TOPICS OF THE TEST aA Chemistry Mathematics Thermal Properties of Matter, Thermodynamics, Kinetic Theory of Gases. s-Block Elements, Some p-Block Elements (Group 13 & 14), States of Matter : Gases & Liquids. Three Dimensional Geometry, Derivatives (Class XI), Probability, Mathematical Reasoning.All India Aakash Test Series for JEE (Main)-2023 TEST -5 MM: 300 PART - A: PHYSICS ‘SECTION -1 5, Multiple Choice Questions: This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4), out of which ONLY ONE is correct. For an ideal gas undergoing a thermodynamic process work done is related to temperature change as dW = 2RAT for one mole, Find molar heat capacity of the gas. (1) 2R (2) 4R (3) 3R (4) §R 2. The specific heat capacity of an_idealgas undergoing a thermodynamic progess is given by © = (a + bT) kikkg’C. If the mass of gasis | 7. mkg and the temperature varies from Ty to Ty then find the mean specific heat f-the-gas (in kdlkg"C) 2a+bTp 2ab(Tp +T) w ae ) e-) (a) 2222=) (gy 28 3Te TH) 2 2 3. Which among the following represents the slope of adiabatic process of an ideal gas in In | 8, Vs InP graph. G, 2 og @) 4 c, Gc, (3) 1-2 @) op op 4, Determine the value of polytropic index of | 9 expansion for a process in which final 1 temperature is 2rd of the initial temperature pe 3 P while final volume is thrice the initial volume. (1) 0 (2) 1 (3) 2 (4) 1.33 A vessel contains an ideal gas at a pressure Po. If mass of molecules is tripled and their speed is made half of their intial values, then the final pressure P will be 2 (y 3% (2) Er 3 1 @) 7 (4) 3 An ideal gas is expanded adiabatically. The adiabatic exponent of gas y = 4/3. How many times the volume of gas needs to be increased to make root mean square speed of the gas half ofits initial value? 4 @2 (3) 64 (4) 16 The! PV, diagram of a thermodynamic cyclic process A>BCrA is represented by a triangle ABC with coordinates of points A, B and Cobeing (4, 1), (2, 4) and (2, 1). The pressure axis (y) measures in Nim? and volume ‘axis (x) measures in liters. Find the magnitude of work done during process from state A to state B (1) 2x 1070 (24x10 (3) 5x 10-°N (4) 6x 10% ‘A Carnot heat engine, having efficiency n = 0.1 is used as a refrigerator. If the work done on the system is xJ, then the amount of energy absorbed from the cold reservoir is (in Joules) (1) 9x (2) 10% 10x (3) 11x @ & Equal amount of heat is supplied to a diatomic ideal gas first at constant pressure and then at constant temperature. What is the ratio of work done by the gas in two processes respectively? (1) (2) (3) (4) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : (011) 47623456All India Aakash Test Series for JEE (Main)-2023 EZ (Crm 10. A rigid diatomic ideal gas undergoes an | 14. 10 litres of water i filed in a glass vessel upto adiabatic process at room temperature. The full, Coefficient of cubical expansion of water relation between temperature and volume for sat ty tg» 1040 ana this process is TV" = Constant, then ‘x is and glass are given by ani 0.9 x 10~/°C. If the temperature is increased 2 2 m2 @ $ by 30°C, how much water wl spill out? 5 3 (1) 7ec (2) 10 cc @ ¢ 2 3 5 (3) 12cc (4) Sec 11. A Carnot engine has a cycle as shown. If Wm | 45 Heat at constant rate is supplied to an ice cube and We represent the work done by 1 mole of monoatomic and diatomic gases in one cycle that kept melting at a rate of 0.4 gris for 50 sec respectively then til it _metts completely. The rate at which P, temperature rises further with same constant supply is (Li= (1) 0.6°Cis (2) 1.2°Cis (2) 16°CIs (4) 18°C/s ve Gav, 16. A steelring of radius r and cross sectional area (1) Wena AA at room température is fited onto a wooden wi dise/6P radius) (R > r) by