General Instructions

1. The question paper consists of 3 Subject (Subject I: Physics, Subject II: Chemistry, Subject III: Mathematics).
Each Part has two sections (Section 1 & Section 2).

2. Section 1 contains 2 types of questions [Type A and Type B].

Type A contains SIX (06) Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.

Type B contains SIX (06) Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE THAN ONE CHOICE is correct.

3. Section 2 contains THREE (03) Paragraphs. There are TWO (02) questions corresponding to each Paragraph.
The answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value
of the answer. If the answer is a decimal numerical value, then round-off the value to TWO decimal places.
If the answer is an Integer value, then do not add zero in the decimal places. In the OMR, do not bubble the
 sign for positive values. However, for negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50,
3.25, 0.08)

4. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your Test Code,
Roll No. and Group properly in the space given in the ANSWER SHEET.
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MARKING SCHEME
SECTION-1 | Type A
 This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of
these four options is the answer. For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.

SECTION-1 | Type B
 This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If unanswered;
Negative Marks : –2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers,
then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get –2 marks.

SECTION-2
 This section contains THREE (03) Paragraphs. There are TWO (02) questions corresponding to each
Paragraph. The answer to each question is a NUMERICAL VALUE. For each question, enter the correct
numerical value of the answer. If the answer is a decimal numerical value, then round-off the value to
TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In the
OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be
bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct Integer value is entered. There is NO negative marking.
Zero Marks: 0 In all other cases.

SUBJECT I : PHYSICS 60 MARKS

SECTION-1 | Type A

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This section consists of 6 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. Specific heat of a liquid varies with temperature according to the graph below. If equal quantity (1 kg each)
of the liquid at temperature 0° and 100°C are mixed, what is the final temperature of mixture?

(A) 51.6°C (B) 50°C (C) 45.8°C (D) 54°C


2. A particle initially at (3, 1, 2) can move with constant velocity v. If the minimum time taken by him to

reach x-axis is 2s, value of v is:
 ˆj  2kˆ ˆj  2kˆ 3iˆ  ˆj  2kˆ iˆ  3kˆ
(A) (B) (C) (D)
2 2 2 2
3. Two blocks of mass 2kg and 1kg are connected as shown. At the moment blocks were moving with a
velocity of 2m/s, the 2kg block is given an impulse to the right so that it acquires a velocity of 4 m/s
towards right. Velocity of the blocks just after string becomes taut again is: [All surfaces are smooth, take
g  10m/s 2 ]

16 14
(A) 4 m/s (B) m/s (C) m/s (D) 5 m/s
3 3
4. A small satellite is to projected horizontally from a height ‘2R’ above the surface of earth so that it revolves
around earth without hitting the surface. Minimum value of v0 is:

GM GM
(A) (B)
R 3R

GM GM
(C) (D)
6R 8R

R
5. A circular portion of radius is removed from a disc of mass M and radius R. The setup is placed on a
2
rough horizontal floor such that line joining the center of disc and cavity is horizontal. In order to keep the
disc in equilibrium a force F is applied as shown. Value of F is:
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Mg Mg Mg Mg
(A) (B) (C) (D)
4 6 8 16
6. A swimmer starts from A and wants to cross the river flowing with 5 ms 1 and reach the point B on the
other bank. He swims with minimum speed v (relative to water) in order to achive this. As he crosses half
the width of river, river stops flowing but he continues to swim with same v (relative to water) in the same
direction. Time taken by swimmer to cross the river is:

1000 1100 725 1250

(A) s (B) s (C) s (D) s
3 3 2 3

SECTION-1 | Type B
This section consists of 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.

