SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MasterSeal P 698

Product code : 000000000050107272

Manufacturer or supplier's details

Company : Master Builders Solutions
Yapı Kimyasalları Sanayi ve Ticaret Ltd.
Sti.,

Address : Ataşehir Kuzey, C Kapısı 3E/ 5-12

İstanbul, Turkey T30 34746

Telephone : +902162178800

Emergency telephone : ChemTel: +1-813-248-0585

Telefax : +902162178800

Recommended use of the chemical and restrictions on use

Recommended use : Product for construction chemicals
Restrictions on use : Reserved for industrial and professional use.

2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3

Acute toxicity (Inhalation) : Category 5

Skin corrosion/irritation : Category 2

Serious eye damage/eye irri- : Category 2A

tation

Respiratory sensitization : Category 1

Skin sensitization : Category 1

Carcinogenicity : Category 2

Specific target organ toxicity - : Category 3 (Respiratory system, Central nervous system)
single exposure

Specific target organ toxicity - : Category 2 (Respiratory system)

repeated exposure
(Inhalation)

GHS label elements

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H226 Flammable liquid and vapor.

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H333 May be harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Respiratory system)
through prolonged or repeated exposure if inhaled.

Precautionary Statements :
Prevention:
P203 Obtain, read and follow all safety instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P260 Do not breathe mist or vapors.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection/ hearing protection.
P284 Wear respiratory protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate-
ly all contaminated clothing. Rinse affected areas with water.
P304 + P317 IF INHALED: Get medical help.
P304 + P340 + P319 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Get medical help if you feel
unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P318 IF exposed or concerned, get medical advice.
P333 + P317 If skin irritation or rash occurs: Get medical help.
P337 + P317 If eye irritation persists: Get medical help.
P342 + P316 If experiencing respiratory symptoms: Get emer-
gency medical help immediately.
P362 + P364 Take off contaminated clothing and wash it before
reuse.

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

P370 + P378 In case of fire: Use dry sand, dry chemical or

alcohol-resistant foam to extinguish.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

If applicable information is provided in this section on other hazards which do not result in classi-
fication but which may contribute to the overall hazards of the substance or mixture.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Preparation based on:
Aromatic isocyanates
Components
Chemical name CAS-No. Concentration (%
w/w)
1-methoxy-2-propylacetate 108-65-6 >= 30 - < 50
Methylenediphenyl diisocyanate 26447-40-5 >= 20 - < 30
1,2-Ethanediamine, polymer with methyloxirane 25214-63-5 >= 10 - < 20

4. FIRST AID MEASURES

General advice : First aid personnel should pay attention to their own safety.
Remove contaminated clothing immediately and clean before
re-use or dispose it if necessary.

If inhaled : Keep patient calm, remove to fresh air.

If symptoms persist, seek medical advice.
Remove to fresh air immediately. Get medical attention imme-
diately.
If breathing difficulties develop, aid in breathing and seek im-
mediate medical attention.
In case of skin contact : Take off all contaminated clothing immediately.
After contact with skin, wash immediately with a polyethylene
glycol solution, followed by plenty of water.
or
Wash off immediately with soap and plenty of water.
Get medical attention if irritation develops and persists.
Wash contaminated clothing before re-use.
In case of eye contact : In case of eye contact, remove contact lens and rinse imme-
diately with plenty of water, also under the eyelids, for at least
15 minutes.
Seek medical advice.
If swallowed : Rinse mouth with water.
Do not induce vomiting unless told to by a poison control cen-

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

ter or doctor.
Never give anything by mouth to an unconscious person.
If accidentally swallowed obtain immediate medical attention.
Most important symptoms : Causes skin irritation.
and effects, both acute and May cause an allergic skin reaction.
delayed Causes serious eye irritation.
May be harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficul-
ties if inhaled.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated
exposure if inhaled.
Notes to physician : Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam

Dry chemical
Carbon dioxide (CO2)
Water spray in large fire situations
Unsuitable extinguishing : water jet
media
Specific hazards during fire : Evolution of fumes/fog.
fighting In case of fire hazardous decomposition products may be
produced such as:

Hazardous combustion prod- : harmful vapours

ucts Carbon dioxide (CO2), carbon monoxide (CO), oxides of ni-
trogen (NOx), dense black smoke.
isocyanate
hydrogen cyanide

Specific extinguishing meth- : The degree of risk is governed by the burning substance and
ods the fire conditions.
Containers may rocket or explode in heat of fire.
Collect contaminated extinguishing water separately, do not
allow to reach sewage or effluent systems.
Contaminated extinguishing water must be disposed of in
accordance with official regulations.
Special protective equipment : Wear self-contained breathing apparatus and chemical-
for fire-fighters protective clothing.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective clothing.

tive equipment and emer- Breathing protection required.
gency procedures Ensure adequate ventilation.
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
Wear eye/face protection.
Handle in accordance with good building materials hygiene
and safety practice.
Information regarding personal protective measures, see sec-
tion 8.

