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Infineum P6060

This safety data sheet provides information on Infineum P6060, which is an additive for car engine lubricating oil. It lists the product identification and supplier contact information. The main hazards are that it is harmful to aquatic life with long lasting effects. It contains hazardous substances including bis(nonylphenyl)amine and various petroleum distillates. Instructions are provided for first aid measures and firefighting.

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0% found this document useful (0 votes)
459 views28 pages

Infineum P6060

This safety data sheet provides information on Infineum P6060, which is an additive for car engine lubricating oil. It lists the product identification and supplier contact information. The main hazards are that it is harmful to aquatic life with long lasting effects. It contains hazardous substances including bis(nonylphenyl)amine and various petroleum distillates. Instructions are provided for first aid measures and firefighting.

Uploaded by

Burcu Taşçı
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 28

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006


Infineum P6060

Version 6.0 Revision Date 29.07.2020 Print Date 03.12.2020

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING

1.1 Product identifier

Trade name : Infineum P6060


Other means of Identification : 73282

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture : Additive for car engine lubricating oil

Recommended restrictions on use : This material should not be used for any other
purpose than that recommended without
expert advice.

1.3 Details of the supplier of the safety data sheet

Company : INFINEUM UK LIMITED


P. O. Box 1
Milton Hill
Abingdon
Oxfordshire OX13 6BB United Kingdom
Tel: +44 1235 54 9501

Company (EU) : INFINEUM UK LIMITED


P. O. Box 1
Milton Hill
Abingdon
Oxfordshire OX13 6BB United Kingdom
Tel: +44 1235 54 9501

E-mail address for further information [email protected]

Website for further information http://www.infineum.com

1.4 Emergency telephone number

04-4274.4690 (France) (+33-4.4274.4690)


0221-7499 3355 (Germany) (+49-221-7499 3355)
019-2150 221 (Italy) (+39 019-2150 221)
01235 549777 (UK) (+44 1235 549777)

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

GHS-Classification (REGULATION (EC) No 1272/2008)


Chronic aquatic toxicity: Category 3 H412: Harmful to aquatic life with long lasting

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effects.

2.2 Label elements

GHS-Labelling (REGULATION (EC) No 1272/2008)


Hazard statements : H412 Harmful to aquatic life with long lasting effects.

Precautionary statements : Prevention:


P273 Avoid release to the environment.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Supplemental information:
EUH208 Contains: C14-16-18 Alkyl phenol. May produce an allergic reaction.

2.3 Other Hazards

Contact with hot material may cause thermal burns

This mixture contains no substance considered to be persistent, bioaccumulating and toxic (PBT).

This mixture contains no substance considered to be very persistent and very bioaccumulating (vPvB).

This product is not classified as a skin sensitiser, but contains between 0.1 to <1.0 wt% of substances
known to cause skin sensitisation

This product is not classified as a respiratory sensitiser and contains less than 0.1 wt% of any substance
known to cause respiratory sensitisation

This product is not classified as a skin sensitiser and contains less than 0.1 wt% of any substance known
to cause skin sensitisation

Warning: If this material is overheated, especially in the presence of water, hydrogen sulphide may be
released; this can cause rapid respiratory collapse, coma and death without necessarily any warning
odour being sensed.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Hazardous components

Component EC-No. Concentration Classification


Registration number (REGULATION (EC)

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[%] No 1272/2008)

bis(nonylphenyl)amine 253-249-4 >=2,5 - <10 Aquatic Chronic 4;


01-2119488911-28 H413

distillates (petroleum), 265-157-1 >=1 - <10 Asp. Tox. 1; H304


hydrotreated heavy 01-2119484627-25
paraffinic

Distillates (petroleum), 265-159-2 >=1 - <10 Asp. Tox. 1; H304


solvent-dewaxed light 01-2119480132-48
paraffinic

Distillates (petroleum), 265-169-7 >=1 - <10 Asp. Tox. 1; H304


solvent-dewaxed heavy 01-2119471299-27
paraffinic

paraffin oils (petroleum), 265-174-4 >=1 - <10 Asp. Tox. 1; H304


catalytic dewaxed heavy 01-2119487080-42

Phosphorodithioic acid, 283-392-8 >=3 - <6,25 Skin Irrit. 2; H315


mixed O,O-bis(1,3- 01-2119493626-26 Eye Dam. 1; H318
dimethylbutyl and iso-Pr) Aquatic Chronic 2;
esters, zinc salts H411

C14-16-18 Alkyl phenol -- >=0,1 - <1 Skin Sens. 1B; H317


01-2119498288-19 STOT RE 2; H373

For the full text of the H-Statements mentioned in this Section, see Section 16.

