1

MANZIL
IUPAC Nomenclature
Practice Sheet-1
1. 6. The IUPAC name of the compound,

(A) 1-amino prop-2-enal

(B) 3-amino prop-2-enal (A) 2-methylpent-1-en-4-yne
(C) 1-amino-2-formylethene (B) 4-methylpent-4-en-1-yne
(D) 3-amino-1-oxoprop-2-ene (C) 2-methylpent-2-en-4-yne
(D) 4-methylpent-1-en-4-yne
2. The IUPAC name for
CH3
|
CH3CH(OH)CH 2  C  OH
| 7. The IUPAC name of is
CH3 (A) But-3-enoic acid
(A) 1,1-dimethyl-1,2-butanediol (B) But-1-enoic acid
(B) 2-methyl-2,4-pentanediol (C) Pent-4-enoic acid
(C) 4-methyl-2,4-pentanediol (D) Prop-2-enoic acid
(D) 1,3,3-dimethyl-1,3-propanediol 8. 3-methyl penta-1,3-diene is :
(A) CH2 = CH(CH2 )2 CH3
3. IUPAC name of the compound, (B) CH2 = CHCH(CH3 )CH2 CH3
CH 2  CH  CH 2 is: (C) CH3 CH = C(CH3 )CH = CH2
| | | (D) CH3 − CH = CH(CH3 )2
CN CN CN
(A) 1,2,3-trieyanopropane 9. Give the correct IUPAC name for
(B) Propane-1,2,3-tricarbonitrile CH3
(C) 1,2,3-cyanopropane |
(D) Propane tricarbylamine CH3 . CH2 OCH. CH2 . CH2 . CH2 Cl
(A) 2-ethoxy-5-chloropentane
4. The IUPAC name of C6 H5 COCl is (B) l-chloro-4-ethoxy-4-methylbutane
(A) Benzoyl chloride
(C) 1-chloro-4-ethoxypentane
(B) Benzene chloro ketone
(C) Benzene carbonyl chloride (D) Ethyl-1-chloropentylether
(D) Chloro phenyl ketone
10. The IUPAC name of compound shown
5. Which is wrong IUPAC name? below is
(A) CH3 CH2 CH2 COOCH2 CH3 (Ethyl
butanoate)
(B)

(C)
(A) 2-bromo-6- chlorocyclohex-1-ene
(B) 6-bromo-2-chlorocyclohexene
(D) (C) 3-bromo-1-chlorocyclohexene
(D) 1-bromo-3-chlorocyclohexene
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11. IUPAC name of the compound 15. IUPAC name of the following compound is

(A) 3, 5-dimethylcyclohexene
(B) 3, 5-dimethly-1-cyclohexene
(C) 1, 5-dimethly-5-cyclohexene
(D) 1, 3-dimethyl-5-cyclohexene

(A) 5- methyl-4-isopropyl-6,
16. The correct IUPAC name of the following
6’diethyloctane
compound is
(B) 3, 3-dimethyl, 3-ethyl-5- isopropyl
octane CH3CH 2 CH  C  C  CH  CH 2CH 2CH 2CH3
| | |
(C) 3, 3-diethyl-4-methyl-5-(1,1-dimethyl) CH3 C2 H5 C2 H5
octane
(A) 5, 6-dimethyl-8-methyl dec-6-ene
(D) 3, 3- diethyl-4-methyl-5-(1’-
methylethyl) octane (B) 6-butyl-5-ethyl-3-methyl oct-4-ene
(C) 5, 6-diethyl-3-methyl dec-4-ene
12. (D) 2, 4, 5-triethyl non-3-ene

17. IUPAC name of,

CH3 CH(OH)CH2 CH2 COOH is :
(A) 2-ethyl-3-methylbutanoyl chloride (A) 4-hydroxypentanoic acid
(B) 2,3-dimethylpentanoyl chloride (B) 1-carboxy-3-butanoic acid
(C) 3,4-dimethylpentanoyl chloride (C) 1-carboxy-4-butanol
(D) 1-chloro-l-oxo-2,3-dimethylpentane (D) 4-carboxy-2-butanol

