Soudafoam FR HY

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
Reference number: 61519gb
Issue date: 15-3-2019 Revision date: 11-8-2021 Supersedes version of: 20-1-2021 Version: 2.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture
Trade name : Soudafoam FR HY
Reference number : 61519gb
Vaporizer : aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Intended for general public
Main use category : Consumer use,Professional use
Use of the substance/mixture : Polyurethane

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Soudal N.V.
Everdongenlaan 18-20
2300 Turnhout - Belgium
T +32 14 42 42 31 - F +32 14 42 65 14
[email protected] - www.Soudal.com

1.4. Emergency telephone number

Emergency number : +32 14 58 45 45 (BIG)
24h/24h

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU > 2015: According to Regulation (EU)
2015/830, 2020/878 (REACH Annex II)
Aerosol, Category 1 H222;H229
Acute toxicity (inhalation:dust,mist) Category 4 H332
Skin corrosion/irritation, Category 2 H315
Serious eye damage/eye irritation, Category 2 H319
Respiratory sensitisation, Category 1 H334
Skin sensitisation, Category 1 H317
Carcinogenicity, Category 2 H351
Specific target organ toxicity — Single exposure, Category 3, Respiratory H335
tract irritation
Specific target organ toxicity — Repeated exposure, Category 2 H373
Full text of H- and EUH-statements: see section 16

Adverse physicochemical, human health and environmental effects

Pressurised container: May burst if heated. Extremely flammable aerosol. Suspected of causing cancer. May cause damage to organs through
prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye
irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

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Soudafoam FR HY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS02 GHS07 GHS08

Signal word (CLP) : Danger
Contains : diphenylmethane diisocyanate, isomers and homologues
Hazard statements (CLP) : H222 - Extremely flammable aerosol.
H229 - Pressurised container: May burst if heated.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 - May cause respiratory irritation.
H351 - Suspected of causing cancer.
H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements (CLP) : P101 - If medical advice is needed, have product container or label at hand.
P102 - Keep out of reach of children.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P211 - Do not spray on an open flame or other ignition source.
P251 - Do not pierce or burn, even after use.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P405 - Store locked up.
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
Extra phrases : Persons already sensitised to diisocyanates may develop allergic reactions when using this
product.
Persons suffering from asthma, eczema or skin problems should avoid contact, including
dermal contact, with this product.
This product should not be used under conditions of poor ventilation unless a protective
mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
As from 24 August 2023 adequate training is required before industrial or professional use.

2.3. Other hazards

The product does not meet the PBT and vPvB classification criteria

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

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Soudafoam FR HY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

3.2. Mixtures

Name Product identifier % Classification according to

Regulation (EC) No.
1272/2008 [CLP]
polymethylene polyphenyl isocyanate (CAS-No.) 9016-87-9 ≥ 25 – < 50 Carc. 2, H351
substance with national workplace exposure limit(s) Resp. Sens. 1, H334
(GB) Skin Sens. 1, H317
Acute Tox. 4 (Inhalation), H332
STOT RE 2, H373
Skin Irrit. 2, H315
Eye Irrit. 2, H319
STOT SE 3, H335

reaction products of phosphoryl trichloride and 2- (CAS-No.) 1244733-77-4 ≥ 10 – < 25 Acute Tox. 4 (Oral), H302
methyloxirane (EC-No.) 807-935-0
(REACH-no) 01-2119486772-26

dimethyl ether (CAS-No.) 115-10-6 ≥ 10 – < 25 Flam. Gas 1A, H220

(Propellant gas (aerosol)) (EC-No.) 204-065-8 Press. Gas (Liq.), H280
(EC Index-No.) 603-019-00-8
(REACH-no) 01-2119472128-37

isobutane (CAS-No.) 75-28-5 ≥ 5 – < 10 Flam. Gas 1A, H220

(Propellant gas (aerosol)) (EC-No.) 200-857-2 Press. Gas (Liq.), H280
(EC Index-No.) 601-004-00-0
(REACH-no) 01-2119485395-27

propane (CAS-No.) 74-98-6 ≥1–<5 Flam. Gas 1A, H220

(Propellant gas (aerosol)) (EC-No.) 200-827-9 Press. Gas (Liq.), H280
(EC Index-No.) 601-003-00-5
(REACH-no) 01-2119486944-21

Comments : polymethylene polyphenyl isocyanate, contains > 0.1% MDI isomers

Product subject to CLP Article 1.1.3.7. The disclosure rules of the components is modified in this case.
Full text of H- and EUH-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : IF exposed or concerned: Get medical advice/attention. Call a poison center or a doctor if
you feel unwell.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a
doctor if you feel unwell.
First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash
occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

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Soudafoam FR HY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : None known.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Extremely flammable aerosol.
Explosion hazard : Pressurised container: May burst if heated.
Hazardous decomposition products in case of fire : Toxic fumes may be released.