heating the ring and (8) Wn = We 4) Wy = then eooling it. If ¥ is Young's modulus of ring 42, N moles of perfect moncatom Specs then fension in the steel ring developed after contained in a cylinder with insulating walls cooling is (neglect change in area A) closed at one end by insulating piston. The . initial volume is V and initial temperature is: TIF Os @) va(5=*) the volume is suddenly increased, by On vr withdrawing the piston rapidly, to 2V, then find A R . ga) to 4) yak the final temperature. ee vad wt at TE Three identical metal fods A, 8 and Cre a Qe placed end to end with temperature difference 1 between free ends of rods A and © maintained @T 4) Tiai8 at 0. If thermal conductivity of B is twice that of 13. How much steam at 100°C is needed to be © and half that of A, then temperature added to 10 lies of water at 30°C to have difference at the ends of rod B is cal water at 50°C finally? (Ly = 540 2, oy = 4 Q vt om os cal ) x 3 q om—"C 2) 2. @ 4 20 20 1) 22 2 2% y Brg @ Drs 8 ® 5 10 a) 2x (4) 03k 28 @) Pa (4) 03 kg w 2 Corporate Office : Aakash Tower, 8, Pusa Rodd, New Delhi-110005. Phone : (011) 47623456poor) All India Aakash Test Series for JEE (Main)-2023 18. A frustum shaped rod has cross sectional area that varies from its one end with distance x as A= As (1 + ax), where Ao and a are constants, ‘The rod has length J and is maintained between the temperatures T; and Te (Ti < Tz) with Ty being the temperature at cross section with Which of the following represents the temperature at a cross section at distance x from the end at temperature T:? smaller radius. In(t + x) 4) 7 =(7-7 yea) 0 Te -Wineah In(t ax) 2) T+ Tetnaral In(t+ 0x) ) te ® Te Tn al) 19. For the following graphs of spectral intensity of heat radiation and frequency _at=given temperatures by the black body, which among the folowing ean be correct possiiity” (1) Tr> Ta Ts (3) Ts>T2> Th 2) Te> Tats (4) Te> Toe Tr 20. Two heat engines are connected in series with heat rejected by first engine being used as heat input of second engine. The efficiency of engines are 0.2 and 0.25 respectively. The net efficiency of the combination is (1) 04 (2) 03 (3) 0.36 (4) 0.27 ‘SECTION - I Numerical Value Type Questions: This section contains 10 questions. Attempt any five questions out of 10. The answer to each question is a NUMERICAL VALUE. For each question, enter the e.g. 06.25, 07.00, -00,33, 00.30, 30.27, -27.30) using the mouse and the on-screen virtual numeric, keypad in the place designated to enter the answer. 21. PV diagram of an ideal diatomic gas is a straight line passing through origin. The molar heat capacity of the ideal gas in the process is n times the molar heat capacity of gas at the constant volume. Find the value of n. 22. A monoatomic gas undergoes a process in which it uses 60% of heat in doing work. If the process equation of gas is P*V° = Constant, then find the value of @ + 6. (a & b being coprime numbers) 23. A solid metal cube of volume V and density p has specific heat capacity $ and coefficient of linear expansion a. The heat required to be added to the cube to increase its volume by 1% igre REI nd no va of 24. _A monoatomic ideal gas is heated in such a way thatthe molar specific heat of gas during the process'is 32 During heating the volume of the gas becomes & times. By what factor does the absolute temperature of the gas increases? 