18. The IUPAC name of the compound,

13. IUPAC name of CH3  CH  CH 2  CHO is
|
Cl
(A) 3-chlorobutanol
(A) 2-ethylbutanamide
(B) 3-chlorobutanaldehyde
(B) 2-methylbutanamide
(C) 3-chlorobutanal
(C) 1-amino-2-methylpropane
(D) 2-chlorobutanol
(D) None of the above
19. Give the IUPAC name for,
14. The IUPAC name of is

(A) 2-methyl-3-bromohexanal (A) Ethyl-4- oxoheptanoate

(B) 3-bromo-2-methylbutanal (B) Methyl-4- oxoheptanoate
(C) 2-bromo-3-bromobutanal (C) ethyl-4- oxohexanoate
(D) 3-bromo-2-methylpentanal (D) Methyl 4- oxohexanoate

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20. The correct IUPAC name of the compound, 25. Which nomenclature is not according to
IUPAC system?

(A)

(A) 3-(1-ethyl propyl) hex-1-ene (B)

(B) 4-Ethyl-3-propyl hex-1-ene
(C) 3-Ethyl-4-ethenyl heptane (C)
(D) 3-Ethyl-4-propyl hex-5-ene

21. IUPAC name of (CH3 )2 N − C2 H5 is :

(A) Dimethyl ethyl amine
(B) Dimethylaminomethane (D)
(C) Dimethylaminoethane
(D) 𝑁, 𝑁-dimethylethanamine
26. The IUPAC name of
22. The IUPAC name of
CH3 CH3 − CH = CH − C ≡ CH is
| (A) Pent-3-en-1-yne
CH3 − CH − CH2 − C − CH3 (B) Pent-3-en-4-yne
| | (C) Pent-2-en-4-yne
OH OH (D) Pent-2-en-3-yne
(A) 1, 1-dimethyl-1, 3-butanediol
(B) 2-methyl-2, 4-pentanediol 27. IUPAC name of
(C) 4-methyl-2, 4-pentanediol
(D) l, 3, 3-trimethyl-1, 3-propane diol
(A) 4-bromo-3-ethyl-1,4-pentadiene
23. The correct structure of 4-bromo-3-methyl- (B) 2-bromo-3-ethyl-1,4pentadiene
but-1-ene.
(C) 2-bromo-3-ethyl-1-5-pentadiene
(A) Br − CH = C(CH3 )2
(D) None of the above
(B) CH2 = CH − CH(CH3 ) − CH2 Br
(C) CH2 = C(CH3 )CH2 CH2 Br
(D) CH3 − C(CH3 ) = CHCH2 − Br 28. 𝑡- butyl alcohol is
24. IUPAC name of the compound (A) 2-methyl propane-2-ol
(B) 2-methyl propane-1-ol
(C) 3-methyl butan-1-ol
(D) 3-methyl butan-2-ol

29. IUPAC name of C6H5CN is:

(A) 4-isoprophyl, 6-methyl octane (A) Phenyl nitrile
(B) 3-methyl, 5-(1-methylethyl) octane (B) Benzene nitrile
(C) 3-methyl, 5-isopropyl octane (C) Benzyl nitrile
(D) 6-methyl, 4-(1-methylethyl) octane (D) Phenyl cyanide

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30. The IUPAC name of 35. Which one is not is IUPAC system?
(A)

(A) 4-hydroxy-1-methylpentanal (B)

(B) 4-hydroxy-4-methylpent-2-en-1-al
(C) 2-hydroxy-2-methylpent-2-en-5-al
(C)
(D) 2-hydroxy-3-methylpent-2-en-5-al