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7. In the arrangement shown below bead of mass m is free to slide along a smooth horizontal wire. System is
released at t  0 and after some time it is found when   37 velocity and acceleration of block with
mass 2m is v and a respectively. String and pulley are ideal. Choose correct alternative(s).
4v
(A) Velocity of bead is at this moment
5
4a
(B) Acceleration of bead at this moment is
5
5a
(C) Acceleration of bead at this moment is greater than
4
11mg  6 ma
(D) Force exerted by wire on the bead is
5
8. A block of mass m is kept on a plank of mass 2m which is kept on a rough horizontal surface. Coefficient
of friction between the block and plank and between plank and surface is '  '. At t  0 a force F0
(constant) acts on the block and it is found that acceleration of block and plank are in ratio 1 : 2. Choose the
correct alternative(s):
F0
(A) 
8mg
F0
(B) 
4mg
3gF0t 2
(C) Work done by friction between the plank and surface in t sec is 
8
F gt
(D) Average power delivered by friction between the block and plank in time t is  0
16

9. In the figure shown a system of two blocks constrained to move along horizontal are connected with light
strings and pulleys. Mass of both blocks is equal to m and friction is absent everywhere A force F0 is
applied on the bigger block as shown. Choose the correct alternative(s):

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(A) Correct relation between acceleration(s) a1 and a2 of the blocks as shown in figure is
2a1  a2  0
F0
(B) a1 
5m
F
(C) a2   0
10m
4 F0
(D) Tension in the string connected to bigger block is
5
10. In the arrangement shown two blocks of equal mass are connected by two strings and the arrangement is
kept on horizontal surface. The blocks are held by a string such that spring -1 is compressed by 2x0 and
the other spring -2 is in its natural length. Both springs are ideal and have spring constant K and kx0  mg.
String is cut at t  0, Choose the correct alternative(s).
(A) Just after string is cut acceleration of upper block is zero
k
(B) Maximum speed of upper block in subsequent motion is x0
2m
mg
(C) Maximum elongation in spring-2 in subsequent motion is
k
(D) Normal on the lower block by the floor at the moment upper block has maximum speed is 2mg

 
11. Two particles A and B initially at origin and (0, d ) respectively start moving with velocities v A  v0 iˆ and
 d
vB  2 v0iˆ simultaneously. After time t  ,
v0
V0
(A) Rate at which separation between A and B is increasing is
2
v0
(B) Angular velocity of B w.r.t A is
2d
v0
(C) Angular velocity of A w.r.t (0, d ) is
2d
4v0
(D) Rate of which separation between B and origin is changing is
5
12. An empty cylindrical vessel of height H and area A is kept on a smooth horizontal table. Vessel has a small
hole of area ‘a’ in its side wall at a distance H/4 from bottom and another hole at its bottom also with area
a. Initially side hole is kept closed with a plug and vessel is filled by placing it below a top supplying it

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 Q2 
water at a constant volume rate Q  2  1 , after sometime level of liquid in the container becomes
 a gH 
 
constant, equal to h1. Now tap is closed, the side plug is opened and bottom plug is closed, a force F is
applied along horizontal to the vessel to keep it at rest. Choose the correct alternative(s): [Assume table has
a hole so that bottom hole is open to atmosphere]

H
(A) h1 
2
gHa
(B) Value of force F just after the plug is opened is
2
(C) Time for level of water to reach the level of side hole from the moment plug was opened is
A H
2a 2 g
(D) It the tap was not closed while the bottom hole was closed & side hole opened then after long time
3H
a steady level of will be present in vessel
2

SECTION-2

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This section consists of THREE (03) Paragraphs. There are TWO (02) questions corresponding to each Paragraph. The
answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value of the answer.
If the answer is a decimal numerical value, then round-off the value to TWO decimal places. If the answer is an Integer
value, then do not add zero in the decimal places. In the OMR, do not bubble the  sign for positive values. However,
for negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08).

Paragraph for Questions 1 - 2

Consider a planet with uniform mass density  having a spherical cavity made in it. Using principle of
 4G 
superposition we can find that gravitational field inside the cavity is uniform and equal to g   OO
3
where O is the center of the planet and O is center of cavity.
R
Consider a planet of mass M and radius R with a cavity of radius made in it as shown. Another small mass 2M
2
is kept at a distance 2R from O’ as shown.

A 1 kg mass is projected from A towards O ' with speed v0 .