25. Determine the mean free path in multiples of 10° m, if diameter of molecules is 1 A and 26. (V, 7) diagram of a quasi-static process of a monoatomic ideal gas is a straight line passing through (Ve, Ta) and (3Ve, 57s). The value of heat capacity of gas at point (Vo, To) is given by xR where Ris universal gas constant. Find the value of x. 27. In an adiabatic process 6000J of work is performed on a system. Then the system ‘comes back to the initial state by adding 2000 J of heat. The work done by the system in second correct numerical value (in decimal notation, partis given by n * 102 J. Find the value of n. truncated/rounded-off to the second decimal place; Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : (011) 47623456All India Aakash Test Series for JEE (Main)-2023 28. Ina thermodynamic cyclic process consisting of four steps, the heat supplied to the system and work done by the system for each step are as follows. Step 1 | Step2 | Step 3 | Step 4 Q 40s | 104 | 155 ] 5 w: | tos | t5u | -5s | ov Determine the thermal efficiency of the cycle in percentage. 29. 30, Test (Crm ‘An ideal gas at pressure P is initially expanded freely to thrice its volume and then compressed adiabatically to original volume such that the pressure becomes (3)'"P. The ratio of average speed of gas molecules in the final state to that in the iniial state is given by (3)", find the value of n. In an isothermal process containing n moles of ideal gas volume quadruples from its inital value. Change in entropy during the process is given by AS = 2nRin(x). Find the value of x PART — B : CHEMISTRY SECTION -I Multiple Choice Questions: This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4), out of which ONLY ONE is correct. 31. Which of the following order given belowsis correct according to the indicated property? (1) BeO > Mg0 > Cad > S10 > Bad (Basicity ordet) (2) BeO < MgO < CaO. (LED) (3) MgO >Ca0>BeO (Melting point) (4) MgQ2 > CaQz > S102 > BaO> (Stabilty of peroxide) 32. BeChz in vapour state above 1200 K exists as A and below 1200 K exists as B, Which of the following is incorrect about structures A and B. (1) In structure A, the hybridization of Be is sp (2) In structure 8, the hybridization of Be is sp? (8) In structure 8, the hybridization of Be is sp* (4) The structure of Ais linear 33. Which one of the following compounds is polymeric as well as electron deficient? 34, 36. 36. 37. Which one of the following compounds is present in maximum amount in Portland cement? (1) Cao, (2) SiOz (3) ALOs (4) Mgo Which one of the following orders is incorrect for alkaline earth metals with the indicated property? (i) Ba>si>'ca>Mg>Be (Radius) (2) Be” >Mg?* > Ca® > Sr?* > Ba” (Magnitude of hydration enthalpy) (9) Be>Mg>Ca> Sr>Ba (lonization eneray) (4) Be> Mg > Ca> Sr> Ba (Density) Which of the following is correct match for the flame coloration of alkali metal salts? “yk Golden yellow (2) Na Lilac (Violet) (3) Rb Blue 4) ui Crimson red The carbonates are remarkably stable and will melt before they eventually decompose into oxide, Which of the given bicarbonate exists as adimer? (1) MgHe (2) BeCke (solid) (1) NHsHCOs (2) LiHCos (3) Cale (4) Ab(CHe)e (3) NaHCOs (4) KHCOs Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : (011) 47623456pcr) 38. The properties of lithium and its compounds differ far from those of the other alkali metals. ‘Some of the differences are given below. Which of the difference is not shown by lithium? (1) The metting and bolling point of lithium are much higher than those of the other alkali metal elements (2) Lithium reacts directly with carbon to form carbide (3) LO and LiF are insoluble in water (4) Lithium forms ethynide on reaction with ethyne 39. Which of the following is not correct about Solvay ammonia process (1) NaCl is used as one of the reactants.in the reaction (2) NHsHCOs is formed during the reaction (3) The materials used are NaCl and CaCO’ and there is one useful product, NazGOs and one by product, CaCle (4) KeCOs process can be manufactured by this 40. 