All concentrations are weight percent units for liquids or volume percent units for gaseous products.

Other ingredients are either not hazardous or are below the regulatory disclosure limit..

SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures

General advice : No hazards which require special first aid measures.

If inhaled : If unconscious, place in recovery position and seek medical


advice.
If symptoms persist, call a physician.

If breathing has stopped, assist ventilation with a mechanical


device. Do not use mouth-to-mouth resuscitation if exposure
to hydrogen sulphide is suspected.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.

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If symptoms persist, call a physician.


In case of burns apply cold water until pain subsides then
seek medical advice.

In case of eye contact : Flush eyes with water as a precaution.


Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists: Get medical advice/ attention.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms : irritant effects

4.3 Indication of any immediate medical attention and special treatment needed

Treatment : Show this safety data sheet to the doctor in attendance.


The first aid procedure should be established in consultation
with the doctor responsible for industrial medicine.
If a person vomits when lying on his back, place him in the
recovery position.
Keep patient warm and at rest.

SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing : Use water fog, foam, dry chemical or carbon dioxide (CO2) to
media extinguish flames

Unsuitable extinguishing : High volume water jet


media

5.2 Special hazards arising from the substance or mixture

Combustibility : Not classified as flammable or combustible, but will combust if


ignited.

Hazardous combustion : Metal oxides


products
Nitrogen oxides (NOx)

Hydrogen sulphide, Sulphur oxides and Phosphorus oxides

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Zinc oxides

Carbon monoxide, carbon dioxide and unburned


hydrocarbons (smoke).

Flammable properties : See Section 9 for information on flammability.

5.3 Advice for firefighters

Protective equipment and : In the event of fire, wear self-contained breathing apparatus.
precautions for firefighters Exposure to decomposition products may be a hazard to
health.

Fire Fighting Instructions : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Fire-fighters should exercise extreme caution in enclosed


spaces due to the possible presence of toxic decomposition
and combustion products. Self-contained full-face
overpressure breathing apparatus should be used in enclosed
spaces. Use standard body protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Advice for emergency responders


Ensure adequate ventilation.
Use personal protective equipment.
Material can create slippery conditions.
For personal protection see section 8.

Advice for non-emergency personnel


Avoid contact with spilled material. Do not touch or walk
through spilled material.

6.2 Environmental precautions

Environmental precautions : See attached ES

Prevent entry into waterways, sewers, basements or


confined areas.

Local authorities should be advised if significant spillages


cannot be contained.
Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so.
Try to prevent the material from entering drains or water

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courses.
If the product contaminates rivers and lakes or drains inform
respective authorities.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Prevent further leakage or spillage if safe to do so.


Large Spills: Dyke far ahead of liquid spill for later recovery
and disposal.
Recover by pumping or with suitable absorbent

Report spills as required to appropriate authorities.


Seek the advice of a specialist before using dispersants.
Dispose of according to local regulations.
In the event of a spill or accidental release, notify relevant
authorities in accordance with all applicable regulations.
Material will float on water, use containment booms as a
barrier to protect shorelines.

Wipe up with absorbent material (e.g. cloth, fleece).


Keep in suitable, closed containers for disposal.
Clean contaminated floors and objects thoroughly while
observing environmental regulations.

6.4 Reference to other sections

Other information : For personal protection see section 8.


See section 13

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Avoid contact with skin and eyes.


For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the application area.
Dispose of rinse water in accordance with local and national regulations.

This product contains Zinc Dialkyl DithioPhosphate (ZDDP), a thermally sensitive substance.

Do not reheat above the maximum loading temperature. Higher temperatures can result in
exothermic decomposition of the ZDDP leading to the release of highly toxic hydrogen sulphide and
possibly extremely odorous alkyl mercaptans. Alkyl mercaptans can be smelled at extremely low
concentrations, and vapours may travel for many miles at detectable concentrations. These
decomposition vapours are also flammable and may suddenly ignite when mixed with air in the
presence of ignition sources such as sparks or flames.

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Caution must be exercised when heating this product. Electrical or steam heating systems with a self
limiting maximum temperature not exceeding 120 deg C (e.g. low pressure steam at 1 bar(g) (15
psig)) is recommended when product cannot be agitated to avoid localised high temperatures. When
heated, product temperature should be constantly monitored.
Product should be stored below the recommended maximum loading / unloading temperature to
avoid degradation of product quality and eventually decomposition.