GM
1. If magnitude of acceleration of 1 kg mass just after projection is , value of  is ______ .
R2
GM
2. Minimum value of v0 for the mass 1 kg to reach O ' is , value of  is ________.
R

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Paragraph for Questions 3 – 4

A mat is moving with constant velocity 5 m/s along x-axis on a horizontal floor (x-y plane). A block of mass 5kg is

projected with velocity v  2 iˆ  4 ˆj on the mat such that it moves along the x-y plane afterwards. Coefficient of
friction between the mat and block is   0.1. (g = 10 m/s2)

3. What is angle (  ) made by friction force with positive x-axis (in degrees) just after projection?

4. What is displacement of the block (in meters) in the reference frame fixed to mat till relative motion
between the block and mat ceases?

Paragraph for Questions 5 – 6

A solid sphere of radius 0.5 m is rotated with angular velocity (0  45 radian/s) and dropped from height of 10m,
on a rough horizontal surface. Coefficient of restitution of surface e  0.5 and coefficient of friction is 1/3.
( g  10 ms 2 )

5. What is horizontal displacement of sphere (in m) between first two collisions of sphere with horizontal
surface?

6. What is angular velocity (in radian/s) of sphere just after first collision between sphere and horizontal
surface? (use 2  1.414 )

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SUBJECT II : CHEMISTRY 60 MARKS

SECTION-1 | Type A
This section consists of 6 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. 50 mL of 0.1 M HCl was added to 150 mL of 0.2 M NaOH. The resulting solution is just sufficient to
completely absorb V mL of CO2 (g) at STP conditions. The value of ‘V’ is:
(A) 280 (B) 140 (C) 270 (D) 360

2. A sample of excited hydrogen atoms can produce maximum 10 lines in the emission spectrum. de-Broglie
wavelength of the electrons in the excited state would be : (Bohr’s radii is a 0 )
(A) 5  a0 (B) 10  a 0 (C) 8  a0 (D) 2  a0

3. Select the correct order of atomic radii.

(A) Al  Ga  In (B) Ti  Zr  Hf
(C) Na  K  Rb (D) CNO

4. Which of the following solution have maximum pOH at 25°C ?

(A) [HCl]  10 8 M
(B) [NaOH]  10 8 M
(C) [NaHCO3 ]  102 M ; pK a1 and pK a 2 for H2CO3 are 6 and 9 at 25°C
(D) Equimolar mixture of CH3COOH and CH3COONa ; pKa of CH3COOH is 4.7 at 25°C

5. 10 mL of a H 2O2 solution; labelled “5.6 volumes” was just sufficient to decolourise 20 mL of KMnO4
solution (in presence of H 2SO4 ). Molarity of KMnO4 solution is :
(A) 0.1 M (B) 0.2 M (C) 0.3 M (D) 0.4 M

6. 2 moles of I 2 when treated with hot concentrated KOH produces nearly 3.33 moles of KI and 0.67 moles
of salt “X”. Oxidation number of iodine in the salt “X” is :
(A) +1 (B) +3 (C) +5 (D) +7

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SECTION-1 | Type B
This section consists of 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.
7. Which of the following is NOT paramagnetic ?
(A) CO(g) (B) NO (g) (C) C2(g) (D) B2(g)

8.  P at 300 K.
For a reaction A 

 f H (A)   100 kJ / mole, SA  10 J / Kelvin

 f H (P)   80 kJ / mole, SP  20 J / Kelvin

Then incorrect statement/s are :
(A) At 300 K  r Gº  0; Reaction will be spontaneous at 300 K
(B) At 300 K r Gº  ()ve; Reaction will be spontaneous at 2000 K
(C) At 300 K r Gº  ()ve; Reaction will be spontaneous at 2100 K
(D) At 300 K r Gº  ()ve; Reaction will be spontaneous at 2100 K

9. Select incorrect statement/s :

(A) An ideal gas system perform greater amount of mechanical work under irreversible conditions as
compared to reversible condition
(B) Heat exchange between system and surrounding is a path function while enthalpy change of the
system is a state function
(C) Work done by an ideal gas system under isothermal conditions is greater in magnitude than work
done by the system under isobaric conditions
(D) For all spontaneous processes, entropy change of the system is positive

10. Select the pair/s of constitutional isomers :

(A) (B)

(C) (D)

11. Which of the following statement/s is/are correct according to kinetic theory of gases ?
(A) Collision between ideal gas particles are perfectly inelastic
(B) Average molar thermal kinetic energy of an ideal gas is a function of temperature
(C) Speed of maximum fraction of particles is the root mean square speed
(D) The molecular speed distribution curve becomes more wider at higher temperature

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12. Which of following is NOT true according to Le Chatelier's principle?