2NelBH,} +1, — "vee, P + + 2Nal Qis a combustible gas, B,O, +Q+Al—3"_5P + ALO, e+( Jer Which of the following is not correct about the reactions given above? (1) P=BHe (2) P= He (3) Q= He 2, 4) Re —BH, (4) OI 44 42, 43, Sirus) Statement |: In bleaching powder oxidation state of Cais +2, Statement Il : In bleaching power, chlorine is present in both +1 and ~1 oxidation states, Which of the following statement(s) is/are correct? (1) Both statements are correct, (2) Both statements are incorrect (3) Statement | is correct but statement Il is incorrect, (4) Statement | is incorrect but statement II is correct ‘A compound is made up of elements X, Y and Z with their oxidation number +3, +5 and -2 respectively. Which of the following is incorteet? (4) The possible formula of the compound is XoYZiy (2) Two ‘of these elements can be from the aime group of periodic table (3) Xand Y may be from 15" group (4) Allof three elements must be metals At high temperature the metals of group 1 and the group 2 metals (alkaline earth metals) Ca, Sr and Ba form ionic hydrides. Which of the following is incorrect for ionic hydrides (1) Molten LH conducts electricity and liberates He at anode (2) Cab liberates He on reaction with Ha (3) The crystal structures show evidence of directional bonding (4) The density of these hydrides is greater than that of the parental metals Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone (011) 47623456DUI kc 44, Assume you have a glass tube of 100 om long Some NHh(g) is allowed to diffuse along the tube from one end and some HBr) diffuses along the tube from opposite end under identical conditions. If at X distance along the tube the gases meet and react to form NH:Br from NHs gas side. The value of X in cm is, (atomic mass of Br is 80 u, (4.76)"? = 2.18) Solid NHBr — (1) 68.55 om (2) 25.50 om (3) 34.00 em (4) 39.00 em 45. Which of the following statement is not correct, according to the kinetic theory of gases? (1) The total volume occupied by’ the gas molecules is negligible in comparison to the total volume of the gas (2) Collisions of gas molecules are perfectly elastic (3) The molecules are in rapid motion, which is, completely random (4) A given molecule can have energy ranging) from a small value to very large value, because of that average kinetic energy changes 46. Which of the following is correct about the compresibilty factor of the given gases? (1) Zis always equal to one for He (2) For Ny Z > 1 pressure in the lower range of (3) For gases which are easily liquefied Z dips sharply below the ideal line in the high pressure region (21, over attractive forces When repulsive forces dominate rey 47. [Gas] a (kPa dmé mot) | b(dm? mot) He 21.764 0.02661 Oz 137.802 0.03183, Ch 657.903, 0.05622 H.0 553.639, 0.03049 Which one of the following gases is most easily liquefiable? (1) He (2) (3) Ck (4) H20 48. Which one of the following relation is not correct for critical constants and van der Waals constants a and b? 49. The temperature at which the average speed of H2,equal to the average speed of Fzat 320 K is (1) 67.368 (2) 16.84K (3)/ 33.68 k (4) 168.42 K 50, <—— gas B ! <0 v— Which of the following option is correct for the curves given above? (1) Gas Ais He and gas B is ideal gas (2) Gas Ais ideal gas and gas Bis Hz (3) The curves are for same real gas under identical conditions (4) The curves are for ideal gas under identical conditions Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone (011) 47623456perce SECTION -11 Numerical Value Type Questions: This section contains 10 questions. Attempt any five questions out of 10. The answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value (in decimal notation, truncatedirounded-off to the second decimal place; e.g. 06.25, 07.00, -00.33, -00.30, 30.27, -27.30) using the mouse and the on-screen virtual numeric keypad in the place designated to enter the answer. 