C.coek - Info - A Review of The Stratigraphy and Geological Settin
C.coek - Info - A Review of The Stratigraphy and Geological Settin
Precambrian Research
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a r t i c l e i n f o a b s t r a c t
Article history: The Palaeoproterozoic Magondi Supergroup lies unconformably on the Archaean granitoid-greenstone
Received 29 April 2010 terrain of the Zimbabwe Craton and experienced deformation and metamorphism at 2.06–1.96 Ga to form
Received in revised form 31 July 2010 the Magondi Mobile Belt. The Magondi Supergroup comprises three lithostratigraphic units. Volcano-
Accepted 13 August 2010
sedimentary rift deposits (Deweras Group) are unconformably overlain by passive margin, back-arc,
and foreland basin sedimentary successions, including shallow-marine sedimentary rocks (Lomagundi
Group) in the east, and deeper-water shelf to continental slope deposits in the west (Piriwiri Group). Based
Keywords:
on the upward-coarsening trend and presence of volcanic rocks at the top of the Piriwiri and Lomagundi
Carbon isotopes
Lomagundi anomaly
groups, the Piriwiri Group is considered to be a distal, deeper-water time-equivalent of the Lomagundi
Palaeoproterozoic Group. The Magondi Supergroup experienced low-grade metamorphism in the southeastern zone, but the
Magondi grade increases to upper greenschist and amphibolite facies grade to the north along strike and, more dra-
matically, across strike to the west, reaching upper amphibolite to granulite facies in the Piriwiri Group.
Carbonates form prominent horizons in the lower Lomagundi Group, occur in the Deweras Group as
thick packages in the northern part of the basin, but form only thin discontinuous beds elsewhere, and
are rare in the Piriwiri Group. Beds of anhydrite and sulphate pseudomorphs are relatively common
in the Deweras Group, and also occur in the Lomagundi Group. Schidlowski et al. (1975, 1976) found
extreme enrichment in 13 C in carbonates of the Lomagundi Group, with an average ␦13 C value of +8.2‰
VPDB. Subsequent work in the Magondi Basin has shown that high ␦13 C carbonates are also present in
the continental rocks of the underlying Deweras Group.
The initiation of the Deweras rift is not well constrained geochronologically, but it may have started as
early as 2.26 Ga, and was followed by deposition of the lower part of the Lomagundi Group on a passive
continental margin. Assuming that the deepening trend in the upper Lomagundi Group and upward-
coarsening trend in the Piriwiri Group reflect subsidence in a back-arc and subsequent foreland basin
setting, with sediment derivation from an approaching volcanic arc, the age of the onset of Magondi
deformation at ca. 2.0 Ga provides an upper age limit for sedimentation.
Combining all available data for the Magondi Basin, the Limpopo Belt between the Zimbabwe and
Kaapvaal cratons, and the Kheis Belt on the southwestern margin of the Kaapvaal craton, a new tectonic
model is presented for the assembly of the Kaapvaal and Zimbabwe cratons at ca. 2.1–2.0 Ga. These
cratons along with the Archaean cratons in West Africa and South America record an assembly of a large
continent at the time when Archaean cratons in North America and Fennoscandia experienced extension
and breakup. Carbonates of the Magondi Basin, the Kheis Belt, and the northern margin of the Kaapvaal
craton therefore reflect the carbon isotope composition of the open ocean at 2.2–2.1 Ga and provide
further evidence that the ␦13 C values reaching to +10‰ VPDB and higher record a seawater signal rather
than local diagenetic or closed basin conditions. The emerging picture is that Earth experienced dramatic
tectonic reorganization between 2.1–2.0 Ga, which likely influenced ocean circulation and redox state
and potentially ended the conditions that promoted high burial of organic matter with sediments during
the Lomagundi excursion.
© 2010 Elsevier B.V. All rights reserved.
0301-9268/$ – see front matter © 2010 Elsevier B.V. All rights reserved.
doi:10.1016/j.precamres.2010.08.013
S. Master et al. / Precambrian Research 182 (2010) 254–273 255
1. Introduction (Fig. 1) are also part of the Magondi Supergroup. Formerly grouped
under the “Lomagundi System”, rocks of the Magondi Supergroup
Arguably one of the most dramatic changes in Earth’s history crop out in the northwestern part of Zimbabwe, and are bounded
was the rise of atmospheric oxygen in the early Palaeoprotero- to the north by the Zambezi rift valley, in the east by the Archaean
zoic (2.45–2.32 Ga ago; Farquhar et al., 2000; Bekker et al., 2004; granite-greenstone terrain of the Zimbabwe craton, and in the west
Partridge et al., 2008). In association with and immediately after by a series of Palaeoproterozoic gneisses. In the south they disap-
this event there was a prominent positive carbon isotope excursion pear under Mesozoic and Cenozoic cover until they reappear to the
in seawater composition, called the “Lomagundi carbon isotope southwest in the Dete-Kamativi Inlier. Magondi-aged rocks also
excursion” or “Lomagundi Event” and named after the Loma- crop out and have been intersected in boreholes in NE Botswana
gundi Group of the Palaeoproterozoic Magondi Belt in northwest (Carney and Dowsett, 1991; Majaule et al., 2001), where they may
Zimbabwe where it was first recognised in the carbonate record link with temporally similar rocks in the Limpopo Belt (Buick et al.,
(Schidlowski et al., 1975, 1976). The Lomagundi Event was con- 2003).
