318 INTERNATIONAL CRITICAL TABLES Mia Br, SS | Boosttone (e EAmageman |Bst,) Mf v0 749 mm a1 Cs SCH een TaL.08F 0 BT ws | G0 Biloba [34.153 1708 128 wo | 304 50.5 | CillwO n-Butyl alecol (phase). | oz.25 71 | saz 108.83 202 20 52:8 | CallyO Toobatylalooba 80.09) 67.14) 531 06.88 307 Ba 45:0 | Cato cez-Butyl alcobal 33.5 | 66. | 520 79 04 2.1 gos | Cal0 tot-Butsl alebal 7o.01| 35.41) 526 20.98 50:2 16.8 32:9 | CaH.0 Taoamy aleohot @ phase). 5.15] 82.70) 5x0 5.80 oo. BS 26:4 | Citt40 ert -Amylaloobl sr fos | 590 51 702 wor 19.7 | Calle Bnsone (2phase) 69.25] 20.6 | 1700, S161 80.2 06 13.0 | Cll, Toluene phar) ser | 44-4 | 1708 70.38, 90:0 34 a7 Sati 8.84 ° w.6 wat | Gi Telus 109-15 8] WRT 11.39 25 23 483 105.32 187 m9 4 100-01 3 m5 aa 95.42 383 23.8 ms Crane 92.00 $32 m1 me ‘The E-Arrangement by A-Coostituent (ep. vil) 38.08 ma 4 m2 TBF, | Mele) Eo 00 ae red aes B-Consttaent (the CArrangement) |B e" |W] a2 737 90 ua | a. aa oe |= CCN; Chloropiin |_ss7_ | 5.2__| CGH ATT abo [a _18 Tas ° 18.5 waa | See Ale seth o oa escaee 13.40 12 ee] BG | cans Carbon tteatloride 105.08 ae Ma Bz — | GO Metipratesor 35.70 [tab] ai 38.08 Bi Rs $23 | Cato Baty! ateobol e405 | o1'3 | 353 ett 4 1ot $3 | G0 alist alcohol raise | 7a | ao 0.23 26 38 336 3H,O n-Fropy alohol ms [7 | 408 57.08 ae 60 30.3 | CWO Tooprops alcool a [ou] a7 scat 22 $2 g's | CaMO Methyl ethyl ketone m8 | 53.4 | 1012 sua ar 34 Tia | Cato, Beds! acetate wars [ae | 1901 mir 4 ir 43 | Catt0s Methyl propionate 7.8 [45 | 1900 C140 Ieobuty! loahol qa [so | 42 CONSTANT-BOILING (AzeOTROPIC) MncruRES | CllHO fert-Butyl alobol, oo.5 |r| 38s ‘The data in the following tables are based largely on Lecat, ee Lea tension. de vapeur des mélanges de liguides.” Lraxtoropiome, | CHO Meth aleohol Hide, Ethylene bromide ar.ss | 41.3] 1290 Brussels, 1918, ¢. & for literature and for further details ‘Only those systems are included for which both the composition | C+#40s Methyl formate. oe 41 2 and the boiling point are kacwn, To a few cases, the system is | CsH0 Ethyl alooko aaa [as | sis Composed of twoliqud phases.” Such cases are marked “2-phase.” | CoH Acetone 90.25 | 61 | 1087 ‘The pressure is 760 tam unleas otherwise stated. “L. No” = | Cs#iOs Ethyl formate 30.35 | 62.5 | 1658 “Lecat's number. CiHOs Methyl nostate 40.15 | 69-5 | 1659, Commas sH40 Isopropyl aleahol 44.6 | 90 | 516 1, Two-component mista soe | C40, Methyla 37.25 | 46 | 1682 ‘Minimum boiling pain. ais | CLO Methyl ethyl Ketove 45.85 | 64.1 | 1088, ect of presure Ban | Cilke0 tert-Butylsloobol. asa | ou | siz Maximurn baling point 25 | CalvO Echt ether sa. | 1_| eso 2, Three-component mixtures 32 ‘CHBrCi, Dichlorobromomethane CHO BibsTateokal. 