19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL

OUT GOING SR(MPC) Date: 19-06-2022

Time: 3 Hrs GTM-14 Max. Marks: 300

Name of the Student: ___________________ H.T. NO:

19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS

MATHEMATICS : TOTAL SYLLABUS

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
PHYSICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. A spaceship in space sweeps stationary interplanetary dust. As a result, its mass

dM  t 
increases at a rate  bv 2  t  , where v(t) is its instantaneous velocity. The
dt
instantaneous acceleration of the satellite is
2bv 3 bv 3 bv 3
1) bv3  t  2)  3)  4) 
2M  t  M t  2M  t 

2. A ring is hung on a nail. It can oscillate, without slipping or sliding (i) in its plane
with a time period T1 and, (ii) back and forth in a direction perpendicular to its plane,
T1
with a period T2 . The ratio will be
T2

2 2
1) 2) 2 3) 4) 3
3 3 3 2

1 E l
3. The quantities x  ,y and z  defined where C-capacitance, R-
 0 0 B CR

Resistance, l -length, E-Electric field, B-magnetic field and  0 , 0 , free space

permittivity and permeability respectively. Then
1) Only x and y have the same dimension
2) Only x and z have the same dimension
3) x, y and z have the same dimension
4) Only y and z have the same dimension

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
4. Ten charges are placed on the circumference of a circle of radius R with constant
angular separation between successive charges. Alternate charges 1, 3, 5, 7, 9 have
charge (+q) each, while 2, 4, 6, 8, 10 have charge (–q) each. The potential V and the
electric field E at the centre of the circle are respectively.
(Take V = 0 at infinity)

10q 10q
1) V  0; E  0 2) V  ;E 
4 0 R 4 0 R 2

10q 10q
3) V  ;E  0 4) V  0; E 
4 0 R 4 0 R 2

5. The correct match between the entries in column I and column II are
I II
Radiation Wavelength
(a) Microwave (i) 100 m
(b) Gamma rays (ii) 10–15 m
(c) A.M. radio waves (iii) 10–10 m
(d) X - rays (iv) 10–3 m
1) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii) 2) (a)-(iv), (b)-(ii), (c)-(i), (d)-(iii)
3) (a)-(iii), (b)-(ii), (c)-(i), (d)-(iv) 4) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)
6. Two Zener diodes (A and B) having breakdown voltages of 6 V and 4 V respectively,
are connected as shown in the circuit below. The output voltage V0 variation with

input voltage linearly increasing with time, is given by : Vinput  0 at t  0 

(figures are qualitative)

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL

7. Two different wires having lengths L1 and L2 , and respective temperature coefficient
of linear expansion 1 and  2 , are joined end-to-end. Then the effective temperature
coefficient of linear expansion is
1 2 L2 L1
1) 2 1 2 2) 4
1   2  L2  L1 2

1   2 1 L1   2 L2
3) 4)
2 L1  L2

8. A driver in a car, approaching a vertical wall notices that the frequency of his car
horn, has changed from 440 Hz to 480 Hz, when it gets reflected from the wall. If the
speed of sound in air is 345 m/s, then the speed of the car is
1) 36 km/hr 2) 54 km/hr 3) 24 km/hr 4) 18 km/hr
9. A radioactive nucleus decays by two different processes. The half life for the first
process is 10 s and that for the second is 100 s. The effective half life of the nucleus
is close to
1) 12 sec 2) 9 sec 3) 55 sec 4) 6 sec

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
10. In the circuit, given in the figure currents in different branches and value of one
resistor are shown. Then potential at point B with respect to the point A is