(D) CH3 − C ≡ C − CH(CH3 )2 (4-methyl-

31. The IUPAC name of CH3  C  CH  CH3
2-pentyne)
|| |
O CH3 36. Which of the following IUPAC names is
is correct?
(A) 2-methyl-3-butanone (A) 2-methyl-3-ethylpentane
(B) 2-ethyl-3-methylpentane
(B) 3-methyl-butan-2-one (C) 3-ethyl-2-methylpentane
(C) 3-methyl butanone (D) 3-methyl-2-ethylpentane
(D) None of these 37. The IUPAC name of

32.
(A) 5-chloro-hex-2-ene
(A) 4,5-dimethyl oct-4-ene (B) 2-chloro-hex-5-ene
(B) 3,4-dimethyl oct-5-ene (C) l-chloro-1-methyl-pent-3-ene
(D) 5-chloro-5-methyl-pent-2-ene
(C) 4,5-dimethyl oct-5-ene
(D) None of the above 38. Which of the following compounds has
incorrect IUPAC nomenclature?
(A) O
33. ∥
CH3 CH2 CH2 COC2 H5
Ethylbutanoate
(A) but-2-ene-2,3-diol (B) 𝐶𝐻3 𝐶𝐻𝐶𝐻2 𝐶𝐻𝑂
|
(B) pent-2-ene-2,3-diol 𝐶𝐻3
(C) 2-methylbut-2-ene-2,3-diol 3-methyl butanal
(D) Hex-2-ene-2,3-diol (C) 𝑂
∥
𝐶𝐻3 𝐶𝐻𝐶𝐶𝐻2 𝐶𝐻3
34. The IUPAC name of |
(CH3 )3 C − CH = CH2 is 𝐶𝐻3
(A) 1, 1, 1-trimethyl-2-propene 2-methyl-3-pentanone
(D) CH3 CHCHCH3
(B) 3, 3, 3-trimethyl-2-propene | |
(C) 2, 2-dimethyl-3-butene H3 C OH
(D) 3, 3-dimethyl-1-butene 2-methyl-3-butanol

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39. IUPAC name of (CH3 )3 CClis 43. Correct the structural formula of
(A) 𝑛-butyl chloride compound-5-nitro-3-methoxy-3-
(B) 3-chloro butane methylhexanoyl chloride is
(C) 2-chloro 2-methyl propane (A) NO2 OCH3 O
(D) 𝑡 −butyl chloride | | ∥
CH3 − CH − CH2 − C − CH2 − C − Cl
|
40.
CH3
(B) NO2 Cl CH3
(A) Isopropyl benzene | | |
(B) Cumene CH3 − CH − CH − C − CH2 − CHO
(C) Phenyl isopropane |
(D) 2-phenyl propane OCH3
(C) CH3
41. IUPAC name of following compound, |
CH3 − CH2 − CH − CH2 − CH
| |
Cl OCH3
(D) CH3 − CH2 − CH − C − CH − CH3
| ∥ |
(A) 2-cyclohexylbutane Cl O OCH3
(B) 2-phenylbutane
(C) 3-cyclohexylbutane
(D) 3-phenylbutane 44. The IUPAC name of the following
compound is

42. The IUPAC name of the compound,

(A) 2-iodo-3-chloro-4-pentanoic acid (A) Propionic anhydride

(B) 4-oxo-3-chloro-2-iodo pentanoic acid (B) Dipropanoic anhydride
(C) 4-carboxy-4,3-chloro-2-butanone (C) Ethoxy propanoic acid
(D) 3-chloro-2-iodo-4-oxo-pentanoic acid (D) Propanoic anhydride
45. The correct IUPAC name of the acid

(A) Z-3-ethyl-4-methyl hex-3-en-1-oic

acid
(B) Z-3-ethyl-4-methyl hexanoic acid
(C) Z-3, 4-diethylpent-3-en-1-oic acid
(D) E-3-ethyl-4-methylhex-4-en-1-oic acid

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46. IUPAC name of, 52. Give the IUPAC name of the compound

(A) 1,1,3-trimethylcyclohex-2-ene
(A) 2-ethyl-3-methyl-hexa-l-en-4-yne (B) 1,3,3-trimethylcyclohex-1-ene
(B) 5-ethyl-4-methyl-hexa-2-yn-5-ene (C) 1,1,5-trimethylcyclohex-5-ene
(C) 3-methylene-4-methylhepta-5-yne
(D) 2,6,6-trimethylcyclohex-1-ene
(D) 5-methylene-5-ethyl-4-methylhepta-2-
yne
53.