firmed by studies on carbonate rocks from all other continents The Magondi Supergroup was deformed into a fold-and-thrust
with the exception of Antarctica, indicating the worldwide extent belt and metamorphosed at grades ranging from greenschist to
of this excursion between ca. 2.32 and 2.06 Ga (e.g., Karhu and granulite facies during the ca. 2.0–1.9 Ga Magondi Orogeny. While
Holland, 1996; Bekker et al., 2001a). Since the seminal papers by all the lithologies in the Magondi Supergroup have undergone vary-
Schidlowski et al. (1975, 1976), very little has been published on ing degrees of metamorphism, and are strictly metamorphic rocks,
the sedimentology and chemostratigraphy of the Magondi Belt. The we will refer to the metasedimentary rocks in terms of their sedi-
original work was done on samples collected during regional geo- mentary protoliths.
logical mapping by the Geological Survey of Rhodesia, which did The “Lomagundi System” was originally defined by Molyneux
not allow examination of stratigraphic variations in carbon isotope (1919). The subsequent evolution of stratigraphic nomenclature
values. New studies on chemostratigraphy of the Magondi strati- has been quite complex, with new schemes being proposed by
graphic units were initiated in the 1990s (Master et al., 1990, 1993, virtually everyone who has mapped the “Lomagundi System”.
1999; Master and Verhagen, 1998; Bekker et al., 2001b), and led The various stratigraphic subdivisions of previous authors have
to the discovery of 13 C-enriched carbonate rocks of the Deweras been discussed by Master (1991a,b). Following the recommenda-
Group which underlies the Lomagundi Group. In this paper, follow- tions of Bliss (1968), the former Geological Survey of Rhodesia
ing Master (1991a,b), we review previous work on the stratigraphy, adopted a lithostratigraphic approach to stratigraphic subdivi-
sedimentology, structure, metamorphism, geochronology and tec- sion of the former “Lomagundi System”, which was divided into
tonic setting of the Magondi Supergroup. The paper is intended to the Deweras, Lomagundi and Piriwiri groups (Stagman, 1978,
provide an insight into the tectonic and palaeoenvironmental set- 1981). The term “Magondi Supergroup” was introduced by Treloar
ting of this important sedimentary basin, which is the type locality (1988) and Leyshon and Tennick (1988) to encompass the three
for one of the most dramatic isotopic excursions to affect the global above-mentioned groups. In addition, the Malaputese, Inyantue,
carbon cycle during Earth’s history. Kamativi and Tshontanda formations (Table 2) of the Dete-Kamativi
The Magondi Supergroup is a mainly metasedimentary succes- Inlier are also regarded as being part of the Magondi Supergroup
sion and is found in the early Palaeoproterozoic Magondi Mobile (Master, 1991a,b). The basin in which the rocks of the Magondi
Belt of western Zimbabwe (Figs. 1 and 2). It is subdivided into Supergroup were deposited has long been informally referred
the Deweras, Lomagundi and Piriwiri groups (Table 1). In addi- to as the “Lomagundi basin”, and is now called the “Magondi
tion, lithologies of the Dete-Kamativi Inlier of western Zimbabwe basin” to correspond with the name of the supergroup (Master,
1991a,b).
The rocks of the Magondi Supergroup are host to a large
variety of economically important mineral deposits, including
base metals, precious metals, industrial minerals, and gemstones
(Fig. 2), which were formed at various times during a complex
geological history. The Deweras and Lomagundi groups are host
to several stratabound copper–silver deposits of the Magondi
Copperbelt, which have been exploited in the past (Jacobsen,
1964a,b, 1965a,b; Maiden et al., 1984; Newham, 1986; Master,
1991a). The Piriwiri Group hosts metallic mineralization (mas-
sive Zn–Cu–Pb–Ag sulphides, manganese, and gold–copper) as
well as deposits of industrial minerals (e.g., graphite, kyanite)
(Master, 1991a,b, 1996). Significant stratabound copper sulphide
mineralization in the Malaputese Group of the Dete-Kamativi
Inlier is restricted to interflow sedimentary rocks intercalated with
metabasalts (Lockett, 1979; Bahnemann and Lockett, 1979; Master,
1991a).
2. Deweras Group
Fig. 2. Detailed map of the northern part of the Magondi Mobile Belt, showing the main lithostratigraphic units and the location of the principal mines and mineral deposits
hosted by rocks of the Magondi Supergroup. DW = Doma West; Kw = Kamwa Anticline; Ky = kyanite; MnV = Munyati River Valley; MP = Mafungabusi Plateau; MpV = Mupfure
River Valley; Mz = Mazongororo Anticline; SC = Sheffield Claims.
Table 1
Generalised stratigraphy, lithology and depositional environments of the Magondi Supergroup (after Master, 1991a,b).
Piriwiri Graphitic schists, cherts, phyllites, greywackes, dolomites, Deep marine, distal shelf, continental slope,
Mn beds, massive sulphides, andesitic to felsic lavas, tuffs submarine fan
and agglomerates
Lomagundi Conglomerates, arkosic arenites, quartz arenites, Marginal marine (peritidal) and shallow
stromatolitic dolomites, banded iron formation, striped storm-dominated shelf
and graphitic slates, wackes, felsic volcanic and
volcaniclastic rocks
Unconformity
Deweras Conglomerates, arkosic arenites, mudstones, dolomites, Alluvial fan, braided stream, aeolian dune,
evaporites, basaltic lavas and pyroclastics playa
Unconformity
Basement Complex (Archaean granitoid-greenstone terrain)
S. Master et al. / Precambrian Research 182 (2010) 254–273 257
Table 2
Stratigraphy of the Dete-Kamativi Inlier, NW Zimbabwe. Geochronological data are Rb–Sr whole rock analyses of Priem et al. (1972).