1) +1 V 2) –2 V 3) +2 V 4) –1 V
11. An iron rod of volume 103 m3 and relative permeability 1000 is placed as core in a
solenoid with 10 turns/cm. If a current of 0.5 A is passed through the solenoid, then
the magnetic moment of the rod will be
1) 5102 Am2 2) 0.5102 Am2 3) 500 102 Am2 4) 50 102 Am2
12. In an adiabatic process, the density of a diatomic gas becomes 32 times its initial
value. The final pressure of the gas is found to be n times the initial pressure. The
value of n is
1
1) 128 2) 32 3) 4) 326
32
13. A parallel plate capacitor has plate of length ‘  ’, width ‘w’ and separation of plates is
‘d’. It is connected to a battery of emf V. A dielectric slab of the same thickness ‘d’
and of dielectric constant k = 4 is being inserted between the plates of the capacitor.
At what length of the slab inside plates, will the energy stored in the capacitor be two
times the initial energy stored?
  2 
1) 2) 3) 4)
4 2 3 3
14. The acceleration due to gravity on the earth’s surface at the poles is g and angular
velocity of the earth about the axis passing through the pole is . An object is
weighed at the equator and at a height h above the poles by using a spring balance. If
the weights are found to be same, then h is (h << R, where R is the radius of the
earth)
R 2 2 R 2 2 R 2 2 R 2 2
1) 2) 3) 4)
2g g 8g 4g

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
15. A galvanometer is used in laboratory for detecting the null point in electrical
experiments. If, on passing a current of 6 mA it produces a deflection of 20 , its figure
of merit is close to
1) 6 103 A / div 2) 6660 A / div 3) 3 103 A / div 4) 3330 A / div
16. Two coherent sources of sound, S1 and S2 , produce sound waves of the same
wavelength,   1m , in phase. S1 and S2 are placed 1.5 m apart (see fig). A listener,
located at L, directly in front of S2 finds that the intensity is at a minimum when he is
2 m away from S2 . The listener moves away from S1 , keeping his distance from S2
fixed. The adjacent maximum of intensity is observed when the listener is at a
distance d from S1 . Then, d is

1) 5 m 2) 2 m 3) 12 m 4) 3 m
17. The velocity (v) and time (t) graph of a body in a straight line motion is shown in the
figure. The point S is at 4.333 seconds. The total distance covered by the body in 6 s
is

37 49
1) m 2) 11 m 3) 12 m 4) m
3 4
18. In an experiment to verify Stokes law, a small spherical ball of radius r and density 
falls under gravity through a distance h in air before entering a tank of water. If the
terminal velocity of the ball inside water is same as its velocity just before entering
the water surface, then the value of h is proportional to (ignore viscosity of air)
1) r 4 2) r 3 3) r 4) r 2

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
19. An infinitely long, straight wire carrying current I, one side opened rectangular loop
and a conductor C with a sliding connector are located in the same plane, as shown,
in the figure. The connector has length  and resistance R. It slides to the right with a
velocity v. The resistance of the conductor and the self inductance of the loop are
negligible. The induced current in the loop, as a function of separation r, between the
connector and the straight wire is

0 Iv 0 Iv 0 Iv 20 Iv

1) 2) 3) 4)
4 Rr  Rr 2 Rr 2 Rr
20. In the circuit shown, charge on the 5 F capacitor is

1) 16.36 C 2) 18.00 C 3) 5.45 C 4) 10.90 C

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the decimals ,
Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be evaluated
according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

21. Nitrogen gas is at 300°C temperature. The temperature (in K) at which the rms speed
of a H 2 molecule would be equal to the rms speed of a nitrogen molecule, is ___
(nearly)(Molar mass of N 2 gas 28 g).

NARAYANA IIT ACADEMY

 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
22. A thin rod of mass 0.9 kg and length 1 m is suspended, at rest, from one end so that it
can freely oscillate in the vertical plane. A particle of mass 0.1 kg moving in a
straight line with velocity 80 m/s hits the rod at its bottom most point and sticks to it
(see figure). The angular speed (in rad/s) of the rod immediately after the collision
will be ____ .

23. A prism of angle A = 1° has a refractive index   1.5 . A good estimate for the
N
minimum angle of deviation (in degrees) is close to . Value of N is ____ .
10
24. The surface of a metal is illuminated alternately with photons of energies
E1  4eV and E2  2.5eV respectively. The ratio of maximum speeds of the

photoelectrons emitted in the two cases is 2. The work function of the metal in (eV)
is _____.
25. A body of mass 2 kg is driven by an engine delivering a constant power of 1 J/s. The
body starts from rest and moves in a straight line. After 9 seconds, the body has
moved a distance (in m) _______.
26. A proton and an  –particle enter a uniform magnetic field perpendicularly with the
same speed. If proton takes 25 milli-sec to make 5 revolutions, then the periodic time
for the particle would be ____ milli-sec.
27. Three long, straight and parallel wires carrying currents are arranged as shown in the
figure. The wire C which carries a current of 5.0 amp is so placed that it experiences
no force. The distance of wire C from wire D is ____ cm.

