SECTION 1.
Chemical Product and Company Information
Product Identifier
Product : HALOGEN 2.5EC
Common Name : Lambdacyhalothrin 2.5EC
Relevant identified uses of the substance and uses advised against
Product Use : Pyrethroid Insecticide
Details of the supplier of the Safety Data Sheet
Manufacturer : Iprochem (Tianmen) Co., Ltd.
SECTION 2. Hazards Identification
Classification of the substance or mixture
Acute Toxicity – Oral – Category 4
Acute Toxicity – Dermal – Category 5
Acute Toxicity – Inhalation – Category 4
Serious eye Damage/ Eye irritation – Category 1
Specific Target Organ Toxicity Single exposure – Category 3 (CNS, Respiratory tract irritation,
Lung)
Specific Target Organ Toxicity Single exposure – Category 1 (Lung)
Specific Target Organ Toxicity Repeated exposure – Category 1 (CNS)
Carcinogenicity – Category 2
Hazardous to the Aquatic Environment Short term/ Acute – Category 1
Hazardous to the Aquatic Environment Long term/ Chronic – Category 1
Flammable Liquid – Category 3
Aspiration Hazard – Category 1
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Label elements
Pictogram:
Signal word: DANGER!
Hazard Statements:
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H313 May be harmful if in contact with skin.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory tract irritation.
H336 May cause drowsiness and dizziness.
H351 Suspected of causing cancer
H370 Causes damage to lungs
H372 Causes damage to nervous system through prolonged or repeated
exposure.
H410 +411 Very toxic to aquatic life with long lasting effects
Precautionary Statements:
P203 Obtain, read and follow all safety instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P235 Keep cool.
P260 Do not breathe vapors.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271 Use in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
P301 + P312 IF SWALLOWED: Call a poison center o doctor/physician if you feel unwell.
P330 Rinse mouth.
P331 Do not induce vomiting.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in position
comfortable for breathing.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P302 + P352 IF ON SKIN: Gently wash with plenty of soap and water.
P308 + P316 If exposed or concerned: Get emergency medical help immediately.
P370 + P378 In case of fire, carbon dioxide, dry powder, or alcohol-resistant foam
for extinction.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container as hazardous waste to an approved waste
disposal plant.
Contains: SOLVENT NAPHTHA (PETROLEUM), HEAVY AROMATIC
Other Hazard Information:
PHYSICAL/CHEMICAL HAZARDS
Material can accumulate static charges which may cause an ignition. Material can release
vapours that readily form flammable mixtures.
SECTION 3. Composition/Information on Hazardous Ingredients
Chemical Name:
(S)-α-cyano-3-phenoxybenzyl (Z)-(1R,3R)-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-
dimethylcyclopropanecarboxylate
Chemical Family:
Pyrethroid
Chemical Class:
Insecticide
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Chemical Nature:
Emulsion Concentrate, Lambdacyhalothrin 25 g/L
Hazardous Components:
Name CAS. No. Concentration
Lambdacyhalothrin 91465-08-6 25 g/L
Solvent
N/A 875 g/L
Emulsifier
N/A 100 g/L
SECTION 4. First Aid Measures
Inhalation : Remove from further exposure. For those providing assistance, avoid
exposure to yourself or others. Use adequate respiratory protection. If
respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation
with a mechanical device.
Skin Contact : Remove all contaminated clothing; wash off exposed skin with plenty of
soap and water. Seek medical advice if there is more than trivial exposure.
Eye Contact : Flush immediately with plenty of water for at least 15 mins. Get medical
attention if irritation persists.
Ingestion : Wash out mouth. Give plenty of water or bland fluids to drink. Get medical
attention.
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Most important symptoms and effects, both acute and delayed
A single prolonged exposure may result in the material being absorbed in harmful amounts.
Emergency personnel should wear a self-contained breathing apparatus because noxious fumes
are under fire consition.
May cause irritation which may result in permanent impairment of vision. A single prolonged skin
exposure may result in the material being absorbed in harmful amounts.
Indication of any immediate medical attention and special treatment needed
NOTE TO PHYSICIAN
No specific antidote is known. If the patient is conscious and is known to have swallowed
deltamethrin, it may be useful to carry out gastric lavage. Activated charcoal may be useful in
reducing further adsorption of the compound. Symptomatic treatment and supportive therapy is
indicated.
SECTION 5. Firefighting Measures
Fire and Explosion
Flash Point : 43ºC
Extinguishing Media
Suitable:
Small fires: Carbon dioxide, dry chemical powders, regular foam and water spray.
Large fires: Water spray, fog, or regular foam. Move containers from fire area if you can do it
without risk. Dike fire control water for later disposal; do not scatter the material.
Water fog or fine spray is the preferred medium for large fires. Ensure that no spillage enters
drains or water courses.
Unsuitable:
Avoid straight streams of water.
