附件 2：安全数据单样本（英文） 报验号：37000010202106756
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Chemical Safety Data Sheet
Section 1 IDENTIFICATION
GHS Product identifier: Sodium hydroxide solution.
Other means of identification: /
Recommended use of the chemical and restrictions on use:
Emergency phone number: /
Section 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture:
Corrosive to metals Category 1
Acute toxicity, oral Category 4
Skin corrosion/irritation Category 1B
Serious eye damage/eye irritation Category 1
Hazardous to the aquatic environment, acute hazard Category 3
GHS Label elements, including precautionary statements:
Symbol:
Signal word: Danger
Hazard statement(s): May be corrosive to metals. Harmful if swallowed. Causes severe skin burns
and eye damage. Harmful to aquatic life.
Precautionary statement(s):
Prevention:
Keep only in original container. Wash …thoroughly after handling. Do not eat, drink or smoke
when using this product. Do not breathe dusts or mists. Wear protective gloves/protective
clothing/eye protection/face protection. Avoid release to the environment.
Response:
Absorb spillage to prevent material damage. If swallowed: Get medical help. Rinse mouth. Do
NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing.
Immediately rinse with water for several minutes. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. Get emergency medical
help immediately. Specific treatment (see under for further information). If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical help.
Storage:
Store in corrosive resistant/... container with a resistant inner liner. Store locked up.
Disposal:
Dispose of contents/container in accordance with local/regional/national/international
regulations.
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Other hazards which do not result in classification: /
Section 3 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Concentration%
Sodium hydroxide 1310-73-2 32.1%
Section 4 FIRST AID MEASURES
Description of necessary first aid measures
If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician immediately.
In case of skin contact: Wash off with soap and plenty of running water. Consult a physician.
In case of eye contact: Rinse thoroughly with plenty of running water for at least 15 minutes
and consult a physician immediately.
If ingestion: Rinse mouth with water. Do not induce vomit. Consult a physician.
Most important symptoms/effects, acute and delayed: /
Indication of immediate medical attention and special treatment needed, if necessary: /
Section 5 FIREFIGHTING MEASURES
Suitable extinguishing media: Use foam, dry powder, water spray, etc.
Special hazards arising from the chemical: This product is non-flammable. Contact with
moisture or water may generate sufficient heat to ignite combustible materials.
Special protective actions for fire-fighters: Firefighters must wear air breathing apparatus, fire-
fighting suits and protective gloves to extinguish in the upwind direction. Whenever possible,
remove the container from the fire to open space and use spray water to cool unopened containers.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: It is recommended
that emergency personnel wear protective masks and fire protective overalls. Do not touch the
spill directly.
Environmental precautions: Isolate contaminated areas and restrict access.
Methods and materials for containment and cleaning up: Small amount of leakage:
adsorption with sand or other inert materials. Do not allow products to enter restricted areas such
as sewers. A large amount of leakage: building a dike or digging a pit to contain. Transfer to a
tank truck or special collector with a pump and transport to a waste disposal site for disposal.
Section 7 HANDLING AND STORAGE
Precautions for safe handling: There should be sufficient local exhaust in workplace. Operators
should be trained and strictly follow the operating procedures. Operators are advised to wear
protective masks, corrosion-resistant protective clothing and rubber gloves. Operators should
load and unload lightly during handling to prevent damage to the package. There should be
leakage treatment equipment in workplace. There may be harmful residues in empty containers.
Conditions for safe storage, including any incompatibilities: Store in a cool, dry, well-
ventilated warehouse. Keep away from fire and heat. Protect from direct sunlight. The package
should be sealed and not exposed to moisture. It should be stored separately from oxidants, acids,
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flammable materials, etc., and should not be mixed. The storage area should be provided with
suitable materials to contain spills.
Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters: /
Appropriate engineering controls: Close strictly and provide sufficient local exhaust.
Individual protection measures
Eye/face protection: Wear a protective mask.