NARAYANA IIT ACADEMY

 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
28. The current through an ideal PN junction shown in the following circuit diagram will
be ___ mA.
P N 700

5V 2V

29. In the figure shown the block B moves down with a velocity 10 m/s. The velocity of
A in the position shown is ___ m/s.

30. Error in the measurement of radius of a sphere is 1%. The error in the calculated
value of its volume is ___%.

CHEMISTRY MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

31. The major product of the following reaction is

1) 2) 3) 4)

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
32. Which one of the following polymers is not obtained by condensation
polymerization?
1) Buna-N 2) Nylon 6 3) Bakelite 4) Nylon 6, 6
33. The compound that has the largest H – M – H bond angle (M = N, O, S, C) is
1) H 2 S 2) CH 4 3) NH 3 4) H 2O
34. The correct order of the ionic radii of O 2 , N 3 , F  , Mg 2 , Na  and Al 3 is
1) Al 3  Mg 2  Na   F   O 2  N 3 2) Al 3  Na   Mg 2  F   O 2  N 3
3) N 3  F   O 2  Mg 2  Na   Al 3 4) N 3  O 2  F   Na   Mg 2  Al 3
35. Adsorption of a gas follows Freundlich adsorption isotherm. If x is the mass of the
x
gas adsorbed on mass m of the adsorbent, the correct plot of versus p is
m

1) 2)

3) 4)
36. The correct statement about probability density (except at infinite distance from
nucleus) is
1) It can never be zero for 2s orbital 2) It can be zero for 3p orbital
3) It can be zero for 1s orbital 4) It can be negative for 2p orbital
 
37. Consider the complex ions, trans- Co  en 2 Cl2   A and cis  Co  en 2 Cl2   B  .

The correct statement regarding them is

1) both (A) and (B) can be optically active.
2) both (A) and (B) can not be optically active.
3) (A) can not be optically active, but (B) can be optically active.
4) (A) can be optically active, but (B) can not be optically active.

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
38. The variation of molar conductivity with concentration of an electrolyte (X) in
aqueous solution is shown in the given figure.

The electrolyte X is
1) NaCl 2) HCl 3) CH 3COOH 4) KNO3
39. The increasing order of boiling points of the following compounds is

1) III < I < II < IV 2) IV < I < II < III

3) I < III < IV < II 4) I < IV < III < II
40. An element crystallises in a face-centred cubic (fcc) unit cell with cell edge length
‘a’. The distance between the centres of two nearest octahedral voids in the crystal
lattice is
a a
1) a 2) 2a 3) 4)
2 2

41. The following molecule acts as an

1) Anti-depressant 2) Antiseptic 3) Anti-bacterial 4) Anti-histamine

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
42. Hydrogen peroxide, in the pure state, is
1) linear and blue in colour 2) planar and blue in colour
3) linear and almost colourless 4) non-planar and almost colourless
43. Among the following compounds geometrical isomerism is exhibited by

1) 2)

3) 4)
44. Reaction of ammonia with excess Cl2 gives
1) NH4Cl and HCl 2) NCl3 and HCl
3) NCl3 and NH4Cl 4) NH4Cl and N2
45. The rate constant (k) of a reaction is measured at different
temperatures (T), and the data are plotted in the given figure. The
activation energy of the reaction in kJ mol–1 is (R is gas constant)

1) 1/R 2) 2/R 3) 2R 4) R
46. The major product formed in the following reaction is
HBr
CH 3CH  CHCH  CH 3  2  

1) Br  CH 2 3 CH  CH 3 2 2) CH 3CH  Br  CH 2CH  CH 3 2

3) CH 3CH 2CH  Br  CH  CH 3 2 4) CH 3CH 2CH 2C  Br  CH 3 2

NARAYANA IIT ACADEMY
 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
47. Boron and silicon of very high purity can be obtained through
1) vapour phase refining 2) electrolytic refining
3) liquation 4) zone refining
48. The final major product of the following reaction is

