INORGANIC CHEMISTRY : V.K.

JAISWAL(VKJ SIR)

ASSIGNMENT-3
Single Choice Questions :

1. The correct set of four quantum numbers for the valence electron of rubidium (Z = 37) is

(A) n = 5,  = 0, m = 0, s = + 1/2 (B) n = 5, = 1, m = 0, s = + 1/2

(C) n = 5, = 1, m = 1, s = + 1/2 (D) n = 6, = 0, m = 0, s = + 1/2

2. Magnetic moment of V (Z = 23), Cr (Z = 24) and Mn (Z = 25) and x, y and z respectively. Then

(A) x = y = z (B) x < y < z (C) x < z < y (D) z < y < x

3. Magnetic moment of Mx+ (Z = 26) is 24 B.M. Hence the number of unpaired electrons and value of x

respectively are

4.
VIBRANT ACADEMY
(A) 4, 2 (B) 2, 4 (C) 3, 1 (D) 0, 2

Find correct set of quantum numbers of n, , m, ms for last electron of element (atomic number 89)

1 1 1 1
(A) 4, 3, 0, + (B) 5, 3, 0, + (C) 6, 2, 0, + (D) 7, 0, 0, +
2 2 2 2

5. For a d-electron, the orbital angular momentum is

h h h h
6 2 12

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(A) (B) (C) (D)
2 2 2 2
6. Which of the following statements is not correct for an electron that has the quantum numbers n = 4 and
m = 2?

(A) The electron may have the quantum number s = +1/2

(B) The electron may have the quantum number = 2

(C) The electron may have the quantum number = 3

(D) The electron may have the quantum number = 0, 1, 2, 3

7. If each orbital can hold a maximum of 3 electrons, number of elements in fourth period of periodic table is
(A) 48 (B) 54 (C) 27 (D) 36

8. If Aufbau rule is not followed, 19th electron in Fe (Z = 26) will have

(A) n = 3,  = 0 (B) n = 3, = 1 (C) n = 3, = 2 (D) n = 4, = 0

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9. Consider these ions : (1) Ni2+ (2) Co2+ (3) Cr2+ (4) Fe3+

(atomic numbers : Cr = 24, Fe = 26, Co = 27, Ni = 28)

The correct sequence of the increasing order of the number of unpaired electrons in these ions is

(A) 1, 2, 3, 4 (B) 4, 2, 3, 1 (C) 1, 3, 2, 4 (D) 3, 4, 2, 1

10. In transition elements, the incoming electron occupies (n - 1)d subshell in preference to

(A) np - subshell (B) ns - subshell (C) (n – 1) p - subshell (D) (n + 1) s - subshell

11. Which shape is associated with the orbital designated by n = 2,  = 1.

(A) Spherical (B) Tetrahedral (C) Dumbell (D) Pyramidal

12. Which of the following rule could explain the presence of three unpaired electrons in phosphorus atom.
(A) Hund's rule (B) Pauli’s exclusion principle
(C) Heisenberg's uncertainty principle (D) None of these
13. The maximum energy is present in any electron at :
(A) Nucleus (B) Ground State
(C) First excited state (D) Infinite distance from the nucleus

14. VIBRANT ACADEMY

Electrons represented by quantum numbers

(i) n = 4,  = 1 (ii) n = 4,  = 0 , (iii) n = 3,  = 2 (iv) n = 3,  = 1

are placed in order of increasing energy level as

(A) iv < ii < iii < i (B) ii < iv < i < iii (C) i < iii < ii < iv (D) iii < i < iv < ii

The set of quantum number, n = 3  = 1 m = 0

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15.
(A) describes an electron in a 2s-orbital
(B) describes an electron in one of the three degenerate orbitals
(C) describes an electron in one of the five degenerate orbitals
(D) it is not permissible

Match the column :

16. Column-I Column-II

(A) Orbital angular momentum (P) Unpaired electrons

(B) Stark and zeeman effect (Q) Azimuthal quantum Number

(C) Magnetic moment (R) Magnetic quantum number

(S) Spin quantum number

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT-4
Single Choice Questions :
1. In 2s and 2p orbitals of an element, five electrons a, b, x, y and z are filled such that the spins of a, x and z
are same, whereas spins of y and z are opposite to the spin of b. Which sets of electrons will have three
identical quantum numbers?

ab x y z
2s2 2p3
(A) ax, by, byz (B) ab, yz (C) ab only (D) ax, by, xz
2. The maximum probability of finding electrons in dxy orbitals is
(A) along with X and Y axis (B) along Y and Z axis

(C) along with Y and Z axis (D) at an angle of
with X axis
4
3. What is the atomic number of the element with the maximum number of unpaired 4p electrons.
(A) 33 (B) 26 (C) 23 (D) 15

4.