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

Use breathing apparatus if exposed to vapours/dust/aerosol.

Environmental precautions : Contain contaminated water/firefighting water.

Do not discharge into drains/surface waters/groundwater.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Neutralize with a solution of 5 - 10 % Sodium carbonate, 0,2 -
2 % detergents and 90 - 95 % water.
Dike spillage.
Dispose of absorbed material in accordance with regulations.

7. HANDLING AND STORAGE

Advice on protection against : The product is neither self-ignitable, nor an explosion hazard,
fire and explosion nor does it promote fires.

Advice on safe handling : Ensure thorough ventilation of stores and work areas.
Avoid aerosol formation.
Avoid contact with the skin, eyes and clothing.
Avoid inhalation of dusts/mists/vapours.
When handling heated product, vapours of the product should
be ventilated, and respiratory protection used.
Wear respiratory protection when spraying.
Clean up contamination as soon as they occur.
Provide basic employee training to prevent/minimize expo-
sures.
Products freshly manufactured from isocyanates can contain
incompletely reacted isocyanates and other dangerous sub-
stances.
Persons suffering from asthma, eczema or skin problems
should avoid contact, including dermal contact, with this prod-
uct.
Further information on stor- : Keep only in the original container in a cool, dry, well-
age conditions ventilated place away from ignition sources, heat or flame.
Protect against moisture.
Protect from direct sunlight.
Formation of CO2 and build up of pressure possible.
Danger of bursting when sealed gastight.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Contains no substances with occupational exposure limit values.
Engineering measures : Ensure adequate ventilation.
Personal protective equipment
Respiratory protection : Respiratory protection in case of vapour/aerosol release.
Combination filter for gases/vapours of organic compounds
and solid and liquid particles (f.e. EN 14387 Type A-P2)
Particle filter with high efficiency for solid and liquid particles
(e.g. EN 143 or 149, Type P3 or FFP3).

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

Suitable respiratory protection for higher concentrations or

long-term effect:
Self-contained breathing apparatus.
Hand protection

Remarks : Suitable chemical resistant safety gloves (EN 374) also with
prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5
mm), butyl rubber (0.7 mm) etc. Unsuitable materials polyvi-
nylchloride (PVC) - 0.7 mm coating thickness Manufacturer's
directions for use should be observed because of great di-
versity of types.
Eye protection : Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Skin and body protection : Body protection must be chosen based on level of activity and
exposure.
Protective measures : Do not inhale dust/fumes/aerosols.
Avoid contact with the skin, eyes and clothing.
Avoid exposure - obtain special instructions before use.
Handle in accordance with good building materials hygiene
and safety practice.
Wearing of closed work clothing is recommended.
With products freshly manufactured from isocyanates body
protection and chemical resistant protective gloves is recom-
mended.
Hygiene measures : When using, do not eat, drink or smoke.
Handle in accordance with good industrial hygiene and safety
practice.
Take off immediately all contaminated clothing.
Hands and/or face should be washed before breaks and at the
end of the shift.
At the end of the shift the skin should be cleaned and skin-
care agents applied.
Gloves must be inspected regularly and prior to each use.
Replace if necessary (e.g. pinhole leaks).

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : colorless

Odor : solvent

Odor Threshold : not determined

pH : 5-7

Melting temperature : No data available

boiling temperature : No data available

Flash point : approx. 42 °C

Method: Flashpoint test using closed cup, determination of

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

flashpoint.

Evaporation rate : not determined

Flammability (liquids) : Flammable liquid and vapor.