to Shamrocke mine (Fig. 2). The northern outcrop belt is subdivided 2.1. Southern outcrop belt
into the Central, Mhangura, and Doma West areas. In addition, there
is an outlier of Deweras Group rocks in the Silverside area 15 km The Deweras Group in its southern outcrop belt was formerly
ESE of Mhangura (Fig. 2). Stratabound copper–silver deposits in the subdivided into the “Lower Arenite”, “Volcanic” and “Upper Aren-
Deweras Group, which have been exploited in the past, occur in two ite” formations (Bliss, 1970; Sutton, 1979). In order to conform
main areas (Fig. 2), around Mhangura (Mangula, Norah and Silver- to internationally acceptable codes of stratigraphic nomenclature,
side mines) and around Alaska (Shackleton/Avondale, Angwa and the “Lower Arenite” and “Volcanic” formations have been renamed
Hans mines). (after their type localities) the Njerere and Munyati formations
Fig. 3. a. Key for interpreting Figures 3b, 8, 15 and 17. b. Generalized lithostratigraphy of the southern part of the Deweras Group.
258 S. Master et al. / Precambrian Research 182 (2010) 254–273
Fig. 5. Mudstone with dissolution cavities after sulphate nodules overlying Deweras
lavas of the Munyati Formation, Njerere River. A thin palaeosol is developed on top
of the basalt.
Fig. 11. Deformed anhydrite-bearing dolomite (light coloured) with thin argillite
interbeds (dark) of a playa flat environment, Norah Formation, Deweras Group,
Norah Mine.
Fig. 9. Trough cross-bedded arkose representing braided stream deposits, Mangula
Formation, Deweras Group, Mhangura.
group, with ␦13 C ranging from +13.1 to +16.6‰ VPDB (Bekker et al.,
2001b).
and plane-bedded arkosic arenites, together with conglomerates,
wackes, calcareous argillites and diamictites. The lithologies are 2.2.2.3. Suiwerspruit and Chimsenga Formations. The Suiwerspruit
arranged into two upward-fining sequences. The Mangula For- Formation (Master, 1991a,b) consists of a series of mafic lava flows
mation is the correlative of the arkosic rocks of the Nyamachena separated by interflow sedimentary rocks. The lavas overlie a mafic
Formation in the southern outcrop belt of the basin. The carbonate pyroclastic sequence of tuffs and agglomerates (Fig. 13) and are
rocks in the Mangula Formation are 13 C-enriched (Master et al., overlain by arkoses and argillites of the Chimsenga Formation.
1990, 1993), with ␦13 C values in the range 7.0–14.6‰ VPDB. This unit forms the uppermost part of the Deweras Group in the
Mhangura area.
2.2.2.2. Norah Formation. The Norah Formation (Master, 1991a,b)
consists mainly of thinly bedded anhydrite-bearing dolomites and 2.2.2.4. Mafic Intrusions. Mafic dykes and sills are common in the
argillites with interbeds of ripple-marked arkoses. The imper- Deweras Group at Mhangura and consist of dolerites that have been
sistent Norah Orebody Subformation, found intercalated with affected by greenschist-facies metamorphism. These dykes and sills
the dolomitic argillites, consists of trough cross-bedded and may have been feeders to the volcanic Suiwerspruit Formation.
plane-bedded arkosic grits overlain by chloritic quartz wackes
with thin interbedded evaporitic beds consisting of anhydrite, 2.2.3. Silverside area
barite, celestite, chlorite, tourmaline and copper sulphides (Master, 2.2.3.1. Silverside Volcanic Formation. The Silverside Volcanic For-
1991b; Figs. 10 and 11). In the Shackleton and Angwa Mine areas, mation occurs at the base of the Deweras Group in this area and
large-scale cross-bedded sandstones (Fig. 12) are found beneath consists of sheared tholeiitic lavas, which rest unconformably on
mudcracked argillites and carbonates. The rocks of the Norah For- Archaean greenstone lithologies (Stagman, 1959). There are several
mation were deposited in playa and aeolian dune environments, lava flows separated by impersistent interflow sediments consist-
and may be the correlatives of the Nyachechene Formation in the ing of pyritic quartz-sericite schists (Hahn and Steiner, 2001). The
southern part of the basin (Master, 1991a,b). The evaporitic car- lavas are subalkaline basalts, with a similar chemistry to the Dew-
bonate rocks of the Norah Formation have the most 13 C-enriched eras Group lavas from the southern outcrop belt (Hahn, 2002).
values in the Deweras Group, and in the entire Magondi Super-
2.2.3.2. Diamictite. At Silverside, a diamictite containing boulders
and cobbles of various greenstone lithologies is developed above
an unconformity on the Silverside Volcanic Formation. The highly
deformed diamictite is matrix-supported, with a chlorite- and
quartz-rich matrix. Master (1991a) considered it to be a debris-flow
deposit formed in an alluvial fan environment.