175.5 | @ ‘Twn-Companant Mixtures with Minimum Railing Paint CLELO Ally! lechel Bole | ss S-Tasun {C1HO r-Propy! slob B64 | 60 | att Bim arate CaN Tsoprops1 aleobol on B-Constituent (the C-Arrangement) |B. P,| MCh wo, | Calt4O Ioabutylaleobal 190.3 [78 | 435 [tc CHB, Bromoform EA GAO Bihyl aloohol (also p. 310, 323). Cx Allyl alcohol CiHO: Propionic sci. CyHLO Props! aleohol CxO sopropyl aleohol CHO Methyl ethyl ketone, Catis0s Tsobutyrie acid C4HHsOs Bthyl acetate (. also p. 322). TO, Baye acid. ae ‘CHO Moths aloobol [35 CxO Ethy! aleobol wos las | 36 CxTLO Isopropyl sleohol 60.8 (CHO; Formic acid GiiiBr Propyl bromide. CuCl Isobutyl chloride (BP, 68°)CONSTANT BOILING MIXTURES 319 Tue BP, | Mole) ah EP, | Mole] BConsituent (the Carangement) [P.67| Moe] f° | Boonstituent the €-Arrangement) | P,P] Mote] ‘CH Methyl iodide HCH Trcoroothy Tone — (Continued) GH.O Mey aleobo =] 80] 744] 808 | TiHTq0 TacbutyT alookot [asa | S8) a GyH.0, Meth! formate ai | 8) [1275 | Cut,0 ur-Buty! aloobol }75 | 74 | 380 CuHLO Ethyl aleobol 4.5 | 80 | 397 | CH 0 tert-Amylaloahol iss | as {C3840 Tsopropyt soobel 42a fos | om AEC, Fosisiscontiane HHO» Methytal was] | uo | oaocmaprocme __ _ CHINO, CiHhuOs Isovalerie acid (B. P, 176.5 3 GO Aliph alcohol | 8] 39 | Sor | CaH.0 Phenol 1526 CxO n-Propy aloobol | 80.15/44 | sor | Cathx0 Cyetberanol Cikfy0 Tach aleobol o47 | 70 | 00 | Caths0, Toon prpisnts CaHlad Diethyl ketone 99.1 | a4 | 1098 AHCh cist, 2-Acetylove dichloride CiHgO Meth! props} ketone gots) 63 | 1039 | See ES wen CHLO Methy! sleohol ‘CAH tran, 2-Acetslene dichloride GHC, TrihToroetis wet | Ae a GIHAN Acetonitrile | 63.45 | 84.5] 74 | SstteO Ethyl alechal $6.5 [821 38 CrHLCL, Behylene chloride | 50.5 | 2 | 320 CHCl: Dichlorocthylene CHC, 1, 1-Dichloroethane 49.05 | 28.5] 900 | GHOAIpTalohol. es - .8 | TO | OH (GsHBr Ethyl bromide, 84.9514" | 303 | C0 n-Propyl aechol so__|z7_| 400 CAHACIO Chloramethyl methyl ether ..-"| 56° | 57.5 | 382 C,H Ethyl iodide, sa.7 | 52.5] ai7 | —___CsHsCl, Tetrachloroethane __ CHILO: Aestone 58.7 | 20° | 200 | Gills Acetieacid.....- horse 965) CaHi+0; Exhy! formate 50.05 | 30.5) sii | CellOs Methyl lnctate. sas | 36 | 1359 Cutis Mati scat. 54.0 | 35° | 52 (CsHsBrO civAcetyl bromide {HgBr n-Propyl bromi sar [ao | 316 | oO RETae z arora SL | | RC | CHO BtipT sleoko “rT [i05 | ss CatLOy Methylal. : avs2| 4.5] 78 C.HBr0 trons Aestyl bromide (CH,):BO, Trimethy] borate so |r| 583 | GoRO Bip alcohol [75.7 [30.5] 6t SROs Baby senate goa [or] su Cxl.C10. Charosetic uid "H.O, m-Propyl formate 7 GuHCl Iaobutyl chloride 3.05 | 46.4] ane | SBPBr oBromoralone we a CoB 2-Methy2-butene 31.75 | 18.5| 635 | CHHbBr x Bromotaluone naan 31-75 18.5) 698 | Cay.ct Benayl chloride, five Jaa | 205 eae ieeseataes S| GSS | Gietuo Carvel hers |43_ | 210 Gail Benzene 4] oss ‘CoHCh I, 1, 2-Trichlorosthane Gall, 3-Cyclohexadiene 4| 680 | GHOWbplaeohol. | 773 [1S | OE cust gacaaes il aaa C.HC10, Chloral hydrate Calls Gyclohexane. 