47. The IUPAC name of neopentane is :

(A) 2,2-dimethylpropane (A) 3-methyl cyclo-1-buten-2-ol
(B) 2-methylpropane (B) 4-methyl cyclo-2-buten-1-ol
(C) 2,2-dimethylbutane (C) 4-methyl cyclo-1-buten-3-ol
(D) 2-methylbutane (D) 2-methyl cyclo-3-buten-1-ol

48. The prefix name of —SH group in IUPAC 54. The correct IUPAC name
system is :
(A) Mercapto (B) Thiol is
(C) Sulphide (D) None of these
(A) 1- cyclopropyl cyclobutane
49. The correct name for CH3 COCH2 OH is : (B) 1, 1-dicyclobutane
(A) 2-keto propanol (C) 1- cyclobutane-1- cyclopropane
(B) 1-hydroxy propan-2-onec (D) None of the above
(C) Propan-2-one-1-ol 55. Write the IUPAC name of
(D) 3-hydroxy propan-2-one
CH3  O  CH  CH 2  CH3
|
50. The IUPAC name of the compound having CH3
the formula CH ≡ C — CH = CH2 is : (A) 3-methoxy butane
(A) 1-butene-3-yne (B) 2-methoxy butane
(B) 3-butene-1-yne (C) 3-methyl-3-methoxy propane
(C) 1-butyn-3-ene (D) Butoxy methane
(D) But-1-yne-3-ene
56. What is the correct IUPAC name of
51. H3 C − C = CH − CH − CH3 is
| |
Cl CH3
(A) 2-chloro-4-methyl-2-pentene
(B) 4-chloro-2-methyl-3-pentene
(C) 4-methyl-2-chloro-2-pentene (A) 4-methoxy-2-nitrobenzaldehyde
(D) 2-chloro-4, 4-dimethyl-2-butene (B) 4-formyl-3-nitro anisole
(C) 4-methoxy-6-nitrobenzaldehyde
(D) 2-formyl-5-methoxy nitrobenzene

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57. The IUPAC name of the compound 62. 𝑛𝑒𝑜-Heptyl alcohol is correctly represented
CH3 – N  C is: as :
(A) Ethane nitrile
(B) Methane isonitrile (A)
(C) Ethane isonitrile
(D) None of these
(B)
58. IUPAC name of
CH3 CH2 C(Br) = CH − Cl is
(A) 2-bromo-1-chloro butene-1
(C)
(B) 1-chloro-2-bromo butene-1
(C) 3-chloro-2-bromo butene-2
(D) None of the above
(D)
59. The IUPAC name of,

63. The IUPAC name for CH3 COCH(CH3 )2 is :

(A) 4-methyl isopropyl ketone
(A) 4-hydroxy-1-methylpentanal (B) 3-methyl-2-butanone
(B) 4-hydroxy-2-methylpentanal (C) Isopropyl methyl ketone
(C) 3-hydroxy-2-methylpentanal (D) 2-methyl-3-butanone
(D) 3-hydroxy-3-methylpentanal 64. IUPAC name of CH2 = CH — CH(CH3 )2
is :
60. The systematic (IUPAC) name of the (A) 1,1-dimethyl-2-propene
compound with the following structural (B) 3-methyl-1-butene
formula shall be (C) 2-vinylpropane
(D) 1-isopropyl ethylene

