SAFETY DATA SHEET
Issuing Date: 21-Feb-2018 Revision Date: 05-Dec-2018 Version 2.01
1. IDENTIFICATION
Product Name Tide Professional Coldwater Laundry Detergent
Product Code(s) 5-05
Product Identifier PA00216163_PROF_NG
Product Type: Finished Product - Professional Use Only
Recommended Use Detergent.
Synonyms 97202566
Details of the supplier of the safety Procter & Gamble Professional
data sheet 1 P&G Plaza
Cincinnati, Ohio 45202
Procter & Gamble Inc.
P.O. Box 355, Station A
Toronto, ON M5W 1C5
1-800-332-7787
Emergency Telephone Transportation (24 HR)
CHEMTREC - 1-800-424-9300
(U.S./ Canada) or 1-703-527-3887
Mexico toll free in country: 800-681-9531
2. HAZARD IDENTIFICATION
This product is classified under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.
Hazard Category
Acute toxicity - Oral Category 4
Eye Damage / Irritation Category 2B
Flammable Liquids Category 4
Signal Word WARNING
Hazard Statements Causes eye irritation
Harmful if swallowed
Combustible liquid
Hazard pictograms
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Precautionary Statements Wash hands thoroughly after handling
Do not eat, drink or smoke when using this product
Keepawayf r
om heat /sparks/openf
lames/ hotsurfaces.— Nosmoki
ng
Keep container tightly closed
Precautionary Statements - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
Response present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF SWALLOWED:
Rinse with plenty of water
Drink 1 or 2 glasses of water
Call a POISON CENTER or doctor/physician if you feel unwell
In case of fire: Use water, CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage Store in a well-ventilated place. Keep cool
Precautionary Statements - DisposalDispose of contents/container in accordance with local regulation
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation
Chemical Name Synonyms Trade Secret CAS-No Weight-%
Benzenesulfonic acid, Benzenesulfonic acid, No 68081-81-2 5 - 10
mono-C10-16-alkyl derivs., mono-C10-16-alkyl
sodium salts derivs., sodium salts
Poly(oxy-1,2-ethanediyl), Poly(oxy-1,2-ethanediyl No 68585-34-2 5 - 10
alpha-sulfo-omega-hydroxy-, ),
C10-16-alkyl ethers, sodium alpha-sulfo-omega-hydr
salts oxy-, C10-16-alkyl
ethers, sodium salts
Alcohols, C14-15, ethoxylated Alcohols, C14-15, No 68951-67-7 1-5
ethoxylated
Propylene glycol Propylene Glycol No 57-55-6 1-5
Dodecanoic acid, sodium salt Dodecanoic acid, No 629-25-4 1-5
(1:1) sodium salt (1:1)
Disodium tetraborate Boron sodium oxide No 12179-04-3 0.5 - 1.5
pentahydrate (B4Na2O7),
pentahydrate
Glycine, Glycine, No 140-01-2 0.1 - 1.0
N,N-bis[2-[bis(carboxymethyl)a N,N-bis[2-[bis(carboxy
mino]ethyl]-, sodium salt (1:5) methyl)amino]ethyl]-,
sodium salt (1:5)
Additional information Actual substance concentrations fall within the ranges stated. Maximum values do not
necessarily represent the values present in the formula.
4. FIRST AID MEASURES
First aid measures for different exposure routes
Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists.
Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention
immediately if symptoms occur.
Inhalation Move to fresh air. If symptoms persist, call a physician.
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Most important symptoms/effects, None under normal use conditions.
acute and delayed
F. Indication of immediate medical attention and special treatment needed, if necessary
Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media In case of fire: Use water, CO2, dry chemical, or foam for extinction.
Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.
Special hazard Fumes may catch fire.
Special protective equipment for As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
fire-fighters (approved or equivalent) and full protective gear.
Specific hazards arising from the None.
chemical
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing.
Advice for emergency responders Use personal protective equipment as required.
Environmental precautions Should not be released into the environment
Methods and materials for containment and cleaning up
Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers for
later disposal.
Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Keep away from open flames, hot surfaces and sources of ignition. Use personal protective
equipment as required. Keep container closed when not in use. Never return spills in
original containers for re-use. Keep out of the reach of children.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a
cool/low-temperature, well-ventilated, dry place away from heat and ignition sources.
Incompatible products None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
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Exposure Guidelines .
Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL
Disodium tetraborate pentahydrate 12179-04-3 STEL: 6 mg/m3 inhalable (vacated) TWA: 10 mg/m3 Mexico: TWA 1 mg/m3
particulate matter
TWA: 2 mg/m3 inhalable
particulate matter
Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia
Propylene glycol 57-55-6 TWA: 10 mg/m3
TWA: 50 ppm
TWA: 155 mg/m3
Disodium tetraborate 12179-04-3 TWA: 1 mg/m3 TWA: 1 mg/m3 TWA: 2 mg/m3 TWA: 2 mg/m3
pentahydrate STEL: 3 ppm STEL: 6 mg/m3 STEL: 6 mg/m3
No relevant exposure guidelines for other ingredients
Exposure controls
Engineering Measures Distribution, Workplace and Household Settings:
Ensure adequate ventilation
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction
Personal Protective Equipment
Eye Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Use appropriate eye protection
Hand Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Protective gloves
Skin and Body Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Wear suitable protective clothing
Respiratory Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
In case of inadequate ventilation wear respiratory protection
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State @20°C Liquid
Appearance blue
Odor Scented
Odor threshold No information available
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Property Values Note
pH value 7.7 - 8.6
Melting Point / Freezing Point No information available
Boiling point / boiling range No information available
Flash point 65.5 °C / 149.9 °F Closed cup. Does not sustain combustion.
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limits in Air
Upper flammability limit No information available
Lower Flammability Limit No information available
Vapor pressure No information available
Vapor density No information available
Relative density No information available
Water solubility No information available
Partition coefficient: n-octanol/waterNo information available
Autoignition temperature No information available .
Decomposition temperature No information available .
Viscosity No information available
VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer
products.
10. STABILITY AND REACTIVITY
Reactivity None under normal use conditions.
Stability Stable under normal conditions.
Hazardous polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.
Conditions to Avoid Keep away from open flames, hot surfaces and sources of ignition.
Incompatible materials None in particular.
Hazardous Decomposition Products None under normal use conditions.
11. TOXICOLOGICAL INFORMATION
Product Information
Information on likely routes of exposure
Inhalation No known effect.
Skin contact No known effect.
Ingestion May be harmful if swallowed.
Eye contact Irritating to eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity May be harmful if swallowed.
Skin corrosion/irritation No known effect.
Serious eye damage/eye irritation Irritating to eyes.
Skin sensitization No known effect.
Respiratory sensitization No known effect.
Germ cell mutagenicity No known effect.
Neurological Effects No known effect.
Reproductive toxicity No known effect.
Developmental toxicity No known effect.
Teratogenicity No known effect.
STOT - single exposure No known effect.
STOT - repeated exposure No known effect.
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Target Organ Effects No known effect.
Aspiration hazard No known effect.
Carcinogenicity No known effect.
Component Information
Chemical Name CAS-No Oral LD50 Dermal LD50 Inhalation LC50
Poly(oxy-1,2-ethanediyl), 68585-34-2 >2001 mg/kg - -
alpha-sulfo-omega-hydroxy-,
C10-16-alkyl ethers, sodium salts
Alcohols, C14-15, ethoxylated 68951-67-7 > 300 mg/kg bw > 2000 mg/kg bw -
Glycine, 140-01-2 > 5000 mg/kg bw (OECD > 2000 mg/kg bw (OECD -
N,N-bis[2-[bis(carboxymethyl)amino 401) 402)
]ethyl]-, sodium salt (1:5)
12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not expected to be hazardous to the environment.
Persistence and degradability No information available.
Bioaccumulative potential No information available.
Mobility No information available.
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from Residues/Unused Disposal should be in accordance with applicable regional, national and local laws and
Products regulations.
Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.
California Hazardous Waste Codes 331
(non-household setting)
14. TRANSPORT INFORMATION
DOT Not regulated
IMDG Not regulated
IATA Not regulated
15. REGULATORY INFORMATION
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
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Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):.
Chemical Name CAS-No Hazardous Extremely Hazardous CERCLA/SARA 302
Substances RQs Substances RQs TPQ
Sodium hydroxide 1310-73-2 1000 lb -
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act
Amendments of 1990.
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42):.
Chemical Name CAS-No CWA - Reportable CWA - Toxic CWA - Priority CWA - Hazardous
Quantities Pollutants Pollutants Substances
Sodium hydroxide 1310-73-2 1000 lb - - X
California Proposition 65
This product is not subject to warning labeling under California Proposition 65.
U.S. State Regulations (RTK)
.
Chemical Name CAS-No New Jersey
Propylene glycol 57-55-6 X
Chemical Name CAS-No Massachusetts
Disodium tetraborate pentahydrate 12179-04-3 X
Chemical Name CAS-No Pennsylvania
Propylene glycol 57-55-6 X
Ethanol 64-17-5 X
2,2'-Oxybisethanol 111-46-6 X
Sodium hydroxide 1310-73-2 X
International Inventories
United States
All intentionally-added components of this product(s) are listed on the US TSCA Inventory
Canada
This product is in compliance with CEPA for import by P&G
Legend
United States Toxic Substances Control Act Section 8(b) Inventory (TSCA)
CEPA - Canadian Environmental Protection Act
16. OTHER INFORMATION
Issuing Date: 21-Feb-2018
Revision Date: 05-Dec-2018
Disclaimer.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
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disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text
End of SDS
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