Extreme caution must be used in tank gauging or similar operations as overheating could lead to
accumulation of lethal concentrations of hydrogen sulphide in the head-space of containers.

Warning: If this material is overheated, especially in the presence of water, hydrogen sulphide may
be released; this can cause rapid respiratory collapse, coma and death without necessarily any
warning odour being sensed.

If decomposition is suspected, or if the product has been overheated, do not open the container,
discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary
precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as
evacuation of contaminated areas, and use of suitable respiratory protection.

Normal measures for preventive fire protection.

Products may load from Infineum manufacturing site above the standard loading/unloading range.

Loading/unloading : 55 °C (131 ° F) - 65 °C (149 ° F)


temperature

Viscosity @ : 840 cSt - 1.450 cSt


Loading/unloading
temperature

Static accumulator : This material is not a static accumulator.

7.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place.

No decomposition if stored and applied as directed.

Do not reheat above: 65 °C (149 ° F)

Storage temperature : <= 60 °C (140 ° F)

Incompatible materials and : No data available


coatings

7.3 Specific end use(s)

Specific use(s) : : See attached ES for uses

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

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8.1 Control parameters

Exposure limits for materials that can be formed when handling this product: When mists/aerosols can
occur, the following are recommended: 5mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL

Limits/standards shown for guidance only. Follow applicable regulations.

Recommended monitoring : This product contains ingredients with exposure limits,


procedures personal, workplace atmosphere or biological monitoring may
be required to determine the effectiveness of the ventilation
or other control measures and/or the necessity to use
respiratory protective equipment.

Reference should be made to European Standard EN 689 for


methods for the assessment of exposure by inhalation to
chemical agents and national guidance documents for
methods for the determination of hazardous substances.

DNEL
bis(nonylphenyl)amine : End Use: Workers
Exposure routes: Skin contact
Potential health effects: Long-term systemic effects
Value: 0,62 mg/kg

End Use: Workers


Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 4,37 mg/m3

End Use: Consumers


Exposure routes: Skin contact
Potential health effects: Long-term systemic effects
Value: 0,31 mg/kg

End Use: Consumers


Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 1,09 mg/m3

End Use: Consumers


Exposure routes: Ingestion
Potential health effects: Long-term systemic effects
Value: 0,31 mg/kg

distillates (petroleum), : End Use: Workers


hydrotreated heavy Exposure routes: Inhalation
paraffinic Potential health effects: Long-term local effects
Value: 5,4 mg/m3

End Use: Consumers


Exposure routes: Inhalation
Potential health effects: Long-term local effects
Value: 1,2 mg/m3

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Distillates (petroleum), : End Use: Workers


solvent-dewaxed heavy Exposure routes: Inhalation
paraffinic Potential health effects: Long-term local effects
Value: 5,4 mg/m3

End Use: Consumers


Exposure routes: Inhalation
Potential health effects: Long-term local effects
Value: 1,2 mg/m3

Phosphorodithioic acid, : End Use: Workers


mixed O,O-bis(1,3- Exposure routes: Skin contact
dimethylbutyl and iso-Pr) Potential health effects: Long-term systemic effects
esters, zinc salts Value: 12,1 mg/kg bw/day

End Use: Workers


Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 8,31 mg/m3

End Use: Consumers


Exposure routes: Skin contact
Potential health effects: Long-term systemic effects
Value: 6,1 mg/kg bw/day

End Use: Consumers


Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 2,11 mg/m3

End Use: Consumers


Exposure routes: Ingestion
Potential health effects: Long-term systemic effects
Value: 0,24 mg/kg bw/day

PNEC
bis(nonylphenyl)amine : Fresh water
Value: 0,1 mg/l

Marine water
Value: 0,01 mg/l

Intermittent use/release
Value: 1 mg/l

Sewage treatment plant


Value: 1 mg/l

Fresh water sediment


Value: 132000 mg/kg

Marine sediment

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Value: 13200 mg/kg

Soil
Value: 263000 mg/kg

distillates (petroleum), : Oral


hydrotreated heavy Value: 9,33 mg/kg
paraffinic
Distillates (petroleum), : Oral
solvent-dewaxed heavy Value: 9,33 mg/kg
paraffinic
Phosphorodithioic acid, : Fresh water
mixed O,O-bis(1,3- Value: 0,004 mg/l
dimethylbutyl and iso-Pr)
esters, zinc salts
Marine water
Value: 0,0046 mg/l

Intermittent use/release
Value: 0,045 mg/l

Sewage treatment plant


Value: 100 mg/l

Fresh water sediment


Value: 0,022 mg/kg dry weight (d.w.)