1) 2) 3) 4)
49. Lattice enthalpy and enthalpy of solution of NaCl are 788 kJ mol –1
and 4 kJ mol –1 , respectively. The hydration enthalpy of NaCl is
1) 784 kJ mol–1 2) –780 kJ mol–1
3) 780 kJ mol–1 4) –784 kJ mol–1
50. The one that is NOT suitable for the removal of permanent hardness of water is
1) Calgon’s method 2) Ion-exchange method
3) Clark’s method 4) Treatment with sodium carbonate

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the decimals ,
Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be evaluated
according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

51. For a reaction X + Y  2Z, 1.0 mol of X, 1.5 mol of Y and 0.5 mol of Z were taken
in a 1 L vessel and allowed to react. At equilibrium, the concentration of Z was
x
1.0mol L1 . The equilibrium constant of the reaction is ___ . The value of x is ___.
15
52. The volume in mL, of 0.02 M K2Cr2O7 solution required to react with 0.288 g of
ferrous oxalate in acidic medium is _______.(Molar mass of Fe  56 g mol 1 ).

NARAYANA IIT ACADEMY

 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
53. For a dimerization reaction,
2 A  g   A2  g  ,
at 300 K , U 0  20kJ mol 1 , S 0  30 JK 1 mol 1 , then the G 0 will be ____ J .

54. The number of chiral carbons present in sucrose is _____.

2
55. Considering that  0  P , the magnetic moment (in BM) of  Ru  H 2O 6  would be __.

56. How many isomers of C4 H10O reacts with Na metal to evolve H 2 gas. (excluding
stereo isomer)
57. Total number of double bond equivalent (DBE) in Dibenzal acetone
58. How many faradays are required for reduction of 1mol
C6 H5 NO2 into C6 H5 NH 2

59. What is the maximum value of Van’t Hoff factor for Al2  SO4 3 .
60. How many different Grignard reagents when react with ethyl alcohol give n-butane
as product (including stereo isomers)
MATHS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

61. The set of values of P for which the point of extremum of the function
f  x   x3  3 px 2  3  p 2  1 x  1 lies in the interval (-2, 4) is

1)  3,5 2)  3,3 3)  1,3 4)  1, 4 

1 1
 n 
ex  2x
    
ex
 3x
n
ex

62. The value of lim   (where n  N ) is
x  xn
1) ln 2  ln 3 2) ln 3  ln 2 3) 0 4) log 2  ln3
63.  p   q     p  q  is
1) a tautology 2) a contradiction
3) tautology and contradiction 4) neither tautology nor contradiction

NARAYANA IIT ACADEMY

 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
 2  2 4 
sin 2   sin sin 2
64.  7  7  7 
 2 2 2 4
sin 2 sin sin
7 7 7
1) 3 2) 4 3) 5 4) 6
65. The 1st , 2nd and 3rd terms of an arithmetic series are a, b and a 2 where a is negative
then sum of an infinite geometric series whose first three terms are a, a2 and b
respectively is
1 3 1 1
1)  2)  3)  4)
2 2 3 3
66. A student is to answer 10 out of 13 questions in an examination such that he must
choose atleast 4 from the first five questions. The number of choices available to him
is
1) 140 2) 196 3) 280 4) 346
67. If the standard deviation of the numbers 2, 3, a and 11 is 3.5, then which of the
following is true
1) 3a 2  32 a  84  0 2) 3a 2  26 a  91  0
3) 3a 2  23a  44  0 4) 3a 2  26 a  55  0
 1   1 
68. The derivative of the function cos1   2 cos x  3sin x    sin 1   2 cos x  3sin x  
 13   13 
3
with respect to 1  x 2 at x  is
4
3 5 10
1) 2) 3) 4) 0
2 2 3