Fig. 12. Large-scale planar cross-bedded arkosic aeolian arenite from the Deweras Group, Angwa River, near Angwa Mine.
area just north of Mhangura, to the Shamrocke Mine (Figs. 2 and 14). larities with the sources of Enriched-type Mid-Ocean Ridge Basalt
Here the Deweras Group comprises a 2.2 km thick sequence (E-MORB) of Le Roex et al., 1983 (Master, 1991a,b).
of arkoses, arkosic grits and thin conglomerates with minor
quartzites, mica schists, and dolomites (Thole, 1974; Bartholomew, 3. Lomagundi Group
1999). Bartholomew (1999) placed these lithologies into the Kapiri
Formation. The Lomagundi Group overlies the Deweras Group uncon-
formably, and in places also transgresses onto the Archaean
2.3. Volcanic Geochemistry and Petrogenesis basement (Stagman, 1961; Tennick and Phaup, 1976; Stowe, 1978;
Hahn, 2002). In some areas the contact between the two groups
The volcanic rocks of the Deweras Group have undergone is along a thrust (Sutton, 1979; Treloar, 1988). The Lomagundi
greenschist-facies metamorphism. On the basis of immobile Group consists of the Mcheka, Nyagari and Sakurgwe formations
trace element ratios, the volcanic rocks are mainly subalkaline (Fig. 15). The Lomagundi Group contains two economic sediment-
basalts with minor andesites (Master, 1991a; Hahn, 2002). Master hosted copper deposits (Alaska and Shamrocke mines), and minor
(1991a,b) inferred significant crustal contamination based on light gold mineralization, which have been exploited in the past (Master,
rare earth element (LREE) enrichment. Compositional variations 1991a).
in incompatible, immobile trace element contents indicate signif-
icant differences between the volcanic rocks of the Southern and 3.1. Mcheka Formation
Northern facies of the Deweras Group. The source characteristics
of the volcanic rocks of the Munyati and Mupfure areas (Southern The Mcheka Formation was defined by Tennick and Phaup
Facies) show similarities with the sources of Transitional-type Mid- (1976) and is the lowermost unit of the Lomagundi Group. It over-
Ocean Ridge Basalt (T-MORB), while those of the volcanic rocks lies the Deweras Group unconformably, and in places it lies with
of the Alaska and Norah lavas of the Northern Facies show simi- a structural (thrust) contact on Archaean basement rocks. It com-
prises basal pebbly grits (Basal Conglomerate Member) overlain
by the Lower Dolomite, Phyllite, Quartzite, Upper Dolomite, and
Sandy Argillite members. A basal conglomerate grades laterally into
a grit and contains clasts of Deweras Group and Archaean green-
stone belt lithologies (Stagman, 1961; Tennick and Phaup, 1976;
Stowe, 1978). Thin bands of dolomite interbedded with the grits are
indistinguishable from the main dolomite intervals in the Mcheka
Formation, and indicate an interfingering of facies in the gradation
to the overlying Lower Dolomite (Stagman, 1961). The dolomites
of the Mcheka Formation were originally analysed for carbon iso-
tope ratios by Schidlowski et al. (1975, 1976) and were found to be
highly enriched in 13 C, with an average ␦13 C value of +8.2‰ VPDB
(n = 64). In these pioneering studies, however, the dolomites were
not differentiated into the Lower and Upper Dolomite members.
Fig. 13. Pyroclastic rocks (agglomerates and lapilli tuffs) from the Suiwerspruit Dolomites underlying the Karoo Supergroup have been inter-
Formation, Deweras Group, south of Angwa Mine. sected in the Insuza borehole NW of Bulawayo (Thompson, 1975;
262 S. Master et al. / Precambrian Research 182 (2010) 254–273
Fig. 1). A sample from these dolomites had a high ␦13 C value of
+5.4‰ VPDB, within the range of the Lomagundi Group carbonates
reported by Schidlowski et al. (1976), and these dolomites have
been correlated with the Mcheka Formation (Thompson, 1975).
Fig. 14. Middle and northern part of Magondi Belt, from Alaska to Shamrocke,
3.1.2. Sandy Phyllite Member
depicting the distribution of Palaeoproterozoic mafic volcanic rocks and intru-
sions (black) and sediment-hosted copper deposits (modified after Hahn, 2002). The Sandy Phyllite Member consists of sericitic siltstones with
RS = Rusere Syncline. The circle represents the outline of the 20 km-diameter High- small wave ripple marks and massive arkosic arenites. Pebble con-
bury Impact Structure (Master et al., 1995). glomerates form narrow lenses within the sandy phyllites. Rare
S. Master et al. / Precambrian Research 182 (2010) 254–273 263
4. Piriwiri Group
Fig. 19. Cu–Zn–Pb–Fe massive sulphide from Copper Queen Formation, Piriwiri
Fig. 18. Agglomerates of the Nyamakari volcanic centre of the Chenjiri Formation,
Group, Copper Queen Mine.
Piriwiri Group.
The Kamativi and Tshontanda formations are found in two 6.2. Magondi Orogeny
elongated belts. The Kamativi Formation consists of tightly folded
muscovite schists, subordinate fine-grained biotite schists, and The Magondi Orogeny was defined by Leyshon (1969) based
minor arkosic psammites (Fig. 20), while the Tshontanda Forma- on structural work in the Copper Queen area. The term was
tion is composed of garnetiferous mica schists and subordinate applied to the tectono-metamorphic event that was responsible
sillimanite gneisses, with local lenticular intercalations of impure for the intense deformation and metamorphism of the Piriwiri
quartzite (Lockett, 1979). The modal compositions and layering of and Lomagundi Group rocks of the Magondi belt. In the south,
the rocks of the Kamativi and Tshontanda formations suggest that the belt is a typical fold-and-thrust belt, with imbricate stacks
their protoliths consisted of micaceous shales interlaminated with of Magondi Supergroup rocks thrust southeastwards onto the
subordinate silty shales and siltstones, with thin intercalations of Archaean Zimbabwe craton, while in the north the structural style
arkose and feldspathic arenite. The lack of associated arenites and is of a more thick-skinned type, with basement gneisses imbricated
calcareous rocks suggests a deeper-water depositional setting than within the sedimentary sequence (Leyshon and Tennick, 1988;
for the Inyantue Formation. Treloar, 1988). The associated increase in metamorphic grade to
the north reaching granulite facies was explained by thermal relax-
6. Structure and Metamorphism ation following overthrusting of hot “early Proterozoic” gneisses
(Hurungwe gneisses; Treloar, 1988; Treloar and Kramers, 1989).
