oxidize 20.0 g of H2O2, the mass percentage of H2O2 in this
solution is

(a) 2.9 (b) 29 (c) 21 (d) 4

8- Calculate the equivalent weight of Na2CO3 when it is titrated against HCl in presence of
phenolphthalein.
(a) 106 (b) 53 (c) 26.5 (d) 212

9- Calculate the equivalent weight of Na2CO3 when it is titrated against HCl in the presence of methyl
orange.

(a) 5.3 (b) 53 (c) 10.6 (d) 106

10- 0.70 g of impure NH4SO4 was boiled with 100 mL of a 0.2 N NaOH solution till all the NH3(g) evolved.
The remaining solution was diluted to 250 mL. 25 mL of this solution was neutralized using 10 mL of a
0.1 N H2SO4 solution .The percentage purity of NH4SO4 in sample is

(a) 94.3 (b) 50.8 (c) 47.4 (d) 79.8

11- Calculate the molality of a 1-L solution of 90% H2SO4 (w/v), given that the density of the solution is
1.80 g /mL.

(a) 10.2 (b) 8.6 (c) 1.02 (d) 10.8

12- The mole fraction of a given sample of I2 in C6H6 is 0.2. The molality of I2 in C6H6 is

(a) 0.32 (b) 3.2 (c) 0.032 (d) 0.48

13- If the mole fraction of a solute in an aqueous solution is 0.50, the molality of the solution is

(a) 1.55 (b) 0.5 (c) 55.55 (d) 5.55

14- One litre of a sample of hard water contain 4.44 mg CaCl 2 and 1.9 mg of MgCl2. What is the total
hardness in terms of ppm of CaCO3?

a) 2 ppm b) 3 ppm c) 4 ppm d) 6 ppm

15- 2 mole of N2H4 loses 16 mole of electron is being converted to a new compound X. Assuming that all
of the N appears in the new compound. What is the oxidation state of ‘N’ in X?

a) – 1 b) – 2 c) +2 d) +4

16- Ratio of moles of Fe(II) oxidised by equal volumes of equimolar KMnO4 & K2Cr2O7 solution in acidic
medium will be:

a) 5 : 3 b) 1 : 1 c) 1 : 2 d) 5 : 6

17- The NH3 evolved due to complete conversion of N from 1.12 g sample of protein was absorbed in 45
mL of 0.4 N HNO3. The excess acid required 20 mL of 0.1 N NaOH. The % N in the sample is:

a) 8 b) 16 c) 20 d) 25

18- When 2.5 g of a sample of Mohr’s salt reacts completely with 50 mL of N/10 KMnO 4 solution. The %
purity of the sample of Mohr’s salt is:
a) 78.4 b) 70 c) 37 d) 40

19- 100 mL solution of NaOH and Na2CO3 was first titrated with N/10 HCl in presence of HPh, 17.5 mL is
required to end point. After this MeOH was added and 2.5 mL of same HCl is required. The amount of
NaOH in mixture is:

a) 0.06 g per 100 mL b) 0.06 g per 200 mL

c) 0.05 g per 100 mL d) 0.012 g per 200 mL

20- In an iodometric estimation, the following reactions occur

2Cu2+ + 4I− →Cu2I2 + I2 ; I2 + 2Na2S2O3 → 2NaI + Na2S4O6

0.12 mole of CuSO4 was added to excess of KI solution and the liberated iodine required 120 mL of hypo.
The molarity of hypo solution was:

a) 2 b) 0.20 c) 0.1 d) 1.0

21 If water sample are taken from sea, rivers or lake, they will be found to contain hydrogen and oxygen
in the approximate ratio of 1 : 8. This indicates the law of:

a) Multiple proportion b) Definite proportion c) Reciprocal proportions d) None of these

22. Hydrogen and oxygen combine to form H2O2 and H2O containing 5.93 % and 11.2 % hydrogen
respectively. The data illustrates:

a) law of conservation of mass b) law of constant proportion

c) law of reciprocal proportion d) law of multiple proportion

23. One of the following combinations illustrate law of reciprocal proportions:

a) N2O3 , N2O4 , N2O5 b) NaCl , NaBr , NaI c) CS2 , CO2 , SO2 d) PH3 , P2O3 , P2O5

24- Which of the following data pertains the law of conservation of mass?

a) 5.85 g of NaCl reacts with 17 gm of AgNO3 to give 14.35 g of AgCl and 4.25 g of NaNO3

b) 2.08 g of BaCl2 reacts with 10 ml of 2N H2SO4 to give 2.33 gm of BaSO4 and 0.73 gm of HCl

c) 0.28 g of CO reacts with 1.6 g of O2 to give 0.44 g of CO2.

d) 10 gm of Ice is melted to get 10 g of H2O

25- If law of indestructibility of matter holds good, then 1.7 gm of AgNO3 will react with 10 ml of 1M HCl
to give 1.435 g of AgCl and HNO3 equal to

a) 6.3 g b) 0.315 g c) 0.63 g d) None

a) Cu2Cl2 b)CaCl2 c) MgSO4 d) Al2(SO4)3

27- In a reaction, 2M + O2  2MO; if the mass of involved is 48 gm, its equivalent mass is

a) 48 b) 24 c) 12 d) 6

28- The Chloride of the metal M contains 29% of the meta, the equivalent mass of M is

a) 35.5 b) 29 c) 14.5 d) 58

29- The approximate atomic mass of element is 23.92. If its equivalent mass is 7.9, the exact at. mass is

a) 23.7 b) 24 c) 23.92 d) 24.9

30- In an experiment of electrolysis the masses of metal X & Y discharged by passing the same charge
through the solution of X2SO4 and YCl2 are in the ratio of 1:2. The atomic mass of Y is (Given- Eq.mass of
X=23)

a) 46 b) 23 c) 92 d) 11.2

31- Calculate the mole fractions of each compound in each of the following solutions:

a. 19.4 g of H2SO4 in 0.251 L of H2O (density of water is 1.00 g/mL) H2SO4: 0.0143, H2O: 0.986

b. 35.7 g of KBr in 16.2 g of water KBr: 0.250, H2O: 0.750

c. 233 g of CO2 in 0.409 L of water (density of water is 1.00 g/mL) CO2: 0.189, H2O: 0.811

32- The molality of an aqueous solution of sugar (C12H22O11) is 1.62m. Calculate the mole fractions of
sugar and water (Answer= 57.28)

33- What is the molality of NaCl in an aqueous solution which is 4.20 molar? The density of the solution
is 1.05 x 103 g/L. (Answer= 5.22)

34- An aqueous solution is prepared by diluting 3.30 mL acetone (d = 0.789 g/mL) with water to a final
volume of 75.0 mL. The density of the solution is 0.993 g/mL. What are the molarity, molality and mole
fraction of acetone in this solution? (Answer: 0.599M, 0.626m, 0.0112(Acetone), 0.989(Water)

35- 7.45 g of KCl was dissolved in 100 g of water. Calculate the molality of the solution. Answer: 1m