5.
VIBRANT ACADEMY
Which of the given sub-shells will follow relationship n +  = 7
(A) 7s, 6p, 5d, 4f (B) 7s, 6p, 3d, 4f (C) 7s, 5d, 5f, 5p (D) 6s, 4f, 3d, 7p
The total number of subshells in terms of (n + ) level between 7s and 8p orbitals are :
(A) 3 (B) 5 (C) 7 (D) None of these

6. Which of the following electronic configuration does not satisfy all given conditions
(i) The principle quantum number for valence electron is 5.
(ii) The value of spin magnetic moment is 2.83 B.M.
(iii) One electron which has n = 5,  = 0, m = 0
(iv) Paramgnetic atom of element

7.
(A) [Kr] 4d2 5s2
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(B) [Kr] 4d8 5s2 (C) [Kr] 4d10 5s2 5p2

The sum of all the quantum numbers of hydrogen atom is :

1 3
(D) [Kr] 4d10 5s2 5p3

(A) –1 (B) 0 (C) + (D)

2 2
8. Statement-1 : d 2 -orbital is gerade oribtal
z
Statement-2 : d z2 -orbital does not have four lobes like other d-orbitals.
(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true and Statement-2 is NOT correct explanation for Statement-1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true
Multiple Choice Type :
9. Which of the following statement(s) is/are wrong?
(A) If the value of  = 0, the electron dstribution is spherical
(B) The shape of the orbital is given by magnetic quantum number
(C) Orbital angular momentum of 1s, 2s, 3s electrons are equal
(D) In an atom, all electrons travel with the same velocity

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10. There are three elements A, B and C. Their atomic number are Z1, Z2 and Z3 respectively. if Z1 – Z2 = 2 and
z1  z2
= z3 – 2 and the electronic configuration of element A is [Ar] 3d6 4s2, then correct order of magnatic
2
moment is/are
(A) B+ > A2+ > C2+ (B) A3+ > B2+ > C (C) B > A > C2+ (D) B = A3+ > C3+

11. The electronic configuration of an element is

1s2 2s2 2p6 3s2 3p3
The atomic number of the element which is just below the given element in the vertical column in the periodic
table is
(A) 49 (B) 47 (C) 23 (D) 33

Comprehension (Q.12 to Q.14)

The four quantum numbers define completely the position of an electron in an atom. They give its position in
major energy level (n), sub-energy level (), orientation in the sub-energy level (m) and the direction of the
spin (s). It is thus possible to identify an electron in an atom completely by stating the values of its four
quantum numbers. They serve as an 'address' for the electron. According to "Pauli's exclusion principle" It is
impossible for any two electrons in the same atom to have all the four quantum numbers identical.
12. Which of the following statement is incorrect.
(A) Azimuthal quantum number also known as angular momentum quantum number
(B) The principal quantum number determines to a large extent of the energy of electron

13.
VIBRANT ACADEMY
(C) Orbitals in a given energy sublevel within a principal energy level is represented by azimuthal quantum number.
(D) The spin quantum number does not follow wave mechanical model treatment.
The value of four quantum numbers for any electron of element 'X' are 4, 3, –2, –1/2 then incorrect statement
regarding element 'X' is -
(A) Element 'X' may be belongs to Lanthanoids series.
(B) Element 'X' may be belongs to Actinoids series
(C) Element 'X' may be belongs to 2nd transition series.
(D) Element 'X' may be belongs to 3rd transition series.
14. Which quantum number(s) can same for 19th and 23th electrons of cadmium (z = 48).
(A) , m and s

Match the column :

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(B) s only (C) n, , m and s (D) m and s

15. Column I Column II

Elements (Electrons in K, L, M, N....) Statements
(A) W (2, 8, 7) (P) Paramagnetic
(B) X (2, 8, 18, 8) (Q) 3rd group element
(C) Y (2, 8, 14, 2) (R) last electron does not enter to valence shell
(D) Z (2, 8, 18, 25, 8, 2) (S) Reactive non-metal
(T) Diamagnetic

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 ANSWER KEY
ASSIGNMENT-3
1. A 2. C 3. A 4. C 5. A 6. D 7. C

8. C 9. A 10. A 11. C 12. A 13. D 14. A

15. B 16. A–Q ; B–R ; C–P

ASSIGNMENT-4
1. B 2. D 3. A 4. A 5. C 6. D 7. D
8. B 9. BD 10. ABC 11. D 12. C 13. C 14. D
15. A  P,S ; B  T ; C  P,R ; D P,Q,R ;

VIBRANT ACADEMY

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