51. 2NaBO2 + 2H202 + 6H:0 —> A Ais used as brightener in washing powders, The number of 8-O-0-B bonds present in each molecule of A, is 52, BC, +NH C2“ 5 aN D+xH,0—»NH,OH + B(OH), The value of x for one mole of D, is 53. Find the number of compounds’ from the: following with which diborane “cleaves unsymmetrically forming [L2H28)" [BHs1- type of complex (where L being Lewis base) NHs, MesN, MeNH2, CO, Et20. 8c >A+B+C 54, 4Be(NO;). © is a gas which is colourless. paramagnetic and B is an oxide, paramagnetic, which is coloured and The number of Be-O bonds present in ‘compound A is 55. If the weight (in Kg) of O2(g) necessary to fill up a cylinder of 8 L capacity at 27°C and 300 atm H, (Unbalanced) DONT 56. 87. 58, 59. 60, rs pressure, when the compressibility factor is 0.5 is X. Then the value of 10X is (Use R = 0.08 L atm Kt mot) A balloon is filed with He to a volume of 6 L at a pressure of one atm. Oxygen gas is then added, so that the final volume of balloon is 24 LL, with a total pressure of one atm, Mass of added is 9. (Consider temperature is constant throughout as 27°C, use R= 0.08 L atm K* mot") oxygen Diffusion of certain volume of Nz(g) at 1.0 atm and 300 K, takes 50 sec, while same volume of {an unknown gas of xenon (atomic mass 131 u) and fluorine (atomic mass 19 u) at 2.0 atm and 300 K takes 68 sec for diffusion through the same pinhole, The number of atom present in each molecule of unknown gas is__ (Assume the molecular formula of unknown gas is XeFx) The rate of effusion of a sample of ozonized oxygen i8)0.9 times that of pure oxygen, The Tass percentage of Os in the sample is X. Then the Valué/of X is___. (Round off to the nearest integer) If the value of root mean square speed is 100 The pressure exerted by 10% gas particles each of mass 10” g in a container of om st, Cchme ie "Pa. Tho vate tx of (x+y) is PART — C : MATHEMATICS SECTION -1 Multiple Choice Questions: This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4), out of which ONLY ONE is correct. 61. There are 5 wrong questions in a question Paper, consisting of 10 questions. If 6 questions are selected from this question paper, then the probability that there will be exactly 3 wrong questions among them is 5 10 OF Qo 10 5 8) a7 Oa Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone (011) 4762345662, 63, 65. 66. 67. ( If y =logg| 14 x8 + xo |, where \ J oY (0, 1) then I x<(0, 1)then & is equal o 2x 4) 2 2 () ®) jog..0 (3) 2x1og,,€ (4) 2xtoget0 The statement (p <>~q) is equivalent to () peg (2) A tautology 3) Atallacy (4) ~(poa) Statement ~ ((p.q))~ p)is equivalent to (1) Contradiction (2) Tautology (3) ~p (4) ~¢ d ne = -2.(7™"yis (hore In x = logex) equal to ox (1) x*7 Ina. (2) 7 -In7 (3) x*-In7 (4) <7%In7 If y=109, x-|{cos%—sin®)|.{ cos% + sin® 9. ¥-] [9052 — SIND LOPE ) cos(n- x)-282x) Zootx| then & is equal to ox 4 1 Ms @ -+ x x osx (sinx. cos) @) ga Equation of the set of the points which are equidistance from the points (0, 1, -2) and (1,1, -2) is (1) 4y+2x+1=0 (2) 2x-dy+1=0 (3) 4y-2x+1=0 (4) dx-2y+t=0 68, 69, 70. m1 72 73, or) The negation of the statement Ram is intelligent and dishonest if and only i Ram is poor is given by (Consider the following statements. P:: Ramis intelligent Q: Ram is poor R: Ram is honest) (1) Q>Pa~R) (2) ~(Qo(Pa~R)) (3) ~(RO(Pa~Q) (4) ~(@o(Pv ~R)) Three identical dice are rolled. The probability that the same number will appear on exactly two dice, 5 5 (1 a> 5 1 Oa 4) 36 The direction cosines of a tine PQ are v2.2 4, = 2 ana P= 3. Co-ordinates of point P 333 ps are (7, 5, 3), then co-ordinate of Q, can be () 5,3) (2) 6,3,7) (3) (6, 7, 1) (4) (8,7. 