5.3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Do not breathe
dust/fume/gas/mist/vapours/spray. Avoid contact with skin and eyes.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Leave the product to solidify. Mechanically recover the product. Shovel or sweep up and put
in a closed container for disposal. Notify authorities if product enters sewers or public
waters. Wash clothing and equipment after handling. Dispose of the material collected
according to regulations.
Other information : Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn,
even after use. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Wear personal protective equipment. Do not
breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area.
Avoid contact with skin and eyes.
Hygiene measures : Wash contaminated clothing before reuse. Contaminated work clothing should not be
allowed out of the workplace. Do not eat, drink or smoke when using this product. Always
wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Store locked
up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.

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Soudafoam FR HY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Incompatible products : Heat sources. Ignition sources. Strong bases. Strong acids.
Maximum storage period : 1 year
Packaging materials : aerosol.

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.1.1 National occupational exposure and biological limit values

polymethylene polyphenyl isocyanate (9016-87-9)

United Kingdom - Occupational Exposure Limits
WEL TWA (OEL TWA) [1] 0,02 mg/m³

WEL STEL (OEL STEL) 0,07 mg/m³

dimethyl ether (115-10-6)

EU - Indicative Occupational Exposure Limit (IOEL)
Local name Dimethylether

IOEL TWA 1920 mg/m³

IOEL TWA [ppm] 1000 ppm

Regulatory reference COMMISSION DIRECTIVE 2000/39/EC

United Kingdom - Occupational Exposure Limits

Local name Dimethyl ether

WEL TWA (OEL TWA) [1] 766 mg/m³

WEL TWA (OEL TWA) [2] 400 ppm

WEL STEL (OEL STEL) 958 mg/m³

WEL STEL (OEL STEL) [ppm] 500 ppm

Regulatory reference EH40/2005 (Fourth edition, 2020). HSE

8.1.2. Recommended monitoring procedures

No additional information available

8.1.3. Air contaminants formed

No additional information available

8.1.4. DNEL and PNEC

reaction products of phosphoryl trichloride and 2-methyloxirane (1244733-77-4)

DNEL/DMEL (Workers)
Acute - systemic effects, inhalation 22,6 mg/m³

Long-term - systemic effects, dermal 2,91 mg/kg bodyweight/day

Long-term - systemic effects, inhalation 8,2 mg/m³

DNEL/DMEL (General population)

Acute - systemic effects, inhalation 5,6 mg/m³

Acute - systemic effects, oral 2 mg/kg bodyweight

Long-term - systemic effects,oral 0,52 mg/kg bodyweight/day

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Soudafoam FR HY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Long-term - systemic effects, inhalation 1,45 mg/m³

Long-term - systemic effects, dermal 1,04 mg/kg bodyweight/day

PNEC (Water)
PNEC aqua (freshwater) 0,32 mg/l

PNEC aqua (marine water) 0,032 mg/l

PNEC aqua (intermittent, freshwater) 0,51 mg/l

PNEC (Sediment)
PNEC sediment (freshwater) 11,5 mg/kg dwt

PNEC sediment (marine water) 1,15 mg/kg dwt

PNEC (Soil)
PNEC soil 0,34 mg/kg dwt

PNEC (Oral)
PNEC oral (secondary poisoning) 11,6 mg/kg food

PNEC (STP)
PNEC sewage treatment plant 19,1 mg/l

8.1.5. Control banding

No additional information available

8.2. Exposure controls

8.2.1. Appropriate engineering controls

Appropriate engineering controls:

Ensure good ventilation of the work station.

8.2.2. Personal protection equipment

Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection

Eye protection:

Safety glasses

8.2.2.2. Skin protection

Skin and body protection:

Wear suitable protective clothing

Hand protection:

Protective gloves

8.2.2.3. Respiratory protection

Respiratory protection:

[In case of inadequate ventilation] wear respiratory protection.