(A)  2NO 2 (g) (  r H  0) ; yield of paramagnetic gas decreases with
In the reaction N 2 O 4 (g) 
rise in temperature
(B)  2O3 (g) ( r H  0) ; yield of paramagnetic gas decreases with rise
In the reaction 3O 2 (g) 
in temperature
(C)  2SO3 (g) ( r H  0); yield of SO3 (g) increases with
In the reaction 2SO 2 (g)  O 2 (g) 
rise in temperature
(D)  2NO(g) ( r H  0) ; addition of He(g) at constant
In the reaction N 2 (g)  O 2 (g) 
pressure will shift the reaction in forward direction

SECTION-2
This section consists of THREE (03) Paragraphs. There are TWO (02) questions corresponding to each Paragraph. The
answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value of the answer. If
the answer is a decimal numerical value, then round-off the value to TWO decimal places. If the answer is an Integer
value, then do not add zero in the decimal places. In the OMR, do not bubble the  sign for positive values. However,
for negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08).

Paragraph for Questions 1 - 2

Standard molar enthalpy of hydrogenation for and benzene are 120 kJ / mole and  208 kJ / mole

respectively. Standard molar enthalpy of formation of is 80 kJ/mole.

1. Standard molar enthalpy formation of is ________ (kJ/mole).

2. Resonance energy of benzene is ________ kJ/mole.

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Paragraph for Questions 3 - 4

10 mL of 1 M HCl was added to 90 mL of an aqueous solution (x) of CH3COOH having 6% w/v concentration of
CH3COOH. To the resulting mixture 50 mL of 5.6 % w/v KOH was added to prepare the other aqueous solution
(y).

3. pH of the original solution (x) at 25°C is ________.

(K a of CH3COOH is 2 105 at 25°C, log10 2  0.30)

4. pH of the final solution (y) at 25°C is ________. (Atomic mass of K = 39) (log10 5  0.70)

Paragraph for Questions 5 – 6

Consider following organic compound.

5. Number of functional groups present in the compound are _______.

6. Degree of unsaturation (D.O.U) of the organic compound is ________.

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SUBJECT III : MATHEMATICS 60 MARKS

SECTION-1 | Type A
This section consists of 6 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. Let | zi |  i , i  1, 2,3, 4 and |16 z1 z2 z3  9 z1 z2 z 4  4 z1 z3 z 4  z2 z3 z4 |  48 then the value of
1 4 9 16
   is:
z1 z2 z3 z4
(A) 1 (B) 2 (C) 4 (D) 8

B
2. In the quadratic equation A  
3  2 x2  x  C  0 with ,  as its roots, if
 3 2 
1/ 4 8 6 16 k

A  49  20 6  . B = sum of the infinite G.P. as 8 3 
3

3
 ... and     6 6   , where

k  log 6 10  2 log 6 5  log 6  log 6 18  log 6 72  , then find the value of C.

