He a lt h 2

2 3
Fire
2 0
Re a c t iv it y 0
P e rs o n a l H
P ro t e c t io n

Material Safety Data Sheet

Acetylacetone MSDS

Section 1: Chemical Product and Company Identification

Product Name: Acetylacetone Contact Information:

Catalog Codes: 10023, 20026 Finar Limited
184-186/P, Chacharwadi Vasna,
CAS#: 123-54-6 Sarkhej-Bavla Highway,
RTECS: SA1925000 Ta.: Sanand, Dist.: Ahmedabad,
Email: [email protected]
TSCA: TSCA 8(b) inventory: Acetylacetone Web: www.finarchemicals.com
CI#: Not available.
Synonym: 2,4-Pentanedione
Chemical Formula: C5H8O2

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Acetylacetone 123-54-6 100

Toxicological Data on Ingredients: Acetylacetone: ORAL (LD50): Acute: 1000 mg/kg [Rat]. 951 mg/kg [Mouse].
DERMAL (LD50): Acute: 5000 mg/kg [Rabbit].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of
skin contact (permeator). Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin
contact (permeator). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged inhalation of vapors may lead
to chronic respiratory irritation.

Section 4: First Aid Measures

p. 1
Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before
reusing.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that
the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,
tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 340°C (644°F)
Flash Points: CLOSED CUP: 34°C (93.2°F). (TAG) OPEN CUP: 40.6°C (105.1°F) (Cleveland).
Flammable Limits: LOWER: 2.4% UPPER: 11.6%
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances: Not available.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,
water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined
areas; dike if needed. Eliminate all ignition sources.

p. 2
 Section 7: Handling and Storage

Precautions:
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not
breathe gas/fumes/ vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek
medical advice immediately and show the container or the label. Avoid contact with skin and eyes
Storage:
Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away from
sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing
material. A refrigerated room would be preferable for materials with a flash point lower than 37.8°C (100°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Strong.
Taste: Not available.
Molecular Weight: 100.13 g/mole
Color: Clear Colorless.
pH (1% soln/water): Not available.
Boiling Point: 140.5°C (284.9°F)
Melting Point: -23°C (-9.4°F)
Critical Temperature: Not available.
Specific Gravity: 0.976 (Water = 1)
Vapor Pressure: 7 mm of Hg (@ 20°C)
Vapor Density: 3.45 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Soluble in cold water.

p. 3
 Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:
Acute oral toxicity (LD50): 951 mg/kg [Mouse]. Acute dermal toxicity (LD50): 5000 mg/kg [Rabbit].
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Class 3: Flammable liquid.

Identification: : Pentan-2,4-dione : UN2310 PG: III
Special Provisions for Transport: Not available.

p. 4
 Section 15: Other Regulatory Information

Federal and State Regulations:

Pennsylvania RTK: 2,4-Pentanedione Massachusetts RTK: 2,4-Pentanedione TSCA 8(b) inventory: Acetylacetone
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-1A: Material causing immediate and
serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC):
R10- Flammable. R38- Irritating to skin. R41- Risk of serious damage to eyes.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 3
Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 2
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/06/2010
Last Updated: 24/11/2012

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall Finar Limited be liable for any claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Finar
Limited has been advised of the possibility of such damages.

p. 5