670 | Gila bonne Catt n-Hexane or CAEN Acetonitrile Cit Metyledaherane 209 | GHD RTaateL Se GH neptune 608 | cow Pt soi ma [we | wor tase 51 731 | 6.140 Isopropyl aleohol z_{ss_| 706 cick. jHBeCl 1-Bromo-2-shloroethane GHG Bgl aleabol 7a] 8) aT 7 CaHLCI0 a-Epichlorobydria, {rio.12 | 26.5] 1210 | CALCIO e-Bpichlorhydin, =]. 1207 CiHO Allyl alcoho. eo [27 | 300 (C:HLBr; 1, 1-Dibromonthane CxO: Propionie acid 118.95 | 81 | 40 | GO Biylaebol.. «8 H,0 2-Propyl aleohol Joe | | ait | ~~ ogrspes Batgace bromide GIHLO Tsopropst aloabol siz |7s | 3s Calty0 mButyl aloobol rio | ar | 449 | SeBOs Root asi a Guo Tnobuty! alobol jias.os | 40 | 44g. | Cot0: Propionic acid 50 ‘Cult Os Diethyl carbonate 118.55 | 67 | 1330 | CH#iw0 Tsobuty! aloobol. on ‘CiH,,0 Isoamy! aoohol, |t16.0 | 69 | 47 | Eetts© Keoamny! aleabol {Calti0s Isobutyl nectate 116.6 | 35.5 | 1527 | Calle Ethytbonsene, (Calti0; Paraldahy de 118.75 | 63__| 363 CHCl I ‘C:Ch Hexachlorosthane GO Fig atoobol [5 1 THEGLO, Diekloroaooti acid si [8034 C:HCL, Trichloroothylene pees] CHO Allg aeobar 30.05) TO) 306 30.05 | 07.5) 127 GaH.O n-Propy! aleohol sits | 69 | 410 105.4 | 62:7 | 132 CANO Tsoprepylaleohol v4 | 54 | 380 | CoB m Xylene iis.36 | 40 | 135320 INTERNATIONAL CRITICAL TABLES EGimttot the Cavawewrent) [EE [MR] | — womans the armored [P|] de ‘C;H,O; Methyl formate _ ‘C:HL.Br; cis-Dibromopropane THe Baby brome DG] 75 | IO | GO wPropylalookot [97.08] .0a]_aah CHO Ethy] ether. . (28.25 | 61.5 | 1842 ea sus-Dibromopropane ier fel eller Daas ae ce miei eens Ea Egat ae Cais ‘GyH,CIO Chloromethy! methyl ether ~~ GHC 2 Diobloropropane G:H.0 Btyl look, aa TH,W Cyelohexancl [155.6] 70 comer ~ {C,H.CLO 1, V-Dichloroieoprops' aleohol {11.0 Eithy? eleobol. 66. THO, Methyl oxalate. 102 | 18) SB 3H40 n-Propy! alcohol 81 Cia Cymene. tes | 53 | sas CaH4004 Bithy! nootate 63 CyeHye Camphene, isi at | 337 Cath n-Hexane. 63 CuHie Carvene 165.75 | 58 | 830 CiaHie @Finene Caw butyl aleohal co CiH,O Ethyl aloobol GAB ae Bromopropylene, CHAI 8-Lodopropytene. CHO, Dimethy! carbonate CAHsBr n-Propy! bromide CiHCI n-Propy! chloride. CHO Mothy! ethy! ketone. CuHHsO, Ethyl acetate (0. also p. 828) C.H1s04 Methy! propionate. CatisOs n-Propy! formate. ‘CARBr ter.