MSDS Gasoil DMA ENG
MSDS Gasoil DMA ENG
Gasoil
Revision date: 09/10/2018
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended uses: Fuel.
Address: Fiskhamnsgatan 8
City: Göteborg
Country: Sweden
E-mail: [email protected]
Most serious harmful effects: Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin
irritation. Harmful if inhaled. May cause cancer. May cause damage to organs through
prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. The
product releases organic solvent vapours which may cause lethargy and dizziness. At high
concentrations, the vapours may cause headache and intoxication.
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
3.2. Mixtures
CLP-
Substance CAS number EC No REACH Reg. No. Concentration Notes
classification
Flam. Liq. 3;H226
Asp. Tox. 1;H304
01-2119484664- Skin Irrit. 2;H315
Fuels, diesel 68334-30-5 269-822-7 50 - 60% Acute Tox. 4;H332
27-0019 Carc. 2;H351
STOT RE 2;H373
Aquatic Chronic 2;H411
Flam. Liq. 3;H226
Gas oils Asp. Tox. 1;H304
(petroleum), Skin Irrit. 2;H315
01-2119475512- Acute Tox. 4;H332
thermal-cracked, 92045-29-9 295-411-7 20 - 30%
39-0002 Carc. 1B;H350
hydrodesulfurize STOT RE 2;H373
Aquatic Acute 1;H400
d Aquatic Chronic 1;H410
Flam. Liq. 3;H226
Distillates Asp. Tox. 1;H304
(petroleum), Skin Irrit. 2;H315
01-2119485816- Acute Tox. 4;H332
hydrodesulfurize 68333-25-5 269-781-5 10 - 20%
23-0001 Carc. 1B;H350
d light catalytic STOT RE 2;H373
Aquatic Acute 1;H400
cracked Aquatic Chronic 1;H410
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
Inhalation: Seek fresh air. Seek medical advice in case of persistent discomfort.
Ingestion: Wash out mouth thoroughly and drink 1-2 glasses of water in small sips. Do not induce
vomiting. Immediately call a POISON CENTER or doctor/physician.
Skin contact: Remove contaminated clothing. Wash skin with soap and water. Seek medical advice in
case of persistent discomfort.
Eye contact: Flush with water (preferably using eye wash equipment) until irritation subsides. Seek
medical advice if symptoms persist.
Burns: Flush with water until pain ceases. Remove clothing that is not stuck to the skin - seek
medical advice/transport to hospital. If possible, continue flushing until medical attention is
obtained.
General: When obtaining medical advice, show the safety data sheet or label.
4.2. Most important symptoms and effects, both acute and delayed
Harmful by inhalation. May cause chemical pneumonia if ingested or vomited. May cause cancer. Irritating to skin - may cause
reddening. May cause damage to organs through prolonged or repeated exposure. The product releases organic solvent
vapours which may cause lethargy and dizziness. At high concentrations, the vapours may cause headache and intoxication.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms. No special immediate treatment required.
Unsuitable extinguishing Do not use water stream, as it may spread the fire.
media:
For emergency responders: In addition to the above: Protective suit equivalent to EN 368, type 3, is recommended.
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
Measuring methods: Compliance with the stated occupational exposure limits may be checked by occupational
hygiene measurements.
Legal basis: EH40/2005 Workplace exposure limits. Last amended December 2011.
PNEC
Fuels, diesel
Exposure Value Assessment Factor Extrapolation Method Note
PNEC aqua (freshwater) 0,083 mg/l 1 Statistic extrapolation
Distillates (petroleum), hydrodesulfurized light catalytic cracked
Exposure Value Assessment Factor Extrapolation Method Note
PNEC aqua (freshwater) 0,029 mg/l 1 Statistic extrapolation
PNEC oral (foodstuffs) 17 ppm 300 Assessment factor
DNEL - workers
Fuels, diesel
Main Impact
Exposure Value Assessment Factor Dose Descriptor Note
Parameter
Dermal DNEL
(acute/short-term
4300 mg/m3/15m 7,5 NOAEC
exposure - systemic
effects)
Dermal DNEL (long-
term exposure - 2,9 mg/m3/8h 24 NOEL
systemic effects)
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
Inhalation DNEL
(long-term exposure 68 mg/m3/8h 7,5 NOEL
- systemic effects)
Distillates (petroleum), hydrodesulfurized light catalytic cracked
Main Impact
Exposure Value Assessment Factor Dose Descriptor Note
Parameter
Inhalation DNEL
(long-term exposure 30 mg/m3/8h 7,5 NOEL
- systemic effects)
Dermal DNEL (long-
term exposure - 2,4 mg/m3/8h 24 NOAEL
systemic effects)
Inhalation DMEL
(acute/short-term
2230 mg/m3/15m 7,5 NOAEC
exposure - systemic
effects)
Personal protective equipment, Wear safety goggles if there is a risk of eye splash. Eye protection must conform to EN
eye/face protection: 166.
Personal protective equipment, Light use (small volume, shortterm contact (below 10 min.)):
hand protection: Wear gloves. Type of material: Nitrile rubber.