Marine sediment
Value: 0,002 mg/kg dry weight (d.w.)

Soil
Value: 0,0548 mg/kg dry weight (d.w.)

Oral
Value: 10,67 mg/kg food

8.2 Exposure controls

Appropriate engineering : See attached ES


controls No special requirements under ordinary conditions of use and
with adequate ventilation.
If decomposition is suspected, or if the product has been
overheated, do not open the container, discontinue heating
and secure the unit. Initiate emergency procedures, taking all
necessary precautions to avoid exposure to noxious or
flammable gases (e.g. hydrogen sulphide), such as
evacuation of contaminated areas, and use of suitable
respiratory protection.

Personal protective equipment

Respiratory protection : The applicable European standard can be found in EN 140,


EN 137, EN 143, EN 14387.

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Hand protection
Remarks : Polyvinyl alcohol or nitrile- butyl-rubber gloves Before
removing gloves clean them with soap and water. Please
observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local
conditions under which the product is used, such as the
danger of cuts, abrasion, and the contact time. When handling
hot material, use heat resistant gloves.

The selected protective gloves have to satisfy the


specifications of Regulation (EU) 2016/425 and the standard
EN 374 derived from it.

Eye/face protection : The applicable European standard can be found in EN 166.

Eye wash bottle with pure water


Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.

Skin and body protection : Impervious clothing


Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Long sleeved clothing

The applicable European standard can be found in EN 14605.

Advice on general occupational hygiene

Hygiene measures : When using do not eat or drink.


When using do not smoke.
Wash hands before breaks and immediately after handling the
product.
Remove contaminated clothing and protective equipment
before entering eating areas.

Environmental exposure controls


General advice : See attached ES

Prevent entry into waterways, sewers, basements or confined


areas.

Local authorities should be advised if significant spillages


cannot be contained.
Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so.
Try to prevent the material from entering drains or water
courses.
If the product contaminates rivers and lakes or drains inform

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respective authorities.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.

Physical state : liquid

Form : viscous

Colour : brown

Odour : hydrocarbon-like

Odour Threshold : not determined

Relative density : 0,933 at 15,6 °C (60,1 ° F)


Method: ASTM D4052

Bulk density : Not applicable

Density : 0,932 g/cm3 at 15 °C (59 ° F)


Method: ASTM D4052

Flash point : 180 °C (356 ° F)


Method: Pensky-Martens Closed Cup (ASTM D93)

Flammability (solid, gas) : not determined

Lower flammability limit : not determined

Upper flammability limit : not determined

Auto-ignition temperature : Not applicable

Initial boiling point and boiling : not determined


range

Vapour density (Air = 1.0) : not determined

Vapour pressure : < 0,1 hPa (< 0,1 mmHg) at 20 °C (68 ° F)


estimated

Evaporation rate (N-butyl : Not applicable


acetate=1)

pH : Not applicable

Partition coefficient: n- : not determined

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octanol/water

Water solubility : < 0,0001 g/l


estimated

Viscosity, kinematic : 182 mm2/s at 100 °C (212 ° F)


Method: ASTM D 445
3720 mm2/s at 40 °C (104 ° F)
Method: ASTM D 445

Explosive properties : not determined

Oxidizing properties : See Section 2

Decomposition temperature : not determined

Pour point : not determined

Melting point/freezing point : not determined

9.2 Other information

DMSO extract by IP346 : Less than 3.0 wt% (mineral oil component only)

Coefficient of thermal : 0,00067 1/°C ITM 50-020


expansion

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions : No hazards to be specially mentioned.

10.4 Conditions to avoid

Conditions to avoid : Excessive heat.

10.5 Incompatible materials

Incompatible materials : Strong oxidizing agents, water

10.6 Hazardous decomposition products

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Hazardous decomposition : Hydrogen Sulfide


products

If decomposition is suspected, or if the product has been overheated, do not open the container,
discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions
to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of
contaminated areas, and use of suitable respiratory protection.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects


Product
Acute oral toxicity : No data is available on the product itself.

Acute inhalation toxicity : No data is available on the product itself.

Acute dermal toxicity : No data is available on the product itself.

Skin corrosion/irritation : No data is available on the product itself.

Serious eye damage/eye : No data is available on the product itself.


irritation
Respiratory or skin : No data is available on the product itself.
sensitisation
Germ cell mutagenicity
Genotoxicity in vitro : No data is available on the product itself.
Genotoxicity in vivo : No data is available on the product itself.
Carcinogenicity : No data is available on the product itself.