-Buty! bromide CAH,CI Isobutyt chloride ‘Cath Ibutyl inde CAH Br Isoamy! bromidé (B. P, 120°) Cif, Benaene.. Cilh 1, 3:Cyclahexadione, Cie Cyolohexene. Cis 1, 5 Hexadiene, CH, Gyclohexane ‘CiHlu n-Hexane, GiB, Toluene GyHly« Methyleyolohexane. Collis n-Heptane WoRseReSRIIsSeaaAsRaTag Bgoruage SSABERSRER SERENE SE 6:80; Giyeal_ GHGO, Pheagl aootate, . ‘CyB. Diisobuty! carbonate ‘Chole Carvene (2-phase) HO Aligt ‘CAHLO n-Propy! aleohol ‘CHO n-Buty! aleahol ‘Clttu IsoDuty! alco ‘C.Hy0 Taoemy! aleobol CHO tert-Amyl aleobol ‘GH, Toluene. CHCl, 1, 2, &-Trichloropropane GaiiOy Taebutyrie uid C4H),0 Cyelohexanol nH, Pinene, CoH -Lodopropy GHO w-Propyl alechot. CHO Isobuty aloohol CAH.O Diethyl ketone CA40 Methyl propy! keton 100.9 | 5 Ba) os av | ais. 2a | 753, [iss] a7 | 18.3] ass 515 | 401 0.2 | 402 | 20° | 480 | 26 _| 1506. i) eae 38 | ee 55 | 460 ass GAGBr oBromotoluene....-.. CHC! Benzyl ehloride, Cave Carvene CxHLO Allyi loohot C.HoBr Taobatyl bromide or [aso [3 CAC! Isobuty elarde jer | u Calle0, Ethy! propionate | 03.2 | o7 CxH0s lobutyl formate. os | 65 Cale Benzene. | 76.75 | 32.2 Catt 1, 3-Cyelohexadiene | 75.0 | 25:5 Cally Gyetobesene 75.3 | 28.2 Cath, Cyctobexnne | 266 Cathy nttexane 05.5 | 8.3 Cis Tota | oot [en's THO Aeatone SHO, MetigT metae a CiH,CI Taobuty! chloride 8 CaN Diethyamine as | 43.5, Gita Teoningl Todide (B. P., 147.5%) Cal o-Xylene. CoH p-Xylene.- GH, Mesitylene Cufiie aPinene GiH,O n-Propyl aleohol....-0 <0... 88.2 70 7 567 (CUHsBr Teobuty] bromide - CBr =P GHD w- Props aleohol. CAMLO Tsoprops! sleohol ze] gal jesse ‘GxitsCT mob ropyT ehlonde CuHT n-Propyl iodide GH w- Props aloabol [wo] s ) ad C{L1,0 Teobuty! alcohol 6 [or | 438 ClHAO Diethyl ketone. 100.9 | 48.4 | 1021 CHO n-Propyl alcohol TLC TaabugT ahtoride yea] i | wr CoO, Behy! propionate, 934 [oe | 570 CaH1O, Methy! butyrate jo2 | a0.7] sr GH,O, Methy!isobutyrate, S05 | 36 | 568 CiHOs n-Propyl acetate. jot za | an CiH,Br Isoamy! bromide os tao | a6CONSTANT BOILING MIXTURES 321 ] foe) Le B-Constituent (the €-Arrangement) Ee | BeConstituent (the Arrangement) | PE» [Mote] te CHHLO v= Propyt aloohol— (Continued) Cais Iaobutyl aleohat 7H,GI Ghtorobenzene 96 0 | THGBr Tous! bromide, ons) 80) ae Call, Benzene 77 063 | CHCl Chlorobensene. 07.2 | 74 | 5 Call 1, 3-Cyelobenadione..-. 6. 085, | Call, Benzene. 7a.84| 10 | 666 Calle Gyclohexene.. 78. Gat | Calls 1, 3: Cyclohexadione, 70.35 | 12.7| 687 Cats Cyctohexane 74 675. | Calli Cyclohexene 15.6 | 606 GiB n-Hexane. os. 652 | Calis Cyclohexane 15,7 678 Cyl Paiuen 2, no | CéH\en-Hexane 1 | 655 CoH, mOvtane 95 rs_ | GH, Toluene. so | nz CaiL0 Teopropyt slo Cis a Pinene 6.5 | 74 TARO, Fahy sootate EB [50.8] 556 ‘CaO, Meths! propionate 77 | 36.5| 557. | CHO, BihsT propionste 3.5/8) oe CaGBr Isobuty! bromide 75.5 | 53° | 382 | CalluO, n-Propytncotate, 96.5 |6o_| 576 ‘CAALCI Tsobuty chloride. o3.8 |24 | 375 c CAHal Isobats foie. 81.8 for | 383 | Sai,0, Meal butyrate BB) oe iH Benzene... 