Lower explosion limit / Lower : dropped

flammability limit

Vapor pressure : approx. 20 hPa (50 °C)

Relative vapor density : not determined

Density : approx. 1,06 g/cm3 (20 °C)

Bulk density : Not applicable

Solubility(ies)
Water solubility : emulsifiable

Partition coefficient: n- : not applicable for mixtures

octanol/water
Autoignition temperature : No data available

Solvent separation : < 3 %(V) (20 °C)

Explosive properties : Not explosive

Oxidizing properties : not fire-propagating

10. STABILITY AND REACTIVITY

Reactivity : No hazardous reactions if stored and handled as pre-

scribed/indicated.
Container can be pressurized by carbon dioxide due to reac-
tion with humid air and/or water.
Chemical stability : The product is stable if stored and handled as pre-
scribed/indicated.
Possibility of hazardous reac- : Reacts with water to form carbon dioxide and heat
tions Risk of bursting.
Reacts with alcohols.
Reacts with acids.
Reacts with alkalies.
Reacts with amines.
Risk of exothermic reaction.
Polymerization can occur.

Conditions to avoid : Avoid all sources of ignition: heat, sparks, open flame.
Avoid electro-static discharge.
Avoid heat.
Avoid moisture.
See SDS section 7 - Handling and storage.
Incompatible materials : Acids
Alkalines

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

Strong oxidizing agents

Strong reducing agents
Alcohols
Amines
Ammonia
Water
Hazardous decomposition : No hazardous decomposition products if stored and handled
products as prescribed/indicated.
In case of fire hazardous decomposition products may be
produced such as:
Carbon dioxide (CO2)
Carbon monoxide
Nitrogen oxides (NOx)
hydrogen cyanide
Isocyanates

11. TOXICOLOGICAL INFORMATION

Acute toxicity
May be harmful if inhaled.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitization

Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Suspected of causing cancer.
Product:
Remarks : Industrial cleaning with aprotic polar solvents (meeting the
IUPAC definition) may lead to formation of hazardous primary
aromatic amine (>0,1%).

Reproductive toxicity
Not classified based on available information.
STOT-single exposure
May cause respiratory irritation.
May cause drowsiness or dizziness.
STOT-repeated exposure
May cause damage to organs (Respiratory system) through prolonged or repeated exposure if
inhaled.

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

Aspiration toxicity
Not classified based on available information.
Further information

Product:
Remarks : Health injuries are not known or expected under normal use.
The product has not been tested. The statements on toxicolo-
gy have been derived from the properties of the individual
components.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:

Ecotoxicology Assessment
Acute aquatic toxicity : This product has no known ecotoxicological effects.

Chronic aquatic toxicity : This product has no known ecotoxicological effects.

Persistence and degradability

Product:
Biodegradability : Remarks: Taking into consideration the properties of several
ingredients, the product is estimated not to be readily biode-
gradable according to OECD classification.

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: No data available.
Discharge into the environment must be avoided.

Mobility in soil

Product:
Mobility : Remarks: No data available

Distribution among environ- : Remarks: No data available

mental compartments

Stability in soil : Remarks: No data available

Other adverse effects

Product:
Ozone-Depletion Potential : Remarks: The product does not contain substances that are
listed in Regulation (EC) 1005/2009 on substances that de-
plete the ozone layer.

Additional ecological infor- : Do not discharge product into the environment without control.

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

mation The product has not been tested. The statements on ecotoxi-
cology have been derived from the properties of the individual
components.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Observe national and local legal requirements.
The waste code in accordance with the European waste cata-
log (EWC) must be specified in cooperation with disposal
agency/manufacturer/authorities.
Residues should be disposed of in the same manner as the
substance/product.
Contaminated packaging : Contaminated packaging should be emptied as far as possi-
ble; then it can be passed on for recycling after being thor-
oughly cleaned.
Packs that cannot be cleaned should be disposed of in the
same manner as the contents.

14. TRANSPORT INFORMATION

International Regulations

UNRTDG
UN number : UN 1866
Proper shipping name : RESIN SOLUTION
Class : 3
Packing group : III
Labels : 3
IATA-DGR
UN/ID No. : UN 1866
Proper shipping name : Resin solution
Class : 3
Packing group : III
Labels : Flammable Liquids
Packing instruction (cargo : 366
aircraft)
Packing instruction (passen- : 355
ger aircraft)
IMDG-Code
UN number : UN 1866
Proper shipping name : RESIN SOLUTION
Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-E
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

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SAFETY DATA SHEET

MasterSeal P 698

Version Revision Date: SDS Number: Date of last issue: 14.05.2021

1.2 23.11.2022 000000255829 Date of first issue: 01.02.2021

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture

16. OTHER INFORMATION

Revision Date : 23.11.2022

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Sub-
stances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recom-
mendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumu-
lative; WHMIS - Workplace Hazardous Materials Information System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

UN / EN

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