Reproductive toxicity : No data is available on the product itself.

STOT - single exposure : Assessment: No data is available on the product itself.

STOT - repeated exposure : Assessment: No data is available on the product itself.

Aspiration hazard : No data is available on the product itself.

Components:

bis(nonylphenyl)amine:
Acute oral toxicity : LD50 Rat: > 5.000 mg/kg
Method: OECD Test Guideline 401
Test substance: Read-across (Analogy)
Remarks: Based on available data, the classification criteria
are not met.

Acute inhalation toxicity : study scientifically unjustified

Acute dermal toxicity : LD50 Rat: > 2.000 mg/kg


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Method: OECD Test Guideline 402


Test substance: Read-across (Analogy)
Remarks: Based on available data, the classification criteria
are not met.

Skin corrosion/irritation : Species: Rabbit


Result: No skin irritation
Method: OECD Test Guideline 404
Test substance:yes
Based on available data, the classification criteria are not met.

Serious eye damage/eye : Species: Rabbit


irritation Result: No eye irritation
Method: OECD Test Guideline 405
Test substance: yes
Based on available data, the classification criteria are not met.

Respiratory or skin : Test Method: Maximisation Test


sensitisation Species: Guinea pig
Result: Does not cause skin sensitisation.
Method: OECD Test Guideline 406
Test substance: Read-across (Analogy)
Based on available data, the classification criteria are not met.

Germ cell mutagenicity


Genotoxicity in vitro : Result: negative
Test substance: Read-across (Analogy)
Based on available data, the classification criteria are not met.
Genotoxicity in vivo : Test species: MouseTest substance: Read-across (Analogy)
Result: negativeBased on available data, the classification
criteria are not met.
Carcinogenicity : study scientifically unjustified

Reproductive toxicity : Test substance: Read-across (Analogy)


Based on available data, the classification criteria are not met.

STOT - single exposure : Remarks: Based on available data, the classification criteria
are not met.

STOT - repeated exposure : Remarks: Based on available data, the classification criteria
are not met.

Aspiration hazard : Based on available data, the classification criteria are not met.

distillates (petroleum), hydrotreated heavy paraffinic:


Carcinogenicity : No data available

Aspiration hazard : May be fatal if swallowed and enters airways.

Distillates (petroleum), solvent-dewaxed light paraffinic:


Carcinogenicity : No data available

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Aspiration hazard : May be fatal if swallowed and enters airways.

Distillates (petroleum), solvent-dewaxed heavy paraffinic:


Carcinogenicity : No data available

Aspiration hazard : May be fatal if swallowed and enters airways.

paraffin oils (petroleum), catalytic dewaxed heavy:


Carcinogenicity : No data available

Aspiration hazard : May be fatal if swallowed and enters airways.

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts:


Acute oral toxicity : LD50 Rat: 3.150 mg/kg
Method: OECD Test Guideline 401
Test substance: yes
GLP: no
Remarks: May be harmful if swallowed.

Acute inhalation toxicity : LC50 Rat: > 2,3 mg/l


Exposure time: 4 h
Method: OECD Test Guideline 403
Test substance: yes
GLP: no
Remarks: No adverse effect has been observed in acute
toxicity tests.
Based on available data, the classification criteria are not met.

Acute dermal toxicity : LD50 Rat: > 2.002 mg/kg


Method: OECD Test Guideline 402
Test substance: yes
GLP: yes
Remarks: Based on available data, the classification criteria
are not met.

Skin corrosion/irritation : Species: Guinea pig


Exposure time: 4 h
Result: Causes skin irritation.
Method: OECD Test Guideline 404
Test substance:yes
Specific concentration limits : Skin Irrit. 2 H315 >= 6.25 -
100%.

Serious eye damage/eye : Species: Rabbit


irritation Exposure time: 504 h
Result: Causes serious eye damage.
Method: 16 CFR 1500.42
Test substance: yes
Specific concentration limits : Eye Irrit. 2 H319 >= 10 - <
12.5%; Eye Dam. 1 H318 >= 12.5 - 100%.

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Respiratory or skin : Test Method: Buehler Test


sensitisation Species: Guinea pig
Result: Does not cause skin sensitisation.
Method: OECD Test Guideline 406
Test substance: yes
Based on available data, the classification criteria are not met.