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Special Hazards
The material does not burn. It is not explosive. Should the chemical be involved in a
general fire, ensure chemical protective clothing is used. It can produce toxic fumes.
Special Protective Equipment for Firefighters:
Wear positive-pressure, self-contained breathing apparatus and complete protective fire
fighting attire (includes helmet, coat, trousers, boots and gloves). Avoid contact with this material
during firefighting operations. If contact is likely, change to full chemical resistant firefighting
clothing with self-contained breathing apparatus.
Special Exposure Hazards in a Fire:
As for all organic materials, combustion may lead to hazardous oxides of carbon and other
toxic fumes.
SECTION 6. Accidental Release Measures
Personal Precautions
Avoid contact with spilled material. Warm or evacuate occupants in surrounding and
downwind areas if required, due to toxicity or flammability of the material.
For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for
organic vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be
used depending on the size of spill and potential level of exposure. If the exposure cannot be
completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is
recommended. Work gloves that are resistant to aromatic carbons are recommended. Note:
gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for
emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible.
Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of
chemical resistant, antistatic material is recommended.
Environmental precautions
This product contains pyrethroids which are toxic to fish and other aquatic invertebrates.
Do not allow spilled product or wash solution to enter sewages, drains, dams, creeks, or any other
waterways. Contaminated absorbent and wash water should be disposed of according to local,
state/provincial and federal/national regulations.
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Method for Containment
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable
absorbent material. if spill is too large or if absorbent material is not available, try to create a dike
to stop material spreading or going into drains or waterways. Sweep up and shovel or collect
recoverable product into labeled containers for recycling or salvage, and dispose of promptly.
After spills, wash area preventing runoff from entering drains. If a significantly quantity of material
enters drains, advise emergency services.
Method for Cleaning Up
Soak up with earth or other material. Rinse the polluted area with water and suitable
detergents. Collect waste water for treatment.
Spill/Leak procedure:
Notify safety personnel, isolate and ventilate the area, deny entry and stay upwind. Shut off all
ignition sources.
SECTION 7. Handling and Storage
Precautions for safe handling
Advice on safe handling : Relatively safe to handle. Handle all crop protection
chemicals with care and caution. Do not eat, drink, smoke or
go to the toilet with pesticide-contaminated hands.
Advice on general : Wash hands immediately after handling, if necessary, take a
occupational hygiene shower. Remove soiled clothing immediately and clean
thoroughly before using again.
Conditions for safe storage, including any incompatibilities
Sensitivity to Damp, Light
& Oxidation : Stable under atmospheric conditions when stored in close c
ontainers.
Special Storage
Requirements : The type of container used to store the material may affect
static accumulation and dissipation. Keep container closed.
Handle containers with care. Open slowly in order to control
possible pressure release. Store in a cool, well-ventilated
area.
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Incompatible Substances : Sensitive to alkalis. Unstable in methyl and ethyl alcohol
conditions
Suitable Containers/Packing : Tank Trucks; Drums; Barges; Tank Cars
Suitable Materials and Coatings
(Chemical Compatibility) : Carbon Steel; Stainless Steel; Polypropylene; Viton; Epoxy
Phenolic; Copper Bronze; Epoxy Amine Coatings; Monel;
Inorganic Zinc Coatings
Specific end uses Refer to the label and/or leaflet.
SECTION 8. Exposure Controls/ Personnel Protection
Exposure Controls
EXPOSURE LIMIT VALUES : None established
Engineering controls : It is essential to provide adequate ventilation. The measures
appropriate for a particular worksite depend on how this
material is used and on the extent of exposure. Ensure that
control systems are properly designed and maintained.
Comply with occupational safety, environmental, fire, and
other applicable regulations.
Personal protective equipment
If engineering controls and work practices are not effective in controlling exposure to this
material, then wear suitable personal protective equipment including approved protection.
Eye protection : Employee must wear splash-proof safety goggles and face-
shield to prevent contact with this substance. Emergency
eyewash Where there is any possibility that an employee’s
eyes may be exposed to this substance, the employer
should provide an eye wash fountain or appropriate
alternative within the immediate work area for emergency
use.
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Skin protection : Employee must wear appropriate chemical resistant
protective gloves to prevent contact with this substance. Use
gloves chemically resistant to this material e.g. butyl rubber,
when prolonged or repeated contact should occur. Wash
and dry hands.
Body protection : Employee must wear appropriate long-sleeved protective
(impervious) clothing and equipment to prevent repeated or
prolonged skin contact with the substance. Heavy duty
shoes must be worn. Clothing should be laundered
frequently.
Respiratory protection : Take prudent precautions to avoid breathing vapors or spray
mists of this product. Wear a NIOSH-approved organic vapor
respirator if this product will be confined to indoor use.
Where concentrations in air may exceed the limits described,
it is recommended to use a half-face filter mask to protect
from overexposure by inhalation. A type “A” filter material is
considered suitable for this product.