8.2.2.4. Thermal hazards

No additional information available

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Soudafoam FR HY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

8.2.3. Environmental exposure controls

Environmental exposure controls:

Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid
Appearance : aerosol.
Colour : Variable.
Odour : characteristic.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Extremely flammable aerosol.
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : 1,041 (20°C)
Density : 1041 kg/m³ (20°C)
Solubility : No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : Pressurised container: May burst if heated.
Oxidising properties : No data available
Explosive limits : No data available

9.2. Other information

VOC content : 17,88 – 18,72 % (186.10 g/l - 194.83 g/l)

SECTION 10: Stability and reactivity

10.1. Reactivity
Extremely flammable aerosol. Pressurised container: May burst if heated.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

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Soudafoam FR HY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.

Soudafoam FR HY
ATE CLP (dust,mist) 3,296 mg/l/4h

polymethylene polyphenyl isocyanate (9016-87-9)

LD50 oral rat > 10000 mg/kg (Rat, Literature study, Oral)

LD50 dermal rabbit > 5000 mg/kg (Rabbit, Literature study, Dermal)

isobutane (75-28-5)
LC50 Inhalation - Rat [ppm] > 800000 ppm (15 minutes, Rat, Male / female, Experimental value, Inhalation (gases))

dimethyl ether (115-10-6)

LC50 Inhalation - Rat [ppm] 164000 ppm (4 h, Rat, Male, Experimental value, Inhalation (gases), 14 day(s))

propane (74-98-6)
LC50 Inhalation - Rat [ppm] > 800000 ppm (15 minutes, Rat, Male / female, Experimental value, Inhalation (gases))

reaction products of phosphoryl trichloride and 2-methyloxirane (1244733-77-4)

LD50 oral rat 632 mg/kg

LD50 dermal rat > 2000 mg/kg

LC50 Inhalation - Rat > 7 mg/l/4h

Skin corrosion/irritation : Causes skin irritation.

Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.

polymethylene polyphenyl isocyanate (9016-87-9)

IARC group 3 - Not classifiable

Reproductive toxicity : Not classified

STOT-single exposure : May cause respiratory irritation.

polymethylene polyphenyl isocyanate (9016-87-9)

STOT-single exposure May cause respiratory irritation.

STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure.

polymethylene polyphenyl isocyanate (9016-87-9)

STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure (if inhaled).

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Aspiration hazard : Not classified

Soudafoam FR HY
Vaporizer aerosol

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
Hazardous to the aquatic environment, short-term : Not classified
(acute)
Hazardous to the aquatic environment, long-term : Not classified
(chronic)
Not rapidly degradable

polymethylene polyphenyl isocyanate (9016-87-9)

LC50 - Other aquatic organisms [1] > 1000 mg/l (96 h, Literature study)

isobutane (75-28-5)
LC50 - Fish [1] 27,98 mg/l (ECOSAR v1.00, 96 h, Pisces, Fresh water, QSAR)

EC50 96h - Algae [1] 8,57 mg/l (ECOSAR v1.00, Algae, Fresh water, QSAR)

dimethyl ether (115-10-6)

LC50 - Fish [1] > 4100 mg/l (NEN 6504: Water - Determination of toxicity with Poecilia reticulata, 96 h,
Poecilia reticulata, Semi-static system, Fresh water, Experimental value, Lethal)

EC50 - Crustacea [1] > 4400 mg/l (NEN 6501: Water - Determination of toxicity with Daphnia magna, 48 h,
Daphnia magna, Static system, Fresh water, Experimental value, Lethal)

EC50 96h - Algae [1] 154,9 mg/l (ECOSAR v1.00, Algae, QSAR)

propane (74-98-6)
LC50 - Fish [1] 49,9 mg/l (96 h, Pisces, Fresh water, QSAR, Estimated value)

EC50 96h - Algae [1] 11,89 mg/l (ECOSAR v1.00, Algae, Fresh water, QSAR)

reaction products of phosphoryl trichloride and 2-methyloxirane (1244733-77-4)

LC50 - Fish [1] 51 mg/l Pimephalis promelas

EC50 - Crustacea [1] 131 mg/l Daphnia magna

EC50 72h - Algae [1] 82 mg/l Pseudokirchnerella subcapitata

NOEC chronic crustacea 32 mg/l

NOEC chronic algae 13 mg/l

12.2. Persistence and degradability

polymethylene polyphenyl isocyanate (9016-87-9)

Persistence and degradability not readily degradable in water.

isobutane (75-28-5)
Persistence and degradability Readily biodegradable in water.

