MATRIX ACADEMY

MHT-CET-XII - New Syllabus (MH) 2022-23

Time : 45 Min Chem : Groupwise Paper Marks : 50

01) The number of tetrahedral voids in the unit cell C) weak electrolyte
of a face centered cubic lattice of similar atoms is D) all of the above
A) 10
B) 8 10) The species which will behave both as a
C) 6 conjugate acid and base is ....
D) 4 A) HSO4

02) Which of the following solids is isotropic? B) COa 2

A) Pt C) NH4
B) NiO D) H2SO4
C) NaCl
D) Rubber
11) Which arrangement of electrons describes
ferromagnetism?
03) Acetic acid is a weak electrolyte because
A) it does not dissociate much or its ionization is A) 
very less. B) 
B) its molecular weight is high. C) 
C) it is covalent compound. D) 
D) it is highly unstable.
12) In solid CsCl, each Cl is closely packed with
04) When electrons are trapped into a crystal in how many Cs?
anion vacancy; the defect is known as ....... A) 2
A) Frenkel defect B) 6
B) Schottky defect C) 8
C) Stoichiometric defect D) 10
D) F-centres
13) In a crystal, the atoms are located at the
05) The extent of ionization increases position of
A) on stirring the solution vigorously. A) infinite P. E.
B) on decreasing the temperature of solution. B) zero P. E.
C) on addition of excess water to solution. C) minimum P. E.
D) with the increase in concentration of solute. D) maximum P. E.

06) Ionic product of water increases, if 14) A compound is formed by elements A and B.
A) H is added. This crystallizes in the cubic structure when atoms
B) pressure is reduced. A are the corners of the cube and atoms B are at
C) OH is added. the center of the body. The simplest formula of the
D) temperature increases. compounds is
A) A2B
07) The number of tetrahedral sites per sphere in B) AB4
FCC structure is .... C) AB
A) 4 D) AB2
B) 3
C) 2
D) 1 15) Suppose the mass of a single Ag atom is 'm'. If
Ag metal crystallises in FCC lattice with unit cell of
08) Copper belongs to which system? length 'a', the density of Ag metal is .....
A) Cubic system 4m
A)
B) Tetragonal system a3
C) Triclinic system 2m
D) Monoclinic system B)
a3
m
09) The compound has   0.25, it means it is a C)
4a 3
.........
A) ionic salt m
D) 3
B) electrolyte a

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concentration about 0.01 mole / litre. The pH of

16) For an aqueous solution, the characteristic gastric juice is
species of acid is A) 14
A) H4O ion B) 2
B) H3O ion C) 1
D) 0.01
C) H2 ion
D) H ion 25) Which of the following salts, when dissolved in
water, will get hydrolyzed?
17) Lewis acid are those substances A) Na2SO4
A) which accept OH- ion. B) KCl
B) which give electron pair. C) NH4Cl
C) which provide H+ ion in the solution. D) NaCl
D) which accept electron pair.
26) pK a value of the strongest acid among the

18) The number of moles of hydroxide (OH ) ion following is
A) 1.0
in 0.3 litre of 0.005 M solution of Ba(OH)2 is
B) 2.0
A) 0.0075 C) 3.0
B) 0.0050 D) 4.5
C) 0.0030
D) 0.0015 27) A buffer solution has equal volumes of
0.2 M NH4OH and 0.02 M NH4Cl . The pK b of the
19) A metal has bcc structure and the edge length
base is 5. The pH is
of its unit cell is 3.04 Å . The volume of the unit A) 4
cell in cm3 will be B) 7
A) 6.6  1024 cm3 C) 9
D) 10
B) 6.02  1023 cm3
C) 2.81  1023 cm3 28) pH of NaCl solution is
A) zero
D) 1.6  1021 cm3 B) 7
C) > 7
20) Bravais lattices are of D) < 7
A) 8 types
B) 9 types 29) If solubility of calcium hydroxide is 3 , then
C) 12 types
its solubility product will be
D) 14 types
A) 12 3
21) If the solubility product of BaSO4 is 1.5  109 B) 3
C) 9
in water, its solubility in moles per litre, is
D) 27
A) 1.5  105
B) 3.9  105 [salt]
30) Henderson's equation is pH  pKa + log .
C) 7.5  105 [acid]
D) 1.5  109 If the acid gets half neutralized, then the value of
pH will be : [pKa  4.30]
22) A white substance was alkaline in solution. A) 2.15
Which of the following substances could it be? B) 4.3
A) NaNO3 C) 7
B) NH4Cl D) 8.60
C) Na 2CO3
31) On doping germanium with a small amount of
D) Fe2O3 gallium a ..... type semiconductor is obtained
A) intrinsic
23) Coordination number for Cu is B) p-type
A) 12 C) n-type
B) 8 D) both (a) and (c)
C) 6
D) 1 32) Which of the following is a buffer?
A) K2SO4 + H2SO4
24) The gastric juice in our stomach contains B) NH4OH  CH3COONH4
enough HCl to make the hydrogen ion