(A) 136 (B) 164 (C) 128 (D) 64

3. Suppose that x1 and x2 are the positive real solution of x 2  bx  c  0 provided that

x12  x22  2 x2  2x1  1. The minimum value of  b  c  , is:

(A) 2 (B) 3 (C) 4 (D) 5
3 3
4. Let the equation x  y  3xy  1 represent the coordinate of one vertex A and the equation of side BC of
the triangle ABC. If B is the orthocentre of the triangle ABC and the equation of side AB is y  mx  c ,
then absolute value of  4  m  c  , is:
(A) 2 (B) 3 (C) 4 (D) 5

ab
5. If a  c, a  b, b  c are in G.P. and a, c, b are in H.P. where a, b, c  0, then the value of is:
c
3
(A) 3 (B) 2 (C) (D) 4
2
1 1 1 1
6. If x1 , x2 , x3 , x4 are four positive real numbers such that x1   4, x2   1, x3   4 and x4   1
x2 x3 x4 x1
, then which of the following is FALSE?
(A) x1 x3  1 (B) x2 x3  1 (C) x1 x2  1 (D) x3 x4  1

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SECTION-1 | Type B
This section consists of 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.

7. Let x1, x2 ,......., xn be a sequence of integers such that

(i) 1  xi  2, for i  1, 2,......, n;
(ii) x1  x2  ........  xn  19;

(iii) x12  x22  ......  xn2  99.

Let S  x13  x23  .......xn3 , then
(A) Minimum value of S is 19. (B) Maximum value of S is 133.
(C) Minimum value of S is 0 (D) Maximum value of S is 11 4 .

8. Number of ways in which 30 identical things are distributed among six persons is :
17
(A) C5 if each gets odd number of things
16
(B) C11 if each gets odd number of things
14
(C) C5 if each gets even number of things (excluding 0)
15
(D) C10 if each gets even number of things (excluding 0)

9. Let a , b  0 , then:
a b 1 1
(A) a b  a b (B)
2
 2
 
b a a b
a b a2 b2
(C)   a b (D)  1
b a 1  a4 1  b4

10. The values of x between 0 and 2 , which satisfy the equation sin x 8cos2 x  1 are in A.P. Choose
the correct options
(A) Common difference of A.P.is  / 4 (B) x  /8
(C) x  3 / 4 (D) x  5 / 8
11. If for x we have (1  x 2  x 4 )8  C0  C1 x 2  C 2 x 4  .....  C16 x 32 , then:

(A) C0  C1  C2  C3  .....  C16  1 (B) C0  C3  C6  C9  C12  C15  37

(C) C 2  C5  C8  C11  C14  36 (D) C1  C 4  C 7  C10  C13  C16  37

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12. Two equal sides of an isosceles triangle lie along the lines  a  b  x   a  b  y  2 ab  0 and

 a  b  x   a  b  y  2 ab  0. If the third side passes through the point  b  a , a  b  , then the equation
of third side can be:
(A) x y0 (B) x  y  2 b  a 
(C) x b  a  0 (D) yab0

SECTION-2
This section consists of THREE (03) Paragraphs. There are TWO (02) questions corresponding to each Paragraph. The
answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value of the answer. If
the answer is a decimal numerical value, then round-off the value to TWO decimal places. If the answer is an Integer
value, then do not add zero in the decimal places. In the OMR, do not bubble the  sign for positive values. However,
for negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08).

Paragraph for Questions 1 – 2

100
Let N   8
562 
1. The number of irrational terms in the expansion of N is:

2. Sum of all possible values of r, such that Tr 1 i.e. (r  1)th term in the expansion of N is rational, is:

Paragraph for Questions 3 – 4

Let ABC be a triangle and AD, BE and CF are its medians, where E and F are the points E(3, 4) and F(1, 2),
respectively and centroid of ΔABC is G(3, 2), then answer the following questions:

a
3. The equation of side AB, is ax  y  b , then is ______.
b

4. Coordinates of D is (h, k ) , then h  k is ______.

Paragraph for Question 5-6

2 2
Let f ( x)  (c 1) x  2cx  c  4 and g ( x)  cx  2(c  1) x  (c  1) , where c  R .
5. If g ( x) is always negative  x  (0, 1) , then the number of integral values of c in the interval [5, 5] is:

6. If the system of equation f  x   0 and g  x   0 has exactly one solution then the sum of all real values of
c is equal to:

   End of JEE Advanced – 4 | Paper - 1 |JEE -2023 (GEN 1 to 6)  

VMC | JEE-2023 | Paper-1 16 JEE Advanced-4 | Gen 1 to 6