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
Heavy use (high volume, longterm contact (more than 2 hours)):
Wear gloves. Type of material: Nitrile rubber.
Breakthrough time has not been determined for the product. Change gloves often. Gloves
must conform to EN 374.
Personal protective equipment, Light use (small volume, shortterm contact (below 10 min.)):
respiratory protection: Not required.
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
10.1. Reactivity
Reacts with the following: Strong oxidisers.
Ingestion may cause discomfort. The product does not have to be classified. Based on existing data, the classification criteria
are deemed not to have been met.
The product does not have to be classified. Based on existing data, the classification criteria are deemed not to have been met.
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
Fuels, diesel
Organism Test Type Exposure time Value Conclusion Test method Source
Rat LC50 (gases) 4h 4.1 mg/l OECD 403
Distillates (petroleum), hydrodesulfurized light catalytic cracked
Organism Test Type Exposure time Value Conclusion Test method Source
Rat LC50 (dust/mist) 4h 4.65 mg/l OECD 403
Harmful by inhalation.
Skin corrosion/irritation
Fuels, diesel
Organism Test Type Exposure time Value Conclusion Test method Source
Rabbit 24h Irritating (OECD 404)
Distillates (petroleum), hydrodesulfurized light catalytic cracked
Organism Test Type Exposure time Value Conclusion Test method Source
Rabbit 72h Irritating (OECD 404)
Temporary irritation. The product does not have to be classified. Based on existing data, the classification criteria are deemed
not to have been met.
The product does not have to be classified. Based on existing data, the classification criteria are deemed not to have been met.
The product does not have to be classified. Based on existing data, the classification criteria are deemed not to have been met.
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
Carcinogenic properties
Fuels, diesel
Organism Test Type Exposure time Value Conclusion Test method Source
Neoplastic
Mouse 104 weeks (OECD 451)
effects observed.
Distillates (petroleum), hydrodesulfurized light catalytic cracked
Organism Test Type Exposure time Value Conclusion Test method Source
Neoplastic
Mouse 104 weeks (OECD 451)
effects observed.
Reproductive toxicity
Fuels, diesel
Organism Test Type Exposure time Value Conclusion Test method Source
125 mg/kg
Rat Dermal NOAEL 20d OECD 421
bw/day
Distillates (petroleum), hydrodesulfurized light catalytic cracked
Organism Test Type Exposure time Value Conclusion Test method Source
NOAEL 50 mg/kg (OECD 421)
The product does not have to be classified. Based on existing data, the classification criteria are deemed not to have been met.
Single STOT exposure: The product releases organic solvent vapours which may cause lethargy and dizziness. At
high concentrations, the vapours may cause headache and intoxication. The product does
not have to be classified. Test data are not available.
12.1. Toxicity
Fuels, diesel
Organism Species Exposure time Test Type Value Conclusion Test method Source
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
None known.
Category of waste: EWC code: Depends on line of business and use, for instance 13 07 01* fuel oil and diesel
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Not included.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Special Provisions: Special care should be applied for employees under the age of 18. Young people under the
age of 18 may not carry out any work causing harmful exposure to this product.
Directive 2012/18/EU (Seveso), P5c FLAMMABLE LIQUIDS: Column 2: 5000 t, Column 3:
50000 t.
Directive 2012/18/EU (Seveso), E1 Hazardous to the Aquatic Environment in Category
Acute 1 or Chronic 1: Column 2: 100 t, Column 3: 200 t.
The product is comprised by Regulation 1907/2006/EC, Annex XVII concerning restrictions.
(28)
Directive 2012/18/EU (Seveso), Petroleum products and alternative fuels (a) gasolines and
naphthas, (b) kerosenes (including jet fuels), (c) gas oils (including diesel fuels, home
heating oils and gas oil blending streams) (d) heavy fuel oils (e) alternative fuels serving
the same purposes and with similar properties as regards flammability and environmental
hazards as the products referred to in points (a) to (d)): Column 2: 2500 t, Column 3: 25000
t.
Covered by:
Council Directive 94/33/EC of 22 June 1994 on the protection of young people at work.
Council Directive 92/85/EEC of 19 October 1992 on the introduction of measures to
encourage improvements in the safety and health at work of pregnant workers and workers
who have recently given birth or are breastfeeding
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
Other Information: This safety data sheet has been prepared for and applies to this product only. It is based on
our current knowledge and the information that the supplier was able to provide about the
product at the time of preparation. The safety data sheet complies with applicable law on
preparation of safety data sheets in accordance with 1907/2006/EC (REACH) as
subsequently changed.
Training advice: A thorough knowledge of this safety data sheet should be a prerequisite condition.
Classification method: Calculation based on the hazards of the known components. Test data
SDS is prepared by
Company: Bureau Veritas HSE Denmark A/S
Address: Oldenborggade 25
City: Fredericia
Country: DENMARK
E-mail: [email protected]
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Safety Data Sheet
Gasoil
Revision date: 09/10/2018
Phone: +45 75 50 88 11
Fax: +45 75 50 88 10
Homepage: www.hse.bureauveritas.dk
Document language: GB
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