Skin protection: Wear corrosion-resistant protective clothing.
Respiratory protection: Air respirators should be worn during emergency rescue or evacuation.
Thermal hazards: /
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance (physical state, colour etc) Colorless transparent liquid.
Odour /
Odour Threshold /
pH /
Melting point/freezing point /
Initial boiling point and boiling range /
Flash point /
Evaporation rate /
Flammability (solid, gas) /
Upper/lower flammability or explosive limits /
Vapour pressure /
Vapour density /
Relative density /
Solubility(ies) Soluble in water.
Partition coefficient: n-octanol/water /
Auto-ignition temperature /
Decomposition temperature /
Viscosity /
Section 10 STABILITY AND REACTIVITY
Reactivity: /
Chemical stability: This material is stable in normal temperature.
Possibility of hazardous reactions: The solution in water is a strong base. It reacts violently
with acid and is corrosive to metals such as aluminium, tin, lead and zinc. This produces a
combustible/explosive gas. Reacts with ammonium salts. This produces ammonia. This generates
fire hazard. Contact with moisture and water generates heat.
Conditions to avoid: Spark, static electricity and high temperature.
Incompatible materials: Flammable materials, acids and oxidizers.
Hazardous decomposition products: /
Section 11 TOXICOLOGICAL INFORMATION
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Information on the likely routes of exposure: Ingestion (swallowing), skin/eye exposure and
inhalation.
Symptoms related to the physical, chemical and toxicological characteristics: /
Acute health effects:
Ingestion can cause symptoms such as burning, nausea, vomiting and abdominal pain.
Skin contact can cause redness, pain and burn.
Inhalation can cause cough, throat pain and burn.
Eyes contact can cause irritation, pain and burn.
Chronic health effects: Repeated or prolonged contact with skin may cause dermatitis.
Numerical measures of toxicity (such as acute toxicity estimates):
LD50(dermal, rat): 1350 mg/kg
Section 12 ECOLOGICAL INFORMATION
Toxicity:
Endpoint Test Duration (hr) Species Value
LC50 96 Fish 125mg/L
EC50 48 Crustacea 40.4mg/L
EC50 96 Algae or other aquatic plants 3180000mg/L
NOEC 96 Fish 56mg/L
Persistence and degradability: Low.
Bioaccumulative potential: Low (LogKOW = -3.8796).
Mobility in soil: Low (KOC = 14.3).
Other adverse effects: /
Section 13 DISPOSAL CONSIDERATIONS
Disposal methods: Dispose this product by safe burial. Damaged containers are prohibited from
being reused and should be buried in the prescribed place.
Section 14 TRANSPORT INFORMATION
UN number: 1824.
UN proper shipping name: SODIUM HYDROXIDE SOLUTION.
Transport hazard class(es): 8.
Packing group, if applicable: II.
Environmental hazards: /
Special precautions for user: /
Section 15 REGULATORY INFORMATION
Regulations: This safety data sheet is in compliance with the following national standards: GB/T
16483-2008, GB 13690-2009, GB 18218-2018, GB 15258-2009, GB 6944-2012, GB 190-2009,
GB/T 191-2008, GB 12268-2012, GB/T 15098-2008, GBZ 2.1-2019, GBZ 2.2-2007 as well as
the following regulations: Railway Dangerous Goods Transport Administrative Regulation,
Dangerous Chemicals Safety Administrative Regulation.
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Section 16 OTHER INFORMATION
References UN Recommendations on the Transport of Dangerous Goods Model
Regulations
UN Globally Harmonized System of Classification and Labelling of
Chemicals
Form Date 14-Aug-2020
Note 1: When products contain two or more hazardous substances, Safety Data Sheets should be
prepared based on the risk of the mixture.
Note 2: Manufacturer/supplier should ensure the correctness of the information contained in the
safety data sheets, and updated in a timely manner.
Note 3: As a result of product features without the existence of certain information or no data
available (such as boiling point does not exist for the solid) in the table with "/" logo.
