MATERIAL SAFETY DATA SHEET

Section 1: Identification
Product Name:​ Ackuretta CURO Splint
Chemical Name/Synonyms: ​Additive plastic
Application: ​Methacrylate-based resin 3D printing systems with 385 nm or 405 nm light sources for fabrication of dental
spacers.
Company: ​Ackuretta Technologies Pvt Ltd
Manufacturer: MACK4D
Am Kraftwerk Lippendorf 16
D 04575 Neukiritzsch
Tel.: +49 34342 50 98 62
Fax: 0049 231 5556 30
E-mail: ​[email protected]
Internet: ​www.mack4d.de
In emergency call ​+49 34342 50 98 62
MSDS Date of preparation:​ 13th of July, 2020
Section 2: Hazard(s) Identification
Classification of substance or mixture​ according to Regulation (EC) No. 1272/2008:
Skin irrit. Cat. 2 H315
Skin sens Cat. 1 H317
Eye irrit. Cat. 2 H319
STOT SE Cat. 3 H335   
Pictograms:

Signal Word(s): ​hazard

Hazard statements:
315 Causes skin irritation.
317 May cause an allergic skin reaction.
319 Causes serious eye irritation.
335 May cause respiratory irritation.
Precautionary statements:
264.1 Wash hands thoroughly after handling.
280 Wear protective gloves/protective clothing/eye protection/face
protection.
302+352 IF ON SKIN: Wash with plenty of water.
321 Specific treatment: (refer to Section 4).
332+313 If skin irritation occurs: Get medical advice/attention.
362+364 Take off contaminated clothing and wash it before reuse.
Other hazards: ​NA
Classification according to Directive 67/548/EEC or 1999/45/EC Hazard symbols
Hazard Symbols:

R-phrases
Xi Irritant.

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36 Irritating to eyes.
37 Irritating to respiratory system.
38 Irritating to skin.
43 May cause sensitization by skin contact.
S-phrases
20/21 When using do not eat, drink or smoke.
28.2 After contact with skin, wash immediately with plenty of water and soap.
Classification according to NFPA Hazard Identification System
Hazard symbol:

Health hazard: 1
Flammability: 1
Reactivity: 1
Special precautions:
Classification according to HMIS (Hazardous Materials Identification System)
Hazard symbol:

Health hazard: 1
Flammability: 1
Physical hazards: 1
Personal protective equipment: B
Section 3: Composition/Information on Ingredients
Substances: ​This product is a mixture
Mixtures: ​Composition/information on ingredients.
Composition/information on ingredients
Classification
REACH Registration according to Hazard class and
Reagent Percentage EC No.: CAS No.
No. Regulation (EC) No. category
1272/2008

Bisphenol Skin Irrit. 2; H315

A-ethoxylat (2 Skin Sens. 1; H317
41637-38-1 Xi; R36/37/38 -; R43
EO/Phenol) Eye Irrit. 2; H319
Dimethacrylat STOT SE 3; H335

Substance with a common (EC) occupational exposure limit value

Bisphenol Skin Irrit. 2; H315
A-ethoxylat (2 Skin Sens. 1; H317
41637-38-1 Xi; R36/37/38 -; R43
EO/Phenol) Eye Irrit. 2; H319
Dimethacrylat STOT SE 3; H335