The Magondi Supergroup has been affected by at least three
phases of deformation during the Palaeoproterozoic Magondi 6.3. Extension of the Magondi Belt
and Pan-African Zambezi orogenies (Leyshon, 1969; Stowe, 1978;
Treloar, 1988). The most recent (Zambezi) deformation only The Magondi Belt does not correlate with any terrains that are
affected the northern part of the basin (Thole, 1976; Thole and currently to the north of it. Instead, it is separated from the South-
Robinson, 1976; Fey and Broderick, 1990; Hahn et al., 1991), result- ern Irumide Belt (part of the Congo-Tanzania-Bangweulu craton)
ing in the E-W trending Rusere Syncline (Fig. 14), and has not been by an eclogite-bearing suture zone formed during the Pan-African
recognised further south. In the Mafungabusi Plateau area in the Damaran-Lufilian-Zambezi Orogeny (Hanson et al., 1998; Dirks and
south, Sutton (1979) found an early set of folds with an axial planar Sithole, 1999; Johnson et al., 2005).
cleavage, which were affected by crossfolds. In the Mcheka ranges, The southward continuation of the Magondi belt is obscured by
north of the Mupfure River (Fig. 2), the Lomagundi Group has been Mesozoic and Cenozoic deposits of the Kalahari basin in Botswana.
repeated three times through thrust duplication in a thin-skinned A borehole drilled in the Gweta region of NE Botswana intersected
thrust system (Tennick and Phaup, 1976; Leyshon and Tennick, high-grade garnet-orthoclase-sillimanite gneisses that have been
1988; Treloar, 1988). In the central part of the Deweras Group out- correlated with lithologies of the Dete-Kamativi Inlier (Fig. 1) which
crop area, around Alaska, two folding events were also recognised. lies 200 km to the NW (Carney and Dowsett, 1991). High linear
Further north, in the Mhangura area, Master (1984) found three gravity anomalies continue southwards of the Magondi belt along
phases of folding affecting the Deweras Group rocks, the third phase the ‘Kalahari Line’ (Hutchins and Reeves, 1980) and emerge as the
being E-W Zambezi crossfolding, which reversed the plunges of Kheis terrane of the Northern Cape Province (Hartnady et al., 1985;
earlier N-S Magondian folds. Stowe, 1989, 1990).
The metamorphic grade in the southern part of the basin The Kheis terrane includes sedimentary and volcanic rocks of the
is lower greenschist (quartz–muscovite–chlorite–albite subfacies) Transvaal Supergroup. The Elim Group, lying unconformably above
to prehnite–pumpellyite facies. The metamorphic grade around the Beaumont and Ongeluk formations at the top of the Transvaal
S. Master et al. / Precambrian Research 182 (2010) 254–273 267
7. Geochronology
Table 3
Summary of the geochronology of the Magondi Belt. The references are as follows: (1) Priem et al. (1972); (2) Mapeo et al. (2001); (3) Majaule et al. (2001); (4) McCourt et
al. (2001); (5) Treloar and Kramers (1988); (6) Munyanyiwa et al. (1995); (7) Vail et al. (1968); (8) Höhndorf and Vetter (1999); (9) Schidlowski and Todt (1998); (10) Master
and Kramers (2000); (11) Master (1991b); (12) Master et al. (1999); (13) Höhndorf et al. (1989), Hahn (2002); (14) Manyeruke et al. (2004).
Dete-Kamativi Inlier
Granite 2000 ± 80 Rb–Sr WR 1 Postorogenic intrusion
Granodiorite 2159 ± 100 Rb–Sr WR 1 Arc-related intrusion
Gweta paragneiss 2125 U–Pb zircon 2 Detrital zircon (max. age)
Kubu Island Granite 2039.2 ± 1.4 U–Pb zircon 3 Syntectonic intrusion (min. age)
Hurungwe Granite 1997.5 ± 2.6 U–Pb zircon 4 Syntectonic intrusion (min. age)
Piriwiri Group
Granulite 1890 ± 260 Rb–Sr WR 5 Metamorphism
Granulite 1780 ± 280 Rb–Sr WR 5 Metamorphism
Granulite 1960–1940 Pb–Pb zircon evap 6 Metamorphism
Phyllite 1753 ± 65 K–Ar WR 7 Metamorphism
Phyllite 1659 ± 50 K–Ar WR 7 Metamorphism
Sanyati massive sulphide 2122 ± 14 Pb–Pb galena 8 Deposition
Lomagundi Group
Striped Slate 1905 ± 70;1974 ± 70 K–Ar WR 7 Metamorphism
Dolomite 2150 ± 50 Pb–Pb 9 Deposition
Deweras Group
Microcline vein 550 ± 110 Rb–Sr WR 10 Metamorphism
Galena in vein ca. 2000 Pb–Pb model age 11 Metamorphism
Dolomite ca. 2000 Pb–Pb 12 Metamorphism
Mafic lava 2050 ± 100 Rb–Sr WR 13 Deposition/metamorphism
Chimbadzi Hill Intrusive complex 2262 ± 2 U–Pb baddeleyite 14 Syn-Deweras extension
2159 ± 100 Ma and 2000 ± 80 Ma, respectively (recalculated using event, which was linked to the Magondi Orogeny and high-grade
87 Rb decay constant from Steiger and Jäger, 1977). These poorly metamorphic events in the Limpopo Belt (Mapeo and Wingate,
constrained ages reflect magmatic episodes on the western side of 2009).