71.92 | 39.3] 660 | CiptuOs n-Propyl acetate 12 | 38s H, 1, &-Cyelohexadione rot | 42.9] 052 | Ch Bensene [97.7] oot ith, Cyctohexene. m1 | 43.51 601 | Clr 1, 8. Cyciohexadions 40.5) 683 Cally Cyelohexane: 68.6 | 40.8) 672 | Cin, Gyctobexene 40.5 | 602 Cally n-Hexane 61 [20 | 649 | Catia Cyclohexane ao | ora ae 80.6 | 77 | 708 | Cqli,s0; Ethyl isobutyrate, 63 | 585 CHO, Dimethyl oxalate C2H,,0, Methyl isovslera oa | 586 SahgO Gyotaheranol. BRO | ST-D] 605 | Sethu wHoxane, 2 _| 650 CHHGCI p-Chlorotoluene. hs7.o | a1:7 | 1357 Cally Mesitylone 154.8 | 50.2) 1817 | Colle aPinene. we CoH «-Pinene, dat | 37.5 | 1814 | CH Menthene 56_| ust Cathy B-Pinene 71 [ss | ise ‘CxHLO, Dimethyl malonate CaELO Methyl ethyt Ketone THO Ceara za 173.5 [50 [1887 Cali, Benzen [reas wa HoT CoH ,0 Divthyl Ketone CuHiOs Butyric acid GHD ter sAagT aleohol [98:5 50.5] 38S ‘TCT Cheotataone ise) 25.5) 75 ‘CiHfO Methyl propy! ketone CoB Xylene 138.1 | 94.5) 108 | Siwy n-PropaT acetate or.35) 2) 108T Cally p-Xylene, 137.5 | 95.5] 165 | Cyt Methyleystobexane. w.. ft00°6_| 43.5 | 1110 Cally, Mesitylene sss | 7-5| 170 eaneos ena aaa on 151.0 | 30.51 181 | SaBF oBromoteluene. cee TA | S| SS C2HAO, Ioobntyrio acid Challe Camphee..cs.er-sss 2 ss-8 | 80 | 190 ‘TiiieBr Bromobensene TSS [3] —6F | Cutin Corvene, 168.9 | 65 _|_182 CyH.CI p-Chlorototuene s.2 | ss_| os casos Banal peoaeaars Calle Etuylbenzene.. 1a1.9 | 84.7] 154 ; CuBl, 2, 7-Dimethylostane, chur. | 06:4 | 15g, | $elteO to-Amyl aleohol.- [96.5 [or [37 CiHnO; Methyl butyrate CHO, Ethyl aor Toes By TiBe tet-Butgl bromide TS | wo) aoe | Lew tet-Amyt ateohel Ss CultyO tert-Buty! aleobol zsi2 [m6 | 50 ‘CiHi.03 r-Propyl acetate ClO; n Props! formate Gre AmpTatoobol 85 S| oe Ta Bensene [sae ClO, yt hetae CaARe n-Pints] bromide SH Aniaole 160.0 [18ST Ct, Be TeoamyT bromide ‘CW soba aleobal we) 8] 8] 6 REC Teer TiHisO roam aleabol ea] 70] ae ES Tiset sobutyl chlonide ____ | anty0, Paraldehyde is.5 |r| a2 Cer Bug ateoho nee] | | RT Cilia hm ateahol CaEet Foobut Fedde Gis Toa aestate ~ |S) 8-4 | 5 CHO Tooamngl aleohot NS] OF) 455 | CHO, Isobuty! propionate, |iso:5_| 85” | 508 GxHl.0- Taoam! formate 17.8 | 50.4 | 1321 Sa camel ail C.H05 Isobe aasate : 20+ leobuty) nesta 116.6 | 85.8] 1819 | Gor CHtorabensene ans |e) a 0 n Buty! aloohol GH, Styrene nas.5 | oo | 730 Gills Oyelobexane [798 | 1 | OT | Gi. Bthytbenzene 125.0 | 54 | m2 C1H0s m Buty! ootate 13.5 | 58 | 503. | Cathy o-Xytene. zs |e | 729 xi sO Ethyl