69.
1  tan x  dx
2

where  9 11 
 x  ,  is
1   sin x tan x  tan x  2   1 
4 2 2  2 2 

1)  log 1  tan x  c 2) log 1  sec x  c 3) log 1  sec x  c 4) log 1  tan x  c

70. The length of chord x  3 y  13 of the circle x2  y2  4 x  4 y  3  0 is

1) 2 5 2) 5 2 3) 20 4) 10

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
71. If  and  are roots of the equation x 2  x  11  0 , then the value of
3 3  3 2  2 3  2 2  11 is

1) 33 2) -33 3) 22 4) -22
72. Consider the ten numbers ar , ar 2 .....ar10 . If their sum is 18 and the sum of their
reciprocals is 6, then the product of these ten numbers is
1 1
1) 3 2) 3) 4) 243
3 243

73. The equation of common tangent to 9x 2  16 y 2  144 and x 2  y 2  9 is

2 15 3 15
1) y  3 x  15 2) y  3 x 3) y  2 x 4) y  2 x  15
7 7 7 7 7 7 7 7

6
74. The area bounded by y  3  3  x and y  is
x 1

15 13
1)  6ln 2 sq. units 2)  3ln 2 sq. units
2 2
13 13
3)  6 ln 2 sq. units 4)  2 ln 2 sq. units
2 2

x 1 x  2 x  a
75. If a  2b  c  1 , then the value of x  2 x  3 x  b is
x3 x4 x c

1) x 2) x 3) -1 4) 1
x 1 y 1 z x 1 y  3 z 1
76. Acute angle between the lines   and   where l  m  n
l m n m n l
and l, m, n are roots of the cubic equation x 3  x 2  4 x  4 is equal to
 3   63  4 2
1) cos1   2) sin 1   3) cos 1   4) tan 1  
 13   9  9 3
10 10
77. If z  1  3i   1  3i  then arg  z  may be

  2
1) 2)  3) 4)
2 4 3
78. If y  t  satisfies the differential equation y '  t   2 y  t   2e2t , y  0  2 then y 1 equals
3 3 4 4
1) 2) 3) 4)
e e2 e e2

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
79. If the system of linear equations x  ky  3 z  0, 3 x  ky  2 z  0, 2 x  4 y  3 z  0 has a non

zero solution (x, y, z) then xz2 is equal to

y

1) 30 2) -10 3) 10 4) -30
80. If a variable tangent to the curve x2 y  c3 makes intercepts a, b on x and y-axis,
respectively then the value of a 2 b is
4 3 27 3 4 3
1) 27c 3 2) c 3) c 4) c
27 4 9
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the decimals ,
Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be evaluated
according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
81. If A  1, 2,3, 4 then number of one-one onto mapping f : A  A such that

f 1  1, f  2   2, f  4   4 is
8
82. The coefficient of x 7 is the expansion of 1  x  x3  x4  is

83. Let u , v, w be three vectors of magnitude 3, 1 and 2 respectively, Such that

 
u  u  w  3v  0 . If  is the angle between u and w , then 4 cos 2  is

84. If the angle between the normal to the parabola x2  4ay at point P and the focal chord

passing through P is , then the square of the slope tangent at point P is
3
85. A bag contains 10 balls of which 2 are red and the remaining are either blue or black.
11
If the probability of drawing 3 balls of the same colour is and the number of blue
120
balls exceeds the number of black balls, then the number of blue balls is
sin x sin 3 x sin 9 x  
86. Number of solutions of the equation    0 in the interval  0,  is
cos 3 x cos 9 x cos 27 x  4
 /4 2  /4 2
 cos x   sin x  cos x  4U
87. If U     dx and V     dx then the value of is
0  sin x  cos x  0  cos x  V

ba
88. If 0  a  b  3 then greatest possible integral value of is
tan b  tan 1 a
1

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 19-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-14 _QP FINAL
89. If the   plane 7 x    4  y  4 z    0 passing through the point of intersection of the

planes 2 x  3 y  z  1  0 and x  y  2 z  3  0 and is perpendicular to the plane

 12 78 57 
3 x  y  2 z  4 and  , ,  is image of the point 1,1,1 in   plane, then      is
   

1 1 1
90. If x and y are positive integers satisfying tan 1    tan 1    tan 1   then number of
 x  y 7

order pairs  x, y  is

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