the Magondi basin pre- or syn-kinematic (granodioritic gneisses),
as well as postkinematic (unfoliated granites), with respect to the 8. Tectonic setting of the Magondi Supergroup
Magondi Orogeny. The granodioritic gneisses probably represent
a calc-alkaline magmatic arc, while the granites represent post- 8.1. Deweras Group
collisional crustal melts following granulite-facies metamorphism
and migmatite formation. The stratigraphy and sedimentology of the Deweras Group indi-
U–Pb dating of detrital zircons from the paragneisses inter- cates its deposition in a continental rift basin (Cooper, 1978; Sutton,
sected in the Gweta borehole of NW Botswana (Carney and 1979), developed on the western margin of the Archaean Zimbabwe
Dowsett, 1991) showed that their protolith was deposited after craton (Maiden et al., 1984; Master, 1991b). The basin architecture
2125 ± 6 Ma (Mapeo et al., 2001). Granitoids exposed at Kubu Island was in the form of elongated, fault-bounded grabens. The differ-
in Botswana, some 80 km SE of the Gweta borehole, yielded a TIMS ence in stratigraphy between the Southern and Northern facies of
U–Pb zircon age of 2039.2 ± 1.4 Ma (Majaule et al., 2001), indi- the Deweras Group indicates that the basin was fragmented along
cating a southward extension of granitoids emplaced during the strike into tectonic sub-basins. The absence of basinwide strati-
Magondi Orogeny. In the Matsitama Belt of NE Botswana regarded graphic markers, and lack of reliable geochronology, coupled with
as an Archaean greenstone belt (Majaule et al., 1997), a deformed tectonic deformation and lack of complete stratigraphic sections in
supracrustal succession, including stromatolitic carbonates, with the structural inliers makes it impossible to correlate lithological
stratabound copper deposits at Thakadu (Roberts, 1965) led Master units between different parts of the basin. Compositional differ-
(1994) to suggest that these rocks might be a southward exten- ences make it unlikely that the volcanic rocks could be used as
sion of the Magondi Belt. Pb–Pb galena model isotope ages for the stratigraphic markers between different parts of the basin. The
mineralization at Thakadu of 2200 ± 150 Ma (Coomer et al., 1977), basin fill pattern was one of transverse alluvial fans grading into
and the presence of abundant haematitic redbeds, which must be braidplains, with central playa lakes. Evidence from changing clast
younger than 2.3 Ga (Bekker et al., 2004) support such a correla- composition suggests that the alluvial fans were sourced from
tion. North of Thakadu, at the shear zone-hosted Bushman deposit, basement rocks that were displaced northwards during sedimenta-
muscovite associated with Cu–Pb–Zn mineralization has an Rb–Sr tion in a sinistral strike-slip basin (Master, 1995). Consideration of
age of 1.93 Ga, which has been related to the Magondi Orogeny the trends of en-echelon synsedimentary folds also indicates that
(Barton et al., 1994). Further south, the Mahalapye Granite at the the Deweras basin was undergoing left-lateral wrench deforma-
western extremity of the central Limpopo belt gave a SHRIMP U–Pb tion during or shortly after sedimentation (Master, 1991a,b, 1995).
zircon crystallisation age of 2023 ± 7 Ma (McCourt and Armstrong, Modern analogues of such a strike-slip basin are the Salton Sea
1998). The same western Limpopo Belt region has undergone sig- Trough, California, and the Dead Sea basin, Israel–Jordan, although
nificant deformation at ca. 2.0 Ga, coinciding with the Magondi the Deweras Group was not deposited along a plate boundary, but
Orogeny (Holzer et al., 1999). Across the Limpopo Belt on the in a transtensional rift basin.
Kaapvaal craton, monzogranite, microgranite and meta-rhyolite of Basalts of the Deweras Group are subalkaline, which is typi-
the Okwa Inlier of Central Botswana all give ages indistinguish- cal of continental flood basalts, and they show considerable LREE
able from 2056 ± 2 Ma, indicating a possible link with the Bushveld enrichment, which indicates crustal contamination. The temporal
Complex (Mapeo et al., 2006). The 2054 ± 9 Ma Segwagwe-Masoke evolution of the Deweras volcanic rocks, from early T-MORB to
igneous complex in southeastern Botswana, which is also genet- later E-MORB (Master, 1991a,b) indicates the involvement of an
ically related to the Bushveld Complex, predates an F3 folding enriched mantle plume, probably due to asthenospheric upwelling
S. Master et al. / Precambrian Research 182 (2010) 254–273 269
during progressive rifting (McKenzie, 1978; Bhattacharji and Koide, but if their presence is due to extension in a back-arc setting, then
1987). their age must be close to the age of the orogeny, i.e. ca. 2.0 Ga. The
overlying immature greywackes of the Sakurgwe Formation in the
8.2. Lomagundi and Piriwiri groups Lomagundi Group might reflect deposition in the back-arc basin
and, potentially, foreland basin that developed above the back-arc
The lower part of the Lomagundi Group, which overlies the Dew- as the Zimbabwe craton collided with an unknown crustal terrane
eras Group unconformably, has a lithological sequence which is to the west. The unknown terrane overrode the western part of the
characteristic of marginal marine and shallow shelf settings. The Magondi Basin and caused easterly-directed thrusting of the basin
dolomites were deposited in the intertidal to subtidal zones, as sequences onto the adjacent Zimbabwe craton (Treloar, 1988).