Section 4: First Aid Measures

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General information:​ Immediately remove stained and soaked clothing. If symptoms are present or in case you are in
any doubt, seek medical advice. If the person loses consciousness, put them in the recovery position and seek medical
advice immediately..
After inhalation:​ Make sure that there is fresh air. If the product irritates the respiratory tract, consult a doctor
immediately.
After contact with skin: ​Wash out and rinse with plenty of soap and water.
After contact with eyes:​ In the event of contact with the eyes, immediately remove contact lenses and rinse with
running water for 10-15 minutes while keeping the eyes open. Consult an eye specialist as soon as possible.
After swallowing:​ Never administer something orally to an unconscious person or someone who is experiencing cramps.
Consult a doctor immediately. Do not induce vomiting.
The most significant acute and delayed occurring symptoms and impact
Skin contact:​ May cause an allergic skin reaction.
Information about emergency medical aid or special treatment
Note for the physician:​ Treat symptomatically.
Section 5: Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:​ Dry extinguishing powder; Dry sand
Unsuitable extinguishing media:​ Excess water
Special hazards arising from the substance or mixture
In case of fire: Wear self-contained breathing apparatus. Coordinate fire-fighting measures to the fire surroundings.
Advice for firefighters
General information
Do not inhale explosion and combustion gases. Coordinate fire-fighting measures to the fire surroundings.
Special protective equipment for firefighters:
In case of fire: Wear self-contained breathing apparatus. Do not inhale explosion and combustion gases. Coordinate
fire-fighting measures to the fire surroundings.
Section 6: Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Use personal protection equipment. Remove all sources of ignition. Provide adequate ventilation.
Environmental precautions
Do not allow to enter into water or drains.
Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Reference to other sections: ​Reference to other sections: For information on personal protective equipment, see Section
8. Section 13 contains information about waste disposal.
Section 7: Handling and Storage
Safety precautions for safe handling
Safety precautions during use:​ Avoid contact with the eyes and skin. Wash contaminated skin thoroughly after handling.
The hands and all contaminated parts of the body must be washed with soap and water before leaving the factory
premises. Keep away from heat, sparks and open flame. Mechanical suction is required if dust is discharged during
handling. Open and handle containers with care. At work, wear suitable safety equipment in the event of longer
exposure and/or high concentrations of vapors, spray or mist.
General work hygiene measures: ​When using the product, do not eat, drink or smoke.
Conditions for safe storage, taking cases of incompatibility into account
Safety precautions for storage: ​Store in a cool and dry place in a tightly sealed original container. Store at temperatures
between 5°C and 30°C. Keep away from frost and direct sunlight. Keep away from hot surfaces, sparks, open flames and
other types of ignition sources. Do not smoke.
Specific end uses
Intended end use(s): ​The intended uses of this product are described as the application in Section 1.
Section 8: Exposure Controls/Personal Protection
Parameters to be monitored: ​No maximum allowable concentration(s) is/are known for the ingredient(s).
Limitation and monitoring of exposure
Protective equipment

Suitable technical controller: ​Adequate room ventilation and local aspiration must be ensured. The maximum allowable
concentration of the product or ingredients must be observed.

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Eye/face protection: ​Eye protection corresponding to a recognized standard should be worn if a risk assessment shows
that eye contact is possible. The following personal protective clothing should be worn: Chemical safety goggles. Wear
close-fitting chemical safety goggles or face protection.
Hand protection: ​Wear protective gloves. In accordance with the data specified by the protective glove manufacturers, it
is required while using them to check whether the gloves maintain their repellent properties and to change them as soon
as damage is detected. In the case of exposure up to 8 hours, protective gloves made of the following material must be
worn: Nitrile rubber.
Other skin and personal protection: ​Avoid contact with the skin. Wear suitable clothing to prevent possible skin contact.
Hygiene measures: ​Wash contaminated skin thoroughly after handling. Before removing the clothing, wash
contaminated clothing and skin immediately with plenty of water. Immediately remove all contaminated garments and
wash before wearing them again. Contaminated work clothing should not be allowed out of the workplace. When using
the product, do not eat, drink or smoke.
Respiratory protection: ​If ventilation is inadequate, suitable respiratory protection must be worn. Wear a protective
mask with full face protection and the following filter cartridge: Filter against organic vapors. Highly effective particle
filters.
Section 9: Physical and Chemical Properties
Appearance: ​Liquid
Odor:​ Specific
Color:​ Various tooth colors
Density:​ 1.1 g/cm3
Bulk density: ​NA
pH: ​NA
Melting point/freezing point: ​NA
Initial boiling point and boiling range: ​NA
Flash point:​ >150 oC
Flammability (solid, gas): ​NA
Explosivity: ​NA
Lower explosion limit: ​NA
Upper explosion limit: ​NA
Ignition temperature: ​NA
Decomposition temperature: ​NA
Oxidizing potential: ​NA
Vapour pressure: ​NA
Vapour density: ​NA
Evaporation rate: ​NA
Water solubility:​ No
Fat solubility: ​NA
Soluble in:
Partition coefficient: noctanol/water: ​NA
Viscosity:​ ca.700-1200 Pa s
Solvent separation test: ​NA
Solvent content: ​NA
Section 10: Stability and Reactivity
Reactivity:​ No information is available.
Chemical stability​: No information is available.
Possible hazardous reactions:​ No information is available.
Conditions to avoid:​ Incompatible conditions: Reaction with light, risk of polymerization.
Incompatible materials:​ Incompatible materials Keep away from radical-forming initiators, peroxides.
Hazardous decomposition products:​ Hazardous products can polymerize spontaneously.
Section 11: Toxicological Information
Bisphenol A-ethoxylat (2 EO/Phenol) Dimethacrylat 41637-38-1
Specific symptoms in laboratory animals
Irritation and etching
Irritant effect on the skin
Irritant effect on the eye
Irritant effect on the respiratory tract
Additional information
Sensitization
Repeated dose toxicity (subacute, subchronic, chronic)
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)