Germ cell mutagenicity


Genotoxicity in vitro : Type: Ames test
Test species: Salmonella typhimurium
with and without metabolic activation
Result: negative
Method: OECD Test Guideline 471
GLP: yes
Test substance: yes
Based on available data, the classification criteria are not met.
Genotoxicity in vivo : Type: Micronucleus test
Test species: Mouse (male and female)Application Route:
Intraperitoneal injection
Method: OECD Test Guideline 474
GLP: yes
Test substance: yes
Result: negativeBased on available data, the classification
criteria are not met.
Carcinogenicity : No data available

Reproductive toxicity : Species: Rat


Sex: male and female
Application Route: Oral
NOAEL: 160 mg/kg, Method: OECD Test Guideline 422
GLP: yes
Test substance: Read-across (Analogy)
Based on available data, the classification criteria are not met.

STOT - single exposure : Assessment: Based on available data, the classification


criteria are not met.

STOT - repeated exposure : Assessment: Based on available data, the classification


criteria are not met.

Aspiration hazard : Based on available data, the classification criteria are not met.

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
Product:
Toxicity to fish : No data is available on the product itself.

Toxicity to daphnia and other : No data is available on the product itself.


aquatic invertebrates
Toxicity to algae : No data is available on the product itself.

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Components:

bis(nonylphenyl)amine :
Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 100 mg/l
Exposure time: 96 h
Test Method: static test
Test substance: Read-across (Analogy)
Method: OECD Test Guideline 203
Based on available data, the classification criteria are not met.

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Test Method: static test
Test substance: yes
Method: OECD Test Guideline 202
Based on available data, the classification criteria are not met.

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 100 mg/l
Exposure time: 72 h
Test Method: static test
Test substance: Read-across (Analogy)
Method: OECD Test Guideline 201
Based on available data, the classification criteria are not met.

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts :


Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 4,5 mg/l
Exposure time: 96 h
Test Method: semi-static test
Analytical monitoring: no
Test substance: yes
Method: OECD Test Guideline 203
GLP: yes
Toxic to aquatic life.

Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): 23 mg/l
aquatic invertebrates Exposure time: 48 h
Test Method: static test
Analytical monitoring: no
Test substance: yes
Method: OECD Test Guideline 202
GLP: yes
Harmful to aquatic life.

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 21 mg/l


Exposure time: 72 h
Test Method: static test
Analytical monitoring: no
Test substance: yes
Method: OECD Test Guideline 201
GLP: yes
Harmful to aquatic life.

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Toxicity to bacteria : IC50 : 10.000 mg/l


Exposure time: 3 h
Test Method: Respiration inhibition
Test substance: yes
GLP:

Toxicity to daphnia and other : NOEC: 0,4 mg/l


aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Species: Daphnia magna (Water flea)
Analytical monitoring: yes
Test substance: yes
Method: OECD Test Guideline 211
GLP: yes
Toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability


Product:
Biodegradability : No data is available on the product itself.

Components:

bis(nonylphenyl)amine :
Biodegradability : aerobic
activated sludge
Result: Not biodegradable
Biodegradation: 1 %
Exposure time: 28 d
Test substance: Read-across (Analogy)
According to the results of tests of biodegradability this
product is not readily biodegradable.

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts :


Biodegradability : aerobic
activated sludge
Concentration: 10 mg/l
Result: Not readily biodegradable.
Biodegradation: 1,5 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
Test substance: yes
GLP: yes
According to the results of tests of biodegradability this
product is not readily biodegradable.

Stability in water : Hydrolysis: 6,6 % at50 °C(120 h)


pH: 7
Test substance: yes
Method: OECD Test Guideline 111

Hydrolysis: 0 % at50 °C(120 h)

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pH: 4
Test substance: yes
Method: OECD Test Guideline 111

Hydrolysis: 0 % at50 °C(120 h)


pH: 9
Test substance: yes
Method: OECD Test Guideline 111

12.3 Bioaccumulative potential


Product:
Bioaccumulation : No data is available on the product itself.

Partition coefficient: n- : not determined


octanol/water
Components:

bis(nonylphenyl)amine :
Bioaccumulation : Accumulation in aquatic organisms is expected.

Partition coefficient: n- : log Pow: > 7,6


octanol/water

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts :


Bioaccumulation : Test substance: Read-across (Analogy)
Due to the distribution coefficient n-octanol/water,
accumulation in organisms is not expected.

Partition coefficient: n- : log Pow: 0,56


octanol/water

12.4 Mobility in soil


Product:
Mobility : No data is available on the product itself.
Components:

bis(nonylphenyl)amine :
Mobility : After release, adsorbs onto soil.

distillates (petroleum), hydrotreated heavy paraffinic :


Mobility : After release, adsorbs onto soil.