indicated by the presence of stromatolites and oolites. Quartz-rich
arenites were also deposited in intertidal and subtidal environ-
ments, as well as in supratidal aeolian sand dunes (Stowe, 1978). 9. Regional and global tectonic reconstructions and
Striped Slates and minor iron formations were deposited in deeper implications for the Lomagundi carbon isotope excursion
subtidal environments, while the turbiditic greywackes of the
Sakurgwe Formation were likely sourced from a magmatic arc The Neoarchaean position of the Zimbabwe craton with respect
to the west. The Piriwiri Group is likely the distal facies equiv- to the Kaapvaal and other cratons remains debatable. The con-
alent of the contemporaneous, more proximal Lomagundi Group troversy is partially based on ca. 2.7 and ca. 2.0 Ga metamorphic
(Leyshon and Tennick, 1988). Graphitic and pyritic argillites, cherts, ages for the Limpopo Belt that separates these two cratons (e.g.,
and greywackes of the Piriwiri Group were deposited in deep and, Holzer et al., 1999). Recent reconstructions based on ages of major
likely, anoxic waters, possibly in continental slope, submarine fan dykes on these cratons suggest that they did not share a common
and abyssal plain environments. Volcanogenic hydrothermal ema- history until ca. 2.0 Ga and that the Zimbabwe craton could have
nations on the sea floor, possibly in a back-arc setting, may have been positioned against the eastern margin of the Superior cra-
given rise to the deposition of cherts, manganese-rich beds, and ton in the Neoarchaean (Söderlund et al., in press). Interestingly, if
minor iron formations in the Piriwiri Group and the upper part the orientation of the 2512.3 ± 1.8 Ma Crystal Springs dyke in Zim-
of the Lomagundi Group. The manganese and phosphate-bearing babwe and the ca. 2510 Ma Mistassini dykes in Canada is matched
beds of the Umfuli Formation are similar to those in other Palaeo- (Söderlund et al., in press), the Magondi Belt is placed against and
proterozoic successions deposited during the Lomagundi Event (cf. strikes parallel to the Mistassini and Otish basins and the Labrador
Bekker et al., 2003). The Lomagundi and Piriwiri groups record a Trough in Quebec (Fig. 22a). These basins were likely initiated at
marine transgression over the continental sediments of the Dew- ca. 2210–2220 Ma, by rifting in the Labrador Trough, and certainly
eras Group. This implies subsidence of the rift fill below sea level. before intrusion of the ca. 2169 Ma Otish gabbro sills (Hamilton
Most rifts initiate with an upwelling of hot asthenospheric material, and Buchan, 2007). Both of these basins and the Labrador Trough
which then cools and contracts, leading to a phase of thermal subsi- contain carbonate successions with highly positive carbon isotope
dence (McKenzie, 1978; Sclater and Célérier, 1987). The lower parts values (Bekker et al., 2003). It seems therefore plausible that the
of the Lomagundi and Piriwiri groups thus represent the thermal Zimbabwe craton was placed against the eastern margin of the
subsidence phase of the developing Magondi rift basin. Superior craton in the Neoarchaean and until ca. 2.22–2.17 Ga.
Rift basins that undergo large amounts of extension eventually Recognition of passive margin successions along the western
become floored by oceanic crust, and the rift shoulders develop and southern margin of the Zimbabwe craton and along the west-
into passive margins (McKenzie, 1978; LePichon and Sibuet, 1981; ern and northern margins of the Kaapvaal craton that all contain
Sclater and Célérier, 1987). However, passive margins, in contrast 13 C-enriched carbonates and were affected by broadly synchronous
to active continental margins, do not contain felsic to intermediate tectonic events allows some constraints to be placed on the tectonic
volcanic rocks, which are normally associated with magmatic arcs evolution of these cratons between 2.2 and 2.0 Ga. Granulite grade
(Latin and White, 1990), although volcanic rifted margins result- metamorphism and dextral shearing occurred in the Limpopo Belt
ing from plume-related breakup, may contain large volumes of at ca. 2.0 Ga, and a metamorphic event of similar age and grade
bimodal mafic and felsic volcanics (e.g., Gladczenko et al., 1997). affected the northern part of the Magondi Belt. Although a meta-
The occurrence of volcanic rocks in the Nyagari and Chenjiri forma- morphic event of this age has not yet been documented in the Kheis
tions is of critical importance in determining the tectonic setting for Belt, there is a prominent angular unconformity above the Elim
the upper parts of the Lomagundi and coeval Piriwiri groups. The Group, which transgresses progressively over older strata to the
presence of pyroclastic rocks and andesites indicates that explo- south (van Niekerk, 2006). We propose the following plate tectonic
sive volcanism (felsic to intermediate type) was active during their scenario to explain these events. First, an unknown terrane (“Terra
sedimentation. The ca. 2.0 Ga granodioritic rocks from the Dete- Incognita”, Fig. 22b) obliquely approached the western margin of
Kamativi Inlier, as well as granitoids from the Kariba area, may the Kaapvaal craton, terminating deposition of the Elim Group in
have been emplaced contemporaneously with the final stage in the Kheis terrane. The Kaapvaal craton and the unknown terrane
sedimentation in the Magondi Basin, and, if this is the case, rep- rotated around the point of collision catching on both sides the
resent the root of a magmatic arc behind which the upper parts Zimbabwe Craton in a scissor-like fashion (Fig. 22b). The subse-
of the Piriwiri and Lomagundi groups were deposited (cf. Master, quent collision in the Limpopo Belt and the Magondi Basin was
1991a,b). The type of mineralization (e.g., massive base-metal synchronous and led to the escape of the Zimbabwe craton mani-
sulphide deposits, iron and manganese deposits) and volcanism fested by dextral shearing in the Limpopo Belt (Fig. 22c). Differences
associated with this stratigraphic level is also consistent with a in the degrees of deformation and metamorphism between the
back-arc basin tectonic setting. Magondi and Kheis belts may be accounted for by the irregular
The volcanic rocks in the upper parts of the Lomagundi and shape of the western margins of the Zimbabwe and Kaapvaal cra-
Piriwiri groups occur in association with an upward-coarsening tons, interacting with an irregularly shaped Terra Incognita with
succession containing immature greywackes. Deposition of the embayments between promontories (Fig. 22b). As the Terra Incog-
lower parts of both groups is consistent with a passive margin nita rotated towards the Zimbabwe craton, a magmatic arc was
setting. There may be a disconformity between the passive mar- superimposed on the former passive margin in the Magondi basin
gin (proximal and distal shelf) rocks and the overlying successions and led to subsequent back-arc extension (Fig. 22b). Following col-
containing volcanic rocks. The volcanic rocks have not been dated, lision, a foreland basin developed above the arc and back-arc basin.