65. The IUPAC name of the compound

(CH3 )2 CH − CH = CH − CHOH − CH3 is
(A) 1-ethyl-2-methyl cyclohexene (A) 5-methyl-hex-3-en-2-ol
(B) 2-methyl-1-ethyl cyclohexene (B) 2-methyl-hex-3-en-5-ol
(C) 2-hydroxy-5-nethyl-3-hexene
(C) 3-ethyl-2-methyl cyclohexene
(D) 5-hydroxy-2-methyl-3-hexene
(D) 4-ethyl-3-methyl cyclohexene
61. 66. The given compound in IUPAC may be
called,

(A) 𝑁, 𝑁- dimethylethanamine
(B) 𝑁-methyl, 𝑁-ethylmethanamine (A) Diacetone
(C) Dimethyl-ethylamine (B) Acetoneamine
(D) None of the above (C) Diacetoneamine
(D) 4-amino-4-methylpentan-2-one

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67. The IUPAC name of the compound, 72. The IUPAC name of the following
CH2 − CH − COOH compound, is
| |
OH NH2
(A) 2-amino-3-hydroxy propanoic acid
(B) 1-hydroxy-2-amino propan-3-oic acid
(C) 1-amino-2-hydroxypropanoic acid
(D) 3-hydroxy-2-amino propanoic acid
(A) 4-bromo-3-cynophenoal
(B) 2-bromo-5-hydroxybenzonitrile
68. IUPAC name of the compound,
(C) 2-cyano-4-hydroxybromobenzene
ClCH2 CH2 COOH is :
(D) 6-bromo-3-hydroxybenzonitrile
(A) 3-chloropropanoic acid
(B) 2-chloropropanoic acid
73. The IUPAC name of
(C) 2-chloroethanoic acid
(D) Chlorosuccinic acid

69.
(A) 1- cyclohexa-2,4-dienylethanone
(B) 3- cyclohexa-2,4-dienylethanone
(A) 2,4-dimethylhexanone-3 (C) 1- cyclohexa-3,5-dienylethanone
(B) 2,6-dimethylheptanone-4 (D) 3- cyclohexa-3,5-dienylethanone
(C) 2,6-dimethylhexanone-4
(D) 2,6-dimethylheptanone-5 74.

70. The IUPAC name of

(A) 3-ethyl-4,4-dimethyl heptane

(B) 1,1-diethyl-2,2-dimethyl pentane
(A) 4-propoxy pentane (C) 4,4-dimethyl-5,5-diethyl pentane
(B) Pentyl-propyl ether (D) 5,5-diethyl-4, 4-dimethyl pentane
(C) 2-propoxy pentane
(D) 2-pentoxy propane 75. The IUPAC name of the compound,
CH3 CH = CHC ≡ CH is :
(A) Pent-4-yn-2-ene
71. (B) Pent-3-en-1-yne
(C) Pent-2-en-4-yne
(A) 5-methylhexanol (D) Pent-1-yn-3-ene
(B) 2-methylhexanol
(C) 2-methylhex-3-enol
(D) 4-methylpent-2-enol

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ANSWERS KEY
1. (B) 5. (C) 9. (C)
2. (B) 6. (A) 10. (C)
3. (B) 7. (A) 11. (D)
4. (A) 8. (C) 12. (B)
13. (C) 34. (D) 55. (B)
14. (D) 35. (B) 56. (A)
15. (A) 36. (C) 57. (B)
16. (C) 37. (A) 58. (A)
17. (A) 38. (D) 59. (B)
18. (B) 39. (C) 60. (D)
19. (D) 40. (D) 61. (A)
20. (B) 41. (B) 62. (C)
21. (D) 42. (D) 63. (B)
22. (B) 43. (A) 64. (B)
23. (B) 44. (D) 65. (A)
24. (B) 45. (C) 66. (D)
25. (C) 46. (A) 67. (A)
26. (A) 47. (A) 68. (A)
27. (B) 48. (A) 69. (B)
28. (A) 49. (B) 70. (C)
29. (B) 50. (A) 71. (D)
30. (B) 51. (A) 72. (B)
31. (B) 52. (B) 73. (A)
32. (A) 53. (B) 74. (A)
33. (B) 54. (A) 75. (B)

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