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Carcinogenicity
Germ cell mutagenicity
Reproductive toxicity
Section 12: Ecological Information (non-mandatory)
Toxicity
Bisphenol A-ethoxylat (2 EO/Phenol) Dimethacrylat 41637-38-1
Persistence and degradability: ​No information is available.
Bioaccumulative potential: ​No information is available.
Mobility in soil: ​No information is available.
Results of PBT and vPvB assessment: ​No information is available.
Other adverse effects: ​No information is available.
Section 13: Disposal Instructions
Proper disposal/product:​ Disposal in accordance with regulatory requirements.
Proper disposal/packaging:​ May be disposed of in accordance with local regulatory requirements.
Ecology - waste materials:​ Avoid discharge into the environment
Section 14: Transport Information (non-mandatory)
UN number: ​none
Proper UN shipping name: ​none
Transport hazard classes: ​No dangerous goods pursuant to transportation regulations.
Packaging group: ​none
Environmental hazards: ​none
Special precautions for transport: ​none
Bulk transport in accordance with Annex II of the MARPOL Convention 73/79 pursuant to IBC Code: ​No 
Section 15: Regulatory Information (non-mandatory)
Regulations on safety, health and environmental protection/specific laws for the substance or mixture
EU regulations
Information about Regulation (EC) No. 166/2006 concerning the establishment of a European Pollutant Release and
Transfer Register: ​irrelevant
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer: ​irrelevant
Regulation (EC) No. 648/2004 on detergents: ​irrelevant
Regulation (EC) No. 850/2004 [POP regulation]: ​irrelevant
Regulation (EU) No. 649/2012 concerning the import and export of hazardous chemicals: ​irrelevant
Restriction on use in accordance with REACH Annex XVII No.: ​irrelevant
National regulations
National regulations must also be observed.
Instructions on employment restriction: ​No information is available.
Major Accidents Ordinance Not subject to the German Major Accidents Ordinance.
Solvent Ordinance (31st Federal Immission Protection Ordinance [BlmSchV]): ​irrelevant
Storage class:​ 10 Combustible liquids unless LGK 3A or 3B.
Water hazard class (WGK):​ 1 weak water pollutant (WGK 1)
Section 16: Other Information
Text of H and R phrases (number and full text)
H phrases Text
H315 Causes skin irritation
H317 May cause an allergic skin reaction.
319 Causes serious eye irritation.
335 May cause respiratory irritation.
P phrases
36 Irritating to eyes.
37 Irritating to respiratory system.
38 Irritating to skin.
43 May cause sensitization by skin contact.
Training tips:​ Only trained personnel should use this product.
Recommended restriction(s) on use:​ No special measures are required.
Further information:​ REJECTION OF LIABILITY We have obtained the information in this data sheet from sources that we
consider reliable. The accuracy of expressed or implied information cannot be guaranteed. The conditions or methods for
handling, storage, use or disposal of the product are beyond our control and possibly also our knowledge. For these and
other reasons, we accept no responsibility and expressly reject liability for any losses, damage or costs that may arise
from handling, storage, use or disposal of the product or that may be associated therewith in any way. This Safety Data

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Sheet was created for this product and may only be used for this product. If the product is used as a component of
another product, the information indicated in the data sheet may not apply.
This information is based on our current knowledge and should only describe the product with regard to health, safety
and environmental conditions. It must therefore not be construed as a guarantee for any specific property of the
product.

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