Distillates (petroleum), solvent-dewaxed light paraffinic :


Mobility : After release, adsorbs onto soil.

Distillates (petroleum), solvent-dewaxed heavy paraffinic :


Mobility : After release, adsorbs onto soil.

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts :


Mobility : After release, adsorbs onto soil.

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12.5 Results of PBT and vPvB assessment


Product:
Assessment : No data is available on the product itself.
This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.
Components:

bis(nonylphenyl)amine :
Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)., This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).

distillates (petroleum), hydrotreated heavy paraffinic :


Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)., This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).

Distillates (petroleum), solvent-dewaxed light paraffinic :


Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)., This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).

Distillates (petroleum), solvent-dewaxed heavy paraffinic :


Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)., This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts :


Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)., This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).

12.6 Other adverse effects


Product:
Additional ecological : None known.
information

SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product : The product should not be allowed to enter drains, water


courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
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Dispose of contents/ container to an approved waste disposal


plant.

Disposal recommendations based on material as supplied, Disposal must be in accordance with


applicable laws and regulations, and material characteristics at time of disposal

For the safety of persons conducting disposal, recycling or reclamation activities, refer to the information
in Section 8, Exposure control and personal protection.

Empty containers.

Empty Container Warning (where applicable): Empty containers may contain residue and can be
dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should
be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers
should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and
in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC
ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY
OR DEATH.

Regulatory disposal information

European Waste Code : 13 02 XX


waste engine, gear and lubricating oils

SECTION 14. TRANSPORT INFORMATION

ADR / RID

14.1 UN number

UN number Not regulated for transport by land

14.2 UN proper shipping name

Proper shipping name Not regulated for transport by land

14.3 Transport hazard class(es)

Transport hazard class Not regulated for transport by land

14.4 Packing group

Packing group Not regulated for transport by land

Classification Code Not regulated for transport by land

Labels Not regulated for transport by land

Hazard Identification Not regulated for transport by land


Number

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Hazchem Code Not regulated for transport by land

14.5 Environmental hazards

Environmentally Not regulated for transport by land


hazardous

14.6 Special precautions for user

Footnote Not regulated for transport by land

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Remarks Not applicable

IMDG

14.1 UN number

UN number Not regulated for transport by sea under IMDG code

14.2 UN proper shipping name

Proper shipping name Not regulated for transport by sea under IMDG
code

14.3 Transport hazard class(es)

Transport hazard class Not regulated for transport by sea under IMDG code

14.4 Packing group

Packing group Not regulated for transport by sea under IMDG code

Labels Not regulated for transport by sea under IMDG code

EmS Number 1 Not regulated for transport by sea under IMDG code

14.5 Environmental hazards

Marine pollutant Not regulated for transport by sea under IMDG code

14.6 Special precautions for user

Footnote Not regulated for transport by sea under IMDG


code

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Remarks Not applicable

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IATA

14.1 UN number

UN number Not regulated for transport by air

14.2 UN proper shipping name

Proper shipping name Not regulated for transport by air

14.3 Transport hazard class(es)

Transport hazard class Not regulated for transport by air

14.4 Packing group

Packing group Not regulated for transport by air

Packing instruction Not regulated for transport by air


(cargo aircraft)

Classification Code Not regulated for transport by air

Labels Not regulated for transport by air

Hazard Identification Not regulated for transport by air


Number

Hazchem Code Not regulated for transport by air

14.5 Environmental hazards

Environmentally Not regulated for transport by air


hazardous

14.6 Special precautions for user

Footnote Not regulated for transport by air

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Remarks Not applicable

SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Risk classification according : Exempt


to VbF
Major Accident Hazard : 2012/18/EU
Legislation Not applicable

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Water contaminating class : WGK 1 slightly hazardous to water


(Germany)

TA Luft List (Germany)

portion portion portion portion portion other


Class 1 Class 2 Class 3 Class 4 substances
Total dust Not applicable
Inorganic substances in
Not applicable
powdered form
Inorganic substances in
Not applicable
vapour or gaseous form
Organic Substances 0,07 % 98,07 %
Carcinogenic substances Not applicable
Mutagenic Not applicable
Toxic to reproduction Not applicable

National chemical inventory status:

List Status
TSCA : Listed
DSL : Listed
AICS : Listed
NZIoC : Listed
ENCS : Listed
KECI : Listed
PICCS : Listed
IECSC : Listed
TCSI : Listed

To import this product into the EU your company requires registrations for all constituent substances that
are subject to REACH registration. To discuss the possibility of setting up an Only Representative
agreement with Infineum, please e-mail [email protected]

REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous
substances, mixtures and articles (Annex XVII)

Status : Not applicable

REACH - List of substances subject to authorisation (Annex XIV)

Status : Not applicable

Regulation (EC) No 1005/2009 on substances that deplete the ozone layer

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Status : Not applicable

Regulation (EC) No 850/2004 on persistent organic pollutants

Status : Not applicable

REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).