270 S. Master et al. / Precambrian Research 182 (2010) 254–273
Fig. 22. Tectonic evolution of the Zimbabwe craton in the early Palaeoproterozoic. (a) Following Söderlund et al. (in press), the Zimbabwe craton is positioned along the
eastern margin of the Superior craton at ca. 2.2 Ga. Söderlund et al. (in press) based their reconstruction on ages and orientation of mafic dykes. Our reconstruction is based
on sedimentologic and chemostratigraphic similarities between the sedimentary fill of the Labrador Trough and Magondi Belt. (b) Oblique collision between the Kaapvaal
craton and an unknown terrane (“Terra Incognita”) resulted in their rotation, with subduction zones and back-arc basin initiated. (c) Assembly of the Kaapvaal and Zimbabwe
cratons, and unknown terrane Terra Incognita at ca. 2.0 Ga led to tectonic escape of the Zimbabwe craton and dextral shearing in the Limpopo Belt. Irregular shape of colliding
cratons with promotories and embayments led to the higher grade of deformation, metamorphism, and uplift in the northern part of the Magondi Belt and southern part of
the Kheis Belt.
Deformation in the embayment stretching from the northern part breakup, they swapped some of their component cratonic frag-
of the Magondi Basin to the northern part of the Kheis terrane was ments.
less extensive and, potentially, a remnant ocean was preserved in The Lomagundi carbon isotope excursion represents the most
this segment. extreme perturbation of the carbon cycle in Earth’s history. A num-
It has been inferred that two supercontinents existed in the ber of questions remain, the most relevant to this study being the
Neoarchaean to early Paleoproterozoic (Aspler and Chiarenzelli, tectonic setting of the basins (intracontinental vs. open-marine)
1998); one included the Zimbabwe, Kaapvaal, São Francisco, Indian, that record this event and whether the isotopic excursion reflected
and Pilbara cratons, whereas the other contained the Wyoming, the composition of seawater or diagenetic fluids. We have herein
Superior, Fennoscandia, Siberia, Rae, and Hearne cratons. The tec- documented the Lomagundi excursion in four broadly correlative
tonic evolution of these two supercontinents was out of phase; open-marine successions (Silverton, Sengoma Argillite and Luc-
while one was assembling, the other one experienced breakup. know formations, and Gumbi Group) and in one continental rift
Our study supports this interpretation in as far as the Limpopo succession (Deweras Group). Similar carbon isotope signals in these
and Magondi orogenies correspond in age with the rifting and successions deposited on the margins of two separate cratons argue
breakup on the Wyoming, Superior, and Fennoscandia cratons strongly that the Lomagundi excursion reflects an open-marine
(Bekker et al., 2003; Bekker and Eriksson, 2003). If the con- seawater signal rather than a diagenetic signal due to high organic
nection between the Zimbabwe and Superior cratons before ca. matter burial and extreme evaporation in closed intracratonic rift
2.2 Ga is confirmed, it would imply that as these two super- basins. Although extensive development of intracratonic basins
continents followed their own tectonic cycles of assembly and between 2.4 and 2.0 Ga could have factored into this perturbation of
S. Master et al. / Precambrian Research 182 (2010) 254–273 271
the carbon cycle (e.g., Bekker et al., 2008), it was clearly of a global Bekker, A., Holmden, C., Beukes, N.J., Kenig, F., Eglington, B., Patterson, W.P., 2008.
extent and equally affected seawater composition. Although the Fractionation between inorganic and organic carbon during the Lomagundi
(2.22–2.1 Ga) carbon isotope excursion. Earth Planet. Sci. Lett. 271, 278–291.
explanation for this extreme carbon isotope excursion and its dura- Bekker, A., Karhu, J.A., Eriksson, K.A., Kaufman, A.J., 2003. Chemostratigraphy of Pale-
tion remains yet to be found, we emphasize here that the answer oproterozoic carbonate successions of the Wyoming Craton: tectonic forcing of
is unlikely to be a reflection of local conditions. biogeochemical change? Precambrian Res. 120, 279–325.
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reviewers. AB acknowledges support from NSF grant EAR-05-
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