SECTION 9. Physical and Chemical Properties
Physical state : Liquid Color
: Yellowish Odor :
Characteristic pH :
4.0 – 7.0
Vapor pressure : Not available Density
: 0.88 – 0.90 g/mL Persistence Foaming :
≤15 mL after 1 minute
Emulsion stability : 0h Initial emulsification complete
0.5h cream, maximum 1ml
2h cream, maximum 2ml
Free oil: maximum trace
24h Re-emulsification, complete
24.5h cream: maximum 2ml
Free oil: maximum trace
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Corrosivity : Non-corrosive
Boiling point : Not available
Water solubility : Dispersed in water
Known Incompatibility : Lambda-cyhalothrin is incompatible with the formulation
product alkali.
SECTION 10. Stability and Reactivity
Chemical Stability
Stability: Stable under recommended storage and handling conditions (see section 7)
Possibility of hazardous reactions
No hazardous reactions when stored and handled according to prescribed instructions.
Polymerization will not occur.
Conditions to avoid
Contact with open flames, sparks, ignition sources, extremes of temperature, direct sunlight
Incompatible materials
Strong alkalis
Hazardous decomposition products
Combustion may lead to hazardous oxides of carbon and other toxic fumes.
SECTION 11. Toxicological Information
Information on toxicological effects
Acute oral toxicity : 500 mg/kg
Acute dermal toxicity : >2000 mg/kg
Acute inhalation toxicity : 1.51 mg/L air
Skin irritation (rabbit) : Not skin irritant
Eye irritation : Irreversible effects on rabbit eyes
Redness of conjunctivae ≤ 2.00, corneal opacity ≤1.66,
chemosis ≤ 1.66
Skin Sensitizer : Not classified.
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
Sub-chronic toxicity : (Lambda-cyhalothrin) 90 day toxicity in Rat
NOAEL: 2.5 mg/kg/day
Reproductive Toxicity : Not a reprotoxin.
Teratogenicity : Not teratogenic.
Mutagenicity : Non-mutagenic
Carcinogenicity : Suspected of causing cancer
Specific Target Organ
Toxicity Single exposure : Causes damage to lung. May cause respiratory tract irritation.
May cause drowsiness or dizziness.
Specific Target Organ
Toxicity Repeated exposure : Causes damage to nervous system through prolonged or
repeated exposure.
Aspiration Hazard : Aspiration into the lungs when swallowed or vomited
may be harmful.
SECTION 12. Ecological Information Toxicity
Eco- Acute Toxicity
Computed LC50 of mixture based on available data of the ingredients:
Fish : LC50 (96 h) Rainbow trout 0.00959 mg/l
Eco- Chronic
Computed NOEC 0.0000009 mg/l
Species: Aquatic invertebrates
SECTION 13. Disposal Considerations
Product : Controlled incineration. Incineration at high temperatures
(1000ºC) with sufficient residence time leads to
complete detoxification and destruction and is the most
environmentally acceptable method for disposal.
Packaging : Combustible containers should be disposed of
in specified landfill sites. Non-combustible containers must be
triple rinsed using the normal diluent at a volume equal to
approximately 10% of the drum’s capacity. Add the rinsing
mixture or use the recommended disposal methods.
Containers must be punctured and disposed of in specified
landfill areas.
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
SECTION 14. Transportation Information
IATA/ADR
Classified as Dangerous Goods for transport by air. UN
number : 3352
Proper shipping name : Pyrethroid Pesticide Liquid, toxic, (contains
Lambdacyhalothrin)
Transport Hazard Class : 6.1
Packing group : III
Environmentally : YES
Hazardous Mark
IMDG
UN number : 3352
Proper shipping name : Pyrethroid Pesticide Liquid, toxic, (contains
Lambdacyhalothrin)
Transport Hazard Class : 6.1
Packing group : III Marine
Pollutant : YES
SECTION 15. Regulatory Information
Complies with the following national/regional chemical inventory requirements: PICCS.
SECTION 16. Additional Information
MSDS Creation Date: 13/06/2018
The information above is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantability or any other warranty, express
or implied, with respect to such information, and we assume no liability resulting from its use.
Users should make their own investigations to determine the suitability of the information for their
particular purposes. In no event shall we be liable for any claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary damages,
howsoever arising, even if we have been advised of the possibility of such damages.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals CAS: Chemical Abstracts
Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Head Office: C. Mercado St., Brgy. Panginay, Guiguinto, Bulacan 3015 Philippines
Telephone Numbers: TACCP (+6344) 794-3027 / (+6344) 792-1548 / TACAF (+6344) 794-2907 / (+6344) 794-2528 / TACFM (+6344) 760-3942
Branch Office: 014 F. Pasco Avenue, Santolan, Pasig City 1610 Philippines
Telephone Numbers: (+632) 470-8382, (+632) 470-8384 to 86; Fax Number: (+632) 470-4565 Website: www.texicongroup.com