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

dimethyl ether (115-10-6)

Persistence and degradability not readily degradable in water.

propane (74-98-6)
Persistence and degradability Readily biodegradable in water.

reaction products of phosphoryl trichloride and 2-methyloxirane (1244733-77-4)

Persistence and degradability not readily degradable in water.

Biodegradation 14 % OECD 301E

12.3. Bioaccumulative potential

polymethylene polyphenyl isocyanate (9016-87-9)

BCF - Fish [1] 1 (Pisces, Literature study)

Partition coefficient n-octanol/water (Log Pow) 10,46 (Calculated, KOWWIN)

Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

isobutane (75-28-5)
Partition coefficient n-octanol/water (Log Pow) 1,09 – 2,8 (Experimental value, 20 °C)

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

dimethyl ether (115-10-6)

Partition coefficient n-octanol/water (Log Pow) 0,1 (Experimental value)

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

propane (74-98-6)
Partition coefficient n-octanol/water (Log Pow) 1,09 – 2,8 (Experimental value, 20 °C)

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

reaction products of phosphoryl trichloride and 2-methyloxirane (1244733-77-4)

BCF - Fish [1] 0,8 – 14

Partition coefficient n-octanol/water (Log Pow) 2,68

12.4. Mobility in soil

polymethylene polyphenyl isocyanate (9016-87-9)

Organic Carbon Normalized Adsorption Coefficient 9,078 – 10,597 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
(Log Koc)

Ecology - soil Product adsorbs onto the soil.

reaction products of phosphoryl trichloride and 2-methyloxirane (1244733-77-4)

Organic Carbon Normalized Adsorption Coefficient 2,24
(Log Koc)

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

12.5. Results of PBT and vPvB assessment

Soudafoam FR HY
The product does not meet the PBT and vPvB classification criteria

Component
polymethylene polyphenyl isocyanate (9016-87-9) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

dimethyl ether (115-10-6) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

isobutane (75-28-5) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

propane (74-98-6) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Sewage disposal recommendations : Do not discharge into drains or the environment.
Additional information : Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No
1357/2014 and Regulation (EU) No 2017/997.
Ecology - waste materials : Avoid release to the environment.
European List of Waste (LoW) code : 08 05 01* - waste isocyanates
16 05 04* - gases in pressure containers (including halons) containing dangerous
substances
15 01 10* - packaging containing residues of or contaminated by dangerous substances

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / ADN / RID
ADR IMDG IATA ADN RID

14.1. UN number
UN 1950 UN 1950 UN 1950 UN 1950 UN 1950

14.2. UN proper shipping name

AEROSOLS AEROSOLS Aerosols, flammable AEROSOLS AEROSOLS

Transport document description

UN 1950 AEROSOLS, 2.1, UN 1950 AEROSOLS, 2.1 UN 1950 Aerosols, UN 1950 AEROSOLS, 2.1 UN 1950 AEROSOLS, 2.1
(D) flammable, 2.1

14.3. Transport hazard class(es)

2.1 2.1 2.1 2.1 2.1

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according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

14.4. Packing group

Not applicable Not applicable Not applicable Not applicable Not applicable

14.5. Environmental hazards

Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment : No environment : No environment : No environment : No environment : No
Marine pollutant : No

