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SAFETY DATA SHEET

Creation Date 08-Jan-2015 Revision Date 08-Jan-2015 Revision Number 1

1. Identification
Product Name Copper
Cat No. : C3140, C3150, C3180, C3200, C3210, C3220
Synonyms None.

Recommended Use Laboratory chemicals.

Uses advised against No Information available

Details of the supplier of the safety data sheet

Company
Lab Alley LLC
22111 Highway 71 West, Suite 601
Spicewood, Texas 78669
Tel. 512-668-9918

2. Hazard(s) identification
Classification
Classification under 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Based on available data, the classification criteria are not met

Label Elements
None required

Hazards not otherwise classified (HNOC)

None identified

3. Composition / information on ingredients

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Component CAS-No Weight %

Copper 7440-50-8 100

4. First-aid measures
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Obtain medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if
symptoms occur.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. Get medical attention if symptoms
occur.

Ingestion Do not induce vomiting. Obtain medical attention.

Most important symptoms/effects No information available.

Notes to Physician Treat symptomatically

5. Fire-fighting measures
Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.

Unsuitable Extinguishing Media No information available

Flash Point Not applicable

Method - No information available

Autoignition Temperature No information available

Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available

Specific Hazards Arising from the Chemical

Non-combustible. Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container
away from heat and sources of ignition.

Hazardous Combustion Products

Copper oxides
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

NFPA
Health Flammability Instability Physical hazards
1 0 0 N/A

6. Accidental release measures

Personal Precautions Use personal protective equipment. Ensure adequate ventilation. Avoid contact with skin,
eyes and clothing.
Environmental Precautions Avoid release to the environment. See Section 12 for additional ecological information.

Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal.
Up

7. Handling and storage

Handling Wear personal protective equipment. Ensure adequate ventilation. Avoid contact with skin,
eyes and clothing. Avoid ingestion and inhalation.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place.
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8. Exposure controls / personal protection

Exposure Guidelines

Component ACGIH TLV OSHA PEL NIOSH IDLH

Copper TWA: 0.2 mg/m3 TWA: 1 mg/m3 (Vacated) TWA: 0.1 mg/m3 IDLH: 100 mg/m3
TWA: 0.1 mg/m3 TWA: 1 mg/m3
TWA: 1 mg/m3 TWA: 0.1 mg/m3

Component Quebec Mexico OEL (TWA) Ontario TWAEV

Copper TWA: 0.2 mg/m3 TWA: 0.2 mg/m3 TWA: 0.2 mg/m3
TWA: 1 mg/m3 TWA: 1 mg/m3 TWA: 1 mg/m3
STEL: 2 mg/m3
Legend

ACGIH - American Conference of Governmental Industrial Hygienists

OSHA - Occupational Safety and Health Administration
NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations
and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties

Physical State Solid
Appearance Red brown
Odor Odorless
Odor Threshold No information available
pH No information available
Melting Point/Range 1083 °C / 1981.4 °F
Boiling Point/Range 2595 °C / 4703 °F
Flash Point Not applicable
Evaporation Rate No information available
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure 1 mmHg @ 1628 °C
Vapor Density No information available
Relative Density 8.92
Solubility Insoluble in water
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity No information available
Molecular Formula Cu
Molecular Weight 63.54

10. Stability and reactivity

Reactive Hazard None known, based on information available

Stability Stable under normal conditions.

Conditions to Avoid Incompatible products. Excess heat.

Incompatible Materials Strong oxidizing agents

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Hazardous Decomposition Products Copper oxides

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

11. Toxicological information

Acute Toxicity

Product Information No acute toxicity information is available for this product

Component Information
Toxicologically Synergistic No information available
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation No information available

Sensitization No information available

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS-No IARC NTP ACGIH OSHA Mexico

Copper 7440-50-8 Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

Teratogenicity No information available.

STOT - single exposure None known

STOT - repeated exposure None known

Aspiration hazard No information available

Symptoms / effects,both acute and No information available

delayed

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated.

12. Ecological information

Ecotoxicity
This product contains the following substance(s) which are hazardous for the environment.

Component Freshwater Algae Freshwater Fish Microtox Water Flea

Copper 0.031 - 0.054 mg/L EC50 96 0.112 mg/L LC50 96 h 0.8 Not listed 0.03 mg/L EC50 = 48 h
h 0.0426 - 0.0535 mg/L mg/L LC50 96 h 0.3 mg/L
EC50 72 h LC50 96 h 1.25 mg/L LC50
96 h 0.052 mg/L LC50 96 h
0.2 mg/L LC50 96 h 0.0068 -
0.0156 mg/L LC50 96 h
Persistence and Degradability No information available

Bioaccumulation/ Accumulation No information available.

Mobility No information available.

13. Disposal considerations

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Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.

14. Transport information

DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG/IMO Not regulated
15. Regulatory information
All of the components in the product are on the following Inventory lists: Australia X = listed China Canada The product is
classified and labeled according to EC directives or corresponding national laws The product is classified and labeled in
accordance with Directive 1999/45/EC Europe TSCA Korea Philippines

International Inventories

Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL
Copper X X - 231-159-6 - X - X X X
Legend:
X - Listed
E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated
polymer made with any free-radical initiator regardless of the amount used.
P - Indicates a commenced PMN substance
R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S - Indicates a substance that is identified in a proposed or final Significant New Use Rule
T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants
that comprises one of the eligibility criteria for the exemption rule.

U.S. Federal Regulations

TSCA 12(b) Not applicable

SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values %
Copper 7440-50-8 100 1.0

SARA 311/312 Hazardous Categorization

Acute Health Hazard No
Chronic Health Hazard No
Fire Hazard No
Sudden Release of Pressure Hazard No
Reactive Hazard No

Clean Water Act

Component CWA - Hazardous CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants
Substances Quantities
Copper - - X X

Clean Air Act Not applicable

OSHA Occupational Safety and Health Administration

Not applicable

CERCLA

Component Hazardous Substances RQs CERCLA EHS RQs

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Copper 5000 lb -
California Proposition 65 This product does not contain any Proposition 65 chemicals

State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Copper X X X X X

U.S. Department of Transportation

Reportable Quantity (RQ): N

DOT Marine Pollutant N
DOT Severe Marine Pollutant N

U.S. Department of Homeland Security

This product does not contain any DHS chemicals.

Other International Regulations

Mexico - Grade No information available

Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR

WHMIS Hazard Class Non-controlled

16. Other information

Prepared By Regulatory Affairs
Lab Alley LLC
Email: [email protected]

Creation Date 08-Jan-2015

Revision Date 08-Jan-2015
Print Date 08-Jan-2015
Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS)

Disclaimer
The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.

End of SDS