isobutyrate hos.5 | 28 | 501 | Cae mylene 17.0 [ss | m7 Cait iOn Methyl ovalerate is [43 | 502 | catte p-Xvtene 126.8 | 56 | 723 CiH. Toluene 105.5 | 37_| 713. | GattwarPinene.. thao" | s5_|_ 738322 INTERNATIONAL CRITICAL TABLES tituent (the C-Arrangement) | P5&" | MO) S| BConstituent (the @-Arrangoment) | BP» | Mole] GuHCl 1, 8 STvichlorobenzene Gri Be p-Bromotoluene GAN Bayan. Bos [56] om | GMOoGrsol sh? 16s] isan CiHir Bromobenzene G:H,Cl Bonayl chloride Gi Cratohexanal [58 | SF] 4500 | THO, Teoampl butyrate 771 55 _| 1368 CxO Pinacone. ase | se | 406 CyHNO; Nitsotolue CH 02 »-Propyl 5 See a Cullis -Pinene, CWHLCIO p-Chlorophenol ‘C:H.0 Bonsyl aleokol a ETO TaeE Treo | CANO, Gee oeesrseen a | CoE Tolobenmne cate : Bows | et TAD Phew TT ELT | Cutt Carvenee 20! as 1 | 755 ck Nicene 2 lor_| i ties Cull sO Borneo. fao77s | 60 | 500 wseai76 351 30 [107 Callg0 Menthol bbor'e | 60_|s1o CHO Anite CaO Phovsl GF; Toba irate “Ele [= TB pBMOCTI ST [| TT | Cali etn olives | 62 Gat Carvene to0.0 | 49.5 | 1088 CH hthvaniine CieHie a-Pinene. a fusai7s | 25 "| 1957, | Goth Garvene enn eceapeses TAS 116 Ca hana CHE Toa esate Satin Carvene Tae TaS TOE | Gilt wc Xplene nose [1961 a1 8 Cit0, Hii avtonsetate E80; Toba propionate GH, Styrene, 145-2] 3 | 1153 | GiHy Bthylbenzene. [iss | 43_ | 1800, Gata Carvese SE fos | at | too E70: intact Catia enue. iss | 25 | 1154 Cisne Et, stein iat | s0_| tte Calli.0, Delis! oxalate TTB a Bromotoiene iis] ws] ws GsH;Br p-Bromotoluene. ligo.4 | 56:6 G0 Cylhexal hs wows SOS) aS Chor Tooumyl propionate tse? [a | oot C,H, «0, Isobuty! butyrate. 7 15s 26.5 | 603 Git Peevdooureve iss | ous) Tis Gis Masia seb. | 8) Ta CuBl0; Propyl Oren 78 |G : ; Sense cece” [36° | 748 | ao Garni : a8 ae Gat Carvene Soo has | Bs] A | chatso omnes Cuttuetienes cocci hao'a. [43° | 50 | Cathet & RepTansne ae CH Menthe fisr-s Loo _| 40 sO: Tay Formnte Gago Faatienpes 2 are a Effect of Pressure upon Azeotropic Mixtures ClO. Prop sae TBE, Ca SBT ny BOSE mam He [Mt BIT», wm Aig x GEO, Fissone SS Lae | i Bo | 70 | 1 | wo aria baase fos sed 3 v2 | veo | ara | as Call: Pinscone 200 ss | Moo | 53 | 0 GD Posto Wee Ta | 400 Lous | Calls Beal chloride THRO, B = Galo, Hil aca GUTH) soem ae, Tae [BS CHO Bonaldo THT Bimal corte aa) ae Cancer : ia” [3 | er Cat Carvene riz |is_| ss GHBr oBromotalone 130.5 39 CMe trounce iso | se [iseCONSTANT BOILING MIXTURES A = GAHLOH, B = C.H,0, Ethyl acotato (90 31 48) mm Hig [B.P, °C] M 9% A |p, mm Me [B. PO] M&A [1a] 21 oo | 65.4 | 43.6 5 | 410.6) 246 yo | 8 | 46.4 woo | “23.8| 28:2 900 | 76.5 | 48.5 wo | a73{ aa || 100 | ara | 50.4 200 | 38.4} 3.4 || 1200 | 85.0 | 2.2 soo | 47.8| 37.0 || 1350 | 887 | 53.9 +400 sa.9| a96 | 1500 | O18 500__| eos) 41s ‘Two-Component Mixtures with Maximum Boiling Point Panu Max | photo B-Cocaoent (andar amngwmant) | BLP, |S HN HO iF. HCI CIO, HBr, HI... HNO, 738 mm) CHO, Formic aed. ~~ HCI GLO Dimethyl ether. Tame cH, HO Acston [eas 165.5] 2107 ‘CHO; Formic acid CHO Diethyl ketone... CaflWO Methy! propyl THO Gyelohexandl 2081 CHO Benzaldehyde. 