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C) NaOH  Na 2SO4 B) Ksp  [Al3 ]3 (SO24 ]2

D) NaOH  CH3COONa
C) Ksp  [Al3 ]2 (SO24 ]3
33) The true statement is: D) Ksp  [Al3 ] (SO24 ]
A) Electrolytes use free electrons to conduct
electricity. 40) Element A and B constitute bcc type crystalline
B) The size of the band gap decides the electrical structure. Element A occupies body centre position
conductivity of a substance. and B is at the corner of cube. What is the formula
C) Semiconductor prepared by adding a dopant are of the compond? What are the formula of the
called intrinsic semiconductor compound? The coordination numbers of A and B
D) Metalloids are usually insulators above room are
temperature A) AB2 , 6
34) Which of the following can attain ionic B) AB3 , 4
equilibrium? C) AB,8
A) aqueous NaOH D) A2B, 8
B) dilute HCl
C) NH4OH 41) ______ has solid CO2 is an example.
D) H2SO4 A) Ionic crystal
B) Metallic crystal
35) A metal crystallises in fcc and bcc. The ratio of C) Covalent crystal
the densities in two phases is 1.259. If edge length D) Molecular crystal

in fcc is 3.5 A , the edge length in bcc is
42) What are the number of CsCI formula units

A) 3.0 A and the coordination number of each type of ion in
it?

B) 4.4 A A) 4, 4
 B) 4, 8
C) 2.5 A C) 1, 8
 D) 2, 8
D) 4.5 A
43) A compound having the formula X4 Y3
36) The precipitation occurs, if ionic concentration crystallises with ccp lattice of Y atoms. The fraction
is of tetrahedral holes is occupied by X atoms in it is
A) more than solubility product. 1
B) less than solubility product. A)
2
C) equal to solubility product.
D) none of these. 2
B)
3
37) Ksp of a sparingly soluble salt 3
C)
AB2 is 4  1012 mol3 L3 . What is the solubility of 4
1
the salt? D)
8
A) 1  1012 M
B) 4  104 M 44) Which of the following defects is seen in FeO?
C) 2  106 M A) Metal excess
D) 1  104 M B) metal deficiency
C) displacement
38) The solubility product of a sparingly soluble D) impurity
salt AX2 is 3.2  1011 . Its solubility (in 45) The hydrogen ion concentration in weak acid of
moles/litres) is dissociation constant K a and concentration c is
A) 5.6  106 nearly equal to
B) 4  104 A) K a c
C) 3.1  104 B) K a c
D) 2  104 C) c / Ka

39) The expression for the solubility product of D) Ka / c

Al2 (SO4 )3 is
46) An element occurring in the bcc structure has
A) Ksp  [Al3 ]2 (SO24 ]2
12.08  1023 unit cells. The total number of atoms

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of the element in these cells will be

A) 6.04  1023
B) 12.08  1023
C) 24.16  1023
D) 36.18  1023

47) A solid has a bcc structure. If the distance of


closest approach between the two atoms is 1.73 A ,
find the edge length of the cell.
A) 200 pm
B) 3 / 2 pm
C) 2 pm
D) 142.2 pm

48) The density of an ionic solid belonging to cubic

system, with the unit cell dimension of 654 pm is
2.75g /cm3 . If the molecular mass of the solid is
119 . The solid belongs to which one of the
following?
A) fcc system with coordination number =6
B) bcc system with coordination number=8
C) sc system with coordination number =6
D) none of these

49) A solid melts slightly above 00 C and is a poor

conductor of electricity. Hence, it may be a .....
A) network solid
B) ionic solid
C) covalent solid
D) molecular solid

50) pH of 2 M NaCl will be ......

A) 14
B) 3
C) 7
D) 0

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