No supplementary information available

14.6. Special precautions for user

Overland transport
Classification code (ADR) : 5F
Special provisions (ADR) : 190, 327, 344, 625
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P207, LP200
Special packing provisions (ADR) : PP87, RR6, L2
Mixed packing provisions (ADR) : MP9
Transport category (ADR) : 2
Special provisions for carriage - Packages (ADR) : V14
Special provisions for carriage - Loading, unloading : CV9, CV12
and handling (ADR)
Special provisions for carriage - Operation (ADR) : S2
Tunnel restriction code (ADR) : D
Transport by sea
Special provisions (IMDG) : 63, 190, 277, 327, 344, 381, 959
Packing instructions (IMDG) : P207, LP200
Special packing provisions (IMDG) : PP87, L2
EmS-No. (Fire) : F-D
EmS-No. (Spillage) : S-U
Stowage category (IMDG) : None
Stowage and handling (IMDG) : SW1, SW22
Segregation (IMDG) : SG69
Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Y203
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 203
PCA max net quantity (IATA) : 75kg
CAO packing instructions (IATA) : 203
CAO max net quantity (IATA) : 150kg
Special provisions (IATA) : A145, A167, A802
ERG code (IATA) : 10L
Inland waterway transport
Classification code (ADN) : 5F
Special provisions (ADN) : 190, 327, 344, 625
Limited quantities (ADN) : 1L
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01, VE04
Number of blue cones/lights (ADN) : 1
Rail transport
Classification code (RID) : 5F
Special provisions (RID) : 190, 327, 344, 625
Limited quantities (RID) : 1L
Excepted quantities (RID) : E0
Packing instructions (RID) : P207, LP200
Special packing provisions (RID) : PP87, RR6, L2
Mixed packing provisions (RID) : MP9
Transport category (RID) : 2

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Special provisions for carriage – Packages (RID) : W14

Special provisions for carriage - Loading, unloading : CW9, CW12
and handling (RID)
Colis express (express parcels) (RID) : CE2
Hazard identification number (RID) : 23

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export
and import of hazardous chemicals.
Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent
organic pollutants

VOC content : 17,88 – 18,72 % (186.10 g/l - 194.83 g/l)

15.1.2. National regulations

No additional information available

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Indication of changes:

Section Changed item Change Comments

according to Regulation (EC) No.
1907/2006 (REACH) with its
amendment Regulation (EU)
2020/878

Abbreviations and acronyms:

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

ATE Acute Toxicity Estimate

BCF Bioconcentration factor

BLV Biological limit value

BOD Biochemical oxygen demand (BOD)

COD Chemical oxygen demand (COD)

DMEL Derived Minimal Effect level

DNEL Derived-No Effect Level

EC-No. European Community number

EC50 Median effective concentration

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

EN European Standard

IARC International Agency for Research on Cancer

IATA International Air Transport Association

IMDG International Maritime Dangerous Goods

LC50 Median lethal concentration

LD50 Median lethal dose

LOAEL Lowest Observed Adverse Effect Level

NOAEC No-Observed Adverse Effect Concentration

NOAEL No-Observed Adverse Effect Level

NOEC No-Observed Effect Concentration

OECD Organisation for Economic Co-operation and Development

OEL Occupational Exposure Limit

PBT Persistent Bioaccumulative Toxic

PNEC Predicted No-Effect Concentration

RID Regulations concerning the International Carriage of Dangerous Goods by Rail

SDS Safety Data Sheet

STP Sewage treatment plant

ThOD Theoretical oxygen demand (ThOD)

TLM Median Tolerance Limit

VOC Volatile Organic Compounds

CAS-No. Chemical Abstract Service number

N.O.S. Not Otherwise Specified

vPvB Very Persistent and Very Bioaccumulative

ED Endocrine disrupting properties

Full text of H- and EUH-statements:

Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4

Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4

Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4

Aerosol 1 Aerosol, Category 1

Carc. 2 Carcinogenicity, Category 2

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2

Flam. Gas 1A Flammable gases, Category 1A

H220 Extremely flammable gas.

H222 Extremely flammable aerosol.

H229 Pressurised container: May burst if heated.

H280 Contains gas under pressure; may explode if heated.

H302 Harmful if swallowed.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

H319 Causes serious eye irritation.

H332 Harmful if inhaled.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H335 May cause respiratory irritation.

H351 Suspected of causing cancer.

H373 May cause damage to organs through prolonged or repeated exposure.

Press. Gas (Liq.) Gases under pressure : Liquefied gas

Resp. Sens. 1 Respiratory sensitisation, Category 1

Skin Irrit. 2 Skin corrosion/irritation, Category 2

Skin Sens. 1 Skin sensitisation, Category 1

STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2

STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:

Aerosol 1 H222;H229 On basis of test data

Acute Tox. 4 (Inhalation:dust,mist) H332 Calculation method

Skin Irrit. 2 H315 Calculation method

Eye Irrit. 2 H319 Calculation method

Resp. Sens. 1 H334 Calculation method

Skin Sens. 1 H317 Calculation method

Carc. 2 H351 Calculation method

STOT SE 3 H335 Calculation method

STOT RE 2 H373 Calculation method

Safety Data Sheet (SDS), EU-2020

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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