2080 CHO Benzy! alcohol, ..-.--s.. > 2066 GhHO sec-Oetyl aleobol-eeees. ss... (184.05 | 88 | 2068 GO Acetophenone. [poa.7 ) a) aie CyHW0s Phenyl acetate. vers. cssvcr ss. /)98.6 | 42.8 | 2171 GxHWO Methy! hexyl Ketone. 200000000 jnons | 97” | 2135 CyHluOs Isoamy! butyrate 192.0 | 80_| 2167 CLO m-Cresal_ GiFLO Acetophenone... 2133 Gio boesy 20 Ghd Beagle aD Pw CHS eTown ‘Bors [83 | os santa ras| er | doe Cito Keone @ ap 1iu0 Cagis % oa | mr Cio. a oo. | i C0 Ach i. oat a Cad bsp letals.| 18 Cc Diaroawtpns.-22-| 37 Ginn: & cautions itiornciione. | 38 Gion. : colic tortie, 8 Gaon a ich tached ° ‘Cio Alt ae! | GNC, chlorethyne a ‘Cao mop aol it coy Bihyane coe) cinoth | 38 om cy) 8 eam B. eatin 2 ‘Cini Pips browd. |B canoit 2 ‘tig ties catton. | 3 ‘CaHsBr Isobuty! bromide. | 32. catol ». GG snot] catton. 3 Henao & cao: = ite ei 3 caton 2 ‘ills Grdohe ‘t onto. 2 Cis Gyan. tt WH Slolpropyons occ) 8. CuO wrap seals cr CyH¢0 Allyl aleohol. | ‘it Bonsa. CHO Ally! aleohol ‘CH Cyclohoxene, SHO Ally aleohol. ‘Cali Cyclohexane. SHO Ally! alcohol Cd.» Honan CaO -Propy sleohal ‘CsE140 Diath! ketone CHO m-Propy! sleahol. 1H, Benzene. : CxO n-Propy! aleobol | ti, sOydoereing | comb seal | C\H.O n-Propyl aleohol..........) 10.% ite lawn | 0 ot eprops ts Boren, | oti epee 0!) hs Cyclteon | Ra BRtoSESER oR x : 2 Beeees 8 323, 08 mea 2251 2286 2250 28. mar 204 21 2s aa \ 2000 i 2340 ata ats 2a 2305aut INTERNATIO! Constituents (he C-Arrangement)] Mole] BP, “C]L No. HO Topropyl alohol 19.2 Calli Cyclobexane, .... sg |fo3 and E10 trt-Buts! aes. 175 C,H, Benzene, 55.0 |[ 97-20 a Hh 0 tert Butyi seals] 18.0 CaHia Cyclohexane, sr banal crm ‘The G-Arrangement Tian Mole e TOT No chon. . CAHBr Bethyl bromide A = C.H,0, Methyl formate Giliir Binytbromide, 28 TT ‘Call Ieopentane..- aro |; 16:95 | 27 CaHte0 Euhyt ether 72 CoH n-Pentane. | 48.2 } 20.4 ms GHW Phenetale.. Satan | ath [jo | ons NAL CRITICAL TABLE: LITERATURE (fore kay te the peratizats eed of whe) (2) Baty, Unive of Liverpool 2.) Harbandy, $4, 100: 194528.) Beckman, Heashe nel abel 98: 42117. (4) Blanoma, 26,2 417/10 (6) Baetner, 64 40: 322 17) (0) Car, Townsend and Badger, 43, 27° 1,25. (0) Curie and Artand, 84,178 1265; 24. (8) Carre Cervo, 84,177 0128) Carrey 50,8: 19: 90 () Fovand Barker £4,362 64517 (G7) acheter 6,208: 146; 18. (8) Halal and Grandad, 3, (2H) Jane and Gupta, 1862115 (4) taba, a8 1008 31. a, 24 5510.21) Lewy 32," (29) ayer Bugs, A o 108: 170,12, (0 C3) Noses nd Schwenshy £0, 48:720; 20. (08) Pasa, Duprey and Garin 7.987 (G9) Pasa and Gare, 2, 26:00; 18. (0) Peal and Garner, Power sod Marko, 68, 82381738. (9) Prato= (4) Rowan, Bacon and Whit, 1,86: 1505; 1 2) Rosa, Belted Danpay, 1, #622480; 14 46) Sanger and Reig, 65,47: @75: 12.8) Schule #, 86: 408, 1s) Thayer, 60,8232, 9 () ‘Phil nd 0. (4) Tyne 401, 110 13, (0) Wade ond ",82¢68; 02. (1) Barbaudy, 42,4: 1527. (62) Rhode and Bawa, 45,1880; 27, BOILING-POINT ELEVATIONS, NON-VOLATILE SOLUTES Brark Saxton Wn Jawes B. Aus, Haron G. Diernicn, Frorence Fexwiex, Anruvr Furtscuen, Gronoe L. Frean, ‘Exuiot®r J. Roserrs, Ropxer P. Suars, Myer Sovowox ap Haroun M. Seuruin conTENTS ». Introduction sees 3h ‘Two-component systems ‘The solvent isan elementary substance. 32h ‘The solvent isa chemical compound 225 ‘Thres-component aystems,. 37 Four- and five-componeat systems 9 INTRODUCTION This soetion includes systems in which one component only, the solvent, is appreciably volatile o lo which the necessary coeree ton has been made for the small vapor proasure of the solute or solutes. The data represent clevations of the belling point at temperatures at which the vapor pressure of the solvent is equal to the constant external pressure; whenever possible the elevations have been corrected touormsl atmospheric pressure. (Formethod, ®G30)) In the following tables: ‘Alp = boiling-point elevation for normal atmospheric pressure. Te = normal boiling point of solvent, absolute sale 4 = the mole number, oF the total number of ions and mole- cules per formula weight of aolute in a binary eystem, oF ‘the corresponding number in 4 system of more than to components, 12, = mole friction of solute. WN = formality of solute or the gram-formula-weights per kg of solvent, = snturated sotution, For binary eystems: fata y= tim, For aystems of more than two components: i ‘ale tn dlt ‘he Inteat heat of vaporntion ofthe pure alvet, per rar formlaeig ay be computed rom the slaten Le Ete ee ‘TWO-COMPONENT SYSTEMS The exon ean elementary subrance ‘he ystems are ened in crder ofthe stent flowing the Aarogement. "Uodbr each. solvent the aut flow the Sandan ep Cesrengeents pW ", Ti ia S122 in joules = 1.980050 in eas Bre SbBr (4) | ALB (24) eee eile cos | ate | ons oe] es | at on 82.0 0.15 ‘SaBr, (24) °. eecaiies stella: cela pe selec CBr (24) iy ota ASBr, (24) 0.05: B24 (27, 126) OY co | Bt | cotamey 0.05 32.5 CrEBrOs (*4) 0.1 22.6 Ol 82.6 mBromobensolc 0.2 0 0.15 32.8, acid 0.3 Bos