Status : Not applicable

15.2 Chemical safety assessment

A Chemical Safety Assessment has been carried out for one or more of substances within this mixture.

SECTION 16. OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.


H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.

Revision changes since the previous version are marked in the margins throughout this document

Sources of key data used to compile the Safety Data Sheet:

Austria: Regulation on Combustible Liquids VbF AT V1.2


EU Registration, Evaluation and Restriction of Chemicals regulation (REACH): Classification and
Labelling Inventory
Denmark: Executive Order No. 301 Bekendtgørelse om fastsættelse af kodenumre Arbejdstilsynets
bekendtgørelse nr. 301 af 1. maj 1993 (MAL Code)
France: Installations Classées pour la Protection de l'Environnement. (Loi 76/663 (modifiée) relative
aux installations classées).
France: le code de la sécurité sociale (titre VI du livre IV). (maladies professionnelles)
Germany: Administrative regulation for water hazardous substances # VwVwS of 17 May1999 (WGK).
Germany: LGK. Combined storage of chemicals # Federation of Chemical Industries dated July 1998.
Germany: TA Luft
UN Economic Commission for Europe: European Agreement Concerning the International Carriage
of Dangerous Goods by Road (ADR)
Infineum studies
International Agency for Research on Cancer
International Air Transport Association: Dangerous Goods Regulations.
International Maritime Organization: International Maritime Dangerous Goods Code
Component supplier data

Key or legend to abbreviations and acronyms used in the safety data sheet
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DSL : Domestic Substances List (DSL)


NDSL : Non-Domestic Substances List (NDSL)
PICCS : Inventory of Chemicals and Chemical Substances (PICCS)
TSCA : TSCA Inventory
AICS : Australia Inventory of Chemical Substances (AICS)
IECSC : China. Inventory of Existing Chemical Substances in China
(IECSC)
ENCS : Japan. ENCS - Existing and New Chemical Substances
Inventory
KECI : Korea. Korean Existing Chemicals Inventory (KECI)
NZIoC : New Zealand. Inventory of Chemical Substances
EINECS : European Inventory of Existing Commercial Chemical
Substances (EINECS)
ELINCS : European List of Notified Commercial Substances (ELINCS)
ATE : Acute toxicity estimate
STEL : Short term exposure limit
TWA : Time weighted average
LC50 : Lethal Concentration to 50 % of a test population
LD50 : Lethal Dose to 50% of a test population (Median Lethal Dose)
PPE : Personal Protection Equipment
TCSI : Taiwan Chemical Substance Inventory

Procedure used to derive the classification for mixtures according to Regulation (EC)
1272/2008 [CLP]

Classification Classification procedure:


Chronic aquatic toxicity, Category 3, Calculation method
H412

The information contained in this document is based upon data believed to be reliable at the time of
going to press and relates only to the matters specifically mentioned in this document. Although
Infineum has used reasonable skill and care in the preparation of this information, in the absence of
any overriding obligations arising under a specific contract, no representation, warranty (express or
implied), or guarantee is made as to the suitability, accuracy, reliability or completeness of the
information; nothing in this document shall reduce the user's responsibility to satisfy itself as to the
suitability, accuracy, reliability, and completeness of such information for its particular use; there is no
warranty against intellectual property infringement; and Infineum shall not be liable for any loss,
damage or injury that may occur from the use of this information other than death or personal injury
caused by its negligence. No statement shall be construed as an endorsement of any product or
process. For greater certainty, before use of information contained in this document, particularly if the
product is used for a purpose or under conditions which are abnormal or not reasonably foreseeable,
this information must be reviewed with the supplier of such information.

Revision Date : 29.07.2020

Prepared by : Infineum Product Stewardship and Regulatory Compliance

Issuing date : 03.12.2020

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Annex
Exposure scenario
The obligation to undertake a Chemical Safety Assessment, and requirement to place relevant exposure
scenarios in an Annex to the Safety Data Sheet, are provisions of the EU REACH Regulation. The
content is not relevant to this region.

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