5) ‘The statement q — (p — q) is equivalent to (1) pera) 2) py~p @a>eea (4) p> ea) Let p, 9, rbe three statements such that truth value of (pv g) > (~ qs T. Then the truth values of p, g, rare respectively () ATF 2) TAT (3) TTF (4) TAF Which of the following statement is not true? (1) Jaipur is capital of Punjab or Rajasthan (2) $s aratonal or rational number (3) 625 is a multiple of 2 or 3. (4) A square is a quadrilateral or a pentagon Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : (011) 47623456perce 7A, 75, 76. 77. 78, 79, Y) Four distinct numbers are selected from first 50 natural numbers. The probability that all the four numbers are divisible by 2 and 3 is 1 7 4) 2) ” 3090 @) 3290 7 1 ®) 3080 © 290 Wf f()=[[2x-+r), then value of P= 4) is equal to m7 @) -2*() @) -@% (4) 2x (7) Two unbiased dice are thrown simultaneously to get the co-ordinates of a point in the xy plane, then the probability that the point lies inside or on the region bounded by el # W1=3.55 1 1 4 2 m2 as 1 5 a) 1 a & & a ) 36 If an integer N is chosen at random in the interval [0, 8), the probability that the equation one M49 wat nave reall and distinct roots is equal to 3 1 Or Qs 5 Os Ola Axi T 44 yy ty =A thon & is equal ya Fithen & is equalto (1) 4x4 (2) 4x-4 (8) x4 (4) 4x4 If yn 90812 + AC088x + 8008445 thon ‘cos10x+3cos6x+5cos2x " wy % ig equal to ax °° (1) 4sinx (2) ~4sinax (3) 4sinax (4) ~2sin2x DONT rs 80. The negation of the statement: f Ludhiana is in Punjab, then Mumbai is in India’ is (1) If Ludhiana is not in Punjab, then Mumbai is not in India (2) Ludhiana is not in Punjab or Mumbai is not in India (8) Neither Ludhiana is in Punjab nor Mumbai isin india (4) Ludhiana is in Punjab and Mumbai is not in India ‘SECTION - Il Numerical Value Type Questions: This section contains 10 questions. Attempt any five questions ‘out of 10, The answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value (in decimal notation, ‘runcated/rounded-off to the second decimal place; e.g, 06.25, 07,00, -00.33, -00.30, 30.27, -27.30) using the mouse and the on-screen virtual numeric keypad in the place designated to enter the answer. 81. If sunvof the squares of the distances of a point from three co-ordinate axes in 3-D geometry is 32, then its distance from origin is 82. the points (a, ~ 7, ~ 2), (5, 2, 4) and (6, — 2)are collinear, then value of ais 89. If fx) = Ssinx ~ Bcosx + Be" + Stanx then derivative of fix) at x = Os equal to 84. Line joining two points (2, 6, a) and (b, -3, 4) intersects xz-plane at (-2, 0, 6), then a + b is equal to 85. Let the zeros of a quadratic polynomial function ffx) be 9 and 25. A person selects a number randomly from the set {~ 5, - 4, —3 vo 9, 10} then the probability of selecting a number that is a root of x2) = 0 is p then value of 16p is —1tsinx=008* then value of YL ‘cosx ax 86. If when Tesi is equal to 5 seq Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : (011) 47623456DUI kc 87. If the origin is centroid of a triangle ABC having vertices A(a, 1, 3), B(-2, b, -5) and ©(5, 10, ¢), then the value of a + b + cis equal to 88. The vertices of a triangle ABC are A(4, 0, 0), B(O, -2, 0) and C(O, 0, 2). P be a point equidistant from vertices of AABC and origin ©, then the distance of point P from point att, 1,-1)is Cn 89. 12 persons, among whom A and B, sit at random around a circular table then the probability that there are 3 persons between A and Bis k, then 11kis 90. A committee of 3 persons is selected from 2 men and 3 women, probability that the committee will have no man is k, then 20k is, ‘equal to Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : (011) 47623456